Documente Academic
Documente Profesional
Documente Cultură
Deepak Singhal
Asst. Professor
Dept. of Mech. Engg.
KIIT University Bhubaneswar Orissa
E-mail: dsinghal.iiit@gmail.com
IIIT-JABALPUR 1
ME-304
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States of Matter
Matter comes in a variety of states: solid, liquid, gas, and
plasma.
• The molecules of solid are locked in a rigid structure and can
only vibrate. (Add thermal energy and the vibrations increase.)
Some solids are crystalline, like table salt, in which the atoms
are arranged in a repeating pattern. Some solids are
amorphous, like glass, in which the atoms have no orderly
arrangement. Either way, a solid has definite volume and
shape.
• A liquid is virtually incompressible and has definite volume but
no definite shape. (If you pour a liter of juice into several
glasses, the shape of the juice has changed but the total
volume hasn’t.)
• A gas is easily compressed. It has neither definite shape nor
definite volume. (If a container of CO2 is opened, it will diffuse
throughout the room.)
Fluids
The term fluid refers to gases and liquids. Gases
and liquids have more in common with each other
than they do with solids, since gases and liquids
both have atoms/molecules that are free to move
around. They are not locked in place as they are in
a solid. The hotter the fluid, the faster its molecules
move on average, and the more space the fluid will
occupy (if its container allows for expansion.) Also,
unlike solids, fluids can flow.
Definition of a Fluid
“a fluid, such as water or air, deforms continuously
when acted on by shearing stresses of any magnitude.”
Water
Oil
Air
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Distinction between solids and
fluids
According to our experience: A solid is “hard” and
not easily deformed. A fluid is “soft” and deforms
easily
A fluid is defined as a substance that deforms
continuously when acted on by a shearing stress of
any magnitude
Solid may regain partly or fully its original shape when
the tangential stress is removed
A fluid can never regain its original shape, once it has
been distorded by the shear stress
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Introduction
Any characteristic of a system is called a property.
Familiar: pressure P, temperature T, volume V, and mass m.
Less familiar: viscosity, thermal conductivity, modulus of elasticity,
thermal expansion coefficient, vapor pressure, surface tension.
Intensive properties are independent of the mass of the
system. Examples: temperature, pressure, and density.
Extensive properties are those whose value depends on
the size of the system. Examples: Total mass, total
volume, and total momentum.
Extensive properties per unit mass are called specific
properties. Examples include specific volume v = V/m
and specific total energy e=E/m.
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Continuum
Atoms are widely spaced in the gas
phase.
However, we can disregard the
atomic nature of a substance.
View it as a continuous,
homogeneous matter with no
holes, that is, a continuum.
This allows us to treat properties as
smoothly varying quantities.
Continuum is valid as long as size
of the system is large in
comparison to distance between
molecules.
Density and Specific Gravity
Density is defined as the mass per unit volume ρ = m/V.
Density has units of kg/m3
Specific volume is defined as v = 1/ρ = V/m.
For a gas, density depends on temperature and pressure.
Specific gravity, or relative density is defined as the ratio
of the density of a substance to the density of some standard
substance at a specified temperature (usually water at 4°C),
i.e., SG=ρ/ρH20. SG is a dimensionless quantity.
The specific weight is defined as the weight per unit
volume, i.e., γs = ρg where g is the gravitational
acceleration. γs has units of N/m3.
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Vapor Pressure and Cavitation
Vapor Pressure Pv is defined as
the pressure exerted by its vapor
in phase equilibrium with its
liquid at a given temperature
If P drops below Pv, liquid is
locally vaporized, creating
cavities of vapor.
Vapor cavities collapse when
local P rises above Pv.
Collapse of cavities is a violent
process which can damage
machinery.
Cavitation is noisy, and can
cause structural vibrations.
Energy and Specific Heats
Total energy E is comprised of numerous forms: thermal,
mechanical, kinetic, potential, electrical, magnetic,
chemical, and nuclear.
Units of energy are joule (J) or British thermal unit (BTU).
Microscopic energy
Internal energy u is for a non-flowing fluid and is due to molecular
activity.
Enthalpy h=u+Pv is for a flowing fluid and includes flow energy
(Pv).
Macroscopic energy
Kinetic energy ke=V2/2
Potential energy pe=gz
In the absence of electrical, magnetic, chemical, and
nuclear energy, the total energy is eflowing=h+V2/2+gz.
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Viscosity
Viscosity is a property
that represents the
internal resistance of a
fluid to motion.
The force a flowing
fluid exerts on a body
in the flow direction is
called the drag force,
and the magnitude of
this force depends, in
part, on viscosity.
Viscosity
To obtain a relation for viscosity,
consider a fluid layer between two
very large parallel plates separated
by a distance ℓ
Definition of shear stress is τ =
F/A.
Using the no-slip condition,
u(0) = 0 and u(ℓ) = V, the velocity
profile and gradient are u(y)= Vy/ℓ
and du/dy=V/ℓ
Shear stress for Newtonian fluid: τ
= µdu/dy
µ is the dynamic viscosity and
has units of kg/m·s, Pa·s, or poise.
Newton's law of viscosity
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Types of fluid
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Effect of Temp on the fluid Viscosity
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Surface Tension
Liquid droplets behave like small
spherical balloons filled with
liquid, and the surface of the
liquid acts like a stretched elastic
membrane under tension.
The pulling force that causes this
is
due to the attractive forces
between molecules
called surface tension σs.
Attractive force on surface
molecule is not symmetric.
Repulsive forces from interior
molecules causes the liquid to
minimize its surface area and
attain a spherical shape.
Surface Tension
Ever wonder why water beads up on a car, or how some
insects can walk on water, or how bubbles hold themselves
together? The answer is surface tension: Because of
cohesion between its molecules, a substance
tends to contract to the smallest area possible. Water on a
waxed surface, for example, forms round beads because in this
shape, more weak bounds can be formed between molecules
than if they were arranged in one flat layer. Cohesive forces are
greater in mercury than in water, so it forms a more spherical
shape. Cohesive forces are weaker in alcohol than in water, so it
forms a more flattened shape.
continued
Cohesion & Adhesion (cont.)
The meniscus in a graduated cylinder of water is due to the adhesion between
water molecules the sides of the tube. The adhesion is greater than the cohesion
between the water molecules.
The reverse is true about a column of mercury: Mercury atoms are attracted to
each other more strongly than they are attracted to the sides of the tube. This
causes a sort of “reverse meniscus.”
H2O Hg
Pressure
• Pressure is defined as a normal force exerted by a fluid
per unit area.
• Units of pressure are N/m2, which is called a pascal
(Pa).
• Since the unit Pa is too small for pressures
encountered in practice, kilopascal (1 kPa = 103 Pa) and
megapascal (1 MPa = 106 Pa) are commonly used.
• Other units include bar, atm, kgf/cm2, lbf/in2=psi.
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Pressure in a Fluid
The pressure is just the weight of all the fluid above
you
Atmospheric pressure is just the weight of all the air
above on area on the surface of the earth
In a swimming pool the pressure on your body surface
is just the weight of the water above you (plus the air
pressure above the water)
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Absolute, gage, and vacuum
pressures
Actual pressure at a give point is called the absolute
pressure.
Most pressure-measuring devices are calibrated to
read zero in the atmosphere, and therefore indicate
gage pressure, Pgage=Pabs - Patm.
Pressure below atmospheric pressure are called
vacuum pressure, Pvac=Patm - Pabs.
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Absolute, gage, and vacuum
pressures
Pressure at a Point
Pressure at any point in a fluid is the same in all
directions.
Pressure has a magnitude, but not a specific direction,
and thus it is a scalar quantity.
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Direction of fluid pressure on
boundaries
Heat exchanger
Dam
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Variation of Pressure with Depth
In the presence of a gravitational
field, pressure increases with
depth because more fluid rests on
deeper layers.
To obtain a relation for the
variation of pressure with depth,
consider rectangular element
Force balance in z-direction gives
∑F z = maz = 0
P2 ∆x − P1∆x − ρ g ∆x∆z = 0
Dividing by ∆x and rearranging gives
∆P = P2 − P1 = ρ g ∆z = γ s ∆z
Variation of Pressure with Depth
Pressure in a fluid at rest is independent of the
shape of the container.
Pressure is the same at all points on a horizontal
plane in a given fluid.
Scuba Diving and Hydrostatic
Pressure
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Compressible fluid
Gases are compressible i.e. their density varies with
temperature and pressure ρ =P M /RT
For small elevation changes (as in engineering
applications, tanks, pipes etc) we can neglect the effect
of elevation on pressure
In the general case start from:
dP
= − ρg
dz
for T = T o = const :
g M ( z 2 − z1 )
P2 = P1 exp −
RT o
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Pascal’s Law
Pressure applied to a
confined fluid increases
the pressure throughout by
the same amount.
In picture, pistons are at
same height:
F1 F2 F2 A2
P1 = P2 → = → =
A1 A2 F1 A1
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Fluid Statics
• Fluid Statics deals with problems associated with
fluids at rest.
• In fluid statics, there is no relative motion between
adjacent fluid layers.
• Therefore, there is no shear stress in the fluid
trying to deform it.
• The only stress in fluid statics is normal stress
– Normal stress is due to pressure
– Variation of pressure is due only to the weight of the
fluid → fluid statics is only relevant in presence of
gravity fields.
• Applications: Floating or submerged bodies, water
dams and gates, liquid storage tanks, etc.
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Motivation?
What are the pressure forces behind the Hoover Dam?
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Hydrostatic Forces on Plane
Surfaces
On a plane surface, the
hydrostatic forces form a
system of parallel forces
For many applications,
magnitude and location of
application, which is called
center of pressure, must
be determined.
Atmospheric pressure Patm
can be neglected when it
acts on both sides of the
surface.
First moment of an area and the
centroid
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Second moment of area
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Resultant Force
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Liquid subjected to Horizontal acceleration
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Vertical acceleration
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Buoyancy and Stability
Buoyancy is due to the fluid displaced by a body.
FB=ρfgV.
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Buoyancy and Stability
Buoyancy force FB is equal
only to the displaced
volume ρfgVdisplaced.
Three scenarios possible
1. ρbody<ρfluid: Floating body
2. ρbody=ρfluid: Neutrally buoyant
3. ρbody>ρfluid: Sinking body
Example: Submarine Buoyancy and Ballast
Normal surface trim SSN 711 nose down after accident
which damaged fore ballast tanks
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Stability of Immersed Bodies