A.

LATIMER DIAGRAMS IN ACID Eo½ vs SHE in 1 M H+

+0.10 - 0.37 -1.63 +1.0 +0.36 -0.25 -0.2

TiO2+ ----- Ti3+ ------- Ti2+ -------Ti VO2+ ------- VO2+ ------- V3+ --------V2+ ---------V

+1.33 -0.41 -0.91 1.82 -0.28 1.68 -0.25

Cr2O72- ------ Cr3+ --------Cr2+ --------Cr Co3+ --------- Co2+ --------- Co NiO2 ------Ni2+ -------- Ni
↓ ------------------------↑
-0.74
+0.564 +2.26 +1.0 +1.5 -1.20 2.20 0.77 -0.41
MnO4- ------ MnO42- ------ MnO2 (s)------Mn+3 ----- Mn2+ ----- Mn (s) FeO42- -----Fe3+ -------Fe2+ ------- Fe
↓ -------------------------------------------------------------↑
+1.51
0.361 0.73 0.40 0.26 -0.4 2 1.26 0.99
Fe(CN)63- -------Fe(CN)64- ReO4- ------- ReO3 ----------ReO2 -------- Re ----- Re- PdO3 -------Pd4+ ---------Pd2+ --------Pd

0.9 1.6 1.3 0.45 1.8 0.153 0.521

RuO4 ------- RuO4- ---------- RuO42- ------- Ru2+ -------Ru CuO+ -------Cu2+ --------Cu+ -------Cu
↓ -----------------------↑
0.34
2.1 1.98 0.799 0.22 -0.152 0.92 0.789
AgO+ ------ Ag2+ ------ Ag+ -------Ag AgCl (S) -----Ag AgI (s)------- Ag Hg2+ ------- Hg22+ ------- Hg

1.36 1.83 1.00 0.84 1.19

Au3+ --------- Au+ -----------Au AuCl4- ------------Au PtO2 --------Pt2+ --------Pt

-0.76 -0.40 -2.7 -2.35 +0.267

Zn2+ ------- Zn Cd2+ ---------- Cd Na+ --------Na Mg2+ --------Mg Hg2Cl2 (S) -------- Hg

0.15 -0.136 1.46 -0.126 1.25 -0.336 -1.68

Sn4+ ------- Sn2+ ---------Sn PbO2 (S) --------Pb2+ -------- Pb Tl3+ --------Tl+ -------- Tl Al3+ -------- Al

-0.106 0.517 0.132 -0.848 -0.143 -0.25 -0.42

CO2 -------CO ------- C ---------CH4 SiO2 ------- Si ----------SiH4 GeO2 ------------Ge --------GeH4

0.79 1.07 1.00 1.59 1.77 -1.87 +1.41 +1.28

NO3- -----N2O4 (g) ------- HNO2 --------NO (g) -------N2O (g) ------N2 (g) ------NH3OH+ ------ N2H5+ ------ NH4+
↓----------------------------↑ ----------------------------- --------------------------- ------------------------------
0.94 1.29 - 0.050 1.35

-0.28 -0.50 -0.51 -0.05 0.559 0.247 -0.38

H3PO4 --------H3PO3 ----------H3PO2 -------P4 (s) --------PH3 (g) H3AsO4 -------H3AsO3 --------As ------- AsH3 (g)

0.58 0.212 -0.51 1.6 0.32 1.15 0.74 -0.32

Sb2O5 ------ SbO+ -------Sb ------SbH3 (g) Bi2O5 ---- BiO+ ----- Bi SeO42- -----H2SeO3 ------Se------- H2Se

2.075 0.68 1.77 -0.22 0.57 0.51 0.08 0.50 0.14

O3 ------- O2 ------ H2O2 ------ H2O SO42- --------S2O62- -------SO2 (g) ------S4O62- ------S2O32- -------S (s) ------ H2S (g)
----------------------- ---------------------------- -----------------------------------------
+1.23 0.17 0.45
1.51 1.1 0.37 -1.0 0.17 0.380 -0.52 -1.66
PoO3 ---------PoO2 ---------Po2+ ----------Po -------H2Po UO22+ --------UO2+ --------U4+ --------U3+ --------U

1.19 1.21 1.64 1.63 1.36 1.82 1.49 1.59 1.07

ClO4- ------- ClO3- ------ HClO2 ------HOCl -----Cl2 (g) ------ Cl- BrO4- ----BrO3- -----HOBr-----Br2 -----–Br-

1.7 1.14 1.45 0.536 1.23 1.06 3.06 2.87

H5IO6 ------IO3- ------HOI --------I2 (s) --------I- IO3- ------- ICl2- -------I2 F2 -------- HF F2 -------- F-
B. LATIMER DIAGRAMS IN BASIC SOLUTION ( 1 M OH-)

-1.69 0.13 -0.13 -1.1 -1.4

3- 2-
TiO2 (s) -------Ti VO4 -------- V CrO4 ----- Cr(OH)3 (s) -------Cr(OH)2 (s) ------- Cr

0.558 0.603 0.1 -0.2 -1.58 -1.285

- 2- 2-
MnO4 ------- MnO4 --------MnO2 (S) ----- Mn(OH)3 (S) ---- Mn(OH)2 (S) ------ Mn ZnO2 ------- Zn

0.72 -0.56 -0.86 0.14 -0.72 -2.31

FeO42- --------Fe(OH)3 (S) -----Fe(OH)2 (S) ------Fe Co(OH)3 --------Co(OH)2 ---------Co H2AlO3- ------- Al

0.49 -0.72 -0.73 0.07 -0.08 -0.36

NiO2 -------- Ni(OH)2 ----------Ni Pd(OH)4 --------Pd(OH)2 --------Pd Cu(OH)2 -------Cu2O ------ Cu

0.74 0.57 0.344 0.098 -0.90 -0.91 0.28 -0.54

Ag2O3 ------AgO ------ Ag2O------ Ag HgO -------Hg Sn(OH)62- -----HSnO2- ------Sn PbO2 ------PbO-----Pb

-0.86 0.88 -0.46 0.76 0.94 -3.04 0.73 0.1

NO3- ----- N2O4 ------ NO2- -------NO ------N2O ------ N2------ NH2OH ------N2H4 -------NH3
-------------------------- ---------------------- ----------------------- ---------------------------
0.01 -0.14 -0.76 0.42

-1.12 -1.57 -2.05 -0.89 -0.67 -0.68 -1.21

3- 2- -
PO4 ------HPO2 ---------H2PO2 -------P4 -------PH3 (g) AsO43- -
-------H2AsO3 -------As --------- AsH3 (g)

-0.93 -1.12 -0.04 -0.74 -0.48 0.05 -0.37 -0.84

2- 2- 2- 2- -2
SO4 ------SO3 ------S2O4 ------S2O3 -------S ------S 2- 2-
SeO4 ------SeO3 ------Se -------Se2-
-------------------------------------------
-0.66
0.36 0.33 0.66 0.40 1.36 0.99 0.54 0.45 1.07
- - - - -
ClO4 ------ClO3 ---------ClO2 -------- ClO -----Cl2 (g) -----Cl - -
BrO4 ------BrO3 -----BrO -----Br2 (l) ------Br-
-

0.7 0.14 0.45 0.54 -0.828 -0.08 0.87

H3IO62- -----IO3- --------IO- -------I2 (S) ------ I- OH- --------H2 (g) O2 ------HO2- ------OH-
---------------------- ---------------------
0.49 0.401

-1.01 - 0.52 -0.70 -1.69 -0.93

CO32- -------- HCO2- -------C -------CH4 (g) SiO32- --------- Si ---------SiH4

* SKIP STEP POTENTIALS E = (n1E1 + n2E2)/(n1 + n2) ; the weighted average of connecting potentials