Documente Academic
Documente Profesional
Documente Cultură
EQUIPMENT.............................................................................................................................................................................................................. 6
GENERAL PROCESSING
Start up....................................................................................................................................................................................................................... 8
Mold filling, packing and screw rotation............................................................................................................................. 8
Estimating molding cycle time........................................................................................................................................................ 9
Drying of the material................................................................................................................................................................................ 10
Coloring .................................................................................................................................................................................................................... 10
Regrinding ............................................................................................................................................................................................................. 11
Shrinkage.................................................................................................................................................................................................................. 11
MOLD DESIGN
Mold steel selection..................................................................................................................................................................................... 12
Mold surfaces...................................................................................................................................................................................................... 12
Mold plating and coating...................................................................................................................................................................... 13
Mold venting........................................................................................................................................................................................................ 13
Sprue, runner and gate design....................................................................................................................................................... 14
Ejection....................................................................................................................................................................................................................... 19
Undercut design guidelines................................................................................................................................................................ 19
Mold temperature control.................................................................................................................................................................... 19
MULTI-MATERIAL MOLDING
Overmolding........................................................................................................................................................................................................ 23
Insert-molding.................................................................................................................................................................................................... 23
Two-shot molding......................................................................................................................................................................................... 23
Co-injection molding................................................................................................................................................................................. 23
TROUBLESHOOTING.................................................................................................................................................................................... 24
INTRODUCTION - 5
Safety guidelines
ExxonMobil Chemical is committed to continually improving the
safety of operations so they are free from injury or incident.
Remember, the typical processing operation uses powerful and
potentially dangerous electrical, hydraulic and mechanical
systems. Material temperatures can be as high as 290 °C (550
°F). Hot and cold water and hot machine oil can be
encountered. Industry best practices strongly recommend the
following when processing TPVs:
Figure 1
Exterior view of a typical thermoplastic injection molding machine
control
drive injection mold clamping
system unit unit
Figure 2
Cross section of a typical thermoplastic injection molding machine
nonreturn
motor and gears valve
for screw rotation
EQUIPMENT Figure 3
Nozzle types
Screw design
In most cases, a generalpurpose polyolefinic screw with a Full internal taper
compression ratio of 2:1 to 2.5:1 and a length to diameter ratio
between 16:1 and 22:1 is sufficient. A low shear screw, such as
those used in PVC processing, is not recommended. Unlike
many thermoplastic materials, Santoprene TPVs demonstrate
better flow characteristics during the injection filling phase
when subjected to high levels of shear during fill.
Barrel capacity
Avoid underutilization of the barrel wherever possible, since it Nylon reverse taper
can lead to long residence times. Small shots run on a large
capacity barrel complicate processing. The best practice for any
injection molding is to utilize 20 to 80% of the barrel capacity
for each shot. This typically translates to 1.3 to 5 shots in the
barrel.
Nozzle
Most common TPVs do not typically drool or degrade at normal
processing temperatures and therefore do not require a special
nozzle. A conventional generalpurpose nozzle is commonly
suited to most applications (see Figure 3).
The nozzle orifice is usually 10 to 15% smaller than the “O”
diameter of the sprue bushing. Hot runner manufacturers
recommend that hot sprues should run at the same
temperature as the nozzle setting or slightly higher.
GENERAL PROCESSING 11. Set the packhold pressure to 50% of the injection pressure
setting.
12. Set the packhold time to 2 to 3 seconds to ensure that the
Start-up remaining 5% of the part is filled and that there is enough
additional material to compensate for shrinkage.
General conditions 13. Finetune the packhold time by running a series of test
Most of our TPVs process with mediumfast to fast injection molding cycles. Weigh each part after each test cycle.
rates. Fill times are typically between 0.5 and 2.0 seconds. The Continue to increase the packhold time as required until the
melt temperatures for most materials are approximately 205 °C part weight does not increase. This ensures that gate
(400 °F); injection pressures are moderate. Starting conditions freezeoff has occurred and that parts have a repeatable,
can be found in the Product Data Sheet for each grade and/or correct weight. Watch out for overpacking, usually indicated
the Quick Processing Reference. These contain detailed by a series of rings around a gate or evidenced by a
information on processing setup and unique features. Both “punchedin” gate.
documents are available on www.santoprene.com
The following guidelines can help to estimate and minimize (density x specific heat) ((kg/m ) x (J/kg °C))
3
s
molding cycle time. These guidelines assume the use of
recommended temperatures and processing procedures, and a Source: How to make injection molds:
Hanser-ISBN: 3-466-16305-0 Chapter 8.1 / pg 272
mold that has a fixed number of cavities plus adequate knock
out area to permit easy part removal.
Cooling time can be estimated by use of the Moldflow Plastics
Molding cycle
Insight (MPI™) or Moldflow Plastics Advisers (MPA™) programs
Santoprene TPVs from ExxonMobil Chemical allow the use of
from Moldflow Pty Ltd. Also, the equation above can be iterated
automatic molding cycles, which eliminates costly manual part
manually.
removal and reduces the overall molding cycle time by
minimizing cooling time. Typically, molded parts form a solid
Cooling complex and thicker parts
skin and become semirigid, even while their interiors are still
If a part has deep undercuts that measure more than 1.6 mm
molten. This allows parts to be demolded quickly with minimal
(0.0625”), increase the cooling time to ensure demolding
deformation problems. Obviously, reducing molding time
without deforming the part. If a mold has untapered cores as
means more costeffective processing.
long as 100 mm (4”), decrease the cooling time ; otherwise, the
part may shrink tightly on the core, which could cause defor
Oversized runners can be the biggest time wasters in a system.
mation when the core is pulled.
Mold fill usually takes 0.5 to 2.0 seconds, depending on part
volume, runnergate style and size, cavity location and injection
pressure. Pack (hold time) is usually 2 to 3 times the mold fill
times, depending on gate size. If larger gates are used, expect a
longer molding cycle time. The speed of an injection molding
machine and the part geometry determine the times of other
molding cycle phases such as mold close, mold open, ejection
and part removal.
10 - GENERAL PROCESSING
Drying of the material 8. A best practice would be to measure and confirm the
moisture level with a moisture analyzer. For best results, the
moisture level should not exceed 0.08%.
Most of our general purpose and injection molding grades are 9. After the dryer is empty, power it down and again clean the
hygroscopic. More details are available from the Product Data hopper.
Sheet for each grade and/or the Quick Processing Reference.
This includes detailed information on processing setup and
unique features. Both documents are available on
www.santoprene.com
Coloring
Effective moisture control ensures high quality parts that have
an appealing surface appearance. It is recommended for these
Parts molded with Santoprene TPV from ExxonMobil Chemical
grades that the moisture be reduced to 0.08% or less before
can be produced on conventional molding equipment in any
processing. Specialized grades may have different drying
color to match or com plement a finished product. Simply blend
requirements. These will be spelled out on the Quick Processing
neutral Santoprene TPV pellets with the appropriate colorant to
Reference for that grade. With any TPV, moisture impacts
achieve nearly any color or hue desired. Precolored TPV pellets
processing, physical properties, product performance,
are available from several sources.
appearance, or a combination of these properties. Specifically,
moisture can cause poor melt quality, splay, voids, porosity, Solid color concentrates
rough surfaces, uneven appearance and/or silver streaking. For Solid color concentrates are a versatile, pelletized form of a
some of the specialty bonding grades, drying is essential to colorant. These are widely used in the plastics industry due to
prevent material degradation. their stability, compatibility and dispersibility in almost any resin.
Color concentrates commonly consist of a pigment
Recommended best practices for drying
compounded with a carrier resin such as polypropylene or
polyethylene. Additionally these are well known for allowing
1. If possible, tumbleblend colorants with the thermoplastic
good control of color intensity in daytoday consistency. They
pellets before drying in a desiccant/dehumidified hopper
are also dustfree and easily used. Color concentrates can be
dryer or vacuum oven. If colorants or additives are metered
either tumbleblended with the base resin or accurately metered
at the hopper, predry colorants separately, unless not
into a batch prior to processing. Color changes normally are
recommended by the colorant supplier.
quick while minimizing cleanup.
2. Open the drying hopper and make sure it is free of material.
Clean the hopper as needed. Be sure to follow standard
The addition of any carrier resin can affect material properties,
safety guidelines. Close the hopper and power it up.
including hardness, and it may slightly affect the material
3. Set the temperature control to ensure that air into the
processing and can affect part shrinkage. Some pigments also
hopper inlet is at the set point. We recommend using 80° C
affect these properties. Carrierless color concentrates are also
(180 ° F) for most general purpose and injection molding
available to minimize property and processing effect.
grades. Some specialty bonding grades have different drying
require ments. Please refer to the Product Data Sheet for
Please follow the individual manufacture’s recommendations
each grade or Quick Processing Reference for detailed
for loading. Typically this is about 1 to 5 weight percent,
recommendations.
depending on the application and the final color required.
4. Once the dryer temperature is steady, check the dewpoint
indicator to ensure that a dew point temperature of 1 8 °C (0
Colorant carriers
°F) or lower exists. Fill the dryer hopper. Be sure to record
We recommend using polyolefinic carriers such as
the material, grade, lot number, date and drying startup
polypropylene with most colorable grades. The specialty
time. As a suggestion, duplicate the same information on an
bonding grades may require specific or unique carrier or carrier
index or note card and attach it to the side of the dryer.
less systems. Please refer to the Quick Processing Reference for
5. Dry virgin TPV pellets at least three hours, or dry blends of
these recommen dations. Never use incompatible carriers. An
virgin and regrind for four hours.
incompatible carrier can cause problems with melt quality,
6. Once the drying cycle is complete, record the finished drying
which is evidenced by delamination in high shear regions or by
time and move the TPV material to the processing
discoloration. Also, do not use polyvinyl chloride (PVC) as it is
equipment. A best practice would be to have the drying
not stable at normal TPV processing conditions.
hopper integrated with the injection molding machine. This
insures that moisture cannot return to the dried material.
As noted in the drying section above, most colorants absorb
7. To eliminate the chance of an undried material “dead zone”
moisture, so always follow proper drying procedures unless it
in the dryer, recycle some material from the bottom to the
not recommended by the colorant supplier.
top of the hopper.
GENERAL PROCESSING - 11
0
Virgin 1st pass 2nd pass 3rd pass 4th pass 5th pass
Santoprene TPVs allow for regrinding and reprocessing of clean Santoprene 201-80 TPV, lot #PGF1369, per Test Method TPE-0153
runners, sprues and scrap parts with minimal variation in
material properties. Our materials can be exposed to multiple
heat histories with minimal change in tensile strength, modulus,
elongation and other properties. Although regrind levels up to Table 2
100% can be successfully employed. We recom mend using a Hardness change of Santoprene 20180 TPV after multiple
consistent percentage of regrind, i.e., 10 to 60%. The ability to molding cycles (25% regrind material / 75% virgin material)
use higher regrind levels depends on factors such as machine
part configuration, uniformity of the virginregrind blend and
Virgin 1st pass 2nd pass 3rd pass 4th pass 5th pass
adherence to good housekeeping practices. Higher
percentages of regrind (above 40%) tend to cause feeding Hardness, 84.9 84.7 84.9 85.3 85.6 85.1
problems. It is industry best practice to use hopper or feed Shore A
throat magnets to capture ferrous metal contami nates from Santoprene 201-80 TPV, lot #PGF1369, per Test Method TPE-0189
other manufacturing operations.
regrind from the previous shot. Thus, the last pass contained
(Pa* sec)
MOLD DESIGN
Mold steel selection Mold surfaces
The specifics of the considered injection molding application The mold cavity finish determines the surface finish of a part.
determines the type of steel to use in a mold. Table 3 matches Typically, an SPI B3 to SPI D1 finish (VDI 3036 / Ra 36), provides
certain applications with an appropriate steel grade. good mold release for TPVs ; however, if a highpolish, SPI A1 or
A2 finish (<3Ra / 30 VDI) is used, an air assisted ejection is
Usually, structural mold sections are made from mediumcarbon required for easy part removal and minimal distortion. When
SAE 1030 or AISI 4130 steel. Since Santoprene TPVs are texturing a surface, we suggest a minimum draft of ½° per side,
generally noncorrosive and nonabrasive, we recommend P20 plus ½° per each 0.025 mm (0.001”) depth of texture used.
steel for base plates.
For mold construction, obtain more information about mold
Some TPVs, however, can corrode untreated tool steel after steel selection from steel suppliers and moldbase
long term contact. In this case, specify H13 steel or use a manufacturers. They can provide more detailed information
protective mold coating. Alternately, a corrosion resistant steel about the steels listed in table 4.
like H13 or AISI 420 can be used.
Table 3
Typical high grade mold steels from applications for typical mold steels
Table 4
Mold surface plating and treatments
The working area of a mold can/should be plated, coated and/ CAVITY VENT DETAIL
or heattreated to resist wear, corrosion and release problems.
Table 4: Mold surface plating and treatmens lists treatments
that can help reduce wear on gates, runners, ejector pins, core
pins, inserts and particularly cavities opposite a gate.
0.020 - 0.025 mm
Mold venting vent depth
(0.0008 - 0.0010”)
Runner types
0.05 mm (0.002”) 0.05 mm (0.002”)
Fullround runners have the smallest surfacetovolume ratio and
are the most efficient crosssection for pressure transmission
and heat retention. This type of runner is cut identically into the
2 mold halves so machining must be precise.
Sprue, runner and gate design Trapezoidal runners also deliver efficient melt flow. This type of
runner system is machined into a single mold plate. Runner
walls should have a 5° taper with a round runner bottom. A
Sprues modified trapezoidal runners mold is shown in the Runner
They promote a smooth melt transition to the runner and Types figure (see Figure 9).
permit easy extraction while providing an optimum pressure
drop. Halfround runners are not recommended since they give the
lowest flow and are the most easily overcooled of all runner
A standard sprue bushing with a minimum taper per side types in common use.
approximately a 2.5 to 3.5 ° included angle (see Figure 8).
MOLD DESIGN - 15
Figure 9
Runner patterns
H-type Radial Herringbone
Figure 10
Cold slug well size and location
D D
Vent to atmosphere
L = 1.0 to 1.5 D
Cold slug wells As a general rule, minimize the number of gates per cavity. One
Cold slug wells (see Figure 10) capture the cooled material gate per cavity is usually best to avoid weld lines and crossflow
found in the nozzle tip and the material that is cooled during patterns ; however, some applications may require multiple
the runner filling. If injected into a part, a cold slug can lead to gating. For more information contact the AnswerpersonSM at:
surface imperfections. A cold slug well captures solidified tpe.answerperson@exxonmobil.com or visit us at
material and prevents it from interfering inside that cavity. www.santoprene.com
Additional wells should be used at the end of each runner
section (turn/split).
Gating
Gates play a number of crucial roles in injection molding.
Figure 15
60° Edge (rectangular) gate
30° 45°
L
D t
D:W Ratio
Smaller parts: 1:1
Medium parts: 1:2
Ejector pin Large parts: 1:3
Gates diameter
Figure 14
Curved submarine (cashew) gate
Parting line
18 - MOLD DESIGN
L
T t Flash gates
A flash gate is used to minimize warping in flat or very large
parts. Flash gates extend across a part from 0.38 to 0.76 mm
(0.015 to 0.030”) deep and have a chisel taper across the gate
land length. Flash gates require a post molding degating
L = Land length operation and may leave noticeable vestige.
T = 40 - 60% of t
W = 2 D min.
Figure 18
Flash gate
Tab gates
Tab gates provide a uniform melt orientation when an
application requires a large volume for mold filling. Tab gates
help reduce the effect of residual stresses, gate blush and
jetting in the gate area. They are used where flatness is critical
or in large surface areas that may have a tendency to warp. Tab
gates require a post molding degating operation and may leave
noticeable vestige.
MOLD DESIGN - 19
HOT RUNNER SYSTEMS or unmelted material can enter the melt flow. During long cycle
interruptions, the entire unheated runner can freeze off and
require disassembling the mold for cleaning.
Hot runner tooling techniques can be used to efficiently process
Santoprene TPVs in a variety of commercial applications. In fact,
in most cases, hot runner processing can actually improve part
quality and reduce molding cycle time.
Mold design
Hot runner systems have runners that are internal to the mold,
and the system maintains material in the runner at about the Manifolds
same temperature as the barrel. The benefits of hot runner In general, hot runner manifolds for most TPVs have reduced
systems are that there are no runners or gates to be trimmed flow channel diameters compared to those used for rigid
and recycled, and cooling the runner does not require additional thermoplastics. For most TPV applications requiring the use of
cycle time. In addition, smaller gates can be used to improve hot runners, we recommend smallbore, fullround channels with
molded part appearance. a 6.4 mm (0.25”) diameter. This channel size provides a uniform
pressure drop that minimizes material residence time within the
manifold. Make sure all material passages are smooth and
streamlined without protrusions, sharp corners or blind spots.
System selection To take advantage of the melt flow properties of Santoprene
TPVs, flow channels should be cylindrical rather than annular.
For successful processing, a hot runner system should keep the A balanced manifold system is essential for efficient, multicavity
material melt temperature at or near nozzle temperature as the hot runner processing. In each section of a mold, match the
material passes through the gate and into the mold cavity. length and diameter of the primary and secondary flow
These four steps are recommended: channels. Since flow channels in a manifold function as full
round runners, the melt flow must be balanced to uniformly fill
1. Minimize the time material remains in a hot runner system. If all cavities.
possible, it should contain no more than one shot.
2. Design melt channels for uniform pressure drop throughout Shot size verses manifold volume
the system. Shot size verses the manifold volume determines the residence
3. Prevent or eliminate possible “hangups” (i.e. burrs, sharp time. If the diameter of a manifold is too large, the material
corners and heating rods) and other melt flow interruptions. tends to hang and form channels, which results in an
4. Maintain precise temperature control and make sure heat is insufficient shear rate and an excessive residence time possibly
evenly distributed throughout the system, including drops leading to degradation. Ideally, the manifold volume (runners
and manifolds. plus probes) should be significantly less than the shot volume ;
however, high residence times with small parts cannot be
Externally heated manifold avoided.
An externally heated manifold contains a manifold block with a
hollow interior that channels the main runner flow. Heaters Probes
parallel the runner flow channel and heat the entire manifold Gates are an integral part of a heated probe. The probe is
block. Drops or auxiliary channels are usually heated as well and attached to the downstream end of the melt channel. The
feed the melt into the mold cavity. probe fits down the melt channel center, forming an annular
flow path for the material. Manufacturers of probes offer
We recommend using this type of manifold system for hot various models according to the type of gate: hot tip, edge,
runner tooling since it provides a “straightthrough” melt flow valve or core. Remember all probes need to be insulated using
path. It minimizes pressure drop and reduces the chance of DuPont™ Vespel ® or equivalent. An end cap or bushing will
material “hangup,” discoloration and burning. In addition, the restrict the amount of dead material coming into contact with
entire manifold block is heated, making it easier to maintain the relatively cold mold steel. This forms a cold slug.
uniform temperature. An externally heated manifold system
requires a sufficient number of heaters and temperature It is essential in any gating system to maintain the melt
sensors for precise temperature control. temperature with minimum temperature loss between the flow
channel and the mold cavity. Excessive temperature loss could
Insulated runner molds cause a cold slug to form at a gate. The cold could cause a
We do not recommend insulated runner molds. Insulated defect on the surface of a molded part. Probe recommen
runner molds incorporate an oversized runner and create a skin dations are summarized below:
of cooled material that insulates the melt. As a result, degraded
HOT RUNNER SYSTEMS - 21
Figure 19
Probe clearance
Probe
Melt
channel
Probe tip
setting
Gate size
22 - HOT RUNNER SYSTEMS
Figure 20 Figure 21
Open / torpedotip gates Valve gates
Insulation
Overmolding slides or rotates to shut off the first runner system and opens
the second for the next shot of material. After the second shot,
the part is cooled and ejected normally.
For an even wider variety of part applications, polymers can be
combined through several different types of multishot injection Twoshot molding requires that the two materials be compatible
molding processes. These include insert molding, twoshot or no bonding occurs. The bond strength of a twoshot molded
molding/2K or 2component molding, and coinjection molding. part is generally better than that of an insertmolded part due to
We offer TPVs that can bond directly to a variety of substrates. the higher temperature at the melt interface.
Two-shot molding
Twoshot (also known as 2K or 2component) molding consists
of a machine having two independent injection units shooting
two different materials into the same mold through separate
runners and gates. The first material is shot through a primary
runner system as in normal molding, while the runner system
for the second material is shut off. After the first shot, the mold
24 - QUICK REFERENCE NOTES
Screw cushion
Screw cushion should be 3 to 6 mm (0.120 to 0.250”) Refer
to the processing section on page 7 of this manual.
TROUBLESHOOTING - 25
Troubleshooting guide
3. Cold mold causes moisture A. Increase mold temperature; make sure cavity is dry.
condensing.