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The Third Question
a. For one component homogenous system that contains very large number of
particles, prove that: U = KT ln Ω + nKT ln P, where P is the partition function of
the system. (8)
b. Calculate the entropy increase when 10 grams of gold are mixed with 20 grams of
silver to form an ideal homogenous alloy. The atomic weights of Au and Ag are
197 and 108, respectively. (7)
The Fourth Question
a. For sulfur dioxide gas, Tcrit = 430.7K and Pcrit = 77.8 atm. Calculate:
i. the van der Weals constants for the gas, (5)
ii. the critical volume of van der Waals SO2, and (5)
iii. the pressure exerted by 1 mole of SO2 occupying a volume of
500 cm at 500K. Compare this with the pressure which would be exerted by
an ideal gas having the same temperature, comment on your results. (5)
b. A solid metal M can form two oxides, MO and M3O4. The metal can exist in
equilibrium with one of these oxides at low temperatures and can exist in
equilibrium with the other oxide at high temperatures. The standard free energies
of formation of these oxides are:
Determine which of the two oxides is in equilibrium with the metal at room
temperature, and the maximum temperature at which this oxide is in equilibrium
with M. (14)
The Sixth Question
a. Small droplets of gold have been observed to supercool by a maximum amount of
approximately 230 °C. What is the entropy change associated with the isothermal
solidification of 1 gm atom of such supercooled droplets of gold? What is the
entropy change of the surrounding if its temperature remains at the same
temperature of the supercooled gold? Also, calculate the total entropy change;
given that: (10)
ΔH°(fus) of Au = 3,050 cal/(gm atom)
Cp (Au)s = 5 cal/ (deg-gm atom)
Cp (Au)l = 7 cal/ (deg-gm atom)
Melting point of gold = 1063 °C
2
b. The rate constants k for the leaching of galena in an aqueous medium containing
ammonite acetate under constant oxygen pressure at different temperatures are
listed below:
log k -10.9 -11.1 -11.2 -11.5 -12.1 -12.6
3
(1/T) x 10 2.3 2.35 2.38 2.45 2.61 2.75
2 -4 -1
where k in mole .cm .min and T in K. Calculate the activation energy of the
leaching process. (10)
Good Luck
Prof. Dr. Fawzi A.
Elrefaie