Documente Academic
Documente Profesional
Documente Cultură
MATERIALS
SEMINAR REPORT
Submitted by
ATHIRA SOMAN
SBW18CECS06
to
of
Master of Technology
in
Civil Engineering
Place : Elavumthitta
CERTIFICATE
I would also like to thank my guide Mrs. Archana Sukumaran, Asst. Prof.,
Department of Civil Engineering for her valuable advice and wholehearted co-
operation without which this Seminar would not have seen the light of the day.
Above all, I thank the almighty GOD without whose blessing I would never have
been able to complete this work successfully.
ATHIRA SOMAN
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ABSTRACT
Materials, energy and modern sciences are the three pillars of modern technology.
New material developments and research are leading the invention of materials, as
the cornerstone of 21st century high tech field. In recent years the materials
science gained rapid developments. The reason is the increased interdisciplinary
interactions as one hand and introduction of cross penetration of new theories,
new methods and new experimental techniques on the other hand. Also, the urgent
need for practical application of the material has put forwards new demands. The
FGM is the one which can solve practical problems arising from production and
application of new type of composite materials. Functionally graded materials
(FGMs) are composite materials, microscopically inhomogeneous, in which the
mechanical properties vary smoothly and continuously from one surface to
another, and it finds application in various outlets of industry. It is the advanced
materials in the field of composites, which can resist high temperatures and are
proficient in reducing the thermal stresses. In this paper study is performed on
review of FGM composite materials. Various methods and theories for modelling
and analyses of functionally graded materials had been reviewed. The
characteristics, applications and advantages of functionally graded materials are
also briefly described.
ii
CONTENTS
Contents Page No.
ACKNOWLEDGEMENT i
ABSTRACT ii
LIST OF FIGURES vi
LIST OF ABBREVIATIONS ix
1. INTRODUCTION
1.1 General 1
2. FABRICATION PROCESS
2.1 General 6
3.1 General 8
3.2 Classification 8
4.1 General 12
iii
4.2 Mori Tanka Method 12
5. APPLICATIONS OF FGM
5.1 General 17
5.2.1 Aerospace 17
5.2.2 Medicine
5.2.3 Defence
5.2.4 Energy
5.2.5 Optoelectronics
6. ADVANTAGES OF FGM 22
6.1 General 22
6.2 Advantages 22
7. LIMITATIONS OF FGM
7.1 General 27
7.2 Limitations 27
8. CONCLUSION 33
REFERENCES 34
iv
LIST OF FIGURES
v
LIST OF ABBREVIATIONS
FGM
PM
SFF
CVD
PVD
RVE
SHS
FE
vi
1. INTRODUCTION
1.1 GENERAL
In the development of our society materials have played an essential role. The
scientific use of available base materials into various inorganic and organic
compounds has made the path for developing the advanced polymers, engineering
alloys, structural ceramics, etc. For satisfying the ever increasing requirements,
newer and newer materials such as polymers, engineering alloys, structural
ceramics and composites were developed. As the human race evolved from stone-
age to the space age, the development of technology necessitated and was
supported by the innovation of new materials.
Pure metals were of little use in engineering applications because of the demand
of conflicting property requirement. For example, an application may require a
material that is hard as well as ductile, there is no such material existing in nature.
To solve this problem, combination (in molten state) of one metal with other
metals or non-metals is used. This combination of materials in the molten state is
termed alloying (recently referred to as conventional alloying) that gives a
property that is different from the parent materials. Bronze, alloy of copper and
tin, was the first alloy that appears in human history. But there were limitations to
the amount of material that can be dissolved. Also conventional alloying of two
dissimilar materials with wide apart melting temperature was not possible. A
method to overcome this was powdered metallurgy (PM) were alloys are
produced in powdered form. In spite of its excellent characteristics, there existed
some limitations which included intricate shapes and features that cannot be
produced using PM, the parts were porous and had poor strength. With
advancement composite materials were produced by combining one or more
materials in solid states and had distinct physical and chemical properties different
from the individual parent materials. These materials will fail under extreme
working conditions through a process called de-lamination (separation of fibers
from the matrix).
Materials, energy & modern science are the three pillars of modern technology.
Day by day lots of changes are occurred in this field. New technology will helps
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in production of smart materials all over the world. Hence various theories may
put forward for the analysis use of such smart materials. FGM is the new sort of
materials which can largely used in various civil and structural engineering
applications such as aircrafts, nuclear reactors etc.
Functionally Graded Materials (FGMs) are the heterogeneous composite materials
in which the material properties are gradually varied between two points in a
predetermined manner. FGM can also be defined as a composite in which the
material properties are gradually varied along a certain direction as a function of
the position coordinates to achieve desired strength and stiffness. Thus, mitigating
problems induced due to the sudden change of thermo-mechanical properties as in
the case of laminated composites. Discontinuous changes such as a stepwise
gradation of the material constituents can also be regarded as FGMs. FGMs are
composite materials where the concentration, shape and orientation of constituent
phases vary in one or more directions optimizing the performance.
Functionally graded materials (FGMs) are the advanced materials in the family of
engineering composites made of two or more constituent phases with continuous
and smoothly varying composition. These advanced materials with engineered
gradients of composition, structure and specific properties in the preferred
direction are superior to homogeneous material composed of similar constituents.
The mechanical properties such as Young‟s modulus of elasticity, Poisson‟s ratio,
shear modulus of elasticity, and material density, vary smoothly and continuously
in preferred directions in FGMs. FGMs have been developed by combining the
advanced engineering materials in the form of particulates, fibers, whiskers, or
platelets.
The concept of FGM was first introduced in Japan in 1984 during a space plane
project. Where a combination of materials was required that would form a thermal
barrier capable of withstanding a surface temperature of about 2000 K and a
temperature gradient of the order 1000 K across a 10-mm section. In recent years,
this concept has become more popular in different European countries,
particularly in Germany. A transregional collaborative research centre is funded
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since 2006 in order to use maximum potential of grading mono materials, such as
aluminium, steel and polypropylene, by using thermo-mechanically coupled
manufacturing processes.
The basic structural units of FGMs are elements represented by maxel. The term
maxel was coined in 2005 by Rajeev Dwivedi and Radovan Kovacevic at
Research Centre for Advanced Manufacturing (RCAM). The attributes of maxel
include the location and volume fraction of individual material components. A
maxel is also used to represent various methods of the additive manufacturing
(such as stereo-lithography, selective laser sintering, fused deposition modelling,
etc.) to describe the physical voxel (as derived from the words 'volume' and
'pixel'), that defines the build resolution of either a rapid manufacturing or rapid
prototyping process, or the total resolution of a design produced by such
fabrication methods.
1.3 CHARACTERISTICS OF FGM
FGM are materials in which some particular physical properties are changed with
dimensions. One unique characteristics of FGM is the ability to tailor a
material for specific application. The development of FGMs emerged as a means
to improve the toughness behavior of composite materials, when compared to
homogeneously reinforced composites; this improvement is due to the balanced
contributions of reinforced and non reinforced regions within the composite.
There are three phases of FGMs (Ceramic/ Metal, Ceramic/Ceramic,
Metal/Metal). As a representative example for FGMs, we just mention the
metal/ceramic FGMs, which are compositionally graded from a ceramic phase to a
metal phase.The ceramic/metal FGMs can be designed to reduce thermal stresses
and take advantage of the heat and corrosion resistances of ceramic and the
mechanical strength, high toughness, good machinability and bonding capability
of metals without severe internal thermal stresses.The ceramic-metal FGMs
exhibit higher fracture resistance parameters resulting in higher toughness due to
crack bridging in a graded volume fraction. Due to the high mechanical and
thermal properties of the constituent materials, the Ceramic/Metal FGMs can
exhibit good service performance under some severe environments, such as super
high temperature and great temperature. FGMs has an advantage of potential
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reduction of in-plane and through-the thickness transverse stresses, improved
thermal properties, high toughness, etc. FGMs consisting of metallic and ceramic
components are well-known to enhance the properties of thermal-barrier systems,
because cracking or de-lamination, which are often observed in conventional
multi-layer systems are avoided due to the smooth transition between the
properties of the components.
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2. FABRICATION PROCESS
2.1 GENERAL
Thin functionally graded materials are usually in the form of surface coatings,
there are a wide range of surface deposition processes to choose from depending
on the service requirement from the process.
There are different types of vapour deposition techniques, they include: sputter
deposition, Chemical Vapour Deposition (CVD) and Physical Vapour Deposition
(PVD). These vapour deposition methods are used to deposit functionally graded
surface coatings and they give excellent microstructure, but they can only be used
for depositing thin surface coating. They are energy intensive and produce
poisonous gases as their byproducts. Other methods used in producing
functionally graded coating include: plasma spraying, electrodeposition,
electrophoretic, Ion Beam Assisted Deposition, Self-Propagating High-
temperature Synthesis etc.
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Chemical Vapour Deposition (CVD)
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2.2.3 Self-Propagating High Temperature Synthesis
In its usual format, SHS is conducted starting from finely powdered whereas in
other cases, they are sintered to minimize their surface area and prevent
uninitiated exothermic reactions, which can be dangerous. The synthesis is
initiated by point-heating of a small part of the sample.Once started, a wave of
exothermic reaction sweeps through the remaining material.
All the above mentioned processes cannot be used to produce bulk FGM because
they are generally slow and energy intensive, therefore they are uneconomical to
be used in producing bulk FGM. Some of the fabrication methods for producing
bulk functionally graded materials are as follows:
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requirement, stacking and ramming of the premixed-powders, and finally
sintering. PM technique gives rise to a stepwise structure. If continuous structure
is desired, then centrifugal method is used.
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2.3.3 Solid Freeform (SFF) Fabrication Method
SFF involves five basic steps: generation of CAD data from the software like
AutoCAD, Solid edge etc, conversion of the CAD data to Standard Triangulation
Language (STL) file, slicing of the STL into two dimensional cross-section
profiles, building of the component layer by layer, and lastly removal and
finishing. There are various types of SFF technologies, laser based processes are
mostly employed in fabrication of functionally graded materials. Laser based SFF
process for FGM include: laser cladding based method , Selective Laser Sintering
(SLS) , 3-D Printing (3-DP) and Selective Laser Melting (SLM). Laser cladding
based system and selective laser melting are capable of producing fully dense
components. Solid freeform provide manufacturing flexibility amongst other
advantages but the technology is characterized by poor surface finish making it
necessary to carry out a secondary finishing operation.
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3. CLASSIFICATION OF FUNCTIONALLY GRADED
MATERIALS
3.1 GENERAL
3.2 CLASSIFICATION
Functionally graded materials is diverged according to different application
criteria for variety of classification.
o Metal/Ceramic
o Ceramic/Ceramic
o Ceramic/Plastic
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According to application areas, it is classified into Heat resisting FGM,
Biology FGM, Chemical Engineerimg etc.
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4. VARIOUS ANALYTICAL APPROACHES
4.1 GENERAL
The fabrication of FGM is made by mixing the two different materials often it will
be the mixture of metal and ceramic. The material properties are depends upon the
volume fraction .The analytical approaches, both finite element methods and
micromechanical models are frequently used for FGM modeling. The most
important subjects of FGM modeling are: elastic strain, elastic stress, plastic
yielding and deformation, creep at elevated temperature, crack propagation etc.
Such a method works well for composites with regions of the graded
microstructure have a clearly defined continuous matrix This method assumes a
small spherical particle embedded in a matrix. The matrix phase (denoted by the
subscript 1), is assumed to be reinforced by spherical particles of a particulate
phase (denoted by the subscript 2). K1, G1 and V1 represents the bulk modulus, the
shear modulus and the volume fraction of the matrix phase respectively; whereas
K2, G2 and V2 denote the corresponding material properties and the volume
fraction of the particulate phase. It should be noticed that V1 + V2 = 1. The
effective mass density at a point can be given by the rule of mixture (q = q1V1 +
q2V2).
In this model, the effective properties of isotropic composite materials have been
determined analytically, which is based on the simplifying assumption that the
composite material is filled with a fractal assemblage of spheres embedded in a
concentric spherical matrix of different diameters such that the spheres completely
fill the volume of the composite.
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4.4 COMPOSITE CYLINDRICAL ASSEMBLAGE MODEL
This model is used for orthotropic composites and requires both the reinforcing
fiber and matrix are isotropic, while the representative volume elements (RVEs)
microstructure is transversely isotropic in material planes that are perpendicular to
the fiber direction.
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material properties for various constituent material volume fractions; although this
can be alleviated with proper computer software that can automate the process.
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5. APPLICATIONS OF FGM
5.1 GENERAL
FGMs have great potential in applications where the operating conditions are
severe, including spacecraft heat shields, heat exchanger tubes, biomedical
implants, flywheels, and plasma facings for fusion reactors, etc. Various
combinations of the ordinarily incompatible functions can be implemented to
create new materials for aerospace, chemical plants, nuclear energy reactors, etc.
For example, a discrete layer of ceramic material is bonded to a metallic structure
in a conventional thermal barrier coating for high temperature applications.
However, the abrupt transition in material properties across the interface between
distinct materials can cause large inter-laminar stresses and lead to plastic
deformation or cracking. These harmful effects can be eased by smooth spatial
grading of the material constituents. In such cases, large concentrations of ceramic
material are placed at corrosive, high temperature locations, while large
concentrations of metal are placed at regions where mechanical properties need to
be high. The application of these advanced materials was first visualized during a
space plane project in 1984 in National Aerospace Laboratory of Japan to avoid
the stress peaks at interfaces in coated panels for the space shuttle. Combination of
materials used here served the purpose of a thermal barrier system capable of
withstanding a surface temperature of 2000 K with a temperature gradient of1000
K across a 10 mm thick section. Later on, its applications have been expanded to
also the components of chemical plants, solar energy generators, heat exchangers,
nuclear reactors and high efficiency combustion systems.
The concept of FGMs has been successfully applied in thermal barrier coatings
where requirements are aimed to improve thermal, oxidation and corrosion
resistance. FGMs can also find application in the communication and information
techniques. Abrasive tools for metal and stone cutting are other important
examples where gradation of surface layer has improved performance. Various
major fields of application of FGM are:
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5.2.1 Aerospace
Functionally graded materials can withstand very high thermal gradient, this
makes it suitable for use in structures and space plane body, rocket engine
component etc. If processing technique is improved, FGM are promising and can
be used in wider areas of aerospace.
5.2.2 Medicine
Living tissues like bones and teeth are characterized as functionally graded
material from nature to replace these tissues, a compatible material is needed that
will serve the purpose of the original bio-tissue. The ideal candidate for this
application is functionally graded material. FGM has find wide range of
application in dental and orthopaedic applications for teeth and bone replacement
5.2.3 Defence
5.2.4 Energy
FGM are used in energy conversion devices. They also provide thermal barrier
and are used as protective coating on turbine blades in gas turbine engine. They
are used in thermoelectric generators, sensors and solar cells.
5.2.5 Optoelectronics
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retardant doors, etc. The list is endless and more application is springing up as the
processing technology, cost of production and properties of FGM improve.
Nowadays the researches on FGMs have been carried out intensively.FGMs offer
great promise in applications where the operating conditions are more. Potential
applications include those structural and engineering uses that require
combinations of incompatible functions such as refractoriness or hardness with
toughness or chemical inertness with toughness. The FRP materials improve the
corrosion resistance of the steel and enhance the life cycle of the material strength.
Studies have proved that FGMs can be effectively used in multilayered pavement
design. Research has also been carried out to obtain exact analytical solutions.
Numerous research works have been carried out in vibration and dynamic solution
of functionally graded shell panels with rectangular plan form only.
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6. ADVANTAGES OF FGM
6.1 GENERAL
6.2 ADVANTAGES
2. FGM coating and interface can be used to reduce the residual stress and thermal
stress.
3. FGM coating can be used to connect the materials to eliminate the stress at the
interface and end point stress singularity.
4. FGM coating not only enhances the strength of the connections but can also
reduce the crack driving force.
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5. FGM has the ability to control deformation, dynamic response, wear, corrosion
etc.
6. FGM also provides the opportunities to take the benefits of different material
systems e.g., ceramics and metals.
7. Ceramic part has good thermal resistance, wear and oxidation (rust) resistance
whereas metallic part has superior fracture toughness, high strength and bonding
capability.
8. FGM has wide range of applications in dental and orthopedic applications for
teeth and bone replacement.
9. FGM are used in energy conversion devices. They also provide thermal barrier
and used as protective coating on turbine blades in gas turbine engine.
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7. LIMITATIONS OF FGM
7.1 GENERAL
In modern engineered structures pure metals or alloys are less frequently used as a
result of higher requirements and complexity of the applied materials. In order to
fulfill the expectations of constructors, new material combinations are designed
based on metals, ceramic materials and plastics. FGM provides a relative change
in terms of the properties of the materials over the distance and direction. Thus,
the FGM has a wide range of engineering applications and it is expected to
increase as the cost of material processing and fabrication processes are reduced
by improving processing techniques. In the case of functionally graded materials
disadvantageous sharp interfaces existing in a composite material are eliminated.
However, the subject area still requires further advanced research into both
characterization of their properties and their behavior under conditions resembling
operational conditions. It has to be highlighted that at present the production cost
of graded materials is relatively high but due to a tremendous interest in the
subject matter expressed worldwide as well as higher level of knowledge about
these materials, it should be reduced in the long term.
7.2 LIMITATIONS
There are some issues that need further study and to be resolved, mainly in the
following aspects:
2. Still need further research and examination on the physical properties of the
material model. Microscopic structure and the quantitative relationship between
preparation conditions to be established in order to accurately and reliably predict
the physical properties of graded materials.
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3. Research should focus on variation of gradient material with respect to thermal
stress relaxation of the material as well as keep the road open to variety of
engineering applications.
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8. CONCLUSIONS
Functionally graded material is an excellent advanced material that will
revolutionize the manufacturing world. There are a number of hurdles for
realizing this objective.Lots of studies have been conducted on behavior of
functionally graded materials and the literature is very rich on this because
of the wide areas of application of this novel material.Functionally graded
materials are very important in engineering and other applications but the cost
of producing these materials makes it prohibitive in some applications.This
study presents an overview on FGM, its Characteristics, various fabrication
methods and its wide applications. A review of various investigations properties
classifications applications is to be done in this study. An attempt is made to show
the various theories used for analysis of FGM materials used in plates and beams.
These theories are useful in various aspects of civil and structural engineering.
This study is helpful to understand the nature of the functionally graded materials.
FGM marks the emergence of modern material design into ideas for the
development of new materials. Research, development and application of FGM
materials have the current topic and have greater role in the field of aerospace
engineering and structural engineering
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REFERENCE
[8] D. Saji. “Finite element analysis for thermal buckling behavior in functionally
graded plates with cut-outs”. Proceedings of the International conference on
Aerospace Science and Technology June 2008.
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[12] Bao-Lin Wang. “On thermal shock behavior of functionally Graded
materials”. Journal of Thermal Stresses, 2007.
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