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Multiple Choice
1. Forty parts of copperas and lime per million parts of dye house effluent removes 50% of the
CO03 color. How much will be required to reduce the color to 5% if n=8.5?
a. 124.5 ppm b. 50 ppm
c. 110 ppm d. 99.6 ppm
2. Water contains organic color which is to be extracted with alum and lime. Ten parts of alum and lime
CO03
per million parts of water will reduce the color to 50% of the original color and 20 parts will
reduce the color to 7%. Estimate how much alum and lime as parts per million are required to
reduce the color to 1% of the original color.
a. 22.9 b. 18.5 c. 14.8 d. 15.8
5. A solvent-water mixture is to be distilled at 50°C. The vapor pressure of the solvent at this
CO03 temperature is 320 mmHg and that of water is 440 mmHg. The solvent is immiscible in water and
has a molecular weight of 150. The weight of the solvent in kg that will be carried over in the
distillate with 324 kg of water is
a. 1988 b. 1971 c. 1964 d. 1945
6. One hundred moles per hour of solution containing 50 moles of A, the rest B is subjected to simple
CO03 continuous distillation. The distillate contains 40 moles of A. If A is 5 times more volatile than B,
concentration of A in the distillate is_____.
a. 0.85 b. 0.80 c. 0.64 d. none of these
9. Suppose 1000 kJ of heat is needed for a mole of feed to become saturated liquid and 6000 kJ
CO03 is needed to evaporate a mole of it. Calculate the quality (q) of feed.
a. 0.17 b. 6.0 c. 1.17 d. 1.0
10. Using the data in no. 9 calculate the slope of the feed line.
CO03
a. -0.20 b. 1 c. 3.00 d. 6.88
11. Suppose the reflux ratio is 1.0. The slope of the operating line of rectifying section is
CO03 _______.
a. 0.67 b. 1.0 c. 2.0 d. 0.5
12. A binary mixture of 4 moles benzene and 8 moles toluene will boil at
CO03 a. 94°C b. 94°F c. 105°C d. 99°C
13. The percentage change in the boiling point of a 60 mole % benzene toluene solution when
CO03 the pressure is increased from 1 atm to 2 atm is
a. 27.8% increase c. 25.5% increase
b. 25.5% decrease d. None of these
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ENGR. CONRADO P. MONTEROLA
XXX JR. ENGR. JESUNINO AQUINO XXX
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14.The distribution coefficient of n-hexane at 10 atm and 200°C is_____.
CO03 a. 2.6 b. 1.4 c. 0.9 d. none of these
15. A liquid mixture containing 50% benzene and 50% toluene by weight is to be fed to a
fractionating column at a rate of 5000 kg/hr. the feed rate at kg mol/hr is _______.
CO03
A. 29.95 B. 58.80 C. 59.22 D. 28.846
16. The approximate minimum number of stages for a binary system with relative volatility of 5,
CO03 fractionally distilled to yield a composition of 0.90 in the distillate and 0.10 in the bottom is
A. 1.53 B. 2.73 C. 3.45 D. 4.31
LO01 21. Which of the following operations does not involve leaching?
CO01 a. Dissolving gold from ores.
b. Dissolving pharmaceutical products from barks.
c. Dissolving sugar from sugar beets.
d. Removing nicotine from its water solution by kerosene.
24. All of the following are assumptions in ideal leaching except _____.
CO01 a. The inert solid is not dissolved in the solvent.
b. Sufficient contact time is provided so that all solute is dissolved in the solvent.
c. The concentration of solution in the final stage is equal to the concentration of solution in the initial
stage.
d. The solute is infinitely soluble in solvent.
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ENGR. CONRADO P. MONTEROLA
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25. Drying of leaves, barks and roots is done prior to leaching in order to ______.
CO01 a. Reduce the moisture content.
b. Rapture the cell wall.
c. Converts the natural product to its active form.
d. Increases the area of contact.
27. The leaching equipment generally used for sugar beets is _________.
a. thickener
CO01 b. Fixed bed leaching
c. Hilderbrandt extractor
d. Bollman extractor
29. This leaching equipment is generally associated with a slowly rotating rake at the bottom of
container.
CO01 a. thickener
b. Fixed bed leaching
c. Hilderbrandt extractor
d. Bollman extractor
31. In an extraction process the greater the weights of solute in the raffinate relative to that in the
CO01 extract then the distribution coefficient is relatively _________.
a. high b. low c. not affected d. unpredictable
33. When the solvent dissolves very little of the solute then
a. solvent of low latent heat should be used.
CO01 b. solvent of low freezing point should be used.
c. large quantity of solvent will be required.
d. very small quantity of solute is required.
35. Small solute molecule in liquid phase diffuses thru a membrane because of concentration
CO01 gradient to another liquid phase.
a. Dialysis b. gas permeation c. ultrafiltration d. reverse osmosis
36. A medical equipment used to “oxygenate” the blood so that the heart can be stop from
CO01 beating.
a. Hemodialysis c. heart and lung machine
b. Stethoscope d. ECG
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ENGR. CONRADO P. MONTEROLA
XXX JR. ENGR. JESUNINO AQUINO XXX
FORM OVPAA-013A
THIS FORM IS AVAILABLE AT THE OFFICE OF THE VICE PRESIDENT FOR ACADEMIC AFFAIRS
37. Membrane separation process used to purify water from oceans and seas.
CO01
a. Dialysis b. reverse osmosis c. ultrafiltration d. gas permeation
2. Liquid-liquid extraction. An inlet water solution of 100 kg/h containing 0.010 wt fraction nicotine
in water is stripped with pure kerosene stream in a countercurrent multistage tower. The water and
kerosene are essentially immiscible in each other. It is desired to reduce the concentration of the
CO03
exit water to 0.0010 wt fraction nicotine.
a. Determine the minimum flow rate of kerosene. 10 pts
b. Using 1.5 times the minimum flow rate determine the theoretical number of stages needed.
The equilibrium data are as follows with x the weight fraction of nicotine in the water solution
and y in the kerosene. 10 pts
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ENGR. CONRADO P. MONTEROLA
XXX JR. ENGR. JESUNINO AQUINO XXX
FORM OVPAA-013A
THIS FORM IS AVAILABLE AT THE OFFICE OF THE VICE PRESIDENT FOR ACADEMIC AFFAIRS
4. Adsorption/Ion exchange. An ion-exchange column containing 99.3 g of amberlite ion-
exchange resin was used to remove Cu 2+ from a solution where Co = 0.18 M CuSO4. The
tower height = 30.5 cm and the diameter = 2.59 cm. The flow rate was 1.37 ml solutions/s to the
CO03 tower. The breakthrough data are shown below.
5. Membrane Separation. A dialysis machine will be designed to remove urea from the blood
of a kidney patient. The concentration of urea in the blood is initially 30.0 mg/100 cc and after
undergoing dialysis it should be 0.0 mg/100 cc. The membrane thickness is 1.59 X 10 -5 m,
CO03
K’ = 0.75, DAB = 3.5 x 10-11 m2/s inside the membrane, the mass transfer coefficient in the
blood is 1.25 X 10-5 m/s and 3.33 x 10-5 m/s in the dialysate.
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c. Calculate the total area of the membrane of the dialysis machine if it’s to remove 20.00 g
urea /h. 10 pts
6. Filtration. Using the Hagen-Poiseulle equation in the handbook, derive the Poiseulle constants,
CO03
Kp and B. 10 pts
7. Using molecular sieves, water vapor was removed from nitrogen gas in a packed bed at 28.3°C. The column
height was 0.268 m, with the bulk density of the solid bed being equal to 712.8 kg/m 3. The initial
water concentration in the solid was 0.01 kg water/kg solid and the mass velocity of the nitrogen
gas was 4052 kg/m2.h. The initial water concentration in the gas was co = 926 X 10-6 kg water/kg
CO02
nitrogen. The breakthrough data are as follows.
A value of c/c0 = 0.01 is desired at the break point. Calculate the following:
a. Break point time 5 pts
b. Fraction of total capacity used up to break point 5 pts
c. Length of unused bed 5 pts
d. Saturation loading capacity of the solid 5 pts
e. For a proposed column length Ht = 1.00 m, calculate the break point time. 5 pts
8. A saturated liquid feed of 200 mol/h at the boiling point containing 42 mol % heptane and 58 %
ethyl benzene is to be fractionated at 101.32 kPa abs to give a distillate containing 97 mol %
heptane and a bottoms containing 1.1 mol % heptane. Equilibrium data are given below at 101.32
CO04
kPa abs pressure for the mole fraction n-heptane xH and yH .
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d.
1. Calculate the boiling point of water in Tagaytay City (2000 ft in altitude). Assume
LO06 ambient temperature to be 20°C and the average molar mass of air to be 29 g/mole. The
enthalpy of vaporization of water is 40.7 kJ/mole.
2. The blade of an ice skate is ground to a knife edge on each side of the skate.
A. If the width of the knife edge is 0.001 in and the length of the skate in contact with the
LO07
ice is 3 in, calculate the pressure exerted on the ice by Mr. Michael Martinez if he weighs
100 lb (Payat sya d B?).
B. What is the melting point of ice under this pressure?
∆H fus = 1.4363 kcal/mol; ρ ice = 0.92 g/ml ρ water = 1.0 g/ml
3. The vapor pressure of solid CO2 is 76.7 mm Hg at -103C and its normal sublimation point is
-78.5C. What is the heat of sublimation of CO2?
4. At 90°C, the vapor pressure of pure methylbenzene is 53.3 kPa and that of pure 1,2-
dimethylbenzene is 20 kPa. What is the composition of a liquid mixture that boils at 90°C
when the pressure is 0.5 atm? What is the composition of the vapor produced?
5. The partial molar volumes of two liquids A and B in a mixture in which the mole fraction of
LO20 A is 0.3713 are 188.2 cm3 mol−1 and 176.14 cm3 mol−1, respectively. The molar masses of
the A and B are 241.1 g mol−1 and 198.2 g mol−1. What is the volume of a solution of mass
1.000 kg?
6. The solubility product of AgCl at 25°C is 1.82 X 10-10. Assuming Debye-Huckle Limiting
CO6
Law to apply, calculate
A. Solubility at pure water.
B. Solubility at 0.01 M NaF.
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ENGR. CONRADO P. MONTEROLA
XXX JR. ENGR. JESUNINO AQUINO XXX
FORM OVPAA-013A
THIS FORM IS AVAILABLE AT THE OFFICE OF THE VICE PRESIDENT FOR ACADEMIC AFFAIRS
7. The molar conductivity of chloracetic acid at 25°C is 53.1 S cm2mole-1 at
CO6
625 X 10-4 M. If the limiting molar conductivity is 362 S cm2 mole-1, calculate the
dissociation constant of chloracetic acid.
8. Consider the lead acid battery with 1 m H2SO4 for the temperature range 0°C to 60°C, the
CO6 & CO4
cell potential is expressed as:
9. The limiting molar conductivity for NaCl, HCl and Na2CO3 are 126.39 S cm2mol-1, 425.96
CO6
S cm2mol-1 and 238.76 S cm2mol-1 respectively. Calculate the limiting molar conductivity
of carbonic acid (H2CO3).
10. An aqueous solution of gold nitrate, Au(NO3)3, is electrolyzed with a current of 0.555 ampere
CO6 until 1.32 g of Au has been deposited on the cathode. If the atomic weight of Au is 197,
determine the duration of the electrolysis in minutes.
11. A 1.00 m solution of phosphoric acid (H3PO4) freezes at -2.0088°C. What is its percent
CO6
apparent degree of dissociation?
12. The water flea Daphnia performs a constant number of heartbeats and then dies. The flea
CO6 lives twice as long at 15°C as at 25°C. Calculate the activation energy for the reaction that
controls the rate of its heartbeat.
13. Derive the equation for concentrations of reactant A, [A] and product C, [C] against time t
CO6 in a consecutive reaction below:
𝒌𝟏 𝒌𝟐
A→B→C
14. Consider the reaction H2 + I2 → 2HI
CO6 Show that the mechanism
I2 2I (fast, in equilibrium)
𝒌𝟓
H2I + I → 2HI (slow)
Leads to the result that the rate equation for the overall reaction is
v = k[H2][I2].
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ENGR. CONRADO P. MONTEROLA
XXX JR. ENGR. JESUNINO AQUINO XXX
FORM OVPAA-013A
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CO1 1. (15 pts) For the given reaction at 25°C, CaCO3(s) CaO(s) +CO2(g) determine
(a) the standard Gibbs energy of reaction, ΔG°
(b) (b) the equilibrium constant, K
(c) the pressure of CO2 in equilibrium with a mixture of CaCO3 and CaO at 298K.
Note: at SATP, ΔfG° (CO2,g) = –94.3 kcal/mol,
ΔfG° (CaCO3,g) = –269.8 kcal/mol ,
ΔfG° (CaO,s) = –144.4 kcal/mol
2. (10 pts) A container is divided into two equal compartments. One contains 3.00 mol of Ar at 300K. The other
CO1 contains 2.00 mol of N2 at 300K. Assuming ideal gas behavior:
(a) Calculate the ∆G of mixing when the partition is removed.
(b) Calculate the ∆S of mixing.
CO1
3. (10 pts) Deep-sea divers can suffer a condition known as the “bends” if they breathe ordinary air at a pressure equal
to the ambient hydrostatic pressure, because nitrogen gas dissolves in blood at high pressure and is released as
bubbles in the bloodstream when the diver decompresses. Calculate the amount of nitrogen dissolved in 5.000 L of
blood (roughly the volume in an adult human) at equilibrium with air (78 mol% nitrogen) at a depth of 200 m,
assuming that Henry’s law constant for nitrogen in blood is equal to 7.56 x 104 atm, the value for nitrogen in water
at 20.0°C.
CO2 4. (15 pts) At –47°C the vapor pressure of ethyl bromide is 10 mmHg, while that of ethyl chloride is 40 mmHg. Assume
that the mixture is ideal. If there is only a trace of liquid present and the mole fraction of ethyl chloride in the vapor
is 0.80,
(a) what is the total pressure and the mole fraction of ethyl chloride in the liquid?
(b) If there are 5 mol of liquid and 3 mol of vapor present at the same pressure as in (a), what is the overall
composition of the system?
CO3 5. (10 pts) Determine the molecular weight of the solute if the osmotic pressure of a solution containing 10.0 g solute per
liter of solution is 10.0 torr at 27°C.
6. (15 pts) Determine the solubility of PbC2O4 (Ksp = 8.5 x 10–9) (considering ionic interactions) in
CO3
(a) 0.0015 m K2C2O4 solution
(b) a solution which is 0.0010 m in Ca(NO3)2 and 0.0020 m in NaNO3
CO3 7. (10 pts) Consider a 0.010m weak monoprotic acid solution in water with pKa = 5.40. Considering ionic interactions,
determine
(a) the pH of the solution
(b) the boiling point of the solution
CO4 8. (10 pts) Consider the cell: Hg(l)| Hg2SO4(s)| FeSO4 (aq, a = 0.01)| Fe(s)
(a) Write the anode half and cathode half reactions.
(b) Write the overall cell reaction.
(c) Calculate the cell potential, E, the equilibrium constant for the cell reaction, K, and the standard Gibbs energy
change, ΔG° at 25°C.
9. (10 pts) The temperature-composition diagram for the Ca/Si binary system is shown below. If a melt at 20 mole
CO2
percent silicon composition originally at 1500°C is cooled to 1000°C, what phases (and phase composition) would be
at equilibrium? Estimate the relative amounts of each phase.
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ENGR. CONRADO P. MONTEROLA
XXX JR. ENGR. JESUNINO AQUINO XXX
FORM OVPAA-013A
THIS FORM IS AVAILABLE AT THE OFFICE OF THE VICE PRESIDENT FOR ACADEMIC AFFAIRS
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ENGR. CONRADO P. MONTEROLA
XXX JR. ENGR. JESUNINO AQUINO XXX
FORM OVPAA-013A
THIS FORM IS AVAILABLE AT THE OFFICE OF THE VICE PRESIDENT FOR ACADEMIC AFFAIRS