SAMPLE QUESTION PAPER

CLASS XII
CHEMISTRY

Time: 3 hrs MM: 70

GENERAL INSTRUCTIONS:
1. All the questions are compulsory.
2. Q. No. 1 to 5 are very short answer type, carrying 1mark each.
3. Q. No. 6 to 10 are short answer type, carrying 2 marks each.
4. Q. No. 11 to 22 are short answer type, carrying 3 marks each.
5. Q.No.23 is a value based question carrying 4 marks.
6. Q. No. 24 to 26 are long answer type, carrying 5 marks each.
7. Use of calculators is not allowed, use log tables wherever required.

1. Name the non stoichiometric point defect responsible for colour in alkali metal halides.

2. What is shape selective catalysis?

3. Amongst the isomeric alkanes of molecular formula C5H12, identify the one that on
photochemical chlorination yields a single monochloride.

4. Give the IUPAC name and structure of the amine obtained when 3-chlorobutanamide
undergoes Hoffmann –bromamide reaction.

5. How many ions are produced from the complex,[Co (NH3)6]Cl2 in solution?

6. Will the elevation in boiling point be same if 0.1 mol of Sodium chloride or 0.1 mol of
sugar is dissolved in 1L of water? Explain.

7. The following curve is obtained when molar conductivity (  m ) is plotted against the
square root of concentration, c1/2 for two electrolytes A and B

(a) How do you account for the increase in the molar conductivity of the electrolyte A
on dilution.
 (b) As seen from the graph, the value of limiting molar conductivity ( o m ) for
electrolyte B cannot be obtained graphically. How can this value be obtained?

8. Name the following:

(a) A transition metal which does not exhibit variation in oxidation state in its
compounds.
(b) A compound where the transition metal is in the +7 oxidation state.
(c) A member of the lanthanoid series which is well known to exhibit +4 oxidation
state.
(d) Ore used in the preparation of Potassium dichromate.

9. Arrange the following in order of property indicated for each set:

(a) F2, Cl2, Br2, I2 – increasing bond dissociation enthalpy
(b) PH3, AsH3, BiH3, SbH3, NH3 – increasing base strength

10. (a) Predict the major product of acid catalysed dehydration of 1-Methylcyclohexanol.
(b) You are given benzene, conc.H2SO4, NaOH and dil.HCl. Write the preparation of
phenol using these reagents.

OR
Draw the structures of any two isomeric alcohols (other than 1o alcohols) having
molecular formula C5H12O and give their IUPAC names.

11. An element occurs in the bcc structure with cell edge of 288 pm. The density of the
element is 7.2 g cm-3. How many atoms of the element does 208g of the element
contain?

12. Calculate the boiling point of a 1M aqueous solution (density 1.04 g mL-1) of Potassium
chloride (Kb for water = 0.52 K kg mol-1, Atomic masses: K=39u, Cl=39.9u)
Assume, Potassium chloride is completely dissociated in solution

13. A galvanic cell consists of a metallic zinc plate immersed in 0.1M Zn(NO3)2 solution
and metallic plate of lead in 0.02M Pb(NO3)2 solution. Calculate the emf of the cell.
Write the chemical equation for the electrode reactions and represent the cell.
(Given: E o Zn 2 / Zn  0.76V ; E o Pb2 / Pb  0.13V )

14. Answer the following questions:

(a) What happens when a freshly precipitated Fe (OH)3 is shaken with a little amount
of dilute solution of FeCl3?
(b) Why are lyophilic colloidal sols more stable than lyophobic colloidal sols?
(c) What form Freundlich adsorption equation will take at high pressure?
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15. What chemical principle is involved in choosing a reducing agent for getting the metal
from its oxide ore? Consider the metal oxides, Al2O3 and FeO and justify the choice of
reducing agent in each case.

OR

Account for the following facts:

(a) the reduction of a metal oxide is easier if the metal formed is in the liquid state at
the temperature of reduction.
(b) Limestone is used in the manufacture of pig iron from haematite.
(c) Pine oil is used in the froth floatation process used to concentrate sulphide ores.

16. (i) For M2+/M and M3+/M2+ systems, Eo values for some metals are as follows:
Cr2+/Cr = −0.9V Cr3+/Cr2+ = −0.4V
Mn2+/Mn = −1.2V Mn3+/Mn2+ = +1.5V
2+
Fe /Fe = −0.4V Fe3+/Fe2+ = +0.8V

Use this data to comment upon

(a) the stability of Fe3+ in acid solution as compared to that of Cr3+ and Mn3+
(b) the ease with which iron can be oxidised as compared to the similar process
for either Cr or Mn metals
(ii) What can be inferred from the magnetic moment of the complex K4[Mn(CN)6]
Magnetic moment: 2.2 BM?

17. (i) Describe the type of hybridisation for the complex ion [Fe(H2O)6]2+.
(ii) Write the IUPAC name of the ionisation isomer of the coordination compound
[Co(NH3)5Br]SO4. Give one chemical test to distinguish between the two
compounds.
18. (a) Explain why the dipole moment of chlorobenzene is lower than that of cyclohexyl
chloride.
(b) An optically active compound having molecular formula C7H15Br reacts with
aqueous KOH to give a racemic mixture of products. Write the mechanism involved in
this reaction.

19. Give the structures of A, B and C in the following reactions:

(a) C6 H 5 NO2 Fe

/ HCl
 A HNO
  B C
2 ; 273 K
 C
6 H 5OH


3 ;
(b) C6 H 5 N2Cl CuCN
 A H   B NH
2O / H
 C

20. (a) A non reducing disaccharide ‘A’ on hydrolysis with dilute acid gives an equimolar
mixture of D-(+)-glucose and D-(-)-Fructose.

A  H 2O HCl

 C6 H12O6  C6 H12O6
[ ]D = +66.50 + 52.5o −92.4o
Identify A. What is the mixture of D-(+)- glucose and D-(-)-Fructose known as?
Name the linkage that holds the two units in the disaccharide.

(b)  -amino acids have relatively higher melting points than the corresponding halo
acids. Explain.

21. (a) Pick out the odd one from among the following on the basis of their medicinal
properties mentioning the reason: Luminal, Seconal, Phenacetin, Equanil.

(b) Give an example of a substance that can act as a disinfectant as well as antiseptic
depending upon its concentration. (Specify concentration)

(c) Name any two macromolecules chosen as drug targets.

22. The following is not an appropriate reaction for the preparation of tert.-butyl ethyl
ether:
C2 H 5ONa  (CH 3 )3 C  Cl  (CH 3 )3 C  OC2 H 5
(i) What would be the major product of the given reaction?
(ii) Write a suitable reaction for the preparation of tert.-butyl ethyl ether,
specifying the names of reagents used.
Justify your answer in both cases.

23. Study the given passage carefully and answer the questions that follow:

Shalini studied a chapter on Polymers in school and came across the following
paragraph:
 The durability, strength, low cost, water and chemicals resistance, welding properties,
lesser energy, fewer atmosphere emissions and light weight are advantages of plastic
bags.

Shalini is confused as she has been reading in the newspaper about the ban on the usage
of plastic substances.

She further finds that despite the durability, the use of these materials has presented
mankind with serious waste disposal problem as these materials do not disintegrate by
themselves. In view of this, certain polymers are being developed which are broken
down rapidly by microorganisms. Shalini feels relaxed that such kinds of biomaterials
are being developed.

(a) Name the class of these useful polymers which do not harm the environment.
(b) Give any one example of these polymers and name its monomers.
(c) Comment on the qualities of Shalini.

24. (a) Give a plausible explanation for each one of the following:
(i) Although phenoxide ion has more number of resonating structures than
carboxylate ion, carboxylic acid is a stronger acid than phenol.
(ii) There are two -NH2 groups in semicarbazide. However, only one is in
volved in the formation of semicarbazones.
(b) Carry out the following conversions in not more than two steps:
(i) Phenyl magnesium bromide to benzoic acid.
(ii) Acetaldehyde to But-2-enal.
(iii) Benzene to m-Nitroacetophenone

OR

(a) Give a simple chemical test to distinguish between the pair of organic compounds:
Ethanal and Propanal
(b) Name and complete the following chemical reaction:
RCH 2COOH (  
i ) X 2 / redP( ii ) H 2O

(c) Draw the structures of the following derivatives:

(i) The 2,4-Dinitrophenylhydrazone of benzaldehyde
(ii) Acetaldehydedimethyl acetal
(iii) Cyclopropanone oxime

25. (a) Write the rate law for a first order reaction. Justify the statement that half life for a
first order reaction is independent of the initial concentration of the reactant.

(b) For a first order reaction, show that the time required for 99% completion of a
first order reaction is twice the time required for the completion of 90%.
OR
 (a) For the reaction A→B, the rate of reaction becomes twenty seven times when the
concentration of A is increased three times. What is the order of the reaction?

(b) The activation energy of a reaction is 75.2 kJmol-1 in the absence of a catalyst
and it lowers to 50.14 kJmol-1 with a catalyst. How many times will the rate of
reaction grow in the presence of a catalyst if the reaction proceeds at 25oC?

26. (a) Write balanced chemical equations for the following:

(i) Complete hydrolysis of XeF6.
(ii) Disproportionation reaction of orthophosphorus acid.
(b) Draw the structure of a noble gas species which is isostructural with BrO3−.
(c) Considering the parameters such as bond dissociation enthalpy, electron gain
enthalpy and hydration enthalpy, compare the oxidising power of F2 and Cl2.
(d) Why is K a2  K a1 for H2SO4 in water?

OR
Explain the following:
(a) Hydrogen fluoride is a weaker acid than hydrogen chloride in aqueous solution..
(b) PCl5 is ionic in nature in the solid state.
(c) SF6 is inert towards hydrolysis.
(d) H3PO3 is diprotic.
(e) Out of noble gases only Xenon is known to form established chemical compounds.
 SCORING KEY
SAMPLE PAPER (CHEMISTRY)
CLASS XII

Q.No Answers Marks

1. Metal excess or anionic vacancies or F-centres 1

2. Catalysis by zeolites which depends on the shape and size of the reactants and 1
the products as compared to those of the pores and cavitites of zeolites.
3. Neopentane or 2,2-Dimethylpropane 1

4. 3-Chloropropanamine, CH3CH(Cl)CH2NH2 ½, ½

5. Three ions [Co(NH3)6]2+, 2Cl− 1

6. No, the elevation in boiling point is not the same. ½

Elevation in boiling point is a colligative property which depends on the 1½
number of particles. NaCl is an ionic compound which dissociates in solution
to give more number of particles whereas sugar is made up of molecules and
thus does not dissociate.

7. (a) As seen from the graph, electrolyte A is a strong electrolyte which is 1

completely ionised in solution. With dilution, the ions are far apart from each
other and hence the molar conductivity increases.
(b) To determine the value of limiting molar conductivity for electrolyte B, 1
indirect method based upon Kohlrausch law of independent migration of ions
is used.
8. (a) Scandium (Sc) ½
(b) KMnO4 or any other suitable example ½
(c) Cerium (Ce) or any other example. ½
(d) Chromite ore ½

9. (a) I2 < F2 < Br2 < Cl2 1

(b) BiH3 < SbH3 < AsH3 < PH3 < NH3 1
10. (a) 1-Methylcyclohexene 1
(b)
. H 2 SO4 , 
C6 H 6 conc
  C6 H 5 SO3 H NaOH
 , fuse
,575

 K
 C6 H 5ONa dil
. HCl
 C6 H 5OH 1

OR
Any two isomers out of the following:
(i) CH3−CH2−CH2−CH(OH)− CH3 Pentan-2-ol ½+½
(ii) CH3−CH2−CH(OH)- CH2− CH3 Pentan-3-ol
(iii) CH3−CH(CH3) −CH(OH) −CH3 3-Methylbutan-2-ol ½+½
(iv) CH3−CH2−C(CH3)(OH) − CH3 2-Methylbutan-2-ol
11. For the bcc structure, z = 2
Z M
Density   3 ½
a  No
2 M
7.2 g cm 3  10
(288 10 cm)  (6.022 10 23 )mol 1
3
½
Or M = 51.8 g mol-1 ½
By mole concept,
51.8 g of the element contains 6.022 × 1023 atoms
6.022 1023  208 ½
208 g of the element will contain atoms
51.8
= 24.17 × 1023 atoms. ½

12. Molar mass of KCl = 39+35.5 = 74.5 g mol-1

As KCl dissociates completely, number of ions produced are 2.
Therefore, van’t Hoff factor, i=2 ½
Mass of KCl solution = 1000 × 1.04 = 1040 g
Mass of solvent = 1040 – 74.5 = 965.5 g = 0.9655 kg
Molality of the solution:
½
No. of moles of solute 1mol
  1.0357 m
Mass of solvent in kg 0.9655 kg
½
Tb  i  K b  m
 2  0.52 1.0357  1.078o C ½
Therefore, boiling point of solution = 100 + 1.078 = 101.078 oC 1
(deduct ½ mark if unit not written/incorrect)

13. Anode reaction: Zn( s)  Zn 2 (aq)  2e  ½

½
Cathode reaction: Pb2 (aq)  2e   Pb( s)
½
Cell representation: Zn( s) / Zn 2 (aq) // Pb2 (aq) / Pb( s)
According to Nernst equation:
0.059 [ Zn 2 ]
Ecell  E o cell  log ½
n [ Pb2 ]
0.059 0.1
Ecell  [0.13  (0.76)]  log ½
2 0.02
 0.63  0.02955  log 5
 0.63  0.02955  0.6990
 0.63  0.0206  0.6094V ½

14. (a) A reddish brown coloured colloidal solution is obtained. 1

(b) Stability of lyophilic sols is due to:
 (i) same charge on all the colloidal particles. ½+½
(ii) solvation of the colloidal particles.
(c) At high pressures, amount of gas adsorbed (x/m) becomes independent of
pressure (P) 1
x
 k  Po
m
15. The feasibility of thermal reduction can be predicted on the basis of 1
Ellingham diagram. Metals for which the standard free energy of formation (
 f Go ) is more negative can reduce those metals for which  f Go is less
negative. At a given temperature, any metal will reduce the oxide of other
metals which lie above it in the Ellingham diagram.
(a) Below the temperature approx 1623K), corresponding to the point of
intersection of Al2O3 and MgO curves, Mg can reduce alumina. 1
(b) At temperatures below 1073K, the CO,CO2 line lies Fe, FeO line, thus CO
is a better reducing agent.
At temperatures above 1073K, Coke will reduce FeO and itself get oxidised
to CO. 1
OR

(a) Entropy is higher when a metal is in the liquid state than when it is in the
1
solid state. Thus TS increases, thus G o becomes more negative and the
reduction becomes easier.( G  H  TS )
(b) Limestone provides the flux (CaO) which combines with the impurities 1
(SiO2) to form slag (CaSiO3). Thus it helps in the removal of impurities.
(c) Pine oil (Collector) enhances the non wettability of the ore particles,
which become lighter and hence rise to the surface along with the froth. 1
3+ 2+ 3+
16. (i)(a) Cr /Cr has a negative reduction potential. Hence Cr cannot be
reduced to Cr2+. Cr3+ is most stable. Mn3+/Mn2+ have large positive Eo values. 1
Hence Mn3+ can be easily reduced to Mn2+. Thus Mn3+ is least stable.
Fe3+/Fe2+ couple has a positive Eo value but small. Thus the stability of Fe3+ is
more than Mn3+ but less stable than Cr3+.
(b) If we compare the reduction potential values, Mn2+/Mn has the most
negative value i.e its oxidation potential value is most positive. Thus its most 1
easily oxidised. Thus the decreasing order for their ease of oxidation is Mn >
Cr >Fe.
(ii) K4[Mn(CN)6]
Mn is in +2 oxidation state. Magnetic moment 2.2 indicates that it has one
unpaired electron and hence forms inner orbital or low spin complex. In 1
presence of CN− is a strong ligand, hybridisation involved is d2sp3 (octahedral
complex)

17. (i) Fe exists as Fe2+. There are 4 unpaired electrons. Water is a weak ligand.
Thus the hybridisation involved is sp3d2. It is an octahedral outer orbital 1
complex.
(marks to be granted if hybridisation is depicted diagrammatically)
 (ii) The ionisation isomer is [Co(NH3)5SO4]Br. The IUPAC name is 1
Pentaamminesulphatocobalt(III)bromide.
The isomer [Co(NH3)5 Br] SO4 gives a white precipitate of BaSO4 with BaCl2 1
solution whereas the isomer [Co(NH3)5 SO4]Br does not form this precipitate.
(or any other relevant test)
18. (a) Due to greater s-character, a sp2 hybrid carbon is more electronegative
than a sp3 hybrid carbon. Therefore, the sp2 hybrid carbon of C-Cl bond in
chlorobenzene has less tendency to release electrons to Cl than a sp3 hybrid 1
carbon of cyclohexyl chloride.
( marks to be granted if shown with the help of a figure)

(b) Since the alkyl halide reacts with KOH to form a racemic mixture, it must ½
be a 3o alkyl halide and the reaction will follow SN1 mechanism.

19. (a) A – C6H5NH2 B – C6H5N2+Cl− C – C6H5-N2 –C6H4 -OH ½+½+½

(b) A - C6H5CN B - C6H5COOH C - C6H5CONH2 ½+½+½

20. (a) A – Sucrose (C12H22O11) ½

The mixture of D-(+)- glucose and D-(-)-Fructose is known as invert sugar. ½
The linkage which holds the two monosaccharide units through oxygen atom
is called glycosidic linkage. 1
(b) The amino acids exist as dipolar zwitter ion. Due to this dipolar salt like
character they have strong dipole dipole attractions Thus their melting points 1
are higher than the corresponding haloacids which do not exist as zwitter ions.
21. (a) Phenacetin is an antipyretic, while the rest are tranquilizers. ½+½
(b) 0.2% solution of phenol acts as antiseptic whereas 1% solution of phenol 1
acts as disinfectant.
(c) Carbohydrates, proteins, nucleic acids, lipids (any two) ½+½

22. (i) Since the alkyl halide is a 3o halide and C2H5ONa is a strong base,
therefore elimination occurs preferably. The product obtained is 2- 1
Methylprop-1-ene. CH3−C(CH3)=CH2
(ii) To prepare t-Butyl ethyl ether, the alkyl halide should be 1o i.e. ½+½
chloroethane and the nucleophile should be sodium t-butoxide because the 3o
 nucleophile is able to attack 1o alkyl halide. 1
(CH 3 )3 C  O  Na   CH 3CH 2  Cl  (CH 3 )3 C  OCH 2CH 3

23. (a) The class of polymers is Biodegradable polymers. 1

(b) One example of biodegradable polymers is PHBV (Poly-  - 1
hydroxybutyrate-co-  -hydroxyvalerate).
The names of its monomers are: 3-hydroxybutanoic acid and 3- 1
hydroxypentanoic acid
(c) Care for environment, concern for the health of the people or any other
two relevant points. ½+½

24. (a) (i) The delocalisation of benzene electrons contributes little towards the 1
stability of phenoxide ion. The carboxylate ion is much more
resonance stabilized than phenoxide ion.
(ii) Semicarbazide has two –NH2 groups. One of them, which is directly 1
attached to C=O is involved in resonance. Thus electron density on
this group decreases and it does not act as a nucleophile. In contrast,
the lone pair of electrons on the other –NH2 group is available for
nucleophilic attack.

(b) (i) PhMgBr + O=C=O → PhCOOMgBr H


2O
PhCOOH 1

(ii)
 1
2CH 3CHO OH  CH 3CH (OH )  CH 2CHO heat CH 3CH  CH  CHO
(iii)
. H 2 SO4  conc. HNO3
C6 H 6 (   PhCOCH 3 conc
CH 3CO ) 2 O , anhAlCl 3
     m  NO2 C6 H 4 COCH 3 1
or CH3COCl/AlCl3
OR
(a) Ethanal and propanal can be distinguished by Iodoform test.
Ethanal gives a yellow precipitate of iodoform with an alkaline solution of 1
NaOH. Propanal does not give this test.

CH 3CHO  4 NaOH  3I 2  CHI 3  HCOONa  3H 2O  3NaI

½
(b) RCH 2 COOH (   RCH ( X )COOH
i ) X 2 ,red P ( ii ) H 2O

The name of the reaction is Hell Vohlard Zelinsky reaction ½

(c) (i)
1

1
 (ii)

(iii)
1

25. (a) For a first order reaction 1

2.303 [ R]o
k log where [R]o = initial concentration, [R] = conc. after
t [ R]
time t
When half of the reaction is completed, [R] = [R]o/2. Representing, the time
taken for half of the reaction to be completed, by t1/2, equation becomes:

2.303 [ R]o
k log ½
t1/ 2 [ R]o / 2

2.303
t1/ 2  log 2
k
2.303
t1/ 2   0.3010
k
½
0.693
t1/ 2 
k
The above equation shows that half life first order reaction is independent of
the initial concentration of the reactant.

(b) For a first order reaction

2.303 a 1
t log
k ax
2.303 a
t99%  log
k a  0.99a
2.303 a ½
t90%  log
k a  0.90a ½
t99%  2  2.303  2.303
 / =2
t90%  k  k
t99%  2  t90% 1
OR

(a) r = k[R]n
½
When concentration is increased three times, [R] = 3a
 27r = k(3a)n
27r k (3a) n
 n
or 27 = 3n or 33 = 3n ½
r ka
n=3
1
(b)
According to Arrhenius equation,
Ea
log k  log A 
2.303RT
For uncatalysed reaction
Ea (1) ½
(i) log k1  log A 
2.303RT
For catalysed reaction
E a ( 2) ½
(ii) log k 2  log A 
2.303 RT
A is equal for both the reactions.
Subtracting equation(i) from equation(ii)
k E (1)  Ea (2)
log 2  a
k1 2.303RT
k2 (75.2  50.14)kJ mol 1 1
log 
k1 2.303  8.314 JK 1mol 1  298 K
k
log 2  4.39
k1
k2
 anti log( 4.39) 1
k1
= 2.45×104
Rate of reaction increases by 2.45×104 times.

26. (a) (i) XeF6 ( s)  3H 2O(l )  XeO3 ( s)  6 HF (aq) 1

(ii) 4 H 3 PO3 
 PH 3  3H 3 PO4
heat
1
(b) XeO3 is isostructural with BrO3−. (pyramidal structure)

(c) The bond dissociation enthalpy of F-F bond is lower than that of Cl-Cl
bond and hydration enthalpy of F− ion is much higher than that of Cl− ion. 1
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These two factors more than compensate the less negative electron gain
enthalpy of F2. Thus, F2 is a stronger oxidizing agent than Cl2.

(d) H2SO4 ionises in two stages and hence has two dissociation constants. 1
K a2  K a1
.
This is because the negatively charged HSO4− ion has much less tendency to
donate a proton to H2O as compared to neutral H2SO4.

OR

(a) Due to stronger H-F bond than HCl bond, HF ionises less readily than HCl
in aqueous solution to give H+ ions. Therefore HF is a weaker acid than HCl. 1
(b) In solid state, PCl5 consists of ions [PCl4]+[PCl6]− . On melting these ions
become free to move and hence conducts electricity in the molten state. 1
(c) In SF6, S is sterically protected by six F atoms and hence does not allow
H2O molecules to attack the S molecule. Also, F does not have d-orbitals to 1
accept the electrons donated by H2O molecules.

(d) In the structure of H3PO3 , it contains only two ionisable H-atoms which
are present as -OH groups, thus it behaves as a dibasic acid. 1
(e) Except radon which is radioactive, Xenon has least ionisation energy
among noble gases and hence it readily forms chemical compounds
particularly with O2 and F2. 1
Class 12 Chemistry
NCERT Solutions NCERT Exemplar CBSE Notes
Chapter 1 The Solid State Solid State The Solid State
Chapter 2 Solutions Solutions Solutions
Chapter 3 Electro chemistry Electrochemistry Electro chemistry
Chapter 4 Chemical Kinetics Chemical Kinetics Chemical Kinetics
Chapter 5 Surface Chemistry Surface Chemistry Surface Chemistry
Chapter 6 General Principles and General Principles and Processes General Principles and Processes
Processes of Isolation of Elements of Isolation of Elements of Isolation of Elements
Chapter 7 The p Block Elements The p-Block Elements The p Block Elements
Chapter 8 The d and f Block Elements The d- and f-Block Elements The d and f Block Elements
Chapter 9 Coordination Compounds Coordination Compounds Coordination Compounds
Chapter 10 Haloalkanes and
Haloalkanes and Haloarenes Haloalkanes and Haloarenes
Haloarenes
Chapter 11 Alcohols Phenols and
Alcohols, Phenols and Ethers Alcohols Phenols and Ethers
Ethers
Chapter 12 Aldehydes Ketones and Aldehydes, Ketones and Aldehydes Ketones and
Carboxylic Acids Carboxylic Acids Carboxylic Acids
Chapter 13 Amines Amines Amines
Chapter 14 Biomolecules Biomolecules Biomolecules
Chapter 15 Polymers Polymers Polymers
Chapter 16 Chemistry in Everyday
Chemistry in Everyday Life Chemistry in Everyday Life
Life

JEE Main Chemistry Chapter wise Previous Year Questions

Basic Concepts and Stoichometry
States of Matter: Gases,Liquids and Solids
Atomic Structure and Electronic Configuration
Periodic Classification and Properties
Chemical Bonding and Molecular Structure
Elements of S-Block : Hydrogen,Group 1 and 2
Elements of p-Block: Groups 13,14,15,16,17 and 18 Redox Reactions and Electrochemistry
Elements of d-Block,f-Block and Complexes
Metallurgy and Environmental Chemistry
General Organic Chemistry
Alkanes ,Alkenes ,Alkynes and Arenes
Haloalkenes and Haloarenes
Alcohols,Ethers,Carobonyls and Carboxylic Acids
Nitro,Amine and Azo Compounds
Solutions and Colligative Properties
Kinetics,Catalysis and Surface Chemistry
Chemical and Lonic Equilibrium
Thermodynamics and Chemical Energitics
Biomolecules and Polymers
Chemistry in Everyday Life and Miscellaneous

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Class 12 Chemistry Lab Manual
1. Introduction to Basic Laboratory Equipment
1. Viva Questions with Answers.
2. Surface Chemistry
1. Exp-2.1 : To prepare colloidal solution (sol) of starch.
2. Exp-2.2 : To prepare a colloidal solution of gum.
3. Exp-2.3 : To prepare colloidal solution (or sol) of egg albumin.
4. Exp-2.4 : To prepare ferric hydroxide, [Fe(OH)3] sol.
5. Exp-2.5 : To prepare aluminium hydroxide, [Al(OH)3] sol.
6. Exp-2.6 : To prepare colloidal solution of arsenious sulphide, [As2 S3].
7. Exp-2.7 :To study the dialysis of starch sol containing sodium chloride through a cellophane or
parchment paper.
8. Exp-2.8 : Compare the precipitation values of sodium chloride, barium chloride and aluminium
chloride for arsenious sulphide sol.
9. Exp-2.9 : To study the effectiveness of different common oils (castor oil, cotton seed oil,
coconut oil, kerosene oil, mustard oil) in forming emulsions.
10. Exp-2.10 : To compare the effectiveness of a number of emulsifying agents in forming
emulsions.
11. Surface Chemistry Viva Questions with Answers.
3. Chemical Kinetics
1. Exp-3.1 : To study the effect of concentration on the rate of reaction between sodium
thiosulphate and hydrochloric acid.
2. Exp-3.2 : To study the effect of change in temperature on the rate of reaction between sodium
thiosulphate and hydrochloric acid.
3. Exp-3.3 : To study the reaction rate of reaction of iodide ions with hydrogen peroxide at
different concentrations of iodide ions.
4. Exp-3.4 : To study the reaction rate of the reaction between potassium iodate (KIO3) and
sodium sulphite (Na2S03) using starch solution as indicator.
5. Chemical Kinetics Viva Questions with Answers.
4. Thermochemistry
1. Exp-4.1 : Determine the calorimeter constant (W) of calorimeter (polythene bottle).
2. Exp-4.2 : Determine the enthalpy of dissolution of given solid copper sulphate (CuS04.5H20) in
water at room temperature.
3. Exp-4.3 : Determine the enthalpy of neutralisation of hydrochloric acid with sodium hydroxide
solution.
4. Exp-4.4 : Determine the enthalpy change during the interaction (hydrogen bond formation)
between acetone and chloroform.
5. Thermochemistry Viva Questions with Answers.
5. Electrochemistry
1. Exp-5.1 : To set up simple Daniell cell and determine its emf .
2. Exp-5.2 : To set up simple Daniell cell using salt bridge and determine its emf .
3. Exp-5.3 : To study the variation of cell potential in Zn | Zn2+ || Cu2+ | Cu cell with change in
concentration of electrolytes (CuS04 and ZnS04) at room temperature.
4. Electrochemistry Viva Questions with Answers.
6. Chromatography
1. Exp-6.1 : Separate the coloured components present in the mixture of red and blue inks by
ascending paper chromatography and find their Rf values .
2. Exp-6.2 : Separate the coloured components present in the given grass/flower by ascending
paper chromatography and determine their Rf values .
3. Exp-6.3 : Separate Co2+ and Ni2+ ions present in the given mixture by using ascending paper
chromatography and determine their Rf values .
4. Chromatography Viva Questions with Answers.
7. Preparation of Inorganic Compounds
1. Exp-7.1 : To prepare a pure sample of ferrous ammonium sulphate (Mohr’s salt), [FeSO4 .
(NH4)2 SO4.6HO20] .
2. Exp-7.2 : To prepare a pure sample of potash alum (Fitkari), [K2SO4.Al2 (SO4)3. 24H20] .

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 3. Exp-7.3 : To prepare a pure sample of the complex potassium trioxalatoferrate(III),
Kg[Fe(C2O4)3l . 3H20 .
4. Preparation of Inorganic Compounds Viva Questions with Answers.
8. Preparation of Organic Compounds
1. Exp-8.1 : To prepare a sample of acetanilide from aniline.
2. Exp-8.2 : To prepare a sample of dibenzalacetone.
3. Exp-8.3 : To prepare a sample of p-nitroacetanilide from acetanilide .
4. Exp-8.4 : To prepare 2-naphthol aniline or phenyl-azo-β-naphtholdye .
5. Preparation of Organic Compounds Viva Questions with Answers.
9. Tests for the Functional Groups Present in Organic Compounds
1. Exp-9.1 : Identify the functional group present in the given organic compound.
2. Tests for the Functional Groups Present in Organic Compounds Viva Questions with Answers.
10. Tests of Carbohydrates, Fats and Proteins in Pure Samples and Detection of Their Presence in Given
Food Stuffs
1. Exp-10.1 : To study some simple tests of carbohydrates .
2. Exp-10.2 : To study some simple tests of oils and fats .
3. Exp-10.3 : To study some simple tests of proteins .
4. Exp-10.4 : To detect the presence of carbohydrates, fats and proteins in the following food
stuffs : Grapes, potatoes, rice, butter, biscuits, milk, groundnut, boiled egg .
5. Tests of Carbohydrates, Fats and Proteins in Pure Samples and Detection of Their Presence in
Given Food Stuffs Viva Questions with Answers.
11. Volumetric Analysis
1. Exp-11.1 : Prepare 250 ml of M/10 solution of oxalic acid from crystalline oxalic acid .
2. Exp-11.2 : Prepare 250 ml of a N/10 solution of oxalic acid from crystalline oxalic acid .
3. Exp-11.3 : Preparation of 250 ml of M/20 solution of Mohr’s salt .
4. Exp-11.4 : Preparation of 250 ml of N/20 solution of Mohr’s salt .
5. Exp-11.5 : Prepare M/20 solution of ferrous ammonium sulphate (Mohr’s salt). Using this
solution find out the molarity and strength of the given KMn04 solution.
6. Exp-11.6 : Prepare a solution of ferrous ammonium sulphate (Mohr’s salt) containing exactly
17.0 g of the salt in one litre. With the help of this solution, determine the molarity and the
concentration of KMnO4 in the given solution.
7. Exp-11.7 : Prepare M/20 ferrous ammonium sulphate (Mohr’s salt) solution. Find out the
percentage purity of impure KMnO4 sample 2.0 g of which have been dissolved per litre .
8. Exp-11.8 : Determine the equivalent mass and number of molecules of water of crystallisation
in a sample of Mohr’s salt, FeSO4(NH4)2 SO4 . nH20. Provided KMnO4.
9. Exp-11.9 : Prepare M/50 solution of oxalic acid. With its help, determine 50 the molarity and
strength of the given solution of potassium permanganate (KMnO4).
10. Exp-11.10 : Find out the percentage purity of impure sample of oxalic acid. You are supplied
M/100 KMnO4 solution.
11. Exp-11.11 : The given solution has been prepared by dissolving 1.6 g of an alkali metal
permanganate per litre of solution. Determine volumetrically the atomic mass of the alkali
metal. Prepare M/20 Mohr’s salt solution for titration.
12. Exp-11.12 : Determine the percentage composition of a mixture of sodium

oxalate and oxalic acid . Provided M/100

KMnO4 solution.
13. Exp-11.13 : You are provided with a partially oxidised sample of ferrous sulphate
(FeSO4.7H20) crystals. Prepare a solution by dissolving 14.0 g of these crystals per litre and
determine the percentage oxidation of the given sample. Given M/100 KMnO4 solution.
14. Exp-11.14 : Calculate the percentage of Fe2+ ions in a sample of ferrous sulphate. Prepare a
solution of the given sample having strength exactly equal to 14.0 g/litre. Provided M/100
KMnO4 .
15. Exp-11.15 : Prepare N/20 Mohr’s salt solution. Using this solution, determine the normality
and strength of the given potassium permanganate solution.

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 16. Exp-11.16 : Prepare N/20 solution of oxalic acid. Using this solution, find out strength and
normality of the given potassium permanganate solution .
17. Exp-11.17 : Determine the percentage purity of the given sample of oxalic acid. Ask for your
requirement .
18. Exp-11.18 : Determine the percentage composition of a mixture of sodium

oxalate and oxalic acid . Provided N/20 KMnO4 .

19. Exp-11.19 : Determine the equivalent mass and number of molecules of water of
crystallisation in a sample of Mohr’s salt FeSO4 (NH4)2 SO4.nH20. Provided N/20 KMnO4.
20. Volumetric Analysis Viva Questions with Answers.
12. Chemistry Qualitative Analysis
1. Exp-12.1 : To analyse the given salt for acidic and basic radicals .
2. Exp-12.2 : To analyse the given salt for acidic and basic radicals CO, Zn.
3. Qualitative Analysis Viva Questions with Answers.

NEET Chemistry Chapter wise Important Questions

Some Basic Concepts of Chemistry Chemical Kinetics

Atomic Structure Concept of Chemical Kinetics
Classification and Periodicity of Elements Order of Reaction
Chemical Bonding and Molecular Structure Effect of Temperature on Rate of Reactions
States of Matter ( Gaseous and Liquid State) Surface Chemistry
Unit Test 1(General Chemistry) Concept of Surface Chemistry
Chemical Thermodynamics Factors Affecting Adsorption of Gases on Solids
Thermodynamics Promoters and Inhibitors
First Law of Thermodynamics Preparation of Lyophobic Solution
Hess’s Law of Constant Heat Summation Unit Test 5(Physical Chemistry II)
Second Law of Thermodynamics General Principles and Processes of Isolation of Metals
Equilibrium Earth Crust
Equilibrium State Extraction of Crude Metal from Concentrated Ore
Le-Chatelier's Principle Thermodynamics of Metallurgy
Acids and Bases p-Block Elements
Salt Hydrolysis Group-15 Elements: Nitrogen Family
Redox Reactions Dinitrogen
Concepts of Oxidation and Reduction Phosphorus
Oxidation Number Group-16 Elements: Oxygen Family
Redox Reactions Allotropic forms of Sulphur
Unit Test 2(Physical Chemistry I) Group-17 Elements: Halogens
Hydrogen Group-18 Elements: Noble Gases
Occurrence of Hydrogen The d- and f- Block Elements
Compounds of Hydrogen d-Block Elements

CBSE Sample Papers NCERT Solutions LearnCBSE.in

Hard and Soft Water General Properties of the Transition Elements
s-Block Elements Some Important Compounds of Transition Elements
General Introduction of S-Block Elements Coordination Compounds
Anomalous Properties of Lithium Complex or Coordination Compounds
Biological Importance of Sodium and Potassium Effective Atomic Number Rule
p-Block Elements (Inorganic Chemistry) Bonding in Coordination Compounds
Concept of p-Block Elements Crystal Field Theory (CFT)
Group 13 Elements: Boron Family Unit Test 6(Inorganic Chemistry II)
Some Important Compounds of Group 13
Haloalkanes and Haloarenes
Elements
Group 14 Elements: Carbon Family Alkyl and Aryl Halides
Unit Test 3(Inorganic Chemistry I) Preparation of Aryl Halides
Stereochemical Aspects of Nucleophilic Substitution
Some Basic Principles and Techniques
Reactions
Concept of Organic Chemistry Polyhalogen Compounds
Representation of Different Formula Alcohols, Phenols and Ethers
Isomerism Alcohols and Phenols
Free Radicals Chemical Properties of Alcohols
Types of Organic Reactions Phenols
Chromatography Ethers
Hydrocarbons Aldehydes, Ketones and Carboxylic Acids
Concept of Hydrocarbons Aldehydes and Ketones
Chemical Properties of Alkanes Preparation of Aldehydes
Alkenes Preparation of Ketones
Alkynes Properties
Aromatic Hydrocarbons Uses of Aldehydes and Ketones
Environmental Chemistry Organic Compounds Containing Nitrogen
Environmental Pollution Amines
Air Pollution Properties of Amines
Tropospheric Pollution Hofmann Mustard Oil Reaction
Water Pollution Cyanides
Unit Test 4(Oreganic and Environmental
Biomolecules
Chemistry I)
Solid State Concept of Biomolecules
Concept of Solids Structure of Fructose
Packing Efficiency Proteins
Defects or Imperfections in Solids Nucleic Acids
Magnetic Properties of Solids Polymers
Solutions Concept of Polymers

CBSE Sample Papers NCERT Solutions LearnCBSE.in

Solutions in Chemistry Polymerisation
Vapour Pressure Vulcanisation of Rubber
Ideal Solutions Polyesters
Electrochemistry Chemistry in Everyday life
Concept of Electrochemistry Chemicals in Medicines
Electrochemical Cell Antimicrobials
Representation of a Cell Soaps
Nernst Equation Unit Test 7(Organic Chemistry II)
Mock Test 1
Mock Test 2
Mock Test 3

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