SIGMA-ALDRICH

________________________________________________________________________
Material Safety Data Sheet

Date Printed: 26/SEP/2017

Date Updated: 15/APR/2013
Version 1.7
Regulation (EC) No 1907/2006
________________________________________________________________________
1 - Product and Company Information
________________________________________________________________________
Product Name 1-OCTENE
Product Number O7376

Company Sigma-Aldrich (M) Sdn. Bhd.

No:7, Jalan PJS 7/21, Bandar Sunway
46150 Petaling Jaya, Selangor D. E.
Malaysia
Technical Phone # 60 3 563 53321
Fax 60 3 563 54116
________________________________________________________________________
2 - Hazards Identification
________________________________________________________________________
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Flammable. Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.

________________________________________________________________________
3 - Composition/Information on Ingredients
________________________________________________________________________
Product Name CAS # EC no Annex I
Index Number
1-OCTENE 111-66-0 203-893-7 None

Ingredient Name Percent CAS # EC no Annex I

1-OCTENE 97 111-66-0 None None

2-ETHYL-1-HEXENE 2.2 1632-16-2 None None

Formula C8H16
Molecular Weight 112,2200 AMU
________________________________________________________________________
4 - First Aid Measures
________________________________________________________________________
AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.

AFTER SKIN CONTACT

In case of contact, immediately wash skin with soap and copious
amounts of water.

AFTER EYE CONTACT

In case of contact, immediately flush eyes with copious amounts
of water for at least 15 minutes.

AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.

SIGMA www.sigma-aldrich.com Page 1 of 6

GENERAL INFORMATION
Contamination of the eyes should be treated by immediate and
prolonged irrigation with copious amounts of water.
________________________________________________________________________
5 - Fire Fighting Measures
________________________________________________________________________
EXTINGUISHING MEDIA
Suitable: For small (incipient) fires, use media such as
"alcohol" foam, dry chemical, or carbon dioxide. For large
fires, apply water from as far as possible. Use very large
quantities (flooding) of water applied as a mist or spray; solid
streams of water may be ineffective. Cool all affected
containers with flooding quantities of water.

SPECIAL RISKS
Specific Hazard(s): Flammable liquid. Emits toxic fumes under
fire conditions.
Explosion Hazards: Vapor may travel considerable distance to
source of ignition and flash back. Container explosion may occur
under fire conditions.

SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS

Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
________________________________________________________________________
6 - Accidental Release Measures
________________________________________________________________________
PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area. Shut off all sources of ignition. Use nonsparking
tools.

PROCEDURE(S) OF PERSONAL PRECAUTION(S)

Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.

METHODS FOR CLEANING UP

Cover with dry-lime, sand, or soda ash. Place in covered
containers using non-sparking tools and transport outdoors.
Ventilate area and wash spill site after material pickup is
complete.
________________________________________________________________________
7 - Handling and Storage
________________________________________________________________________
HANDLING
Directions for Safe Handling: Do not breathe vapor. Do not get
in eyes, on skin, on clothing. Avoid prolonged or repeated
exposure.

STORAGE
Conditions of Storage: Keep tightly closed. Keep away from heat,
sparks, and open flame.
________________________________________________________________________
8 - Exposure Controls / Personal Protection
________________________________________________________________________
ENGINEERING CONTROLS
Safety shower and eye bath. Use nonsparking tools. Mechanical
exhaust required.

GENERAL HYGIENE MEASURES

Remove and wash contaminated clothing promptly. Wash thoroughly

SIGMA www.sigma-aldrich.com Page 2 of 6

 after handling.

PERSONAL PROTECTIVE EQUIPMENT

Respiratory Protection: Use respirators and components tested and
approved under appropriate government standards such as NIOSH (US)
or CEN (EU). Where risk assessment shows air-purifying respirators
are appropriate use a full-face respirator with multi-purpose
combination (US) or type ABEK (EN 14387) respirator cartridges as
a backup to engineering controls. If the respirator is the sole
means of protection, use a full-face supplied air respirator.
Hand Protection: Compatible chemical-resistant gloves.
Eye Protection: Chemical safety goggles.
________________________________________________________________________
9 - Physical and Chemical Properties
________________________________________________________________________
Appearance Physical State: Clear liquid
Color: Colorless

Property Value At Temperature or Pressure

pH N/A
BP/BP Range 121,000. - 122,000 °
C.
MP/MP Range - 101,000 °C.
Flash Point 21,000 °C Method: closed cup
Flammability N/A
Autoignition Temp 230,00 °C
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits Lower: 0,700 %
Upper: 3,900 %
Vapor Pressure 34,000000000 mmHg 38,00 °C
SG/Density 0,7150 g/cm3
Partition Coefficient Log Kow: 4,570
Viscosity 0,270 Pas
Vapor Density 3,900 g/l
Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility Solubility in Water:Insoluble.
Other Solvents: HYDROCARBON SOLVENTS-SOLUBLE
________________________________________________________________________
10 - Stability and Reactivity
________________________________________________________________________
STABILITY
Stable: Stable.
Materials to Avoid: Acids, Oxidizing agents.

HAZARDOUS DECOMPOSITION PRODUCTS

Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide.

HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur
________________________________________________________________________

SIGMA www.sigma-aldrich.com Page 3 of 6

11 - Toxicological Information
________________________________________________________________________
ACUTE TOXICITY
LD50
Oral
Rat
> 10.000, mg/kg
LC50
Inhalation
Rat
8.050, ppm
4 HR
LD50
Skin
Rabbit
> 10.000, mg/kg

SENSITIZATION
Sensitization: Will not occur

SIGNS AND SYMPTOMS OF EXPOSURE

Headache, dizziness, drowsiness, incoordination, slowed reaction
time, slurred speech, giddiness and unconsciousness. Exposure
can cause: Prolonged or repeated contact with skin can cause
defatting and dermatitis. Contact with eyes can cause redness,
tearing, and blurred vision. Ingestion may cause
gastrointestinal irritation. Aspiration or inhalation may cause
chemical pneumonitis.

ROUTE OF EXPOSURE
Skin Contact: May cause skin irritation.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: May cause eye irritation.
Inhalation: Material may be irritating to mucous membranes and
upper respiratory tract. May be harmful if inhaled.
Ingestion: May be harmful if swallowed.
________________________________________________________________________
12 - Ecological Information
________________________________________________________________________
BIOACCUMULATION POTENTIAL: Indication of
bioaccumulation.

ECOTOXICOLOGICAL EFFECTS
Test Type: EC50 Daphnia
Species: Daphnia magna
Time: 48,0 h
Value: > 3,200. - < 10,000 mg/l.

Test Type: LC50 Fish

Species: Brachydanio rerio
Time: 96,0 h
Value: 4,800 mg/l
________________________________________________________________________
13 - Disposal Considerations
________________________________________________________________________
SUBSTANCE DISPOSAL
Contact a licensed professional waste disposal service to dispose
of this material. Burn in a chemical incinerator equipped with an
afterburner and scrubber but exert extra care in igniting as this
material is highly flammable. Observe all federal, state, and

SIGMA www.sigma-aldrich.com Page 4 of 6

 local environmental regulations.
________________________________________________________________________
14 - Transport Information
________________________________________________________________________
RID/ADR
UN#: 3295
Class: 3
PG: II
Proper Shipping Name: Hydrocarbons, liquid, n.o.s.

IMDG
UN#: 3295
Class: 3
PG: II
Proper Shipping Name: Hydrocarbons, liquid, n.o.s.
Marine Pollutant: No
Severe Marine Pollutant: No
Technical Name: Required

IATA
UN#: 3295
Class: 3
PG: II
Proper Shipping Name: Hydrocarbons, liquid, n.o.s.
Inhalation Packing Group I: No
Technical Name: Required
________________________________________________________________________
15 - Regulatory Information
________________________________________________________________________
CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
INDICATION OF DANGER: N
Dangerous for the environment.
R-PHRASES: 10-51/53
Flammable. Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
S-PHRASES: 61
Avoid release to the environment. Refer to special
instructions/safety data sheets.

COUNTRY SPECIFIC INFORMATION

Germany
WGK: 1
Self-Classification
________________________________________________________________________
16 - Other Information
________________________________________________________________________
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2010 Sigma-Aldrich Co. License granted to make
unlimitedpaper copies for internal use only.

SIGMA www.sigma-aldrich.com Page 5 of 6

DISCLAIMER
For R&D use only. Not for drug, household or other uses.

SIGMA www.sigma-aldrich.com Page 6 of 6