GAS/SPEC A P P L I C AT I O N S

• Gas Treating Applications • Urethanes Production

MDEA
• Paint and Coating Additives
• Emulsifer/Surface End Uses

P H YS I C A L P R O P E R T I E S 1

Specific Gravity @ 25/25° C ___________________________ 1.04

Boiling Point @ 760 mmHg ____________________________ 247.0 °C

Specialty Amine ___________________________

Freezing Point ______________________________________
______________________________________
476.6 °F
-22.5 °C
-8.5 °F
Latent Heat of Vaporization ____________________________ 200.2 Btu/lbm
Methyldiethanolamine (MDEA) is supplied ___________________________ 111.0 Cal/g
globally by INEOS for use in applications Flash Point (PMCC) __________________________________ 127 °C
requiring this molecule. Typical applications __________________________________ 260.6 °F
include gastreating, and as a chemical
intermediate for detergent and fabric softener 1
Typical properties, not to be construed as specifications
manufacture. INEOS has established a global
supply network of storage locations and
distributor partners to meet local delivery
needs. Viscosity

For gas treating applications requiring technical Temperature, ºC

services, GAS/SPEC* SS is also supplied. 0 20 40 60 80 100 120
80
100 wt%
70

60
* GAS/SPEC is a trademark and service mark of INEOS LLC.
50
Viscosity, cP

40

30

20
50 wt%
10
40 wt%
0
32 68 104 140 176 212 248
Temperature, ºF

Density

Temperature, ºC
0 20 40 60 80 100 120 140
8.8 1.054

8.7 1.042

8.6 1.031
Density, g/cm3
Density, lb/gal

8.5 1.019

8.4 1.007

8.3 0.995

8.2 0.983

8.1 0.971
50 wt%
100 wt% 40 wt%
8.0 0.959
32 68 104 140 176 212 248 284
Temperature, ºF
P R O D U C T S E RV I C E S
INEOS offers a broad line of services to our Specific Heat
specialty amine customers, including: Temperature, ºC
• superior simulation capabilities 0 20 40 60 80 100 120 140
• troubleshooting consultations 1.1 1.1
• on-site start-up and optimization
1.0 1.0
• solvent analysis and interpretation
40 wt%

Specific Heat, Btu/lb•ºF

• local stocking & suppl. 0.9 0.9

Specific Heat, cal/g-K

0.8 0.8
M AT E R I A L S O F C O N S T R U C T I O N 50 wt%
The preferred material for storage of MDEA 0.7 0.7
is 304L or 316L stainless steel. Carbon
0.6 0.6
steel tanks are also satisfactory, although discolor-
ation and iron in the amine may occur. Nitrogen 0.5 100 wt% 0.5
padding of the tanks is recommended to prevent
0.4 0.4
oxidation and discoloration of the amine during 32 68 104 140 176 212 248 284
extended storage.The amine can also be stored Temperature, ºF
in high-density polyethylene (HDPE) or
polypropylene (HDPP).
Thermal Conductivity

Materials to avoid include: Temperature, ºC

• Aluminum • Copper 0 20 40 60 80 100 120 140
.30 .52
• Brass • Copper alloy
Thermal Conductivity, Btu/h-ft-ºF

.25 .43

Thermal Conductivity, W/m-ºC

S T O R AG E T E M P E R AT U R E 40 wt%
• The recommended minimum temperature .20 .35
for storing and pumping 100% MDEA 50 wt%
is 20 °F (-7 °C). .15 .26
• Steam tracing and insulation may be required
in cold weather. .10 .17
100 wt%

.05 .09
HANDLING AND SAFETY
• MDEA can cause serious injury to the eyes 0 .0
and may result in permanent eye injury. 32 68 104 140 176 212 248 284
If accidental contact with the eyes occurs, Temperature, ºF

flush them thoroughly with water and seek

medical attention. Surface Tension
• Single-dose oral toxicity of MDEA
Temperature, ºC
is low. 20 40 60 80 100 120 140
• Swallowing large amounts of MDEA may 60
cause severe burns to the mouth, throat,
and digestive tract. If accidental ingestion occurs 40 wt%
Surface Tension dynes/cm

seek medical attention. 50

• Accidental ingestion of small amounts of 50 wt%

MDEA is not expected to cause
40
injury.
• May cause irritation to the skin. Occasional brief 100 wt%
contact with the skin should be washed off 30
immediately and should have few adverse effects.
• If MDEA is heated or a mist
produced, concentrations may be sufficient to 20
68 104 140 176 212 248 284
cause irritation to the upper respiratory tract.
Temperature, ºF
• Consult product Material Safety Data Sheet for
more details.
The following precautions should be observed
when the possibility of exposure exists: Vapor Pressure
Temperature, ºC
• A safety shower and eyewash facility located
nearby 10 38 66 93 121 149 177 204
10000
• Chemical goggles 50 wt%
• Protective clothing, including chemically resistant 1000
100 wt%

Vapor Pressure mmHg

gloves 100
• A well-ventilated work area
10

Accidental Release 1
• Clear non emergency personnel from area.
• PROTECT THE ENVIRONMENT: Keep out of 0 .1

sewers, storm drains, surface waters and soil. 0.01

• Contain spill if possible. Clean up with a non-
0.001
combustible absorbent. Do not use sawdust. 50 100 150 200 250 300 350 400
Temperature, ºF
R E G U L AT O RY
Regulatory requirements may vary for different
locations. Contact your INEOS representative for Freezing Point
more information.
• MDEA is not considered hazardous 0 32

according to the guidelines of the U.S. -5 23

Department of Transportation (DOT).
-10 14
• MDEA, as sold, contains no
Temperature, ºC

Temperature, ºF
chemical subject to SARA Title III Section 313 -15 5

supplier notification requirements. -20 -4

• The export of this product is regulated under
-25 -13
the provisions of the Chemical Weapons
Convention. -30 -22

-35 -31

-40 -40
0 10 20 30 40 50 60 70 80 90 100
Weight % MDEA
GAS/SPEC
Since 1982, the GAS/SPEC name has represented a special focus on
the products, technology and service to chemically remove acid gases
from process streams. The GAS/SPEC business unit has been continu-
ously headquartered in Houston, Texas, with its major technical facility
in Freeport, Texas.
The family of specialty amines offered by the GAS/SPEC
Technology Group, all based on MDEA technology, provides custom
H2S and CO2 removal in amine treating operations. The GAS/SPEC
products and technology are exclusively offered by INEOS LLC and
its specialized distributors.
The GAS/SPEC Technology Group is dedicated to achieving the
highest degree of customer satisfaction globally through the applica-
tion of the best available technology through the supply of cost-effec-
tive products and services. Other companies offer MDEA based
products, some even attempting to emulate GAS/SPEC with similar
sounding names… But only products with the GAS/SPEC name bring
you the formulations, technology and service you are used to.
INEOS LLC is a part of INEOS Oxide.
INEOS Oxide manufactures a full range of products based on its
production of ethylene oxide.

INEOS LLC
Head Office
2925 Briarpark Drive, Suite 870 • Houston, TX 77042
For more information on INEOS LLC products and services:
Phone: 713-243-6200 • Fax: 713-243-6220
Email us at: gastreating@ineos.com
www.gasspec.com
www.gastreating.com
Customer Service: 1-225-242-3005
or 866-865-4767 (toll free in USA and Canada).
Email us at: csr@ineos.com
NOTICE: No freedom from any patent owned by Seller or others is to be inferred. Because use conditions and applicable laws may differ from one location to
another and may change with time, Customer is responsible for determining whether products and the information in this document are appropriate for Customer’s
use and for ensuring that Customer’s workplace and disposal practices are in compliance with applicable laws and other governmental enactments. Seller assumes no
obligation or liability for the information in this document. NO WARRANTIES ARE GIVEN; ALL IMPLIED WARRANTIES OF MERCHANTABILITY OR FITNESS FOR
A PARTICULAR PURPOSE ARE EXPRESSLY EXCLUDED.
GSSS001-4/02