Material Safety Data Sheet regional or national regulations.
Small
Iron Filings
First Aid Measures
Always seek professional medical
attention after first aid measures are
provided.
Eyes: Immediately flush eyes with excess
water for 15 minutes, lifting lower and
upper eyelids occasionally.
Skin: Immediately flush skin with excess
water for 15 minutes while removing
contaminated clothing.
Ingestion: Call Poison Control
immediately. Rinse mouth with cold water.
Give victim 1-2 cups of water or milk to
drink. Induce vomiting immediately.
Inhalation: Remove to fresh air. If not
breathing, give artificial respiration.
Fire Fighting Measures
Nonflammable solid. When heated to
decomposition, emits acrid fumes. 0
Protective equipment and precautions
for firefighters: Use foam or dry chemical
to extinguish fire. Firefighters should wear
full firefighting turn-out gear and
respiratory protection (SCBA). Cool
container with water spray. Material is not
sensitive to mechanical impact or static
discharge.
Exposure Controls, Personal
Protection
Use ventilation to keep airborne
concentrations below exposure limits.
Have approved eyewash facility, safety
shower, and fire extinguishers readily
available. Wear chemical splash goggles
and chemical resistant clothing such as
gloves and aprons. Wash hands
thoroughly after handling material and
before eating or drinking. Use NIOSH-
approved respirator with an dust cartridge.
Exposure guidelines: Iron: OSHA PEL:
Not Available, ACGIH: TLV: Not Available,
STEL: Not Available.
Disposal Considerations
Check with all applicable local, regional,
and national laws and regulations. Local
regulations may be more stringent than
amounts of this material may be suitable
for trash disposal.
Material Safety Data Sheet
Sulfur Powder
First Aid Measures
EYES In case of contact with eyes,
immediately flush with clean, low-pressure
water for at least 15 min. Hold
eyelids open to ensure adequate flushing.
Seek medical attention.
SKIN Remove contaminated clothing.
Wash contaminated areas thoroughly with
soap and water or waterless
hand cleanser. Obtain medical attention if
irritation or redness develops. Thermal
burns require immediate medical attention
depending on the severity and the area of
the body burned.
INGESTION DO NOT INDUCE
VOMITING. Do not give liquids. Obtain
immediate medical attention. If
spontaneous vomiting occurs, lean victim
forward to reduce the risk of aspiration.
Monitor for breathing difficulties.
Small amounts of material which enter the
mouth should be rinsed out until the taste
is dissipated.
INHALATION Remove person to fresh air.
If person is not breathing provide artificial
respiration. If necessary, provide
additional oxygen once breathing is
restored if trained to do so. Seek medical
attention immediately.
Exposure Controls, Personal
Protection
ENGINEERING CONTROLS Use
adequate ventilation to keep vapor,
hydrogen sulfide and dust concentrations
of this product below occupational
exposure limits and flammability limits,
particularly in confined spaces. Use
explosion-proof equipment and lighting in
classified/controlled areas.
EYE/FACE PROTECTION Safety goggles
are recommended for excessive dust
exposure. Use face shield for protection
against molten sulfur.
SKIN PROTECTION Avoid repeated or
prolonged skin contact. For protection
from molten sulfur, gloves and skin
protection constructed of leather or heat
resistant materials are recommended.
RESPIRATORY PROTECTION If a
hydrogen sulfide hazard is present (that is,
exposure potential above H2S permissible
exposure limit), use a positive-pressure
SCBA or Type C supplied air respirator
with escape bottle.
Dust protection: where it has been
determined that there is no hydrogen
sulfide exposure hazard (that is, exposure
potential below H2S permissible exposure
limit), a NIOSH/ MSHA-approved air-
purifying respirator with dust cartridges or
canister may be permissible under certain
circumstances where airborne
concentrations are or may be expected to
exceed exposure limits or for odor or
irritation. Protection provided by air-
purifying respirators is limited. Refer to
OSHA 29 CFR 1910.134, ANSI Z88.2-
1992, NIOSH Respirator Decision Logic,
and the manufacturer for additional
guidance on respiratory protection
selection.
Use a positive pressure, air-supplied
respirator if there is a potential for
uncontrolled release, exposure levels are
not known, in oxygen-deficient
atmospheres, or any other circumstance
where an air-purifying respirator may not
provide adequate protection.
Disposal Considerations
Consult federal, state and local waste
regulations to determine appropriate
disposal options.
Material Safety Data Sheet
Sugar
First Aid Measures
General: Never give anything by mouth to
an unconscious person. If you feel unwell,
seek medical advice (show the label
where possible).
Inhalation: Using proper respiratory
protection, immediately move the exposed
person to fresh air. Obtain medical
attention if breathing difficulty persists.
Skin Contact: Rinse immediately with
plenty of water for 5 minutes. Obtain
medical attention if irritation develops or
persists.
Eye Contact: Rinse cautiously with water
for at least 5 minutes. Remove contact
lenses, if present and easy to do. Continue
rinsing. Obtain medical attention if
redness, pain, or irritation occurs.
Ingestion: Rinse mouth. Do not induce
vomiting. Get medical advice and attention
if you feel unwell.
Most Important Symptoms and Effects
Both Acute and Delayed
General: Not expected to present a
significant hazard under anticipated
conditions of normal use. Prolonged
contact with large amounts of dust may
cause mechanical irritation.
Inhalation: Dust may be harmful or cause
irritation.
Skin Contact: Prolonged exposure may
cause skin irritation.
Eye Contact: May cause slight irritation to
eyes.
Ingestion: Ingestion is not likely to be
harmful or have adverse effects.
Chronic Symptoms: Repeated or
prolonged contact with skin may cause
dermatitis.
Indication of Any Immediate Medical
Attention and Special Treatment
Needed
If exposed or concerned, get medical
advice and attention. If medical advice is
needed, have product container or label at
hand.
Exposure Controls
Appropriate Engineering Controls:
Emergency eye wash fountain capability
should be available in the immediate
vicinity of any potential exposure. Ensure
adequate ventilation, especially in
confined areas. Ensure all national/local
regulations are observed. Proper
grounding procedures to avoid static
electricity should be followed. Use
explosion-proof equipment. Use local
exhaust or general dilution ventilation or
other suppression methods to maintain
dust levels below exposure limits. Power
equipment should be equipped with
proper dust collection devices. It is
recommended that all dust control
equipment such as local exhaust
ventilation and material transport systems
involved in handling of this product contain
explosion relief vents or an explosion
suppression system or an oxygen-
deficient environment.
Personal Protective Equipment:
Gloves. Protective clothing. Protective
goggles. Insufficient ventilation: wear
respiratory protection.
Materials for Protective Clothing:
Chemically resistant materials and fabrics.
Hand Protection: Wear protective gloves.
Eye Protection: Chemical safety goggles.
Skin and Body Protection: Wear
suitable protective clothing.
Respiratory Protection: If exposure
limits are exceeded or irritation is
experienced, approved respiratory
protection should be worn. In case of
inadequate ventilation, oxygen deficient
atmosphere, or where exposure levels are
not known wear approved respiratory
protection.
Other Information: When using, do not
eat, drink or smoke
Disposal Considerations
Waste Disposal Recommendations:
Dispose of contents/container in
accordance with local, regional, provincial,
territorial, national, and international
regulations
Additional Information: Container may
remain hazardous when empty. Continue
to observe all precautions.
Ecology - Waste Materials: Avoid
release to the environment.
Material Safety Data Sheet
Cooking Oil
First Aid Measures
Always seek professional medical
attention after first aid measures are
provided.
Eyes: Immediately flush eyes with excess
water for 15 minutes, lifting lower and
upper eyelids occasionally.
Skin: Immediately flush skin with excess
water for 15 minutes while removing
contaminated clothing.
Ingestion: Call Poison Control
immediately. Rinse mouth with cold water.
Give victim 1-2 cups of water or milk to
drink. Induce vomiting immediately.
Inhalation: Remove to fresh air. If not
breathing, give artificial respiration.
Exposure Controls, Personal
Protection
Use ventilation to keep airborne
concentrations below exposure limits.
Have approved eyewash facility, safety
shower, and fire extinguishers readily
available. Wear chemical splash goggles
and chemical resistant clothing such as
gloves and aprons. Wash hands
thoroughly after handling material and
before eating or drinking. Exposure
guidelines: Vegetable Oil : OSHA PEL:
N/A, ACGIH: TLV: N/A, STEL: N/A.
Disposal Considerations
Check with all applicable local, regional,
and national laws and regulations. Local
regulations may be more stringent than
regional or national regulations. Small
amounts of this material may be suitable
for sanitary sewer or trash disposal.
Material Safety Data Sheet
Chalk Powder
First Aid Measures
General Advice : Take off dirty clothes.
After inhalation : Take the victim into the
fresh air.
After skin contact : Flush away with soap
and water and rise
After eyes contact : Flush eyes with
plenty of water (10-15min.)
After accidental ingestion : Rinse mouth
with water and drink water. Call a
physician.
 Exposure Controls, Personal
Protection
No special measures must be observed.
Provision is required to keep exposure
below permissible limit :
Personal protective equipment
If workplace limits are exceeded, a gas
mask approved for this particular job must
be worn : Filter P2 (Solid and liquid
particles) (DIN 3181)
Disposal Considerations
In accordance with local official
regulations pass on to an appropriate
waste dump. The
product is no water-soluble and can thus
be removed mechanically in suitable
plants.
Material Safety Data Sheet
Sand
First Aid Measures
Eyes: Immediately flush eyes with plenty
of water for at least 15 minutes,
occasionally lifting the upper and lower
eyelids. If irritation develops, get medical
aid.
Skin: Immediately flush skin with plenty of
water for at least 15 minutes while
removing contaminated clothing and
shoes. Get medical aid if irritation
develops or persists.
Ingestion: Do not induce vomiting. Get
medical aid if irritation or symptoms occur.
Inhalation: Remove from exposure and
move to fresh air immediately. If not
breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get
medical aid if cough or other symptoms
appear.
Notes to Physician: Treat
symptomatically and supportively.
Exposure Controls, Personal
Protection
Engineering Controls: Facilities storing
or utilizing this material should be
equipped with an eyewash facility and a
safety shower. Use only under a chemical
fume hood.
Personal Protective Equipment
Eyes: Wear appropriate protective
eyeglasses or chemical safety goggles as
described by OSHA's eye and face
protection regulations in 29 CFR 1910.133
or European Standard EN166.
Skin: Wear appropriate protective gloves
to prevent skin exposure.
Clothing: Wear appropriate protective
clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator
regulations found in 29 CFR 1910.134 or
European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN
149 approved respirator if exposure limits
are exceeded or if irritation or other
symptoms are experienced.
Disposal Considerations
Chemical waste generators must
determine whether a discarded chemical
is classified as a hazardous waste. US
EPA guidelines for the classification
determination are listed in 40 CFR Parts
261.3. Additionally, waste generators
must consult state and local hazardous
waste regulations to ensure complete and
accurate classification.
Material Safety Data Sheet
Acetone
First Aid Measures
General Advice If symptoms persist, call
a physician.
Eye Contact Rinse immediately with
plenty of water, also under the eyelids, for
at least 15 minutes. Get medical attention.
Skin Contact Wash off immediately with
plenty of water for at least 15 minutes. If
skin irritation persists, call a physician.
Inhalation Move to fresh air. If not
breathing, give artificial respiration. Get
medical attention if symptoms occur.
Ingestion Clean mouth with water and
drink afterwards plenty of water.
Most important symptoms and effects
None reasonably foreseeable. Symptoms
of overexposure may be headache,
dizziness, tiredness, nausea and vomiting:
May cause pulmonary edema: Inhalation
of high vapor concentrations may cause
symptoms like headache, dizziness,
tiredness, nausea and vomiting
Notes to PhysicianTreat symptomatically
Exposure Controls, Personal
Protection
Engineering Measures Ensure adequate
ventilation, especially in confined areas.
Ensure that eyewash stations and safety
showers are close to the workstation
location. Use explosion-proof
electrical/ventilating/lighting/equipment.
Personal Protective Equipment
Eye/face Protection Wear appropriate
protective eyeglasses or chemical safety
goggles as described by OSHA's eye and
face protection regulations in 29 CFR
1910.133 or European Standard EN166.
Skin and body protection Long sleeved
clothing.
Respiratory Protection Follow the OSHA
respirator regulations found in 29 CFR
1910.134 or European Standard EN 149.
Use a NIOSH/MSHA or European
Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation
or other symptoms are experienced.
Hygiene Measures Handle in accordance
with good industrial hygiene and safety
practice.
Disposal Considerations
Waste Disposal Methods Chemical
waste generators must determine whether
a discarded chemical is classified as a
hazardous waste. Chemical waste
generators must also consult local,
regional, and national hazardous waste
regulations to ensure complete and
accurate classification
Material Safety Data Sheet
Table Salt-Iodine Mixture
First Aid Measures
Inhalation If dust from the material is
inhaled, remove the affected person
immediately to fresh air. Call a physician if
symptoms develop or persist.
Skin contact Wash off with soap and
water. Get medical attention if irritation
develops and persists.
Eye contact Rinse with water. Get
medical attention if irritation develops and
persists.
Ingestion Give one or two glasses of
water if patient is alert and able to swallow.
Get medical attention if symptoms occur.
Most important symptoms/effects,
acute and delayed Direct contact with
eyes may cause temporary irritation.
Indication of immediate medical
attention and special treatment needed
Treat symptomatically.
General information Ensure that medical
personnel are aware of the material(s)
involved, and take precautions to protect
themselves.
Exposure Controls, Personal
Protection
Biological limit values No biological
exposure limits noted for the ingredient(s).
Appropriate engineering controls
Ventilation should be sufficient to
effectively remove and prevent buildup of
any dusts or fumes that may be generated
during handling or thermal processing.
Individual protection measures, such
as personal protective equipment
Eye/face protection Unvented, tight
fitting goggles should be worn in dusty
areas.
Skin protection
Hand protection Wear appropriate
chemical resistant gloves.
Other Wear suitable protective clothing.
Respiratory protection Use a
NIOSH/MSHA approved respirator if there
is a risk of exposure to dust/fume at levels
exceeding the exposure limits. If
engineering controls do not maintain
airborne concentrations below
recommended exposure limits (where
applicable) or to an acceptable level (in
countries where exposure limits have not
been established), an approved respirator
must be worn.
Thermal hazards Wear appropriate
thermal protective clothing, when
necessary.
General hygiene considerations Always
observe good personal hygiene
measures, such as washing after handling
the material and before eating, drinking,
and/or smoking. Routinely wash work
clothing and protective equipment to
remove contaminants.
Disposal Considerations
Disposal instructions Collect and
reclaim or dispose in sealed containers at
licensed waste disposal site.
Local disposal regulations Dispose in
accordance with all applicable regulations.
Hazardous waste code The waste code
should be assigned in discussion between
the user, the producer and the waste
disposal company.
Waste from residues / unused products
Dispose of in accordance with local
regulations. Empty containers or liners
may retain some product residues. This
material and its container must be
disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Empty
containers should be taken to an approved
waste handling site for recycling or
disposal. Since emptied containers may
retain product residue, follow label
warnings even after container is emptied.
Material Safety Data Sheet
Table Salt-Sulfur Mixture
First Aid Measures
Inhalation If dust from the material is
inhaled, remove the affected person
immediately to fresh air. Call a physician if
symptoms develop or persist.
Skin contact Wash off with soap and
water. Get medical attention if irritation
develops and persists.
Eye contact Rinse with water. Get
medical attention if irritation develops and
persists.
Ingestion Give one or two glasses of
water if patient is alert and able to swallow.
Get medical attention if symptoms occur.
Most important symptoms/effects,
acute and delayed
Direct contact with eyes may cause
temporary irritation.
Indication of immediate medical
attention and special treatment needed
Treat symptomatically.
General information Ensure that medical
personnel are aware of the material(s)
involved, and take precautions to protect
themselves.
Exposure Controls, Personal
Protection
Occupational exposure limits No
exposure limits noted for ingredient(s).
Biological limit values No biological
exposure limits noted for the ingredient(s).
Appropriate engineering controls
Ventilation should be sufficient to
effectively remove and prevent buildup of
any dusts or fumes that may be generated
during handling or thermal processing.
Individual protection measures, such
as personal protective equipment
Eye/face protection Unvented, tight
fitting goggles should be worn in dusty
areas.
Skin protection
Hand protection Wear appropriate
chemical resistant gloves.
Other Wear suitable protective clothing.
Respiratory protection Use a
NIOSH/MSHA approved respirator if there
is a risk of exposure to dust/fume at levels
exceeding the exposure limits. If
engineering controls do not maintain
airborne concentrations below
recommended exposure limits (where
applicable) or to an acceptable level (in
countries where exposure limits have not
been established), an approved respirator
must be worn.
Thermal hazards Wear appropriate
thermal protective clothing, when
necessary.
General hygiene considerations
Always observe good personal hygiene
measures, such as washing after handling
the material and before eating, drinking,
and/or smoking. Routinely wash work
clothing and protective equipment to
remove contaminants.
 Disposal Considerations
Disposal instructions Collect and
reclaim or dispose in sealed containers at
licensed waste disposal site.
Local disposal regulations Dispose in
accordance with all applicable regulations.
Hazardous waste code The waste code
should be assigned in discussion between
the user, the producer and the waste
disposal company.
Waste from residues / unused products
Dispose of in accordance with local
regulations. Empty containers or liners
may retain some product residues. This
material and its container must be
disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Empty
containers should be taken to an approved
waste handling site for recycling or
disposal. Since emptied containers may
retain product residue, follow label
warnings even after container is emptied.