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C OMPATIBILITIE S AN D IN T E R ACT IO N S
Section B12
Solubility of Minerals
and Salts in Formate Brines
B12.1 Introduction.............................................................................................2
B12.2 Solubility of alkaline earth metal sulfates in formate brines...................2
B12.2.1 Effect of brine type...........................................................................2
B12.2.2 Effect of temperature.......................................................................2
B12.2.3 Effect of formate concentration.......................................................2
B12.2.4 Effect of exposure time....................................................................3
B12.2.5 Effect of pH......................................................................................3
B12.2.6 Effect of precipitation reactions........................................................3
B12.2.7 Practical significance of increased alkaline earth metal sulfate
solubility in formate brines................................................................3
B12.3 Solubility of salts in formate brines......................................................... 7
B12.3.1 Solubility of potassium sulfate in potassium formate brine.............. 7
B12.3.2 Solubility of sodium chloride (NaCl) in potassium formate brine...... 7
B12.3.3 Solubility of magnesium chloride (MgCl2) in formate brines............. 7
B12.4 Solubility of clays in formate brines....................................................... 11
B12.5 Solubility of silicates in formate brines.................................................. 11
B12.6 Solubility of galena, hematite, and ilmenate in formate brines............. 11
B12.7 Solubility of calcium carbonate in formate brines................................. 11
References............................................................................................ 12
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Table 1 Solubility of alkaline earth sulfates and scales after 16-hour exposure to various saturated brines at 85°C / 185°F. Some precipitation
of sodium, potassium, and cesium sulfates takes place in all of these tests, so brine sulfate levels do not correspond to levels of dissolved
alkali earth metal sulfates.
BaSO4
100,000 Barite
SrSO4
CaSO4·2aq
10,000
Solubility [mg/L]
1,000
100
10
Figure 1 Solubility of alkaline earth sulfates after 16 hours at 85°C / 185°F in various saturated brine systems with pH of 9.5 (measured
on undiluted brines). The bar chart shows the amount of dissolved sulfate salt calculated from measured barium / strontium / calcium
concentrations in the brine after exposure. Some precipitation of sodium, potassium, and cesium sulfates have taken place in all of these
brines, so brine sulfate levels do not correspond to levels of dissolved alkali earth metal sulfates.
METRIC
10,000
Solubility [mg/L]
100
20 30 40 50 60 70 80 90 100 110
Temperature [°C]
FIELD
100,000
10,000
Solubility [mg/L]
100
70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 220
Temperature [°F]
Figure 2 Influence of temperature on the dissolution of alkaline earth metal sulfates in a concentrated potassium formate brine (75% =
1.57 g/cm3 / 13.1 lb/gal). Contact time = 16 hours. pH = 9.5 (measured in undiluted brine). The graphs show amounts of dissolved
sulfate salt calculated from measured barium / strontium concentrations in the brine after exposure. Some precipitation of potassium
sulfate has taken place, so brine sulfate levels do not correspond to levels of dissolved barium and strontium sulfates.
Dissolved BaSO4
Dissolved SrSO4
10,000
Solubility [mg/L]
1,000
100
10
1
0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80
Figure 3 Influence of formate concentration on the dissolution of alkaline earth metal sulfates in potassium formate brine. Temperature =
85°C / 185°F. pH = 9.5 (measured on undiluted brine). Contact time = 16 hours. The graph shows the amount of dissolved sulfate salt
calculated from measured barium / strontium concentrations in the brine after exposure. Some precipitation of potassium sulfate has
taken place, so brine sulfate levels do not correspond to levels of dissolved barium and strontium sulfates.
11,000
10,000
9,000
8,000
7,000
Solubility [mg/L]
6,000
5,000
4,000
1,000
0
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24
Figure 4 Influence of contact time on the dissolution of alkaline earth metal sulfate salts in concentrated potassium formate brine
(75% = 1.57 g/cm3 / 13.1 lb/gal). pH = 9.5 (measured on undiluted brine). Temperature = 85°C / 185°F. The graph shows the amount
of dissolved sulfate salt calculated from the measured barium / strontium concentrations in the brine after exposure. Some precipitation
of potassium sulfate has taken place, so brine sulfate levels do not correspond to levels of dissolved barium and strontium sulfates.
100,000
Solubility [mg/L]
10,000
Dissolved BaSO4
Dissolved SrSO4
1,000
6.5 7.0 7.5 8.0 8.5 9.0 9.5 10.0 10.5 11.0 11.5 12.0 12.5 13.0 13.5
pH (undiluted)
Figure 5 Influence of pH on the dissolution of alkaline earth metal sulfate salts in concentrated potassium formate brine (75% = 1.57 g/cm3 /
13.1 lb/gal). Contact time = 16 hours. Temperature = 85°C / 185°F. The graph shows the amount of dissolved sulfate salt calculated
from the measured barium / strontium concentrations in the brine after exposure. Some precipitation of potassium sulfate has taken
place, so brine sulfate levels do not correspond to levels of dissolved barium and strontium sulfates.
METRIC
1,000,000
100,000
SO4- solubility [g/mL]
10,000
1,000
FIELD
1,000,000
100,000
SO4- solubility [g/mL]
10,000
1,000
Temperature [°F]
Figure 6 Dissolution of potassium sulfate in three concentrations of potassium formate brine. The figures show measured concentration
of sulfate in liquid. Open symbols represent dissolution type experiments; closed symbols represent precipitation type experiments.
METRIC
250,000
200,000
Cl- solubility [mg/L]
150,000
0
20 30 40 50 60 70 80 90
Temperature [°C]
FIELD
250,000
200,000
Cl- solubility [mg/L]
150,000
0
70 80 90 100 110 120 130 140 150 160 170 180 190
Temperature [°F]
Figure 7 Dissolution of NaCl in three potassium formate brines. The figures show the amount of Cl - in liquid phase as a function of
temperature and formate concentration.
METRIC
800
KFo concentrated
700
KCl concentrated
NaCl concentrated
600
Solubility MgCl2·6H2O [g/L]
500
400
300
200
100
0
20 30 40 50 60 70 80 90 100 110 120
Temperature [°C]
FIELD
800
KFo concentrated
700
KCl concentrated
NaCl concentrated
600
Heated MgCl2 (sat at 60°C)
Solubility MgCl2·6H2O [g/L]
500
400
300
200
100
0
70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 220 230 240
Temperature [°F]
Table 2 Solubility of clays in concentrated formate brines. NaFo (46%wt = 1.33 g/cm3 / 11.1 lb/gal), KFo (75%wt = 1.57 g/cm3 / 13.1 lb/gal),
CsFo (82%wt = 2.26 g/cm3 / 18.9 lb/gal). T = 85°C / 185°F. Exposure time = 16 hours.
Table 3 Solubility of silicates in concentrated formate brines. NaFo (46%wt = 1.33 g/cm3 / 11.1 lb/gal), KFo (75%wt = 1.57 g/cm3 / 13.1 lb/gal),
CsFo (82%wt = 2.26 g/cm3 / 18.9 lb/gal). Temperature = 85°C / 185°F. Exposure time = 16 hours.
References