Data Sheet

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Safety data sheet

according to 1907/2006/EC, Article 31
333300
Revision: 26.05.2015
Printing date: 26.05.2015
01 Identification of the substance/mixture and of the company/undertaking

• Product identifier
• Trade name:
PFINDER 871 E
• Article number:
11871200
• Relevant identified uses of the substance or mixture and uses advised against
• Sector of Use
SU3 Industrial uses: Uses of substances as such or in preparations at
industrial sites
SU22 Professional uses: Public domain (administration, education,
entertainment, services, craftsmen)
• Application of the substance / the preparation
Developer for non-destructive testing
Solvent based developer for penetrant testing
• Details of the supplier of the safety data sheet

• Manufacturer/Supplier:
Pfinder KG
Rudolf-Diesel-Str. 14
D-71032 Böblingen
Tel.: +49 (0)7031 2701-0
Fax : +49 (0)7031 280500
• Further information obtainable from:

Research + Development
Tel: +49 (0)7031 2701-73
Fax: +49 (0)7031 2701-51
E-mail: ProductSafety@pfinder.de
• Emergency telephone number:
Vergiftungs-Informations-Zentrale
Universitätsklinikum Freiburg
Tel.: +49 (0)761 19240
02 Hazards identification
• Classification of the substance or mixture
• Classification according to Regulation (EC) No 1272/2008
GHS02
Flam. Liq. 2 - H225 Highly flammable liquid and vapour.
GHS07
Eye Irrit. 2 - H319 Causes serious eye irritation.

STOT SE 3 - H336 May cause drowsiness or dizziness.
• Classification according to Directive 67/548/EEC or Directive 1999/45/EC
F Highly flammable
Xi Irritant
R 11
Highly flammable.
R 36
Irritating to eyes.
R 66
Repeated exposure may cause skin dryness or cracking.
R 67
(Contd. on page 2)
GB
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Safety data sheet
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PRODUCT : PFINDER 871 E

(Contd. of page 1)
Vapours may cause drowsiness and dizziness.
• Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification
guideline for preparations of the EU" in the latest valid version.
At long or repeated contact with skin it may cause dermatitis due to the degreasing effect of the
solvent.
Product can accumulate static charges which can cause an incendiary electrical discharge.
In use, may form flammable/explosive vapour-air mixture.
• Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and
literature data.
• Label elements
• Labelling according to Regulation (EC) No 1272/2008
GHS02 GHS07
• Signal word
Danger
• Hazard-determining components of labelling:

acetone
• Hazard statements
H225 Highly flammable liquid and vapour.
H319-EUH066 Causes serious eye irritation. Repeated exposure may cause
skin dryness or cracking.
H336 May cause drowsiness or dizziness.
• Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P261 Avoid breathing mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves / eye protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin
with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P370+P378 In case of fire: Use for extinction: CO2, powder or water spray.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/ national/international
regulations.
• Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on
Hazardous Materials.
• Code letter and hazard designation of product:
F Highly flammable
Xi Irritant
• Risk phrases:
R 11 Highly flammable.
R 36 Irritating to eyes.
R 66 Repeated exposure may cause skin dryness or cracking.
R 67 Vapours may cause drowsiness and dizziness.
• Safety phrases:
S9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No smoking.
S 23e Do not breathe fumes/aerosol.
(Contd. on page 3)
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(Contd. of page 2)
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
S 33 Take precautionary measures against static discharges.
S 38 In case of insufficient ventilation, wear suitable respiratory equipment.
S 51 Use only in well-ventilated areas.
S 60 This material and its container must be disposed of as hazardous waste.
• Other hazards
• Results of PBT and vPvB assessment
• PBT:
Not applicable.
• vPvB:
Not applicable.
03 Composition/information on ingredients
• Chemical characterization: Mixtures
• Description:
Solvent mixture with pigment additives
• Dangerous components:
CAS NO. Description Index R-phrases %
67-64-1 acetone 50,0 - <75,0
EC number: 200-662-2
Record number 01-2119471330-49
F Xi
11-36-66-67
Flam. Liq. 2 - H225; Eye Irrit.
2 - H319-EUH066, STOT SE 3 - H336
64-17-5 ethanol 12,5- <20,0
F
11
Flam. Liq. 2 - H225
107-98-2 1-methoxy-2-propanol 1,0 - <2,5
Record number 01-2119457435-35
10-67
Flam. Liq. 3 - H226; STOT SE 3 -
H336
• Additional information:
For the wording of the listed risk phrases refer to section 16.
04 First aid measures

• Description of first aid measures
• General information:
Immediately remove any clothing soiled by the product.
Take affected persons out into the fresh air.
Take affected persons out of danger area and lay down.
• After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if
symptoms persist.
In case of unconsciousness place patient stably in side position for transportation.
• After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
(Contd. on page 4)
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(Contd. of page 3)
• After eye contact:
Rinse opened eye for several minutes under running water. Then consult a doctor.
• After swallowing:
Do not induce vomiting; call for medical help immediately.
• Information for doctor:
If swallowed or in the event of vomitting may cause aspiration into the lungs which can be fatal.
• Most important symptoms and effects, both acute and delayed
Headache
Dizziness
Vertigo
• Indication of any immediate medical attention and special treatment needed
Medical supervision for at least 48 hours.
Treat symptoms.
05 Firefighting measures
• Extinguishing media
• Suitable extinguishing agents:
Foam, dry powder, carbon dioxide, water spray jet
• For safety reasons unsuitable extinguishing agents:
Water with full jet
• Special hazards arising from the substance or mixture
Can form explosive gas-air mixtures.
Fire gas of organic material has to be classed invariably as respiratory poison.
Vapours are heavier than air and spread on ground.
Vapours spread along the ground and distant ignition is possible.
Containers: Effect of heat may cause rise of pressure -danger of bursting
Product possibly swims up on surface and reinflames.
• Advice for firefighters
• Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
• Additional information
Cool endangered receptacles with water spray.
Collect contaminated fire fighting water separately. It must not enter the sewage system.
As possible remove the container from the source of fire.
Avoid afflux of combustible material.
06 Accidental release measures

• Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources.
Use respiratory protective device against the effects of fumes/dust/ aerosol.
Take precautionary measures against static discharges (earthing (grounding) of equipment / fittings.
• Environmental precautions:
Inform respective authorities in case of seepage into water course or sewage system.
In case of seepage into the ground inform responsible authorities.
Do not allow to enter sewers/ surface or ground water.
Do not allow to penetrate the ground/soil.
Send in suitable containers for recovery or disposal.
• Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
Dispose of the material collected according to regulations.
Embank large quantities and pump with an ex-proof apparatus in containers.
• Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
GB
(Contd. on page 5)
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(Contd. of page 4)
07 Handling and storage
• Handling:
• Precautions for safe handling
Keep away from heat and direct sunlight.
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Avoid splashes or spray in enclosed areas.
Use solvent-proof equipment.
Use only in well ventilated areas.
Ensure good interior ventilation, especially at floor level. (Fumes are heavier than air).
Tightly reclose container after each use.
Keep away from sources of ignition - No smoking
Avoid contact with eyes and skin.
• Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Do not spray onto a naked flame or any incandescent material.
Use explosion-proof apparatus / fittings and spark-proof tools.
Handle only outside or in explosion protected rooms.
Emergency cooling must be available in case of nearby fire.
Highly volatile, flammable constituents are released during processing.
Fumes can combine with air to form an explosive mixture.
Danger of explosion if fluid enters the sewage system.
Flammable gas-air mixtures may form in empty receptacles.
The vapours of product are heavier than air. The heavy vapours may bridge a long distance to source
of ignition.
• Conditions for safe storage, including any incompatibilities

• Storage:
• Requirements to be met by storerooms and receptacles:
Store in a cool location.
Provide solvent resistant, sealed floor.
Prevent any seepage into the ground.
• Information about storage in one common storage facility:
Do not store together with acids.
Do not store together with alkalis (caustic solutions).
Store away from foodstuffs.
Store away from oxidizing agents.
• Further information about storage conditions:
Store in cool, dry conditions in well sealed receptacles.
Protect from heat and direct sunlight.
Store receptacle in a well ventilated area.
• Specific end use(s)
No further relevant information available.
08 Exposure controls/personal protection
• Control parameters
• Ingredients with limit values that require monitoring at the workplace:
CAS No. Designation of material
67-64-1 acetone
WEL
Short-term value 3620 mg/m3
1500 ppm
Long-term value 1210 mg/m3
500 ppm
64-17-5 ethanol
(Contd. on page 6)
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(Contd. of page 5)
WEL
1000 ppm
107-98-2 1-methoxy-2-propanol
WEL
Short-term value 560 mg/m3
150 ppm
100 ppm
Sk
• DNELs
67-64-1 acetone
Dermal, DNEL: 186 mg/kg/d (worker)
Inhalative, DNEL: 1210 mg/m³/d (worker)
Dermal, DNEL: 50,6 mg/kg/d (worker) (langfristig, systemisch)
Inhalative, DNEL: 369 mg/m³/d (worker) (langfristig, systemisch)
• PNECs
67-64-1 acetone
Fresh water, PNEC: 10,6 mg/l
Freshwater sediment, PNEC: 30,04 mg/kg
Seawater, PNEC: 1,06 mg/l
Seawater sediment, PNEC: 3,04 mg/kg
Soil, PNEC: 29,05 mg/kg
Sewage treatment plant, PNEC: 100 mg/l
Makeup water, PNEC: 10 mg/l
Freshwater sediment, PNEC: 41,6 mg/kg
Seawater, PNEC: 1 mg/l
Seawater sediment, PNEC: 4,17 mg/kg
Soil, PNEC: 2,47 mg/kg
Sewage treatment plant, PNEC: 100 mg/l
The lists valid during the making were used as basis.
• Exposure controls
• Personal protective equipment:
• General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Do not inhale gases / fumes / aerosols.
Avoid contact with the eyes.
Do not eat, drink, smoke or sniff while working.
Use skin protection cream for skin protection.
Be sure to clean skin thoroughly after work and before breaks.
Do not carry product impregnated cleaning cloths in trouser pockets.
• Respiratory protection:
Breathing apparatus in the event of aerosol or mist formation
Use suitable respiratory protective device in case of insufficient ventilation.
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer
exposure use self-contained respiratory protective device.
Combined filter: Particle-filtering half mask (filter P2 or P3) and gas filter type AX
• Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
Solvent resistant gloves
• Material of gloves
(Contd. on page 7)
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(Contd. of page 6)
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to
be checked prior to the application.
Butyl rubber, BR
Natural rubber, NR
Recommended thickness of the material: >= 0,7 mm
Nitrile rubber, NBR
Gloves of butyl rubber (thickness 0,5 mm; permeation time at least 8 h)
• Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and
has to be observed.
• Eye protection:
Tightly sealed goggles
• Body protection:
Protective work clothing
09 Physical and chemical properties

Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Colour: White
Odour: Characteristic
Odour threshold: Not determined.
pH-value: Not determined.
Change in condition
Boiling point/Boiling range: 56,00 - 78,00 °C
Flash point: >= -20,0 °C
Flammability (solid, gaseous): Not applicable.
Ignition temperature: > 400,00 °C
Self-igniting: Not determined.
Danger of explosion: Product is not explosive. However, formation of explosive air/vapour
mixtures are possible.
Explosion limits:
Lower: 2,00 Vol %
Upper: 15,00 Vol %
Vapour pressure: at 20,00 °C 240,0000 hPa
Density: 0,8700 g/cm3 15°C
Solubility in / Miscibility with
water: Partly miscible.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
Organic solvents: ca. 82 %
VOC (EC) ca. 82 %
Solids content: ca. 18 %
Other information No further relevant information available.
GB
(Contd. on page 8)
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(Contd. of page 7)
10 Stability and reactivity
• Reactivity
• Chemical stability
• Thermal decomposition / conditions to be avoided:
Flames, sparks, heat.
• Possibility of hazardous reactions
No dangerous reactions known.
• Conditions to avoid
• Incompatible materials:
Strong oxidizing agents
Reacts with acids under formation of carbon dioxide (CO2).
• Dangerous reactions
Forms explosive gas mixture with air.
• Hazardous decomposition products:
Flammable gases/vapours
Carbon dioxide
11 Toxicological information
• Information on toxicological effects
• Acute toxicity:
• LD/LC50 values relevant for classification:
67-64-1 acetone
Oral, LD50: 5800 mg/kg (rat)
Dermal, LD50: 20000 mg/kg (Rabbit)
Inhalative, LC50/4h: 76 mg/l (rat)
64-17-5 ethanol
Dermal, LD50: 13000 mg/kg (Rabbit)
• Primary irritant effect:
• on the skin:
Frequent resp. persistent skin contact may degrease skin, what may cause skin complaints and
dermatitis.
• on the eye:
Irritating effect.
• Sensitization:
No sensitizing effects known.
• Additional toxicological information:
Irritant
The risk assessment of the preparation concerning adverse health effects is based on the available
data.
After inhalation of vapors: irritations of mucous membranes, drowsiness; in high doses: head aches,
nausea, vomiting, dizziness, narcosis
12 Ecological information
• Toxicity
• Aquatic toxicity:
• Persistence and degradability
• Behaviour in environmental systems:
• Bioaccumulative potential
(Contd. on page 9)
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(Contd. of page 8)
• Mobility in soil
• Additional ecological information:
• General notes:
Do not allow product to reach ground water, water course or sewage system.
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
• Results of PBT and vPvB assessment
• PBT:
Not applicable.
• vPvB:
Not applicable.
• Other adverse effects
13 Disposal considerations
• Waste treatment methods
• Recommendation
After prior treatment product has to be landfilled or incinerated adhering to the regulations pertaining
to the disposal of especially hazardous waste.
• Waste disposal key:
The waste key number has to be specified acc. European Waste Catalogue (depending on branches
and processes).
• Uncleaned packaging:
• Recommendation:
Also empty containers are still contaminated and have to be disposed by specialists or must be
subjected to recondition. Waste key number: 150110 (EAK)
14 Transport information
• UN-Number
ADR UN1993
IMDG UN1993
IATA UN1993
• UN proper shipping name
ADR 1993 FLAMMABLE LIQUID, N.O.S. (ACETONE,
ETHANOL (ETHYL ALCOHOL)), SPECIAL PROVISION
640D
IMDG FLAMMABLE LIQUID, N.O.S. (ACETONE, ETHANOL
(ETHYL ALCOHOL))
IATA FLAMMABLE LIQUID, N.O.S. (ACETONE, ETHANOL
(ETHYL ALCOHOL))
• Transport hazard class(es)
ADR
Class 3 (F1) Flammable liquids.
Label 3
IMDG
Class 3 Flammable liquids.
(Contd. on page 10)
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(Contd. of page 9)
Label 3
IATA
Class 3 Flammable liquids.
Label 3
• Packing group
ADR II
IMDG II
IATA II
• Environmental hazards:
Not applicable.
• Special precautions for user
Warning: Flammable liquids.
Danger code (Kemler): 33
EMS Number: F-E,S-E
• Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
• Transport/Additional information:
Not applicable.
Excepted quantities (EQ): E2
Limited quantities (LQ) 1L
Transport category 2
Tunnel restriction code D/E
• UN "Model Regulation":
UN 1993 FLAMMABLE LIQUID, N.O.S. (ACETONE, ETHANOL (ETHYL ALCOHOL)),
3, II
15 Regulatory information
• Safety, health and environmental regulations/legislation specific for the substance or
mixture
• National regulations:
• Information about limitation of use:

Employment restrictions concerning juveniles must be observed.
• Chemical safety assessment:
A Chemical Safety Assessment has not been carried out for the mixture.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for
any specific product features and shall not establish a legally valid contractual relationship.
• Relevant phrases
EUH066 Repeated exposure may cause skin dryness or cracking.
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
(Contd. on page 11)
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(Contd. of page 10)
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
R 10 Flammable.
R 11 Highly flammable.
R 36 Irritating to eyes.
R 66 Repeated exposure may cause skin dryness or cracking.
R 67 Vapours may cause drowsiness and dizziness.
• Training hints
BGI 621: Leaflet "Solvent" (ZH 1/319), (M 017)
BGI 660: Leaflet "General protection measurements for hazardous materials handling" (M 053)
BGR 190 - Rules for the use of respiratory protection (ZH 1/701)
BGR 195 - Rules for the use of protective gloves (ZH 1/706)
BGI 595: Leaflet "Reizende Stoffe - Ätzende Stoffe / Irriating substances - Corrosive substances" (M
004)
• Department issuing MSDS:

Research+Development, Product Safety
• Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European
Agreement concerning the International Carriage of Dangerous Goods by Road)
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de
fer (Regulations Concerning the International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
VCI: Verband der chemischen Industrie, Deutschland (German chemical industry association)
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent

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Page: 1 / 11

Safety data sheet

01 Identification of the substance/mixture and of the company/undertaking

• Details of the supplier of the safety data sheet

• Further information obtainable from:

Flam. Liq. 2 - H225 Highly flammable liquid and vapour.

Eye Irrit. 2 - H319 Causes serious eye irritation.

PRODUCT : PFINDER 871 E

• Hazard-determining components of labelling:

• Code letter and hazard designation of product:

PRODUCT : PFINDER 871 E

04 First aid measures

PRODUCT : PFINDER 871 E

06 Accidental release measures

PRODUCT : PFINDER 871 E

• Conditions for safe storage, including any incompatibilities

08 Exposure controls/personal protection

PRODUCT : PFINDER 871 E

PRODUCT : PFINDER 871 E

09 Physical and chemical properties

PRODUCT : PFINDER 871 E

PRODUCT : PFINDER 871 E

PRODUCT : PFINDER 871 E

• Information about limitation of use:

PRODUCT : PFINDER 871 E

• Department issuing MSDS:

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