Documente Academic
Documente Profesional
Documente Cultură
This Section contains 29 multiple choice questions. Each question has four choices A), B), C) and
D) out of which ONLY ONE is correct. 29 × 4 = 116 Marks
1. The percentage of Se in peroxidase enzyme is 0.5% by mass (atomic mass of Se = 78.4 amu). Then,
the minimum molecular mass of enzyme which contains not more than one Se atom is:
a. 1.568 × 104 amu b. 1.568 × 107 amu c. 1.568 × 103 amu d. 1.568 × 106 amu
A
Sol. 0.5 g Se is present in 100 g enzyme.
100
78.4 g Se will be present in = 78.4 g enzyme
0.5
= 15680 amu = 1.568 × 104 amu
2. The formula of an acid is HXO2. The mass of 0.0242 moles of the acid is 1.657 g. What is the atomic
weight of X?
a. 3M b. 3 M c. M/3 d. M / 3
C
Sol. Vapour density of A = 3 × Vapour density of B.
mol. wt. of A = 3 × mol. wt. of B.
10. If the specific heat of a metallic element is 0.214 cal/ g, the atomic weight will be closest to:
a. 66 b. 12 c. 30 d. 65
C
6.4
Sol. At. wt. × specific heat 30
0.214
11. 4.48 litre of methane at S.T.P. corresponds to:
a. 10 mL H2 b. 5 mL H2 c. 10 mL O2 d. 5 mL O2
D
1
Sol. H2 (g) O 2 (g) H2 O(g)
1 v ol 2
30 mL 1 v ol
2
15 mL
Remaining O2 at the end = 20 – 15 = 5 mL
14. Which of the following will have maximum number of atoms
Column – I Column – II
A. 1. 0.224 L CO2
10 g CaCO3 CaO + CO2
decomposition
B. 1.06 g Na2CO3 ExcessHCl 2. 4.48 L CO2
2NaCl + CO2 + H2O
C. Excess O 3. 0.448 L CO2
2.4 g C
2
CO2
combustion
D. ExcessO2 4. 2.24 L CO2
0.56g CO CO2
combustion
5. 22.4 L CO2
Codes
A B C D A B C D
a. 4 1 2 3 b. 5 1 2 3
c. 4 1 3 2 d. 1 4 2 3
A
Sol. (A) CaCO 3 CaO CO 2
100 g decomposition 22.4 L
100 g CaCO3 on decomposition gives = 22.4 L
22.4 10
10 g CaCO3 on decomposition will give = L CO 2
100
= 2.24 L CO2
ExcessHCl
(B) NaNO 3
2NaCl H2 O CO 2
106 g 22.4 L
106 g Na2CO3 gives = 22.4 L CO2
22.4 1.06
1.06 g Na 2 CO 3 w ill give L CO 2
106
= 0.224 L CO2
ExcessO
(C) C
2
CO 2
12 g combustion 22.4 L
12 g carbon on combustion gives = 22.4 L CO2
22.4 2.4
2.4 g carbon on combustion gives = L CO 2
12
= 2 × 2.24 L CO2 = 4.48 L CO2
Excess O
(D) 2CO
2
2CO 2
2(12 16 ) Combustion 2 22.4 L
56 g
56 g carbon monoxide on combustion gives = 2 × 22.4 L CO2
2 22.4 0.56
0.56 g carbon monoxide on combustion will give = L CO 2
56
= 0.448 L CO2
25. What will be the molarity of chloroform in the water sample which contains 15 ppm chloroform by
mass? (M.Wt. of CHCl3 = 119.5)
This Section contains 6 multiple choice questions. Each question has four choices A), B), C) and
D) out of which ONLY ONE is correct. (6 × 4 = 24 Marks)
This Section contains 8 multiple choice questions. Each question has four choices A), B), C) and
D) out of which more than one answer is correct. (8 × 5 = 40 Marks)
a. 2KClO 3 2KCl 3O2 b. NH 4NO 3 N2O 2H2O
1
c. MgCO 3 MgO CO 2 d. AgNO 3 Ag NO 2 O2
2
A,B,D
8. Which of the following disproportionation?
This Section contains 2 questions. Each question has four choices (A, B, C and D) given in Column I
and five statements (p, q, r, and s) in Column II. Any given statement in Column I can have correct
matching with one or more statement(s) given in Column II. 2 × 8 = 16 Marks
This Section contains 10 questions. The answer to each question is an integer ranging from 0 to 10.
10 × 5 = 50 Marks
1. The hydrated salt Na2SO4. nH2O, undergoes 55.9% loss in weight on heating and becomes
anhydrous. The value of n will be:
Sol. 10
Na2SO4nH2O Na 2SO 4 nH2O
44.1 55.9
44.1 combine with 55.9 gm
55.9
142 will combine with = 142gm
44.1
= 180 gm
Mole of H2O = 10
2. CaCO3 is decomposed by HCl (density 1.825 g/cc)
CaCO3 + 2HCl CaCl2 + H2O + CO2
Volume of HCl in (ml) required to decompose 10 g of 50% pure CaCO3 is:
Sol. 2
Weight of CaCO3 = 5 gm
5
Mole = 0.05
100
Mole of HCl = 0.05 × 2 = 0.1
M
Weight = 0.1 × 36.5 = 3.65 d
V
3.65
Volume of HCl = 2 ml
1.825
3. 10 g of hydrogen and 64 g of oxygen were filled in a steel vessel and exploded. Moles of water
1
produced in this reaction will be: H2 O 2 H2 O
2
Sol. 4 mol
Mole ratio of H2 : O2 : H2O :: 2 :1 : 2 [oxygen is limting Reagent]
4. 2N; 100 ml H2SO4 is mixed with 200 ml solution of NaOH of unknown Normality. Normality of NaOH
will be
Sol. 1
2 × 100 =, N × 200
5. How many times the molecular mass of glucose (C6H12O6) is multiple of empirical formula mass?
Sol. 6
6. How many of the following compounds have at least one atom in +6 oxidation state
H2SO4; SO2; SO3; H2SO5; XeF6; XeO8; HNO3; H3PO4; K2Cr2O7
Sol. 5
H2SO4; SO3; H2SO5; XeF6; K2Cr2O7
7. What is oxidation number of Iron in the given compound K3[Fe(CN)6]
Sol. +3
8. How many significant figures will be present in 0.0025 × 105
Sol. 2
9. What is the equivalent mass of CH4 in its combustion reaction
Sol. 2
CH 4 2O 2 CO 2 2H2O
4 4
8e