Documente Academic
Documente Profesional
Documente Cultură
KIMS A-2
CHEMISTRY 9701/42
Paper 4 A Level Structured Questions OCT-- 2019
1 hour 30 minutes
Total Marks:- 60
Candidates answer on the Question Paper.
Additional Materials: Data Booklet
Write your Centre number, candidate number and name on all the work you hand in.
Write in dark blue or black pen.
You may use an HB pencil for any diagrams or graphs.
Do not use staples, paper clips, glue or correction fluid.
At the end of the examination, fasten all your work securely together.
The number of marks is given in brackets [ ] at the end of each question or part question.
[Turn over
(a selection only – see also the extended alphabetical list on the previous pages)
Electrode reaction E /V
⦵
.............................................................................................................................................
(ii) Use your expression and the value of Kw in the Data Booklet to calculate the pH of
0.150 mol dm–3 NaOH(aq).
HN
piperidine
.............................................................................................................................................
.............................................................................................................................................
(iv) How would you expect the basicity of piperidine to compare to that of ammonia?
Explain your reasoning.
.............................................................................................................................................
.............................................................................................................................................
[5]
(b) 20.0 cm3 of 0.100 mol dm–3 HCl was slowly added to a 10.0 cm3 sample of 0.150 mol dm–3
piperidine. The pH was measured throughout the addition.
(i) Calculate the number of moles of HCl remaining at the end of the addition.
(ii) Hence calculate the [H+] and the pH at the end of the addition.
pH = .....................
(iii) On the following axes, sketch how the pH will change during the addition of a total of
20.0 cm3 of 0.100 mol dm–3 HCl. Mark clearly where the end point occurs.
14
pH
7
0
0 5 10 15 20
volume HCl added / cm3
(iv) From the following list of indicators, put a tick in the box by the side of the indicator most
suitable for this titration.
A 0-1
B 3-4
C 11 - 12
D 13 - 14
[6]
[Total: 11]
2(a) (i) Draw a fully labelled diagram of the equipment needed to measure the voltage of an
electrochemical cell consisting of the standard hydrogen electrode and the standard
Cu / Cu2+ electrode.
[4]
(ii) For the cell drawn in (i), calculate the and state which electrode is positive.
pH = ............................ [2]
(ii) An electrochemical cell similar to the one you have drawn in (c)(i) was set up using a
0.100 mol dm–3 solution of D in the hydrogen electrode instead of the standard solution.
Use the data and the Nernst equation, E = E o + 0.059 log [H+(aq)], to calculate the new E cell
in this experiment.
[Total: 9]
The initial rate of this reaction was measured, starting with different concentrations of the two
reactants. The following results were obtained.
(i) Use the data in the table to determine the order with respect to each reactant. Show your
reasoning.
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
(ii) Calculate the initial rate in experiment 4. Give your answer to two significant figures.
.............................................................................................................................................
(iv) Use the results of experiment 1 to calculate the rate constant, k, for this reaction.
Include the units of k.
● draw two Boltzmann distribution curves, at two different temperatures, T1 and T2 (T2 > T1),
● label the curves and the axes.
(ii) State and explain, using your diagram, the effect of increasing temperature on the rate of
reaction.
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
[5]
[Total: 11]
4 (a) Complete the table using ticks () to indicate whether the sign of each type of energy change,
under standard conditions, is always positive, always negative or could be either positive or
negative.
electron affinity
ionisation energy
lattice energy
[2]
ΔH5
ΔH4
Mg2+(g) + 2Cl –(g)
Mg+(g) + 2Cl (g) + e–
ΔH3
Mg(g) + 2Cl (g)
ΔH2
Mg(g) + Cl 2(g) ∆H6
ΔH1
Mg(s) + Cl 2(g)
ΔH7
MgCl 2(s)
.............................................................................................................................................
....................................................................................................................................... [1]
(ii) What names are given to the enthalpy changes ΔH6 and ΔH7?
ΔH6 ......................................................................................................................................
ΔH7 ......................................................................................................................................
[2]
Suggest the trend in the first electron affinity of the elements in Group 17. Explain your answer.
....................................................................................................................................................
....................................................................................................................................................
.............................................................................................................................................. [2]
(d) The equation for the formation of magnesium oxide from its elements is shown.
1
Mg(s) + 2 O2(g) MgO(s) ΔH o = – 602 kJ mol–1
Use the equation and the data given in the table to calculate ΔG o for the reaction at 25 °C.
[Total: 9]
B D E
C F
A ................................................................. D ..............................................................
B ................................................................. E ...............................................................
C ................................................................. F ...............................................................
[3]
(b) I n another experiment, an Fe3+(aq) / Fe2+(aq) half-cell was connected to a Cu2+(aq) / Cu(s)
half-cell.
= .............................. V [1]
State and explain how the electrode potential changes if the concentration of Ni2+(aq) is
decreased.
.............................................................................................................................................
.............................................................................................................................................
....................................................................................................................................... [1]
Calculate the electrode potential when [Cr3+(aq)] is 0.60 mol dm–3 and [Cr2+(aq)] is
0.15 mol dm–3. Use the Nernst equation.
E = .............................. V [2]
[Total: 8]
The initial rate of the reaction was measured at different initial concentrations of Cl O2 and OH–.
The table shows the results obtained.
(i) U
se the data in the table to determine the rate equation, showing the order with respect to
each reactant. Show your reasoning.
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
(ii) C
alculate the value of the rate constant, k, using the data from experiment 2. State its
units.
(b) (i) Explain the difference between heterogeneous and homogeneous catalysts.
.............................................................................................................................................
.............................................................................................................................................
....................................................................................................................................... [1]
(c) Some reactions are catalysed by one of the products of the reaction. This is called autocatalysis.
An example of autocatalysis is the reaction between acidified manganate(VII) ions, MnO4–,
and ethanedioic acid, (CO2H)2. Mn2+ ions catalyse this reaction. The reaction is slow in the
absence of a catalyst.
concentration
of reactant
time
On the axes below, sketch the curve you would expect for the autocatalysed reaction in (i).
concentration
of MnO4–
time
[2]
[Total: 12]
Electrode reaction E /V
⦵
Ag+ + e– ⇌ Ag +0.80
Al 3+ + 3e– ⇌ Al –1.66
Electrode reaction E /V
⦵
K+ + e– ⇌ K –2.92
Li+ + e– ⇌ Li –3.04
Mg2+ + 2e– ⇌ Mg –2.38
2+
Mn + 2e –
⇌ Mn –1.18
Mn3+ + e– ⇌ Mn2+ +1.49
MnO2 + 4H + 2e + –
⇌ 2+
Mn + 2H2O +1.23
MnO4 + e – –
⇌ MnO4 2–
+0.56
MnO4– + 4H+ + 3e– ⇌ MnO2 + 2H2O +1.67
–
MnO + 8H + 5e
4
+ –
⇌ 2+
Mn + 4H2O +1.52
NO3– + 2H+ + e– ⇌ NO2 + H2O +0.81
NO3– + 3H+ + 2e– ⇌ HNO2 + H2O +0.94
–
NO3 + 10H + 8e + –
⇌ +
NH + 3H2O
4 +0.87
Na+ + e– ⇌ Na –2.71
Ni2+ + 2e– ⇌ Ni –0.25
[Ni(NH3)6] + 2e 2+ –
⇌ Ni + 6NH3 –0.51
H2O2 + 2H+ + 2e– ⇌ 2H2O +1.77
–
HO2 + H2O + 2e –
⇌ 3OH –
+0.88
O2 + 4H + 4e + –
⇌ 2H2O +1.23
O2 + 2H2O + 4e– ⇌ 4OH– +0.40
O2 + 2H + 2e + –
⇌ H2O2 +0.68
O2 + H2O + 2e– ⇌ HO2– + OH– –0.08
Pb2+ + 2e– ⇌ Pb –0.13
4+
Pb + 2e –
⇌ Pb 2+
+1.69
PbO2 + 4H+ + 2e– ⇌ Pb2+ + 2H2O +1.47
SO42– + 4H+ + 2e– ⇌ SO2 + 2H2O +0.17
2–
S2O8 + 2e –
⇌ 2SO 4
2–
+2.01
S4O62–+ 2e– ⇌ 2S2O32– +0.09
2+
Sn + 2e –
⇌ Sn –0.14
4+
Sn + 2e –
⇌ Sn 2+
+0.15
V2+ + 2e– ⇌ V –1.20
3+
V +e –
⇌ V2+
–0.26
VO2+ + 2H+ + e– ⇌ V3+ + H2O +0.34
VO2+ + 2H+ + e– ⇌ VO2+ + H2O +1.00
–
VO3 + 4H + e + –
⇌ 2+
VO + 2H2O +1.00
Zn2+ + 2e– ⇌ Zn –0.76
All ionic states refer to aqueous ions but other state symbols have been omitted.
(a selection only – see also the extended alphabetical list on the previous pages)
Electrode reaction E /V
⦵
7 9 11 12 14 16 19 20
Li Be B C N O F Ne
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
3 4 5 6 7 8 9 10
23 24 27 28 31 32 35.5 40
Na Mg Al Si P S Cl Ar
Sodium Magnesium Aluminium Silicon Phosphorus Sulphur Chlorine Argon
11 12 13 14 15 16 17 18
39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
85 88 89 91 93 96 101 103 106 108 112 115 119 122 128 127 131
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
133 137 139 178 181 184 186 190 192 195 197 201 204 207 209
15
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
Caesium Barium Lanthanum Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
55 56 57 * 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
226 227
Fr Ra Ac
Francium Radium Actinium
140 141 144 150 152 157 159 162 165 167 169 173 175
*58-71 Lanthanoid series
Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
†90-103 Actinoid series Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium
58 59 60 61 62 63 64 65 66 67 68 69 70 71
a a = relative atomic mass 232 238
Key X X = atomic symbol Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium
b b = proton (atomic) number 90 91 92 93 94 95 96 97 98 99 100 101 102 103
The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).