SERIES : I MID TERM /FN/ 2019 - 2020

CODE : M 043

TIME ALLOWED : 2 HOURS MARKS : 50

CHEMISTRY

1. Write the empirical formula of compound having the molecular formula 1

B2H6

2. What volume will 250g of mercury occupy ? ( density of Hg = 13.6g/cm3) 1

3. What quantum numbers n and l are assigned to a 3p orbital? 1

4. Give the electronic configuration of O2- ion. 1

5. Indicate the number of unpaired electrons in Fe3+ ion. 1

6. Define Law of Multiple proportion. 2

7. Calculate the percentage composition of sodium in Na2SO4 ( Atomic mass 2

of Na = 23u,
S= 32u & O=16u)

8. Calculate the molality of a solution by dissolving 0.850g of NH3 in 100g of 2

water.

9. Why is molality preferred over molarity in handling solutions in chemistry? 2

10. List two differences between orbit and orbital. 2

11. Calculate the Kinetic energy of ejected electron when UV radiation of 2

frequency 1.6x1015 S-1 strikes the surface of potassium metal. Threshold
frequency of potassium metal is 5x1014 S-1 ( Planck’s constant h = 6.626
x10-34 J s)

12. (i)How many nodes are present in 3p orbital? 2

(ii)What are the atomic numbers of elements whose electronic configuration
are represented by (a) [Ne] 3s23P3 (b) [Ar] 4s2 3d1

13. Derive the Debroglie relation between wavelength and momentum of 2

particle in motion.

14. Define the following : 3

(i)Aufbau principle
 (ii)Pauli’s exclusion principle
(iii) Hund’s rule of maximum multiplicity

15. (i)State Heisenberg’s unceretainty principle. 3

(ii) A golf ball has a mass of 40g and a speed of 45m/s. If the speed can be
measured with accuracy of 2%. Calculate the uncertainty in position.

16. (i)Define photoelectric effect . 3

(ii)What is the wavelength of light emitted when the electron in hydrogen
atom undergoes transition from an energy level with n=4 to an energy level
with n=2?

17. Two particles A and B are in motion. If the wavelength associated with the 3
particle A is 5x10-8 m, calculate the wavelength of particle B if its
momentum is half of A.

18. Calcium carbonate reacts with aqueous HCl to give CaCl2 and CO2 3
according to the reaction:
CaCO3(s) + 2HCl (aq) →CaCl2(aq) + CO2(g) + H2O(l)
What mass of CaCO3 is required to react completely with 25ml of 0.75M
HCl?

19. The elemental composition of butyric acid was found to be 54.2%C,9.2%H 3

and 36.6%O. Determine its empirical formula,its molecular mass was
determined by an experiment to be 88u. What is its molecular formula?

20. If 20g of MgCO3 is treated with 20g of HCl, how many grams of CO2 can 3
be produced according to the reaction:
MgCO3 + 2HCl → MgCl2 + H2O + CO2
How much excess excess reactant remain unreacted?

21. Commercially available sulphuric acid contains 93% acid by mass and has a 3
density of 1.84g/ml. Calculate the molarity of the solution and volume of
concentrated acid required to prepare 2.5L of 0.50M H2SO4.

22. (i)The density of 3M solution of NaCl is 1.25g/ml. Calculate the molality of 3+1+1
the solution.
(ii) Which of the following orbitals are possible? 1p,2s,2p,3f
(iii) Using s,p,d notaions, describe the orbital with the following quantum
numbers: (a) n=2, l=1 ; (b) n=3, l=2
 ANSWER KEY (I MID TERM)

Chemistry - std : XI

q. Value Points Marks

no
1. BH3 1
2. Volume = mass / density = 250g/ 13.6 = 18.38cm3 1
n = 3; l = 1 1
3.
1s22s22p6 1
4.
5 unpaired electrons. 1
5.
Definition 2
6.
Molecular mass of Na2SO4 = 142; Na = 46x100/142 = 2
7. 32.4%
m = n / mass of solvent in Kg (1/2) 2
8. = 0.850/17= 0.05mole(1/2)
m=0.05x1000/100 = 0.5mol/kg (1)
Molality depends on mass of solvent which does not 2
9. change with temperature.
Any two differences ( each ½ m) 2
10.
K.E = hγ –hγ0 = 6.626x10-34 ( 1.6x1015 – 5x1014) s-1 (1) 2
11. 6.626x10-34 x 11 x 10 14 = 7.29 x 10 -19 J (1)
(i) n-l-1 = 3-1-1 = 1node (1) 2
12. (ii) Atomic number (a) 15 & (b) 21 (1/2 m each) .
Derive the λ = h/mv = h/p (each step ½ m) 2
13.
Definition (each 1 mark) 3
14.
Definition (1) 3
15. Uncertainty in speed = 45 x2/100 = 0.9m/s (1/2)
∆x = h/4∏∆v (1/2) = 6.626x10-34 / 4x3.14x40x10-3x0.9 =
1.46x10-33 m (1)
Definition (1) 3
16. 1/λ = R[1/n12 – 1/n22] (1/2)
1/λ = 109677( 1/4-1/16) cm-1 (1/2) ; 486nm (1)
 17. For particle A :λA = h/PA ; For particle B λB = h/PB
(1/2)
PB = PA/2 ; λB = h/PB = h/PA /2 = 2h/PA (1)
λA /λB =1/2 ; λB = 2xλA (1/2)
λB = 2x 5x10-8 = 10-7m (1)
18. Convert morlarity to moles (1) 3
Mole to mole ratio from stochiometry (1)
Mole to mass (1) Ans: 0.9375 g
19. Empirical formula : C2H4O (2) ; Molecular formula : C4H8O2 3
(1)
20. Limiting reactant : MgCO3 (1) 3
Amount of CO2 produced + 10.472g (1)
Amount of excess reactant remain unreacted : 2.628g (1)
21. Molarity = 17.5M (2) 3
V1 = 71ml (1)
22. (i) Find mass of solute = 175.5g(1) 3+1+1
Mass of solvent = 1074.5g (1)
Molality = 2.79m (1)
(ii) 2s,2p (1)
(iii) (a) 2p(1/2) (b) 3d(1/2)