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Granville Delahaye
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Contents
B) (i) A)
0.0546
2
Halide Reaction Observation
K eq =
0.0389 0.0111 Products
=6.90
NaCl (i) Misty fumes
Equilibrium attained HCl
(ii)
C) Cl2(g)+2NaOH(aq) NaCl(aq) +
NaClO(aq) + H2O(l) Average PO 43
Solution to Question 3:
(iii) [PO43-] within
A) (i)
acceptable limits
(organic phosphate)
pesticides
Solution to Question 4:
fertilizer
A) Buffer solution - regulates pH by
detergents
responding to small additions of
acid or alkali.
C) (i) a. (ii)
Equilibrium shifts to
K CH COOH
produce H2CO3 H + = a 3
CH COO-
3
H2CO3 dissociates to
1.75×10 ×0.025
-5
+
=
increase H concent- 0.010
=4.4×10-5 mol dm -3
ration in the blood or
lower pH of blood . pH=-log H +
b.
=-log 4.4×10-5
=4.4
Deep rapid breath-
ing, clean lungs of
CO2 or decrease CO2
concentration.
Equilibrium will shift
to the left to release
CO2 from blood or
n
Solution to Question 5:
6×10-3 k× 2×10
-3
=
3×10-3 k× 1×10-3
n
A) (i) a. Using expts (4) and (5)
or any combination 2=2n
n 1 1st order
Doubling of [R - X]
B) Overall order m + n =2
doubling of rate
Rate equation
1:1 proportionality
1st order Rate = K [R - X] [NaOH]
OR
1×10 -3
0.5×10 -3
C) Using expt. (1) or any other expt
K=
3 10 5 10
3
2
6 10 6
2=2 m
Units dm3 mol-1 s-1
m=1
Doubling of [NaOH]
doubling of rate
OR
B) (i) Basic
Higher concentrations
(ii) Atmospheric
Number of collisions per unit
time increases
C) (i) Na2O(s) + H2O(l)
Probability of favorable coll-
2NaOH(aq)
isions increases
Rate increases (ii) SiCl4(l) + 4H2O(l) Si
(OH)4(s) +4HCl(aq)
Number of molecules with
K.E Ea (iii) PCl5(s) + 4 H2O (l)
H3PO4(aq) + 5HCl(aq)
Increased surface results in
2H 2S(g) + 3O2(g) D)
2H2O(l)+ 2SO2(g) Chose proximity for raw
(1 for equation, 1 for materials.
balancing) Port/ deep harbour facilities.
Good infrastructure e.g.
roads.
(ii) Both NO2 and SO2 will
Isolation from residential
form acid rain. Acid rain
areas.
destroys buildings and
Power supply
problems.
Takes part in the
formation of photo-
chemical smog.
Destroys materials such
as rubber.
Destroys vegetation
Destroys organic matter
Solution to Question 1: B)
A) Reagent Condition
A → B bromine/ Br2 UV
light/heat
C → A hydrogen/ H2 Pd/ Ni
catalyst
Mechanism C)
1o 2o 3o
A → B free radical
OBS Given Colour No
substitution change change
( from
C→A
orange
to
C → B electrophilic addition
green)
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Solution to Question 2: b.
(iii) a.
Solution to Question 3:
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Solution to Question 4:
Alkene
Ester
Ketone
Phenyl
(ii)
Reagent Functional Change
Group Solution to Question 5:
HCN A) Principles
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B) Solution to Question 6:
20 B) (iii)
( ) x 100 = 80%
25 Increase in pressure
(200 atm).
D) Pure water is obtained and the Moderate temper-
azeotrope. ature (400 -500℃) .
E) Use of catalyst (Fe +
Rum Fe2O3 + other metals)
Perfume High pressure - gives
Petroleum high yield as equilibrium
shifts to the right.
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(ii)
Wear helmets, masks,
protective clothing
Observe all clearly
marked safety signs
Mark hazardous
materials clearly
Exit signs should be
clearly marked
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Solution to Question 1:
A) (i) b.
Lone pair on phen-
ylamine is deloca-
lized into 𝜋 system of
benzene ring.
decreases availability
of lone pair to accept
(ii) Condition for Stage I: 55 proton.
-60°C Greater hydrogen
(iii) Reagent for Stage II: Sn/HCl bonding of ammon-
or Fe/HCl ium ion with water
provides great stabi-
B) (i) lity.
C) (i)
(Cl- is optional)
(ii) a. Phenylamine is less basic
than ammonia.
(ii) Reagent: HCl + NaNO2
(or KNO2) OR HNO2/
HCl
Condition: < 5℃
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angement of atoms/
groups in molecule.
b. Chiral centre
Optical isomerism
c. pH=7
(iii)
B) (i) Condensation
(iv) a. Ph=2
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Stretching
Bending
(iii) Steps
OR
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Water is decomposed to
D) (i) Disadvantages
produce hydrogen by reduction
Partially hydrolysed (electron gain)
product 2H2O(l) + 2e- H2(g) +
Difficulties in 2OH-(aq)
removing all the
water
Yield will be lower Sodium Hydroxide
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B)
Insecticides
Bleaches/ disinfectants
Antiseptics
Weedkillers
Chlorinated organic compo-
unds/ solvents
C)
SO2 is a reducing agent
which prevents oxidation of
the product, thus retarding
food spoilage.
Disadvantage – distorts the
taste of the food.
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(IV)
(ii)
present.
C) (ii) Polymer – a large
D) Amino acid
molecule made up of
many identical rep-
eating subunits called
Monomers.
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B) (i) 1 x 10-5
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NO3-
Acidified FeSO4 + conc.
H2 SO4 to yield brown
ring at junction (or
interface)
Cu or Zn with NaOH rel-
eases NH3 with boiling.
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Solution to Question 5: C)
A)
(75.77×34.97)+(24.23×36.96)
Determination of relative is- =35.45
100
otopic masses and relative
isotopic abundance.
Distinguish between molec- D) Two uses of chromatography:
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E)
Pollutant Possible Polluting Effect
Source
-
(NO3) Fertilisers - Eutrophication
Synthetic / algal bloom
detergents - Reduction in
Untreated O2 for marine
sewer waste life
or BOD
3-
(PO4) Fertilisers Eutrophication /
Synthetic algal bloom
detergents
Untreated
sewer waste
2+
Pb (aq) Water - Cumulative
pipes, paint, poison affects
lead gut
batteries and nervous
(any system.
relevant - Can be
source) carcinogenic
and
teratogenic
- Brain damage
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precise hydrocarbons.
Heating separate compon-
3 – neither precise nor
ents according to volatility
accurate
(b.pts).
4 – both accurate and
Components are collected by
precise
use of a fractionating tower
D) (more volatile collected first).
Weigh a (clean, dry, empty)
beaker on an analytical bal-
B) Cracking: the breaking up of
ance.
large molecules into smaller
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E) (i) A : Yeast
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C) Ozone formation:
D)
Dissociation of oxygen into
Determining amount of glu-
atoms by UV radiation
cose in blood
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Ozone breakdown:
O3(g)
hv
O2(g) + O(g)
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Solution to Question 2:
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Electrophilic Addition
B) (i)
[ester(toluene)]eqm
=r
[ester(water)]eqm
B) Compound A does not exhibit
(partition coefficient)
transisomerism.
C)
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(ii) (iv)
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Solution to Question 1:
A) (i) B) (i) a. Yellow/orange ppt is
formed.
b. KMnO4 decolourized.
c. Z is an aldehyde.
d. Z is an aromatic
aldehyde. Or Z is not a
(ii)
reducing sugar..
B) (ii)
(iii) a. P – saponification
b. Q – transesterification
C)
(iv) a. P – soap
b. Q – biodiesel fuel
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B) OH at 3400 cm-1
at 1715 cm-1
(ii) They are ideal because
OH at 3400cm-3
NaCl is transparent to
infrared radiation.
(ii) a. B: 2 – propanol
b. OH at 3350 cm-1
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Concentration water
B) Using k
Concentration either
(iii) Electrophilic Substitution
0.854
∴ 10 5.36 = k
(iv) NO2 is a meta director so 0.159
it directs the substitute- 10
nts to the meta position. Let mass found in water = x g
x
C) (i) Nitrobenvene< benzene< 10 5.36
1 x
methylbenzene 10
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D) NaAl(OH)4 (aq) →
Liquid of composition x NaOH(aq) + Al(OH)3 (s)
heated produce vapour.
2Al (OH)3 (g) → Al2O3 (s) +
Composition a1.
3H2O(g)
Vapour on condensing pro-
duce liquid composition x1.
Liquid has greater conce- B) (i) Red mud (sodium hyd-
ntration of A than B. roxide residue)
Repeated vapourization and (ii)
condensation produce liquid
Harms flora and
A (ditillate).
fauna
Disfigures the envir-
Solution to Question 6: onment
A) Removes valuable
land space from
Ore is crushed and treated
agricultural produc-
with NaOH
Mixture is filtered tion or housing.
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Large quantity of
energy needed
Need to replace
carbon anodes
Degree of purity of
metal
b. Recycling reduces:
Exploitation of
resources
Environmental
scarring
Energy demands
Pollution effects
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B) (i)
RNH 3+ OH -
Kb
RNH 2
(ii) Ethylamine
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D – Condensation /
cooling
Positional Isomerism
(ii) Finely divided iron
(iii)
(iii) Liquid
Solution to Question 4:
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C) (i) 88
D) (i) Creamy yellow preci-
(ii) 43
pitate formed.
Solution to Question 5:
D)
A) (i) Electron beam – bom-
bards molecules, prod-
ucing molecules, ions
and fragments.
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Solution to Question 1:
(ii) Bromine with propane in
A) (i) Cracking
sunlight.
(ii) Vapour passed over cat-
alyst/ Thermal crack
ing Al2O3/SiO2 at 450oC. Propagation:
high temperature (grea-
ter than 600oC).
C: propene, CH3CH=CH2/
CH3CHCH2
B) (i)
There is the unpair-
ing of 2s2 electrons
and one electron en-
ters the empty P orb-
ital.
The four orbitals are
hybridised to give 4 Two steps are required
sp3 orbitals. in the propagation stage,
if two steps are present
and no fish hook arrow.
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Termination: Br Br Br : Br
OR
OR
Bromine with propene
(without sunlight)
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(ii) Precision:
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0.05 1000
1000 cm3 contain
24.5
=2.04 M HCl
Solution to Question 3:
D) A)
25 cm3 NaOH added to a Increased pressure/ conc. Of
polystyrene cup using a reactants.
pipette. Decreased temperature
(Solution allowed standing Use of catalyst
for few minutes) and temp-
erature noted.
5 cm3 portions of acid added
from burette, mixture stirred
and temperature noted.
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(iii)
Solution to Question 4:
The sulphur trioxide
A) Additional polymerisation invo-
is dissolved into
lves the linking of one type of
conc. Sulphuric acid
monomer with double or triple
to form oleum.
bonds to give the polymer as the
The oleum is diluted
only product.
with water to form
Condensation polymerisation
conc. Sulphuric acid.
involves the linking of two types
of monomers OR monomers
(iv)
H2SO4(l) + SO3(g) with bifunctional group (two
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B) Carboydrates/ Polysaccharides
Proteins
E,g., glycogen, cellulose, starch, giving
pectin, albumin, keratin, monomers:
collagen.
C)
Solution to Question 5:
A)
Chromatography involves
the separation of compo-
D) The link between the two nents of a mixture between
two phases.
monomers is Involves the partitioning of
components between a
because one end of unit is stationary phase and a
mobile phase.
and the other end is . The Partitioning occurs because
remaining part of repeating unit the components of the
mixture will experience
different absorption forces
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