KVPY ARCHIVE CLASS – XI - CHEMISTRY

HINT & SOLUTIONS

FIITJEE KVPY ARCHIVECHEMISTRY SOLUTIONS FOR XI CLASS- FIITJEE

1. MOLE CONCEPT & STOICHIOMETRY

1. A
Sol. Ammonium sulphate is (NH4)2SO4
Molecular mass of (NH4)2SO4 = 132
Mass of nitrogen present in (NH4)2SO4 = 28 gram
Mass % of nitrogen = (28/132) ×100 = 21.21%  21%

2. C
Sol. Normality(N) of H2SO4 = 1
Molarity(M) of H2SO4 = 1/2
1
 200
M V 2
Moles of H2SO4 =   0.1
1000 1000
 One mole H2SO4 contains one mole S atom
0.1 mole H2SO4 contains 0.1 mole S atom
A
No. of sulphur atoms = 0.1 × A0 = 0
10

3. C

Sol. Cr2O72  14H 

 2Cr 3  7H2O
The oxidation no. of Cr in Cr2O72 is +6
3+
The oxidation no. of Cr in Cr is +3
No. of electrons gained = 2(+6) – 2(+3) = 6

4. C
262
Sol. Moles of xenon = 2
131
152
Moles of F2 = 4
  19 
2
Xe + F2  XeF2
Xe + 3F2  XeF6
In the reaction one mole of XeF2 and one mole of XeF6 are formed.

5. C

Sol. Moles of CO2 = 89.6/22.4 = 4

Moles of H2O = 72 /18 = 4
1 mole of CO2 contains one mole of O2 gas
4 moles of CO2 will contain 4 moles of O2 gas
1 mole H2O contains 1/2 mole of O2 gas
4 mole of H2O contains (1/2)×4 = 2 mole of O2 gas
 Total moles of O2 needed = 4 + 2 = 6
Volume of six moles of O2 at STP = 6 × 22.4 = 134.4 L

6. D
C  s   O2  g 
 CO2  g
Sol. moles = 1 mole 1 mole 1 mole
weight = 12gm 32 gm 44 gm
12gm of C require  1 mole of CO2
1
 2.4 gm of C will require   2.4 mole of O2
12
KVPY ARCHIVECHEMISTRY SOLUTION FOR XI CLASS- FIITJEE

22.4  2.4
Volume of 2.4/12 mole O2 at STP = litre = 4.48 litre
12
7. B
Sol.
 NH4 2 SO4
2NH3  H2SO4 
10ml(2M)
m.molof NH3
millimole of H2SO4 =  20
2
m. mol NH3 = m.mol of N = 40
40  14 560
WN    0.56 g
1000 1000
0.56
% of N =  100  28
2

8. D
Sol. 1.125 L of H2 produced by 0.1 equivalent of metal
0.1 1.85
1.85 L a of H2 will be produced by equivalent
1.125
2 2
 No. of gram equivalent of metal = 
Equivalent weight x
0.1 2
  1.85 
1.125 x
x = 12.16

9. B
Sol. 3.42 gm sucrose in 100 gm solution
–1
d = 1 gm ml
mass
 d
volume
100
Volume of solution =  100ml
1
n
Molarity =  100
v
3.42
Molarity =  1000  0.1
342  100

10. A
–
Zn + 2OH + 2H2O  [Zn (OH4)] + H2
2–
Sol.
2gm (1 mole) H2 is given by 65.4 gm of Zn
65.4
1 gm is given by gm of Zn
2

11. A
1 1
Sol. Percentage of C2F4 of Molar mass 100 =   100  0.01%
100 100
99 99
Percentage of C2F4 of Molar mass 102 =   100  98.01%
100 100
Percentage of C2F4 of Molar mass 101 = 100 – (0.01 + 98.01) = 1.98%
FIITJEE KVPY ARCHIVECHEMISTRY SOLUTIONS FOR XI CLASS- FIITJEE

12. C
Sol. 2Ca  O2 
 2CaO
20 1
nCa  
40 2
1
nCaO   56  28
2

13. D
mole 0.35
Sol. M=   2.692
volume 1.3

14. (B)
Formula is K2SO4 . Al2(SO4)3 . 24H2O
Empirical formula is KAl(SO4)2.12H2O
So x = 2

15. (B)
eM  eSO24
2 4.8

EM 48
EM  20
Mass of metal sulphate = 6.86
Mass of metal = 2g
Mass of sulphate ion = (6.8 – 2) = 4.8 g

16. B
nH HCl  0.1V
nH H SO   0.2  2 V
2 4

nH HCl  nH H SO 

H   2 4

2V
0.1V  0.4V 0.5V
=   0.25mol / L
2V 2V

17. (a) a = 3, b = 8, c = 3, d = 2 and e = 4

(b) f = 2, g = 1, h = 1.
(c) i = 2, j = 1, k = 1, l = 2
(d) 2.54 g of I2 = 1/100 mole of I2 = 2/100 gm atom of Cu
% Cu = (2/100) × 63.5 / 2) = 63.5%

18. A
25 1
Sol. 25g CaCO3   mole of CaCO3
100 4
CaCO3  CaO + CO2
 1 mole CaCO3 produce 1 mole CO2
 1/4 mole CaCO3 produce 1/4 mole CO2
and 1/4 mole CO2 = 1/4 × 44 g of CO2 = 11 g

19. (a) 2500 × 4.184 kJ = 10460 kJ;

(b) 342 g of sucrose produces 5600 kJ of energy.
To provide 10460 kJ we need 10460 × 342 / 5600 g = 638 g
638 g/342 g × 12 × 22.4 L = 501 L
KVPY ARCHIVECHEMISTRY SOLUTION FOR XI CLASS- FIITJEE

20. B

21. D

22. C
Sol. 3Pb 2  Pb3  AsO4 2
 2 AsO43 
20×0.1=2 millimol 2 4
2  milimol
3 3
74.9×3
=  9.9mg
31000
23. A
Sol. 2LiOH + CO2  Li2CO3 + H2O
2  24 g  44 g
44
1g   0.916 g CO2
48

24. B
Sol. % of carbon in NaHCO3 is 14.28 while others have more than that.

2. SOME BASIC CONCEPTS OF CHEMISTRY

1. B

2. A
Sol.
COOH
 
H 2 SO4 conc.
Heat
 CO2  CO  H 2O
COOH
3. ATOMIC STRUCTURE
1. D
Sol. No. of electron with ‘  ’ = 4  + 2
For  = 4, the no. of electrons = 4 × 4 + 2 = 18

2. C
RHn2
Sol. rn 
Z
53n2 53  12
rHe  =  27 approx.
Z 2
3. C

4. C

5. C
n2
Sol. r  0.529 
z
1
r So correct order is rH  rHe  rLi2
z
6. C
Sol. ne = 18 & nn = 40 – 19 = 21
Hence ne + nn = 18 + 21 = 39

7. B
Intercept on y-axis denotes  &  = /n where  = work function of metal.
0 0
Sol.
FIITJEE KVPY ARCHIVECHEMISTRY SOLUTIONS FOR XI CLASS- FIITJEE

8. D
Sol. n is always greater than 
and m1 = –  …….. 0 ……..+ 
If n = 2, then  = 0, 1
and m1 = 0, {–1, 0, +1}

9. A
4. LIQUID SOLUTIONS
1. D
Sol. Elevation of boiling point is proportional to the no. of foreign species.
CaCl2  Ca + 2Cl ; 3
2+

NaCl  Na + Cl ; 2
+

Sucrose remains undissociated mostly; 1

5. ELECTROCHEMISTRY

1.Sol. Charge passed = 0.5 amp (60×60) sec = 1800 coulomb

96500 coulomb = 1 Faraday
1800 coulomb = 1800/96500 = 0.018 F
1 F deposits 108 g of silver (Eq. mass = Molar mass)
0.018 F will deposit=108×0.018=1.94 =2g

2. B
0
Sol. E red = Sn < Cu < Hg < Au

3. B
0
Sol. E red = K < Mg < Zn < Au

4. A
Sol. At 40ºC solubility is 200 gm per 100 ml (approx)
i.e., 100 ml of water contains = 200 gm of KNO3(approx)
50 ml of water contains = 100 gm (approx)

6. PERIODIC PROPERTIES
1. C
Sol. According to Mendeleev’s periodic law, the properties of elements are a periodic function of the
atomic mass of the elements.

2. D
2 2 6 1
Sol. The element having 1s 2s 2p 3s electron configuration has the lowest first ionization energy.

3. A
Sol. As we move from left to right in period ionisation energy increases.

4. D
Sol. Na2O (alkali metal oxides are most basic in its period)

5. B

6. D

7. A
Sol. Atomic radius decreases from left to right in a period (from group 1 to 17)
KVPY ARCHIVECHEMISTRY SOLUTION FOR XI CLASS- FIITJEE

7. CHEMICAL BONDING

1. A
Sol. CO & N2 are isoelectronic

2. B
Sol. Hydrazine N2H4
H H
N N
H H
LP = 2
BP = 5

3. A
Sol. Nonpolar substance will have high Rf value as solvent is nonpolar therefore (A) will have high R f
value as it have low dipole moment.

4. A
5. D

6. A
Sol.

7. D
Sol. CCl4 has zero dipole moment due to its tetrahedral shape, all C–Cl bond moment cancel each
other.

8. C
Sol. CH3  CH2  O  CH2  CH3

9. B
Sol. BCl3 is electron deficient

Clearly B has only 6 e , Octet is not complete

10. D

11. D
8. CHEMICAL KINETICS
1. D
–kt
Sol. Ct = C0e

2. B
0.693 2.303 a
Sol.  log
t1/ 2 2  60 a / 16
t1/2 = 30 min
FIITJEE KVPY ARCHIVECHEMISTRY SOLUTIONS FOR XI CLASS- FIITJEE

9. GASEOUS STATE
1. D
3
Sol. Volume corresponding to 300°C = 500 cm
3
Volume corresponding to 0°C = 250 cm
V  300C  500
  2
V  0C  250

2. A
1
Sol. Average speed 
M
VHe 32 MO2
 
VO2 4 MHe
= 8 2 2

3. B
2H2  g  O2  g 
 2H2O I
Sol.
0.2mole 0.1mole 0.2mole
Moles of gas remaining = 9.7
n p 10 1
At constant (T) & (V) 1  1  and p2  0.97
n2 p2 9.7 p2

4. B
Sol.

5. B,C
Sol. B & C both are incorrect.

6. D
Sol. Since pressure of the gases are same in both the containers. Therefore the final pressure will not
change.

7. D
3
Sol. (K.E.)average = kT
2
i.e., average kinetic energy depends only on temperature.

8. C
Sol. 2g H2 1 mole gas at 200 K
a 28g N2  1 mole gas at 400 K
PV = nRT
 PV  Nt

9. C

10. A

11. C
P1 T1 1 300
Sol.  , 
P2 T2 P2 600
KVPY ARCHIVECHEMISTRY SOLUTION FOR XI CLASS- FIITJEE

P2  2atm

12. A
1
Sol. Rate of diffusion 
molar mass

10. ORES & METALLUARGY

1. A
Sol. 2ZnS  s  3O2  g 
heat
 2ZnO  s   2SO2  g

2. C
950C
Sol. 2ZnS  3O2   2ZnO  2SO2

11. THERMODYNAMICS & THERMOCHEMISTRY

1. C
Sol. G  RTlnK eq

2. A
Sol. According to KTG
Force of attraction and repulsion amongst molecules of ideal gas are negligible
So, H = 0
and randomness increases due to increase in volume so S = +ve.

3. D
Sol. Intensive variables are density (), temperature (T) & pressure (P).

4. A
495
Sol. H  198.9  142.3 
2
= –304.1 kJ/mol
12. EQUILIBRIUM

1. B
Sol. NH4Cl  acidic salt (pH < 7)
NaCl  neutral salt (pH = 7)
CH3COONa  Basic salt (pH > 7)

2. D
Sol.
FIITJEE KVPY ARCHIVECHEMISTRY SOLUTIONS FOR XI CLASS- FIITJEE

3. A
–5
Sol. C = 0.1 M Ka = 10
K=C
2
–5 –4 –2
10 =  × 0.1  = 10  = 10
2 2

4. B
Sol. QC < KC

5. D
Sol. Meq of CH3COOH = 100 × 0.1 × 1 = 10
Meq of CH3COONa = 50 × 0.2 × 1 = 10
–
pH = pKa + log [CH3COO ] / [CH3COOH]
pH = 4.76 + log 10/10
pH = 4.76 + log 1
pH = 4.76

6. A
Sol. Reaction quotient
HI   0.4  0.4
2

Q
H2 I2  0.1 0.2
Q=8
Q<K

So reaction will proceed in forward direction.

Hence amount of HI increases.

7. D
–2
pH = 2  [H ] = 10
+
Sol.
–5
pH = 5  [H ] = 10
+

H+  new 105

   +   103
H  old 102
8. A

9. C

10. B
13. p-BLOCK(GROUP-18)

1. C
Sol. NH4Cl  NaNO2 
NaCl  N2  2H2O

2. D

Sol.
O O O

P P P
H OH H OH HO OH
H OH OH
So, H3PO2 , H3PO3 and H3PO4 contains 2, 1 and zero P–H bonds.

3. D
Sol. 2KBr + Cl2  2KCl + Br2 (brown)
KVPY ARCHIVECHEMISTRY SOLUTION FOR XI CLASS- FIITJEE

14. REDOX REACTIONS

1. (No option is correct)

5
MnO4  5Br    Br2  Mn2
2
(5 mole Br2)

2. A
Sol. MnO2 oxidises Cl of HCl to Cl2

3. D

4. B

5. D
Sol. 2Ca + O2  2CaO
This is a redox reaction as there are changes in oxidation numbers of Ca and O.

6. D
Sol. Oxidation number of sulphur in
H2S = –2
CS2 = –2
N2SO4 = +6
N2SO3 = +4
15. COORDINATION CHEMISTRY
1. A
+3 6 0
Sol. (i) Co = [Ar] 3d s
NH3 is a strong field ligand

+2 8 0
(ii) Ni = [Ar] 3d 4s
NH3 is a strong field ligand

3d 4s 4p 4d
+3 3 0
(iii) Cr = [Ar] 3d 4s
H2O is a weak field ligand

3d 4s 4p
+2 6 0
(iv) Fe = [Ar] 3d 4s
H2O is a weak field ligand.

3d 4s 4p 4d
So, [Co(NH3)6]Cl3 will be diamagnetic.

16. HYDROGEN & ITS COMPOUND

1. A
Sol. ‘Cu’ is present below hydrogen in activity series. So, it cannot displace hydrogen either from H 2O
or dil. acids.

17. ALKYL AND ARYL HALIDES

1. A
2. C
Sol.
FIITJEE KVPY ARCHIVECHEMISTRY SOLUTIONS FOR XI CLASS- FIITJEE

Br

3. C
Given reaction  SN
2
Sol.

18. s-BLOCK ELEMENTS

1. B
Sol. Baking soda = NaHCO3
Vinegar contains CH3COOH
CH3COOH + NaHCO3  CH3COONa +CO2 + H2O
 CO2 gas is evolved.

2. B
Sol. 2CH3COOH + 2Na  2CH3COONa + H2 
3. B

4. A

5. C
Sol. MnO2  4HCl 
 MnCl2  Cl2  2H 2O
X

Cl2  Ca  OH 2 
 CaOCl2  H 2O
Y

CaOCl2  2HCl 
CaCl2  Cl2  H 2O

19. ELECTROPHILIC AROMATIC SUBSTITUTION

1. B
Sol.

2. A
Sol.
CH3 CH3 CH3
NO 2
CH 3Cl   
Anhyd. Conc. HNO3
AlCl3 Conc.H 2SO4

NO 2
20. ALCOHOL, PHENOL & ETHER
1. A
Sol. CH3CH2OH 
conc.H2SO4
170C
 CH2  CH2  H2O
CH2  CH2  Br2 
CCl4
BrCH2  CH2Br
1,2  dibromoethane

2. B
KVPY ARCHIVECHEMISTRY SOLUTION FOR XI CLASS- FIITJEE

Sol. CH3–O–CH2–CH2–CH3
CH3–CH2–O–CH2–CH3
CH3
H3C O CH CH3
3. C
Sol. I, II & IV compound form H–bond III do not form H–bond.
4. B
Sol.

21. ALDEHYDE & KETONES

1. A
Sol.

2. A

Sol. (A)
Show iodoform test
O
H3C C CH2 CH 2 CH3

(B)
O
H3C CH 2 C CH 2 CH3

(C)
H3C CH2 CH CH2 CH3
OH
(D) CH3–CH2–CH2–CH2–CH2–OH

22. GENERAL ORGANIC CHEMISTRY

1. C
Sol. Acidic Strength:

Electron withdrawing groups (–I, –R) increase acidity and electron releasing groups (+I, +R)
decrease acidic strength
NO2 group exert –I and – R effect
OCH3 group exert –I and + R effect but its +R effect dominates over –I effect at ortho and para
positions.
FIITJEE KVPY ARCHIVECHEMISTRY SOLUTIONS FOR XI CLASS- FIITJEE

2. B
Sol.

3. A
Sol.

Anhydride group

4. B
Sol. Because conjugate acid is stabilised by resonance with complete octate.

5. C
Sol.

6. C

7. C

8. A
–
Sol. Formica cid is strongest among these due to greater stability of its conjugate base (HCOO )

23. CARBOXYLIC ACID & ITS DERIVATIVE

1. B
Sol. C12O9 is mellitic anhydride. Its structure is
O O
O
O

O
O
O O
O
2. A
Sol. CH3COOH + C2H5OH 
HCl
 CH3COOC2H5  H2O
ester

Ester have sweet smell.

KVPY ARCHIVECHEMISTRY SOLUTION FOR XI CLASS- FIITJEE

3. C
Sol.

4. B
Sol.

24. ISOMERISM
1. B
Sol. Ethers having formula C4H10 are
CH3OCH2CH2CH3
CH3CH2OCH2CH3
CH3
CH 3COH
CH3

2. B
Sol.

25. HYDROCARBON

1. D
 
Sol. CH3CH=CHCH3  MnO4 /H
 2 CH3COOH
Two moles of acetic acid is formed.
2. A
Sol.

Markownikoff addition of water takes place.

3. D
Sol. OH


Alkaline
KMnO4 (Syn)


OH

4. A
Sol. CaO  C 
 CaC2  CO2
HC  CH  Ca  OH2
CaC2  H2O 
FIITJEE KVPY ARCHIVECHEMISTRY SOLUTIONS FOR XI CLASS- FIITJEE

3HC  CH 
Red hot
Fe


5. C
Sol.

6. B
Sol.

7. B
Sol.

8. C
Sol. –OCH3 is activating group.
order of deactivating is

9. B
Sol. (i) and (iv) are heteroaromatic compound.
(ii) is non aromatic.

(iii)

10. B
Sol.

11. C
Sol. Possible structural isomers are nine.
KVPY ARCHIVECHEMISTRY SOLUTION FOR XI CLASS- FIITJEE

12. A
Sol.

12 bonds = 10 single + 1 double

13. C

14. C

15. A
Sol. Longest chain comprising double bond is of six carbon lenght.

16. B
 i  KOH
Sol. CH3 
 ii  NaNH 2  H3C
alk .
H3C CH CH C C CH3

Br Br

17. D
Sol. CH  
COOH

4O
KMnO4 Alk .
CH COOH

18. B
Sol. H3C O CH3
H3C CH CH CH3 
O3
 C C 
Zn / H 2O
 2 CH3 C H
H H
O O O

26. QUALITATIVE ANALYSIS

1. D

Sol. (NH4)2Cr2O7   N2 + Cr2O3 + 4H2O

2. Bottle A = III, Bottle B = II, Bottle C = IV, Bottle D = I

Compound with the highest solubility in distilled water: IV

3. A

4. B
FIITJEE KVPY ARCHIVECHEMISTRY SOLUTIONS FOR XI CLASS- FIITJEE