14-5-2019

BIOGAS UPGRADING
130 locations

BIOMETHANE & LIQUID CO2 In 34 countries

ADDED VALUE TO BIOGAS

10,000
employees
PRODUCT LINE MANAGEMENT United in our belief that the future
PRESENTER: NIELS DEN HEIJER of water depends on us
DATE: MAY 8, 2019

PENTAIR 1 PENTAIR

1 2

STORIES TO SHARE
Haffmans story short
Founded First CO2 Started to Acquired by Digital CO2/O2 First Biogas Haffmans,
in Venlo, Gehaltemeter, produce CO2 Norit together Gehaltemeter upgrading Südmo, Norit
Beverage: Industrial Gases: Energy: recovery plants Process
Desalination: Process Services: Holland Type GMT with Südmo Type c-DGM
Breweries Petrochemical Biogas plants systems installed Technology
Contractors Universities
Soft drink bottlers Large industrial groups Farmers and X-Flow
Desalination plant Any existing projects acquired by Combined
Craft brewers Independent gas Industrial Gases
consortiums or company Pentair forces
Distilleries companies Landfill
allow us to
CO2 fermentation and CO2 capture and recovery Recovery and upgrading Safe CO2 technology for Relocation of an existing offer great
purification technologies technologies for obtaining plants for ‘zero-methane’ remineralising the desalted CO2 plant, extending the
1948 1967 1977 2009 2006 2010 2011 technologies,
for efficient and safe a safe endproduct even slip solutions. seawater, in order to capicity or developing a
from a low purity source. supply regions with scarce special technology for components,
endproducts.
The upgrading plants are water resources. scientific purposes. 1933 1972 1984 1994 1995 2013 2017 units and
An extensive product The plants are delivering an available with two different Serious
First CO2 Acquired by Sales and Sales and Acquisition Acquired by
portfolio within quality end-product that exceeds technologies, depending The plants are efficient and Service
plant installed; Norsk Hydro production production of Wittemann, Pentair
and control components. the highest demands form on need and plant size. available and an important globally!
Coca Cola, Danmark in China in Brazil USA
ISBT and EIGA. ingredient in delivering Iran established established
Innovative solutions – also The recovery plants offer a drinking water to the ECO2Brew CO2mpactBrew
for craft brewers. second value stream. people. launched launched
Founded Acquired by
After Market Service In Fredericia, British Oxygen
Serious Service is covering all segment, Denmark Company BOC )
offering an extensive service programme
globally.

Union Engineering’s story short

PENTAIR 3 PENTAIR 4
Biogas

3 4

LEADING PARTNER IN CO2 & BIOGAS UPGRADING

SEGMENT: ENERGY Market Leader in
Breweries & CSD
CO2/O2 in Breweries
BioSENSE

1400+ 20.000+
MEASUREMENT
CO2 PLANTS DEVICES

LEADING PARTNER IN 5000 Nm3/h Biogas

55000 Nm3/h Industrial
300+
AMINE PLANTS
40+
MEMBRANE
PLANTS

BIOGAS UPGRADING
3 Stage & 2 Stage with CO2
> 3000 Nm3/h
No Methane Slip

HAFFMANS & UNION: COMBINING 60 YEARS OF PROCESS TECHNOLOGY

PENTAIR Biogas
5 PENTAIR 6

5 6

1
 14-5-2019

BIOMETHANE APPLICATIONS CO2 APPLICATIONS

- USE the CH4 as fuel
- Bio-CNG (LNG) for:
- Trucks
- Buses
- Cars

- USE the CH4 for pipeline injection

- Bio-methane for:
- Transportation
- Electricity
THE FUTURE: DRY ICE – POWER-TO-GAS – POWER-TO-LIQUID
- Heat
FROM FEEDSTOCK TO GREEN CO2
PENTAIR
PENTAIR PENTAIR
PENTAIR Process Technology
Beverage Systems

7 8

SUSTAINABLE GAS SOLUTIONS – ENERGY/BIOGAS BIOGAS UPGRADING - MEMBRANE GAS SEPARATION

WASTE STREAMS WASTE WATER MANURE ENERGY CROPS LANDFILL

ANAEROBIC DIGESTION

PRE-TREATMENT (COOLING, HEATING, H2S REMOVAL)

LOCAL HEAT

BIOGAS UPGRADING – PRODUCT PORTFOLIO CHP

ELECTRICITY
PRODUCT

STANDARD ADVANCED ADVANCED plus AMINE Solution EXISTING UPGRADER

Membrane Solution Membrane Solution Membrane Solution (PENTAIR OR NON PENTAIR)
Without Without Including Optional
CO2-Liquefaction CO2-Liquefaction CO2-Liquefaction CO2-Liquefaction CO2 BOLT SOLUTION
<0,5% METHANE LOSS 0% METHANE LOSS 0% METHANE LOSS <0,1% METHANE LOSS 0% METHANE LOSS

BIO-METHANE BIO-METHANE BIO-METHANE BIO-METHANE

→GRID INJECTION →GRID INJECTION →GRID INJECTION →GRID INJECTION

BIO-METHANE BIO-METHANE BIO-METHANE BIO-METHANE

PRODUCTS

PRODUCTS
PRODUCTS

PRODUCTS

PRODUCTS

→ CNG → CNG → CNG → CNG

FOODGRADE CO2 FOODGRADE CO2

LNG LNG LNG LNG

FUTURE SOLUTION FUTURE SOLUTION FUTURE SOLUTION SOLUTION

CURRENT PENTAIR PORTFOLIO

0% METHANE LOSS & CO2 ADDITIONAL REVENUE

PENTAIR PENTAIR 10

9 10

BIOGAS UPGRADING - STANDARD BIOGAS UPGRADING - ADVANCED

Biogas AD Biogas AD
Flare Flare

Low Pressure Stage BIOGAS PART Low Pressure Stage BIOGAS PART
Fan Blower Scrubber Activ Carbon Low Pressure Membrane Separation Fan Blower Scrubber Activ Carbon Low Pressure Membrane Separation
Chiller (H2S/VOC) Conditioning Chiller (H2S/VOC) Conditioning
Heater Heater

High Pressure Stage Membrane Stage 1 & 2 Revenue Stream High Pressure Stage Membrane Stage 1 & 2 Revenue Stream
Compression High 1st Stage 2nd Stage Temperature Quality BioMethane Compression High 1st Stage 2nd Stage Temperature Quality BioMethane
Pressure Conditioning Control Pressure Conditioning Control
Conditioning Conditioning

Methane Recovery Green CO2 to free air /

Flare / Digester Flare / Digester
Local gas consumption
Methane Recovery

Membrane Stage 3 High Pressure Stage Purification & Liquefaction Stage

3rd Stage Compression High Regenerative CO2 Liquefier Stripper -
Pressure Activ Carbon Reboiler
Conditioning & Drier

CO2 PART
Vent
Cryogenic Separation

PENTAIR 11 PENTAIR 12

11 12

2
 14-5-2019

BIOGAS UPGRADING ADVANCED plus ADDITIONAL REVENUE WITH CO2 -BOLT-ON

Biogas AD Biogas AD
Flare Flare

Low Pressure Stage BIOGAS PART

Fan Blower Scrubber Activ Carbon Low Pressure Membrane Separation
Chiller
Heater
(H2S/VOC) Conditioning
EXISTING BIOGAS
UPGRADING PLANT
High Pressure Stage Membrane Stage 1 & 2 Revenue Stream
Compression High 1st Stage 2nd Stage Temperature Quality BioMethane
Pressure Conditioning Control
Conditioning
Methane Recovery ~2% of Biogas flow
Green CO2 to free air /
Local gas consumption
Methane Recovery Green CO2 to free air /
Flare / Digester
Local gas consumption

High Pressure Stage Purification & Liquefaction Stage Revenue Stream

High Pressure Stage Purification & Liquefaction Stage Revenue Stream Compression High Regenerative CO2 Liquefier Reboiler + Liquid CO2 Foodgrade
Compression High Regenerative CO2 Liquefier Stripper - Liquid CO2 Foodgrade Pressure Activ Carbon System Stripper + Storage tank Liquid CO2
Pressure Activ. Carbon Reboiler Storage tank Conditioning and Drier Pump
Liquid CO2
Conditioning & Dryer + Pump

CO2-Bolt-On
CO2 PART
Cryogenic Separation • CO2 purity acc EIGA Specs

INTEGRATED PROCESS – NO CH4 SLIP – FOOD-GRADE CO2 – LESS ENERGY

PENTAIR 13 PENTAIR 14

13 14

BIOGAS UPGRADING – Amine Solution REFERENCES BIOGAS UPGRADING AND BOLT-ON CO2
Biogas AD
Flare UK & Ireland
Scandinavia
10x Standard Solution
Low Pressure Stage 2x Advanced Solution
-1x Standard Solution
Fan Blower Scrubber Activ Carbon Low Pressure -1x Amine Solution
6x Advanced Plus Solution
Chiller (H2S/VOC) Conditioning Support by
Heater 1x Bolt-on Solution
DK office
Support by
Ireland office
First Stage Second Stage Revenue Stream
Absorbor Water H2S Polishing Compressor Dryer Quality BioMethane
Scrubber Control
Central Europe
4x Standard Solution
5x Advanced Solution
Flare / Digester
5x Advanced Plus Solution
Amine Treatment Support by
North America NL office
Reboiler Stripper
High Pressure Stage Purification & Liquefaction Stage 3x3220Nm3/h
Compression High Regenerative CO2 Liquefier Stripper - Supported by South Africa &
Pressure Activ Carbon Reboiler
Conditioning & Drier US offices Philippines
1 Advance Plus
Optional CO2 PART 2 CO2 recovery plants
Heat for Digester Cryogenic Separation

Our installed plants can fuel 133,000 homes or 275,000 cars

BASED ON OVER 60 YEARS OF EXPERT KNOWLEDGE
PENTAIR 15 PENTAIR 16

15 16

BIOGAS UPGRADING in Nederland NL 2011: 450 Nm3/h BIOGAS TO GRID & GREEN CO2

NL AD – Bio-Methane
2018 :
268 bio gas installaties met WKK
Geïnstalleerd vermogen 119 MW
Totaal geleverd vermogen 17,0840,720 GWh

34 installaties met bio-methaan productie

Totaal geleverd vermogen van 1,170 GWh

6 AD installaties leveren CO2

In 2018 was de productie van Bio-methaan +/- 1,170 GWh (source EBA)
6 YEARS OF LIQUID CO2 RECOVERY
PENTAIR 17 PENTAIR 18

17 18

3
 14-5-2019

BIOGAS UPGRADING – COMPACT ENCLOSED SKID KALUNDBORG BIOENERGI

5000 Nm3/h heat recovery to AD

BIGADAN BUILDS BIGGEST BIOGAS PLANT IN DK

PENTAIR 19 PENTAIR 20

19 20

Westdorpe (Aben) 2018

3600 Nm3/h Biogas
Jaarlijkse product Bio-methaan : +/- 19 -20 miljoen Nm3
Jaarlijkse productie CO2: +/- 21,000 Ton CO2 from Biogas

Niels den Heijer

Product Line Manager – Biogas
Haffmans B.V.
Niels.denheijer@Pentair.com
www.biogas.pentair.com
+31 77 3232 396

Start productie Q1 2019

PENTAIR 21 PENTAIR 22

21 22

CO2 FROM BIOGAS – QUALITY & EXPERIENCE CO2 - QUALITY

Food Grade-EIGA DOC 70/08 UK Industrial Grade
NL EXPERIENCE Current Feed stock: Unprocessed vegetable matter + Energy Crops

• First plant in operation since 2011

FOOD SAFETY RISK ASSESSMENT
WITH INDUSTRIAL GAS COMPANY
• Food safety risk assessment completed
• Inline / complete batch analysis before supply
(30 vs. 9 components for industrial CO2)
• 1200+ EIGA samples since 2015
• CO2 complies with food-grade requirements
• Test result: < 2 bacteria / dm3
• Mainly bio-waste, vegetable & food waste
• Higher level of impurities -> process control
• CO2 goes via industrial gas companies and
OCAP pipeline mainly to greenhouses
• Demand driven by greenhouses
UK EXPERIENCE
• Energy crops / unprocessed vegetable matter
• High quality -> low risk
• CO2 goes via industrial gas companies to
food & beverage and industrial applications
• Shortage in conventional sources -> imports
• Regional demand & distant industrial sources
Air Liquide + Pentair-Haffmans
• FSRA Air Liquide & Pentair has been completed
• Since July 2015 > 400 samples have been analysed
according to the EIGA standard
• Key Indicaters to be installed to avoid non-conforming
product
-Stricter Values required
-Detailed analysis is required
-FSRA Mandatory by law

FURTHER REFERENCES IN SOUTH AFRICA, USA and PHILIPINES SECURITY AND FUTURE PROOFING
PENTAIR
PENTAIR
PENTAIR Process Technology PENTAIR 24

23 24

4
 14-5-2019

CURRENT NL Bio CO2 to greenhouses (OCAP) CURRENT UK CO2 PRODUCTION SITES

OCAP Nr. Plant Location Process
1. Air Liquide Ince Fertiliser
• 300.000 ton CO2 jaarlijks via OCAP 2. Air Liquide Wissington Bio-ethanol
3. Azelis Billingham Fertiliser
• Vraag glastuinbouw +/- 2 miljoen ton
North Distillery
4. Edinburgh
British Fermentation
• OCAP ontvangst station in Rotterdam
Bio-ethanol
4 North British 5. Yara Teesside (Mothballed) +
• +/- 4 AD installaties leveren nu aan OCAP Import terminal

6 Yara Purfleet Import Terminal

3 Azelis
• Ruimte voor meer!
5 CO2 Import terminal
Yara (Teesside) Centralized supply model

1 AL - Ince • Demand: 500.000 t/a

2 AL - Wissington • Capacity: 450.000 t/a

• Few main production sites

6 CO2 Import terminal

Air Liquide Yara (Purfleet) • Import: 100.000 t/r

3rd Party (Shipment every week)
Yara
• 9 AD-Plants: 65.000 t/a

PENTAIR TECHNICAL & ECONOMIC FEASIBILITY OF SUSTAINABLE CO2 FROM BIOGAS PENTAIR TECHNICAL & ECONOMIC FEASIBILITY OF SUSTAINABLE CO2 FROM BIOGAS

25 26

METHANE SLIP, GHG AND RHI IMPACT

35 1% 34.8 – current GHG limit Questions?

GHG Emissions (gCO2e/MJ of biomethane injected)

30 0%
27.5 – possible future GHG limit?
25 Biogas upgrading - other
Biogas upgrading - methane slip
20 Biogas Production
Silage - production & transport
15
Harvesting - diesel
Cultivation - diesel Niels den Heijer
10
Pesticides Product Line Manager – Biogas
5 Soil N2O emissions Haffmans B.V.
Fertiliser Production Niels.denheijer@Pentair.com
0 Seed www.biogas.pentair.com
Maize (1% CH4 loss) Maize (0% CH4 loss)
+31 77 3232396
Scenario

PENTAIR 27 PENTAIR 28

27 28