CSS Past Papers CHEMISTRY (I & II)

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Sajid Mehsud
CSS Past Papers CHEMISTRY (I & II)

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Sajid Mehsud
CSS Past Papers CHEMISTRY (I & II)

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Sajid Mehsud
CSS Past Papers CHEMISTRY (I & II)

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Sajid Mehsud
CSS Past Papers CHEMISTRY (I & II)

Chemistry 2007

CHEMISTRY, PAPER–I
TIME ALLOWED: THREE HOURS MAXIMUM MARKS: 100
NOTE: (i) Attempt ONLY FIVE questions in all, including QUESTION NO.8, which is COMPULSORY.
All questions carry EQUAL marks.

(ii) Extra attempt of any question or any part of the attempted question will not be considered.
(iii) Candidate must draw two straight lines ( ) at the end to separate each
question attempted in Answer Books.

Q.1. (a) What is hydrogen spectrum? How does it help in understanding the structure ofatom? (10)
(b) Write comprehensive notes on hydrogen and metallic bonding. (10)

Q.2. (a) What do you understand by Ionic Equilibria? (7)

(b) Discuss buffer solutions and their mechanism. (7)
(c) Discuss the principle and working of Glass Electrode. (6)

Q.3. (a) Classify Silicates into different types. Give the composition and structure of atleast two types of
silicates. (6)
(b) Give the preparation, properties and structure of Phosphorus Penta oxide. (5)
(c) Describe the preparation and properties of Nitrogen Dioxide (NO2). (5)
(d) Write a note on Interhalogen Compounds. (4)

Q.4. (a) What are the principal ores of Silver? How Silver is extracted from its ores?(8)
(b) Discuss the metallurgy of copper. (6)
(c) Give the names of Iron Ores. (6)

Q.5. (a) Describe the contact process for the manufacture of sulphuric acid. (8)
(b) What are the different types of Fertilizers? Give their chemical formula. (5)
(c) Discuss the measures for the control of CO (Carbon mono-oxide) pollutionin air. (7)

Q.6. (a) Discuss the general characteristics of transition elements based on theirelectronic configuration.
(10)
(b) How free energy and chemical equilibrium are related to each other? (10)

Q.7. Write notes on any FOUR of the following: (5 each)

(a) Fixation of Nitrogen
(b) Semiconductivity Devices
(c) Metallurgy of Aluminium
(d) Crystal field theory
(e) Entropy and second law of thermodynamics
(f) Water Pollution

COMPULSORY QUESTION

Q.8. Write only the correct answer in the Answer Book. Do not reproduce the question.
(1) Which element has the highest Iomization Energy:
(a) Sodium (b) Aluminium
(c) Calcium (d) Phosphorus

(2) Given the reaction 2CO(g) + O 2 (g) 2CO2(g) when the reaction is subjected to stress, a
change will occur in the concentration of:
(a) reactants only (b)products only
(c) both reactants and products (d)neither reactants nor products

(3) Which type of reaction is occurring when a metal undergoes corrosion:

(a) Oxidation-reduction (b) Neutralization
(c) Polymerization (d) Saponification (e) None of these

(4) What is the pH of 0.00001 Molar HCl solution:

(a) 1 (b)9 (c)5 (d) 4 (e) None of these

(5) What is the total number of atoms contained in 2 moles of nickel?

(a) 58.9 (b) 118 (c) 6.02 ´1023 (d) 1.2 ´1024 (e) None of these

(6) What is the percent by mass of oxygen in magnesium oxide (MgO):

(a) 20 % (b) 40 % (c) 50 % (d) 60 % (e) None of these

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Sajid Mehsud
CSS Past Papers CHEMISTRY (I & II)

(7) Which halogens are gases at STP?

(a) Chlorine and Bromine (b) Chlorine and Fluorine
(c) Iodine and Fluorine (d) Iodine and Bromine

(8) The internal resistance of a liquid to flow is called:

(a) Surface tension (b) Capillary action
(c) Viscosity (d) Van der waals alteraction (e) None of these

(9) Two Cu Cu2+ couples, A and B are prepared with Cu2+ concentration of exactly
twice that of B. If these two couples are joined to make a cell:
(a) No current will flow (b) Current will flow from A to B
(c) Current will flow from B to A (d) The system will be in equilibrium

(10) The valence of an element:

(a) Always equals the oxidation number (b) Never equals the oxidation number
(c) Is unrelated to the oxidation number (d) May be numerically equal to the oxidation number

(11) The basic raw materials used in a Blast furnace to produce Iron are Iron ore, Coke,
Air and:
(a) Scrap Iron (b) Sulphur
(c) Sand (d) Limestone (e) None of these

(12) In contrast to the carbonates of the alkali metals, the alkaline earth carbonates:
(a) Are more soluble
(b) Cannot be isolated
(c) Decompose on heating metal and CO2
(d) Decompose on heating forming oxide and CO2
(e) None of these

(13) Coustic Soda is the common name for:

(a) KOH (b) Na2CO3 (c) K2CO3
(d) NaOH (e) None of these

(14) When 2 g of Copper was heated with Sulphur 2.51 g of sulphide was produced.
The empirical formula of the sulphide is:
(a) Cu S2 (b) Cu2 S
(c) Cu2 S3 (d) None of these

(15) The atomic number of an element is equal to the number of:

(a) Protons in the nucleus (b) Protons and neutrons in the nucleus
(c) Neutrons in the nucleus (d) None of these

(16) A liquid will boil at a given temperature provided the atmospheric pressure is equal
to:
(a) The vapour pressure of the liquid (b) Zero
(c) One atmosphere (d) The critical pressure
(e) None of these

(17) When 12 g of magnesium are dissolved in acid, 1g of hydrogen is produced. What

conclusion may correctly be drawn from this information:
(a) The atomic weight of magnesium is 12
(b) The atomic weight of magnesium is 24
(c) The equivale nt weight of magnesium is 24
(d) Not possible to obtain atomic weight from this information

(18) The more reactive a metal:

(a) The less easily it is oxidized
(b) The more easily it gains electrons
(c) The greater is its tendency to form positive ions
(d) The small is its ionization potential
(e) None of these

(19) Sulphure crystallizes in both monoclinic and rhombic forms. This is an exampleof:
(a) A morphism (b) Isomorphism (c) Allotropy
(d) Supercooling (e) None of these
(20) The oxidation number of sulphur in H2SO4 is:
(a) – 2 (b) +2 (c) + 5
(d) + 4 (e) None of these

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Sajid Mehsud
CSS Past Papers CHEMISTRY (I & II)
CHEMISTRY, PAPER–II

TIME ALLOWED: THREE HOURS MAXIMUM MARKS: 100

NOTE: (i) Attempt ONLY FIVE questions in all, including QUESTION NO.8, which is COMPULSORY.
All questions carry EQUAL marks.
(ii) Extra attempt of any question or any part of the attempted question will not be considered.
(iii) Candidate must draw two straight lines ( ) at the end to separate each
question attempted in Answer Books.

Q.1. (a) In what respect are sigma (s ) and pi (p ) bonds different from each other?
Explain. (7)
(b) What are H-bonds and how do they affect the properties of organic compounds?(6)
(c) Write an essay on hybridizatin and its significance in predicting the shape ofmolecules. (7)

Q.2. (a) Give a comparison of Valence Bond (VB) and Molecular Orbital (MO) theories
of bonding highlighting their important features. (7)
(b) What are aromatic compounds? What is the role of resonance energy towardsstability of the aromatic
compounds? (7)
(c) Write an essay on isomerism. Elaborate its various types giving suitableexamples. (6)

Q.3. (a) How can temperature affect the rate of a reaction? Also make a diagram to
explain the energetics involved. (7)
(b) A ® product(s): is a second order reaction. Develop an integrated rate law for the
reaction and suggest a method to confirm that the reaction is second order.(7)
(c) Reaction of sodium ethoxide (Na+-OCH 2 CH 3 ) with bromomethane (CH3Br)
is about 10,000 times faster as compared to that with neopentyl bromide ((CH3)3
CCH2 Br). Explain with justification. (6)

Q.4. (a) Suggest one convenient method each for the preparation of RCHO
(an aldehyde) and R2CO (a Ketone). How to establish that the compound formed
is an aldehyde (or a Ketone) and not the Vice Versa? (7)
(b) Give a general explanation for the electrophilic substitution of benzene. Give
chemical equations showing all steps (with reaction conditions) for
bromination, nitration and alkylation of benzene. (7)
(c) Write an essay on the Grignard reagents. Give one example each in which
the Grignard reagent acts as base and as nucleophile. (6)

Q.5. (a) Differentiate between physical adsorption and chemisorption. How can the
nature of adsorption be established experimentally? (7)
(b) Explain the Langmuir adsorption isotherm and its applications. (6)
(c) Differentiate between molecularity and order of a reaction. Should they change if
the reaction conditions are changed? (7)

Q.6. (a) Suggest a method for the synthesis of benzene-diazonium chloride (BDC) from
nitrobenzene. Write down chemical equations for the reaction of BDC with 7)
(a) KI (b) HBF4 (c) H3PO2 (d) C6H5NH2.
(b) Organic polymers have brought about a socio-economic revolution of present age.
Justify by referring to three important organic polymers. (7)
(c) Write an essay on Vitamins. Why are the Vitamin-A and C important? (6)

Q.7. (a) What are sulpha drugs? Give their general formula and methods of preparation.
Also write structures of two important sulpha drugs. (7)
(b) Write an essay on carbohydrates. What are special features of the
monosaccharides? (7)
(c) What are amides? What make them different in chemical reactivity compared to
aldehydes and Ketones? (6)

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CSS Past Papers CHEMISTRY (I & II)

COMPULSORY QUESTION

Q.8. Write only the correct answer in the Answer Book. Do not reproduce the question.
(1) R - Product(s): is a 1st order reaction with respect to the concentration [R]. To obtain a straight line
with a slope equal to the rate constant k, which of thefollowings should be plotted against time?
(a) [R] (b) [R]2 (c) 1[R] (d) ln[R] (e) None of these

(2) If the rate of a reaction does not change with time then the reaction should be:
(a) moderately slow (b) very fast (c) catalyzed (d) zeroth order (e) None of these.

(3) If a chemical reaction reaches equilibrium state:

(a) its forward and backward rates are equal (b) its overall free energy change becomes zero
(c) its equilibrium constant is the ratio of the two rate constants (d) all of these (e) none of these

(4) PCl5(g) ® PCl3(g) +Cl2(g). The units of equilibrium constant, Kc for the reaction is:
(a) L mol–1 (b) mol L –1 (c) mol –1 L –1 (d) mol –2 L–2 (e) None of these

(5) Energy of a typical H – bond ranges between:

(a) 2 to 4 kJmol –1 (b) 5 to 10 kJmol –1
(c) 15 to 30 kJmol –1 (d) 40 to 80 kJmol –1 (e) None of these

(6) Which of the pairs makes an “ideal mixture”:

(a) benzene-methanol (b) benzene-toluene
(c) ethanol-methanol (d) ethanol-water (e) None of these

(7) Which of the following concentration units depends on temperature?

(a) molarity (b) molality
(c) mole fraction (d) weight to weight (W/W) % (e) None of these

(8) A 0.4% (W/V) aqueous solution of NaOH is nearly:

(a) 1 M (b) 0.5 M (c) 0.1 M
(d) 0.01 M (e) None of these

(9) Which of the followings is correct for the ground state of O2 molecule?
(a) bond order two and no unpaired electron
(b) bond order two and one unpaired electron
(c) bond order two and two unpaired electron in the bonding orbital
(d) bond order two and two unpaired electrons in the anti-bonding orbital
(e) None of these

(10) Which one should give the simplest proton NMR spectrum?
(a) CH3CH2OH (b) CH3OH (c) CH3OCH3
(d) CH3CHO (e) all are equally complicated

(11) Which group has the highest stretching frequency of IR-region in the gas phase?
(a) º C -H (b) = C –H (c) – O – H
(d) – N – H (e) all are equal

(12) Which of the following should not be formed according to the bonding theories?
(a) H2+ (b) H2- (c) He2
+
(d) He2 (e) None of these

(13) There remains no liquid-vapour boundary at:

(a) boiling point (b) critical temperature (c) triple point
(d) azeotrope composition (e) None of these

(14) For a catalyzed reaction as compared to the uncatalyzed one:

(a) heat of reaction is higher (b) heat of reaction is lower
(c) heat of reaction is same (d) activation energy is same (e) All above are correct

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CSS Past Papers CHEMISTRY (I & II)
(15) When two ideal gases at the same temperature are mixed together:
(a) there is a negative heat of mixing (b) there is a positive heat of mixing
(c) both heat and entropy of mixing are positive (d) entropy of mixing alone is positive
(e) All above are correct

(16) Which of the series is present in the ultraviolet region for the H – atom?
(a) Layman (b) Balmer (c) Paschen
(d) Pfund (e) None of these

(17) pH of 0.01 M HCl solution should be:

(a) 3 (b)2 (c)1.5 (d) 1 (e) None of these

(18) Which of the ions should exhibit highest electrical mobility in aqueous solution?–
(a) Na+ (b) I (c) Cs+ (d) Cd++ (e) Li+

(19) H2 + Br2 ® 2HBr is a very famous gas phase reaction. The overall order of this
reaction is:
(a) two (b) one (c) half (d) one half in the beginning
(e) All above are correct

(20) Presence of a chiral center in molecules makes them:

(a) absorb uv–radiation (b) absorb plane polarized light
(c) rotate plane polarized light (d) emit IR–radiation (e) None of these

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Sajid Mehsud
CSS Past Papers CHEMISTRY (I & II)

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CSS Past Papers CHEMISTRY (I & II)

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Sajid Mehsud
CSS Past Papers CHEMISTRY (I & II)

CHEMISTRY, PAPER-I (2010)

(PART-I) 30 MINUTES MAXIMUM MARKS:20

TIME ALLOWED: 2 HOURS & 30 MINUTES MAXIMUM MARKS:80

PART – I (MCQ)
(COMPULSORY)

Q.1. Select the best option/answer and fill in the appropriate box on the Answer Sheet. (20)

(i) When an electron is brought from infinite distance close to the nucleus of the atom, the energy of
Electron-nucleus system?
(a) increases to a smaller negative value (b) decreases to a greater negative value
(c) decreases to a smaller positive value (d) increases to a greater positive value

(ii) The probability of finding the electron in the nucleus is:

(a) 100% due to forces of attraction (b) finite for all orbitals
(c) Zero for all orbitals (d) Zero for some orbitals and finite for others

(iii) When Zn metal is kept in CuSO4 solution, copper is precipitated and ZnSO4 is formed because:
(a) Atomic number of Zinc is smaller than copper
(b) Atomic number of Zinc is larger than copper
(c) Standard reduction potential of Zinc is more than that of copper
(d) Standard reduction potential of Zinc is less than that of copper

(iv) Electrolytes when dissolved in water, dissociate into their constituent ions, the degree of dissociation
of an electrolyte increases with the:
(a) Presence of a substance yielding common ion (b) Decreasing temperature
(c) Decreasing concentration of electrolyte (d) Increasing concentration of electrolyte

(v) There is a large positive entropy change for an exothermic reaction. It means that the reaction will be:
(a) possible at high temperatures only (b) impossible at all temperatures
(c) possible at low temperatures only (d) possible at all temperatures

(vi) Which of the following statement is false?

(a) the temperature of the system will fall if an exothermic reaction is isolated from its surroundings
(b) Energy is absorbed when one compound is converted into another with higher heat content
(c) the temperature of the system is likely to fall if heat is absorbed during the course of a reaction
(d) None of these

(vii) The H_____ bond is strongest in:

(a) S__H ……O (b) O_H …….S (c) F_H ……..O (d) F_H ……..S

(viii) Heavy water contains:

(a) Large amount of salts (b) Deuterium (c) O18 (d) O16

(ix) pH + pOH of a solution is:

(a) 7 (b) Zero (c) 14 (d) -14

(x) The compound that is not Lewis acid:

(a) BF3 (b) BaCl2 (c) SnCl4 (d) AlCl3

(xi) Strongest acid having Ka:

(a) 104 (b) 10-4 (c) 1 (d) 10-2

(xii) Ore of Aluminium:

(a) Calamine (b) Dolomite (c) Bauxite (d) Limestone

(xiii) Oxidation number of S in sulphuric acid:

(a) Four (b) Six (c) Two (d) Eight

(xiv) d-block elements form coordination compounds because of:

(a) Small Cationic size (b) Large ionic Charge (c) Unfilled d-orbitals (d) Filled d-orbitals

(xv) Brass is an alloy of:

(a) Cu and Zn (b) Cu, Ni, Zn (c) Cu and Ni (d) Cu, Al, Zn

(xvi) Urea is a high quality nitrogenous fertilizer with:

(a) 76% nitrogen (b) 46% nitrogen (c) 66% nitrogen (d) 26% nitrogen
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CSS Past Papers CHEMISTRY (I & II)

(xvii) Diamond is:

(a) Good conductor of electricity (b) Bad conductor of electricity
(c) Bad conductor on heating (d) Good conductor on heating

(xviii) Carbon monoxide is poisonous gas because it:

(a) replaces oxygen from lungs (b) forms carboxy haemoglobin
(c) Forms carbon dioxide with oxygen (d) has a sweet smell

(xix) Rust is:

(a) FeO + Fe(OH)2 (b) Fe2O3 + Fe(OH)2
(c) Fe2O3 (d) Fe2O3 + Fe(OH)3

(xx) Calcium Carbide reacts with water to give:

(a) Methane (b) Ethylene
(c) Acetylene (d) Ethane

PART – II

NOTE: (i) PART-II is to be attempted on the separate Answer Book.

(ii) Attempt ONLY FOUR questions from PART-II. All questions carry EQUAL marks.
(iii) Extra attempt of any question or any part of the attempted question will not be considered.

Q.2. (a) Derive the Principal Quantum number from schrodinger wave equation and justify that if the orbit
of hydrogen atom is spherically symmetrical then expression for energy of electron is the same as
deduced by Bohr. (12)
(b) An atom of Helium is moving in one Dimensional box of width 10-2 m. Calculate the energy difference
between second and third energy level. (8)

Q.3. (a) How do you measure the pH of a solution by potentiometric method using: (15)
(i) Hydrogen Electrode
(ii) Glass Electrode

(b) Calculate the pH of a buffer solution containing 0.2M acetic acid and 0.02 M sodium acetate. pKa of
acetic acid is 4.73. (5)

Q.4. (a) Define following types of processes: (8)

(i) Isothermal
(ii) Adiabatic
(iii) Isochoric
(iv) Isobaric

(b) How the pressure, temperature and volume of a gas are related to each other in adiabatic process: (8)
(c) 1 mole of an ideal gas at 25oc is allowed to expand reversibly at constant temperature from 15dm3 to
30dm3 calculate the work done by gas: (4)

Q.5. (a) What is acid rain? How is it produced? Give in detail its chemistry. (8)
(b) Discuss the harmful effects of acid rain on environment and human health. (8)
(c) Enlist major sources for air pollution. (4)

Q.6. (a) Describe the composition of Portland cement. (6)

(b) Which raw materials are used to manufacture glass on industrial scale? (6)
(c) What is fibre glass? Describe its uses. (4)
(d) Which compounds are added to impart different colours to glass? (4)

Q.7. (a) How is urea manufactured in Pakistan, explain with flow sheet diagram? (10)
(b) Name at least four nigtrogenous fertilizers. (4)
(c) 5.35 gm NH4Cl is heated with excess of quick lime. What is the weight of ammonia obtained? If this
ammonia is dissolved in 1 litre of water, Calculate the normality of this solution. (6)

Q.8. (a) What are transition metals? Discuss their characteristic features. (12)
(b) Why AgCl is soluble in NH3? (4)
(c) What are alloy steels, give some examples? (4)

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CSS Past Papers CHEMISTRY (I & II)

CHEMISTRY, PAPER-II
TIME ALLOWED: 2 HOURS & 30 MINUTES
MAXIMUM MARKS: 80
PART – I (MCQ)
(COMPULSORY)
Q.1. Select the best option/answer and fill in the appropriate box on the Answer Sheet. (20)

(i) Which of the following substituent deactivates benzene ring and is o, p-directing?
(a) __ NH2 (b) __ Cl (c) __ OCH3 (d) __ OH

(ii) Which of the following is most readily nitrated?

(a) Toluene (b) Benzaldehyde (c) Nitrobenzene (d) Benzoic Acid

(iii) Ketones can be prepared by reaction of Grignard reagent with:

(a) Acid Amides (b) Acid Chloride (c ) Carboxylic Acid (d) Epoxides

(iv) Which of the following statements about the order of reaction is true?
(a) The order of a reaction can only be determined by experiment.
(b) A second order reaction is also bimolecular
(c) The order of reaction must be a positive integer
(d) The order of reaction increases with increasing temperature.

(v) Polysaccharides yield many monosaccharides on:

(a) Hydration (b) Oxidation (c) Reduction (d) Hydrolysis

(vi) Which of the following is not aromatic?

(a) Benzene (b) cyclooctatetraene (c) Pyridine (d) Phenol

(vii) Which of the following is most basic?

(a) H2O (b) NH3 (c) CH3 NH2 (d) CH3OH

(viii) Which of the following has lowest pH?

(a) CH3COOH (b) CF3COOH (c) ClCH2COOH (d) Cl3C COOH

(ix) The equilibrium of two readily interconvertible isomers is called:

(a) Stereoisomerism (b) Metamerism (c) Tautomerism (d) Polymorphism

(x) Which of the following compounds exhibit geometrical isomerism?

(a) 1-Pentene (b) 2-Pentene (c) 2-methyl –2-Pentene (d) 2-methyl –2-Butene

(xi) Which of the following gives a tertiary alcohol when treated with Grignard reagent:
(a) HCHO (b) CH3CHO (c) C3H5CHO (d) CH3COCH3

(xii) Which of the following tests is not used to identify aldehydes?

(a) Tollen’s test (b) Benedict solution test (c) Fehling solution test (d) Ammonia test

(xiii) Which is incorrect about alkaloids?

(a) Naturally Occuring (b) Possess a hetrocyclic ring (c) Exhibit biological action (d) acidic in nature

(xiv) Which of the followings will not give iodoform test:

(a) Acetone (b) Ethylacohol (c) Benzaldehyde (d) Acetaldehyde

(xv) The reaction of aniline with bromine water gives:

(a) o-bromoaniline (b) p-bromoaniline (c) 2,4-dibromoaniline (d) 2,4,6-tribromoaniline

(xvi) The reaction of tripalmitin, with sodium hydroxide is called:

(a) Hydrolysis (b) Saponification (c) Esterification (d) Combustion

(xvii) Which one is not Petrochemical?

(a) Napthalene (b) Mineral Oil (c) Wax (d) Table Salt

(xviii) Chemical adsorption:

(a) is exothermic (b) is irreversible (c) takes place at high temp. (d) All of these

(xix) The most commonly used absorbent for chromatographic separation of organic compound is:
(a) Activated charcoal (b) Fuller’s Earth (c) Alumina (d) Silica gel

(xx) Grignard reagent is:

(a) Organo Zinc halide (b) Organo cadmium bromide (c) n-Butyl Lithium (d) Organo Magnesium halide

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CSS Past Papers CHEMISTRY (I & II)

PART – II

NOTE: (i) PART-II is to be attempted on the separate Answer Book.

(ii) Attempt ONLY FOUR questions from PART-II. All questions carry EQUAL marks.
(iii) Extra attempt of any question or any part of the attempted question will not be considered.

Q.2. (a) What is mesomerism? Give the conditions necessary for mesomerism. (10)
(b) What is intramolecular and intermolecular hydrogen bonding? Illustrate with examples. (6)
(c) Indicate the type of hybridization of carbon atom in the following: (4)
(i) Formaldehyde
(ii) Dimethylether
(iii) Hydrogen Cyanide
(iv) Acetylene

Q.3. (a) What is Diazotisation reaction? How will you prepare following via Diazotisation reaction? (14)
(i) Phenol
(ii) Chlorobenzene
(iii) Phenyl ethyl ether
(iv) any dye

(b) Discuss the action of nitrous acid on secondary and tertiary amines. (6)

Q.4. (a) How will you synthesize following? Give reaction conditions and mechanism. (16)
(i) Acetaldehyde from Ethanol
(ii) Benzaldelyde from Benzene
(iii) Cyanohydrin from acetaldehyde
(iv) Salicyldehyde from Phenol
(b) What is the difference between clemmensen and wolff-kishner reduction? (4)

Q.5. (a) Discuss the structure of Grignard Reagent. (4)

(b) How these compounds can be prepared via Grignard Reagent? (16)
(i) 2-Butanol
(ii) Ethane
(iii) Acetic Acid
(iv) Ethyl thiol

Q.6. (a) Explain the difference between: (16)

(i) Homopolymer and Copolymer
(ii) Addition Polymerization and Condensation Polymerization
(iii) Monosaccharide and Polysaccharide
(iv) α-D-glucose and β-D-glucose

(b) Write the structure of monomers from which each of the following would be formed: (4)
(i) PVC
(ii) Teflon
(iii) Nylon 6
(iv) PAN

Q.7. (a) Hydrolysis of Ethylacetate by sodium hydroxide is done by taking different initial concentration.
What will be the rate of this reaction? (6)
(b) A second order reaction has equal concentrations of reactants and is 25% completed in 20 minutes.
How much time is required to complete the reaction by 75%? (10)
(c) Express the rate of reversible decomposition of Phosphorus pentachloride into Phosphorous trichloride
and chlorine in terms of reactants and products. (4)

Q.8. How would you prapre the following compounds from benzene? Name each reaction as well. (20)
(i) Acetophenone
(ii) Bromobenzene
(iii) Maleic anhydride
(iv) Toluene
(v) Benzaldehyde
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Chemistry papers 2012

Chemistry Paper I
Part II

Q No.2.
(i) Glucose is formed according to the following reaction, absorbing 2840 kJ of heat. How much energy will be given out
by combustion of 1.08 of glucose? (4)
6CO2(g)+ 6H2O(l)→ C6H12O6(s) + 6O2 (g)
(ii) State and explain the relationship of ionization energy of an atom with its reactivity.
(iii) Explain: Why dipole movement of BF3 is Zero?
(iv) Why dipole movement of NH3is greater than that of NF3?
(v) Why does SO2 have dipole movement while CO2 does not?

Q No.3.
(i) Differentiate between a gangue and slag. Give an example of a metallurgical step where slag, flux, and gangue are
involved simultaneously.
(ii) Describe the different industrial process for preventing the metals from corrosion.
(iii) Draw diagram extraction of aluminum from soil.
(iv) Name the flux used in the extraction of Iron.

Q No.4.
(i) Given the reaction: XeF4(g) + F(g)XeF6(g) (04) Predict the change in hybridization and consequent, final shape of the
molecule followed in the above reaction.
(ii) Valence shell electron pair repulsion theory can be used to predict the shapes of molecules. Using this theory explain
the shapes acquired by BF3 and CH4.
(iii) Explain why HOH bond angle in H2O is slightly less than the tetrahedral angle 109.5?

Q No.5.
(i) A galvanic cell consists of metallic Zn place immersed in 0.1 M Zn (NO3)2 solution and metallic plate of lead in 0.02 M
Pb (NO3)2 solution. Given EoZn2 + Zn = -0.76 V, EoPB2 + Pb = -0.13 V Write the half cell reaction.
(ii) Write the overall reaction of the cell.
(iii) Calculate the e.m.f. of the cell.
(iv) Explain the Nernst heat theorem.
(v) Define enthalpy of formation.

Q No.6. Write one reaction each for the preparation of the following, Also write one use of each product.
(i) Bleaching Power
(ii) Caustic Soda
(iii) Quick Lime
(iv) Ammonia
(v) How is caustic soda manufactured by using Nelson's cell?
(vi) What is an ideal solution?

Q No.7.
(i) What do you understand by entropy? In what way the total entropy change is related to spontaneity of a system and
to a system in equilibrium.
(ii) Entropy change from liquid water to steam at 373 K is 109J mol−1 K-1. What the enthalpy change for the transition of
liquid water to steam at 373 K?
(iii) Define Gibbs free energy function. Explain its significance.
(iv) Explain following:
(a) Ion selective electrode
(b) Quantum yield
(c) Fuel Cell
(d) Langmuir isotherm

Q No.8.
(i) Why is chlorination not the most desirable method of disinfecting polluted water?
(ii) What are anthropogenic pollutants? Give two examples each of primary and secondary pollutants.
(iii) What are the effects of detergents on fresh water bodies?
(iv) Calculate the pH of 0.001 M HCl solution.
(v) How Global Warming is caused? List and explain four consequences of green house effect.

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CSS Past Papers CHEMISTRY (I & II)
Chemistry Paper II
Part II
Q No.2.
a. What is the difference between Valence Bond Theory and Molecular Orbital Theory? (8)
b. Draw the Molecular orbital Diagram of CO molecule showing sigma, pi bonding, non-bonding and anti
bonding molecular orbital. (8)
c. Discuss the difference between the Hybridization of SO2 and SO3. (4)

Q No.3.
a. Discuss the rate law of SN1 mechanism. (6)
b. What is the importance of half life in the determination of order of reaction? (6)
c. What is the pseudo first order reaction? What is its importance? (8)

Q. No. 4
a. Describe the difference between physical adsorption and chemiadsorplion. (8)
b. The data of Langmuir for the adsorption of Nitrogen and mica at 90 K given

Estimate the surface area of the mica sample in the Langnuir experiment? (8)
c. Define Homogeneous catalyst & Heterogeneous catalyst. (4)

Q. No. 5
a. Discuss stereo isomerism in compounds having 2 similar asymmetric carbon atoms. (6)
b. Draw Fischer projection formulae of the following compounds. (8)
i) R & S 2 - Bromopentane
ii) R & S 3 - chloro-1-pentane.
iii) R & S 3-chloro-3-methylocatne
iv) R & S 2-pentanol
c. What do you understand by the terms Z & E isomers? Illustrate your answer with example. (6)

Q. No. 6
a. Discuss the structure of Grignard Reagent. (4)
b. How these compounds can be prepared by Grignard Reagent? (12)
i) Ethane
ii) Acetic Acid
iii) 2-Butanol
c. What is the diazotization reaction? (4)

Q. No. 7
How would you prepare the following compounds from Benzene? Name each reaction as well. (20)
i) Acetophenone
ii) Bromobenzene
iii) Maleic anhydride
iv) Toluene
v) Benzaldehyde

Q. No. 8
a. Write main steps in the formation of following polymers: (3+3)
i) Nylon 6,6 and polyester by condensation polymerization
ii) Polyethlene by Free Radical polymerization
b. Differentiate between oil, fat & wax with examples. (9)
c. What are alkaloids? (5

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CSS Past Papers CHEMISTRY (I & II)

CHEMISTRY PAPER - I
CE-2013

PART-I ((MCQs) (COMPULSORY)

Q.1. (i) Select the best option/answer and fill in the appropriate Circle on the OMR Answer Sheet. (20x1=20)
(ii) Answers given anywhere, other than OMR Answer Sheet, shall not be considered.

1. What happens when Al dissolves in aqueous NaOH?

(a) Forms soluble NaAl(OH) 4 (b) Forms Al2 O3 (c) Precipitates of Al(OH) 3
(d) Precipitates [Al(OH2 ) 6 ] 3+ forms which then loses H+ (e) None of these

2. The magnetic moment of the fluoride complex is expected to be:

(a) The same as the magnetic moment of the cyanide complex.
(b) Larger than the magnetic moment of the cyanide complex because there are more unpaired
electrons in the fluoride complex.
(c) Smaller than the magnetic moment of the cyanide complex because there are more unpaired electrons in
the fluoride complex.
(d) Larger than the magnetic moment of the cyanide complex because there are fewer unpaired electrons in
the fluoride complex.
(e) None of these

3. When solid CoCl2 is dissolved in water, a pink solution results and the following equilibrium is established:

Which one of the following best describes what will happen when a concentrated HCl is added to the CoCl2
solution without changing the volume significantly?
(a) Because a solution of HCl is colorless, the color of the CoCl2 solution will not change.
(b) Because HCl is a strong acid, the number of unpaired electrons in [Co(H2O)6]2+, but not [CoCl4]2+, will
change.
(c) The concentration of [Co(H2O)6]2+ will decrease and the concentration of [CoCl4]2- will increase; the
color of the solution will become more blue.
(d) The concentration of [Co(H2O)6]2+ will increase and the concentration of [CoCl4]2- will decrease; the
color of the solution will become more pink.
(e) None of these

4. Passage of electric current through the metals is due to:

(a) Oxidation reaction (b) Reduction reaction (c) Electrolysis
(d) Free movement of electrons (e) None of these

5. VBT is unable to explain the nature of some of the complexes of:

(a) Cobalt (b) Copper (c) Nickel
(d) Manganese (e) None of these

6. Energy available to do work at constant________ and _________ is known as Gibb’s free energy.
(a) Pressure, temperature (b) Pressure, volume (c) Temperature, volume
(d) All of these (e) None of these
7. A spontaneous reaction is not possible if:
(a) ΔH and TΔS are both negative (b) ΔH and TΔS are Positive
(c) ΔH is positive and TΔS is negative (d) ΔH is negative and TΔS is Positive (e) None of these

8. Which is not true about thermodynamics?

(a) It ignores the internal structure of atoms and molecule. (b) It involves the matter in bulk.
(c) It is concerned only with the initial and final states of the system.
(d) It is not applicable to macroscopic system. (e) None of these

9. The zero point energy of a particle is 1-D box of dimension 6A0 is:
(a) 10-22J (b) 10-2J (c) 16.22 x 10-20J
(d) 1022J (e) None of these

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10. The salt bridge in the electrochemical cell serves to:

(a) Increase the rate at which equilibrium is attained. (b) Increase the voltage of the cell.
(c) Maintain electrical neutrality (d) Increase the oxidation/reduction rate.
(e) None of these
11.

(a) Gibbs’s Helmohtz equation (b) Kirchoff’s equation (c) Clapeyron equation
(d) Clausius Clapeyron equation (e) None of these

12. The hydrogen molecule may be represented by two wave functions, Ψcovalent and Ψionic and C1 and C2
are coefficient indicating the weight of each function. The real wave function may be written as (N is the
normalization constant)
(a) Ψ= N [Ψcovalent + Ψionic] (b) Ψ= N [C1 Ψcovalent + C2 Ψionic]
(c) Ψ= N [C1 Ψcovalent x C2 Ψionic] (d) Ψ= (C1 + C2 ) N [Ψcovalent x C2 Ψionic]
(e) None of these

13. Copper metal will replace silver ions in solution, resulting in the production of silver metal and copper ions.
This indicates that:
(a) Silver has a higher oxidation potential than copper. (b) A combustion reaction is occurring.
(c) Copper has a higher oxidation potential than silver. (d) Silver is much less soluble than copper.
(e) None of these

14. According to Debye-Huckel theory of strong electrolytes, and ion moving in an atmosphere of oppositely
charged ions experiences a drag. This effect is known as the:
(a) Asymmetric effect (b) Electrophoretic effect (c) Inter-ionic effect
(d)Concentration effect (e) None of these

15. The electrical conductivity of an electrolyte depends upon:

(a) The number of molecules in the electrolyte. (b) The number of ions present in the electrolyte.
(c) The number of ions present in the solution . (d) The number of molecules of the solvent.
(e) None of these

16. Brass is an alloy of:

(a) Cu and Zn (b) Cu, Ni, Zn (c) Cu and Ni
(d) Cu, Al, Zn (e) None of these

17. Urea is a high quality nitrogenous fertilizer with:

(a) 76% nitrogen (b) 46% nitrogen (c) 66% nitrogen
(d) 26% nitrogen (e) None of these

18. When Zn metal is kept in CuSO4 solution, copper is precipitated and ZnSO4 is formed because:
(a) Atomic number of Zinc is smaller than copper.
(b) Atomic number of Zinc is larger than copper.
(c) Standard reduction potential of Zinc is more than that of copper.
(d) Standard reduction potential of Zinc is less than that of copper.
(e) None of these
19. The most important ore of aluminium is:
(a) Bauxite (b) Magnetite (c) Haematite
(d) Monazite (e) None of these
20. The inexpensive and commonly used variety of glass is called soda glass. It is called so because:
(a) Was used initially for making bottles of soda (carbonated drink).
(b) Is made using soda (sodium carbonate)
(c) Was initially used for storing sodium carbonate.
(d) Is made using soda lime.
(e) None of these
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CSS Past Papers CHEMISTRY (I & II)

Q.2.
(a). What is engineering ceramics? Describe the raw materials used in making classic ceramic products. (08)
(b). How urea is manufactured on commercial scale, support with a schematic diagram. (08)
(c). In what respect does inner orbital complexes differ from an outer orbital complexes? (04)

Q.3.
(a). Describe the oxyacids of chlorine. (06)
(b). Describe what is meant by silane and silanol. What is their role in preparation of Silicons. (06)
(c). Define the following types of Processes: (08)
(i) Isothermal (ii) Adiabatic (iii) Isochoric (iv) Isobaric

Q.4.
(a). How CFT and MOT account for the fact that [CoF6]3- is paramagnetic but [Co(NH3)6]3+ is diamagnetic? (06)
(b). Discuss crystal field splitting in complexes having different geometries? (08)
(c). What are the raw materials for the production of calcium superphosphate and cement? (06)

Q.5.
(a). Derive Schrodinger wave equation and calculate the energy of the particle in one dimensional box having
length α. (14)
(b). What are the hazardous effects of acid rain and global warming on plants? (06)

Q.6.
(a). How Debye-Huckel theory is applied to determine activity and activity coefficients for strong electrolytes?
Derive its mathematical form. (12)
(b). How standard electrode potential is measured? (086
(c). What is de Broglie hypothesis? (02)

Q.7.
(a). How chorine is produced on industrial scale? (08)
(b). How Werner’s Theory explains the structure of coordination compounds? (08)
(c). Why the Ozone Layer exists at a certain altitude in Stratosphere? (04)

Q.8.
(a). Give the applications of chelates in biological and analytical systems. (04)
(b). What are the advantages of semi conductive devices? (04)
(c). Derive mathematical form of Clausius-Clapeyron equation. (12)

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CSS Past Papers CHEMISTRY (I & II)

Chemistry Paper - II 2013

Part-II
Q No. 2

(a) Why do we use the three p-orbitals (2Px, 2Py, 2Pz) alone to form the three equivalent hybrid Orbitals
on Carbon? (5)
(b) Give an example of an element that undergoes sp-hybridization in forming covalent bonds with other
elements. What is the value of angle between the bonds that result from s-sp overlap of atomic orbitals?
(5)

(c) What do you mean by kuminiscence? What are its types? (10)

Q No. 3 (a) The rate constant of a reaction is 1.2 x 10^-3 per second at 30 degree centigrade and 2.1 x
10^-3 at 40 degree centigrade. Calculate the energy of activation of the reaction. (10)
(b) What is E/Z system of configuration. Why it is preferred over cos/trans system of nomenclature in
alkenes? (10)

Q No. 4

(a) Arrange the following functional groups in increasing order of stability of carbocation? (CH3)3C+,
CH3+, CH3CH2+, CH=CH-CH2+, C6H5CH2+, (CH3)2CH+ (5)

(b) How can we prepare an aldehyde by following reactions. Gove atleast ONE representative example for
each of these reactions. (10)
(i) Oxidation of Primary and Secondary Alcohol (ii) Friedel Crafts Acylation
(III) Hydration of Alkynes (iv) Glycol Cleavage

(c) Draw the structure of the following componds: (5)

i benzyl alcohol ii 3-pentanol
iii 2,3-dihydroxyhexane iv 2-sulhydrylbutane
v 3-pentanethiol

Q No. 5
(a) What are drying oils. For what purpose they are used? (10)
(b) How can you differentiate between trans-unsaturated and cis-unsaturated fatty acids. Which are more
hazarduous to health? Explain with the help of example.(10)

Q No. 6
(a) Give atleast one representative example of the following reactions. (10)
i Termination Reaction ii Disproportionate Reaction
iii Addition Polymerization iv Friedel Crafts Alkylation
v Clasien Condensation

(b) What do you mean by gels? How are they classified? (10)

Q No. 7
(a) What are applications of colloids? (10)
(b) What are the applications of emulsions? Also give the harmdul effects of emulsions? (10)

Q No 8 Name the following structures:-

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CSS Past Papers CHEMISTRY (I & II)

CHEMISTRY - PAPER I (2015)

PART - II
Q. No. 2.
(a) What is Pauli’s Exclusion Principle? (5)
(b) Give the electronic configuration of Sodium. (5)
(c) What are Bohr’s postulates and how do they explain the hydrogen atom spectrum? (10) (20)

Q. No. 3.
(a) Define Heat of combustion. How is it experimentally determined? (10)
(b) For the combustion of 1 mole of benzene at 25°C, the heat of reaction at constant pressure is given by
(10)

Q. No. 4.
(a) Describe the manufacture of Phosphorus on a large scale. (5)
(b) Draw the figure of Nitrogen cycle in nature. (5)
(c) Compare the physical properties of three allotropic forms of Carbon. (10)

Q. No. 5.
(a) How is steel manufactured? Describe various chemical reactions taking place in the blast furnace. (10)
(b) Describe the electrolytic refining of Copper. (10)

Q. No. 6.
(a) What are fertilizers? Why are they needed? Describe various types of fertilizers and their uses. (10)
(b) Describe the processes of Urea manufacturing in Pakistan. (10)

Q. No. 7.
(a) What are transition metals? Discuss their characteristic features. (5)

(b) Draw molecular orbital diagrams of (10)

(c) What was Rutherford’s atomic model? (5)

Q. No. 8.
(a) What is Greenhouse Effect? How does it cause global warming of Earth? (10)
(b) What is meant by water pollution? Discuss various sources of water pollution. (10)

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CSS Past Papers CHEMISTRY (I & II)

CHEMISTRY - PAPER II (2015)

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CSS Past Papers CHEMISTRY (I & II)

FEDERAL PUBLIC SERVICE COMMISSION

COMPETITIVE EXAMINATION -2016
FOR RECRUITMENT TO POSTS IN BS-17
UNDER THE FEDERAL GOVERNMENT

CHEMISTRY
Time Allowed: Three Hours
Part-I (MCQs): Maximum 30 Minutes
Part-I (MCQs): Maximum Marks = 20
Part-II: Maximum Marks = 80

Q 2.
(a) What is Schrodniger wave equation? Discuss its importance in quantum chemistry. (6)
(b) Solve the Schrodniger wave equation for a particle in three-dimensional box and find the expression for the
energy and wave function. (8)
(c) What is a well-behaved function? What are the requirements of a physically acceptable wave function? (6)

Q.3
(a) What is Gibbs free energy? Discuss its significance in chemistry. (6)
(b) Give a brief account of transition state theory indicating its advantages over collision theory. (8)
(c) Explain 3rd law of thermodynamics. How this law is useful to determine the absolute value of entropy? (6)

Q.4
(a) Define and explain Langmuir adsorption isotherm. What are its limitations? (8)
(b) What is acid-base catalysis? Discuss its significance in chemistry. (6)
(c) What is Phase rule? Discuss its application in one component system. (6)

Q.5
(a) What are solubility product and common ion effect? Discuss their significance in chemical analysis. (8)
(b) Valence shell electron pair repulsion theory can be used to predict the shapes of molecules. Using this
theory explain the shapes acquired by BF3 and IF5. (7)
(c) Explain why HSH bond angle in H2S is slightly less than the tetrahedral angle 109.5. (5)

Q.6
(a) Describe main features of crystal field theory. How this theory explains colour of coordination complexes?
(10)
(b) Write the electronic configuration for each of the following: (4)
Ni2+, Cu, Mn2+, Cr3+
(c) What is John-Teller theorem? Explain its significance in coordination chemistry. (6)

Q.7
(a) What are lanthanides? How are these extracted from their ores? (10)
(b) What is decay law? How half-life and decay constant are related with each other? (5)
(c) What types of statistical tests are employed in chemical analysis? (5)

Q.8
(a) What is solvent extraction? Explain its underlying principle with suitable examples. (7)
(b) What is electrophoresis? How is this technique useful to separate proteins? (7)
(c) What is TLC? Write some advantages of TLC over paper chromatography? (6)

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CSS Past Papers CHEMISTRY (I & II)

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CSS Past Papers CHEMISTRY (I & II)

32
Sajid Mehsud
CSS Past Papers CHEMISTRY (I & II)

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Sajid Mehsud
CSS Past Papers CHEMISTRY (I & II)

FEDERAL PUBLIC SERVICE COMMISSION

COMPETITIVE EXAMINATION - 2017
FOR RECRUITMENT TO POST IN BS - 17
UNDER THE FEDERAL GOVERNMENT
CHEMISTRY, PAPER - I
TIME ALLOWED: THREE HOURS
PART - I (MCQs): MAXIMUM 30 MINUTES
PART - I (MCQs): MAXIMUM MARKS = 20
PART - II MAXIMUM MARKS = 80

NOTE:
(i) Part - II is to be attempted on the separate Answer Book.
(ii) Attempt ONLY FOUR questions from PART - II. ALL questions carry EQUAL marks.
(iii) All the parts (if any) of each Question must be attempted at one place instead of at different places.
(iv) Candidate must write Q. No. in the Answer Book in Accordance with Q. No. in the Q. Paper.
(v) No Page / Space be left blank between the answers. All the blank pages of Answer Book must be crossed.
(iv) Extra attempt of any question or any part of the attempted question will not be considered.

PART - II

Q. 2
(a) Derive Schrodinger wave equation for motion of a particle in one dimensional box. (10)
(b) Solve Schrodinger wave equation to find the expression for wave function energy of a particle in one dimensional
box. (6)
(c) What is Eigen function and Eigen value? Give examples. (4)

Q. 3
(a) Define heat capacities and molar heat capacities. Prove that Cp-Cv=R for ideal gases. (10)
(b) What is Gibbs energy? Derive a relation between standard Gibbs energy change and equilibrium constant. (6)
(c) Differentiate spontaneous and non spontaneous process. (4)

Q. 4
(a) State and explain Kohlrausch's law. Give its applications. (10)
(b) What is meant by standard deviation? Give its significance in analytical chemistry. (6)
(c) Briefly describe conductometric titrations. (4)

Q. 5
(a) Discuss the effect of temperature on rate of chemical reaction on the basis of Arrhenius equation. How can you
determine activation energy and pre-exponential factor for a chemical reaction using Arrhenius equation? (10)
(b) Derive kinetic equation for 1st order reaction. (6)
(c) Prove that half like period for 1st order reaction is independent of initial concentration of reactant. (4)

Q. 6
(a) What is adsorption isotherm? Derive Langmuir adsorption isotherm for adsorption of a gas on solid surface. (10)
(b) What is enzyme catalysis? Discuss its kinetics. (6)
(c) What are surfactants? Give their properties. (4)

Q. 7
(a) What is electrophoresis? Give its principle and discuss its applications in biochemistry. (10)
(b) Give six chemical properties of nitrogen. (6)
(c) What is Common ions effect? Give its applications. (4)

Q. 8
(a) State John-Teller theorem. Explain it using suitable examples from coordination complexes. (10)
(b) Give postulates of Werner's theory of coordination complexes. (6)
(c) Briefly describe nuclear decay rate law for disintegration of radioactive elements. (4)
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Sajid Mehsud
CSS Past Papers CHEMISTRY (I & II)

FEDERAL PUBLIC SERVICE COMMISSION

COMPETITIVE EXAMINATION - 2017
FOR RECRUITMENT TO POST IN BS - 17
UNDER THE FEDERAL GOVERNMENT

CHEMISTRY, PAPER - II
PART - II

Q. 2 Write brief notes on the following: (2 each) (20)

a.Covalent Bond b.Hybridization c.Isomerism d.Monosaccharides e.Triglycerides
f.Electronegativity g. Fertilizers h.The Inductive Effecth i Chemical Shift j.Stereoselectivity

Q. 3 (a) Give a method of synthesis of the following compounds from an appropriate alkene of your choice
with reagents. (12)

(b) Write the Major product for these Reactions. (8)

Q. 4 (a) What is aromaticity? Explain the Huckel criteria for aromaticity. (6)
(b) Write names of the following compounds. (4)

(c) Write the reaction and mechanism of Friedel Craft alkylation and acylation reaction. (10)
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CSS Past Papers CHEMISTRY (I & II)

Q. 5 (a) What is Grignard reagent? What are its applications? How would you prepare Grignard reagent
starting from an alkyl halide of your choice? (8)

(b) Give the product of the following reactions: (3)

(c) Give the IUPAC nomeclature of Aldehydes and Ketonese. (4)

(d) Give the major products of the following reactions. (5)

Q. 6 (a) What is stereoisomerism? Give an account of different types of stereoisomerism. (5)

(b) Assign an R or S configuration to the chiral center in each molecule. (9)

(c) In the following molecules identify that which are diastereomers and which are enantiomers? (6)

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CSS Past Papers CHEMISTRY (I & II)
Q. 7
(a) What is the difference between Dispersive IR Spectrometer and Fourier Transform (FT)-IR
Spectrometer. (5)

(b) Differentiate the following on the basis of IR. (3)

(c) Differentiate the following pairs of compounds on the basis of UV. (8)

(d) Deduce the structure of the product of the given reaction from the following data. (4)

*************************

Q. 8 Write notes on any FOUR of the following (5 each) (20)

(a) Reactions of Monosaccharides
(b) Biosynthesis of Cholesterol
(c) Primary structure of Polypeptides and Protein
(d) Prostaglandins
(e) Synthesis of Peptides

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