Documente Academic
Documente Profesional
Documente Cultură
Supervised By:
Prof. Dr. Arshad Chughtai
Submitted By:
Waqas Iqbal CE09-10M08
SUPERVISOR:
Prof. Dr. Arshad Chughtai .........................................
Institute of Chemical Engineering and Technology, Signature
University of the Punjab, Lahore.
II
Supervisor
Prof.Dr. Arshad Chughtai
Innovators:
Message:
“Throughout our university life we learned a lot of things not just about study but also
about life from our fellows and our teachers. We have made lifelong friendship,
memories and lived a dream life. Our teachers played hugely important role in
grooming our personality, they not only taught us engineering but more importantly
they tried best to make us a good human being and a responsible citizen. Words are not
enough to thanks them and we promise we will carry on this identity of I.C.E.T to new
level where ever we will go in future INSHAALLAH”
III
Acknowledgement
All praises to Almighty ALLAH who gave us light in darkness and gave us ability and
strength to complete our research project and all respects are for His Prophet
Muhammad (PBUH, on whom be ALLAH’S blessings and salutations)
We take immense pleasure in thanking our worthy teachers for their valuable help
regarding our research project. We all owe special thanks to our project supervisor
Prof. Dr. Arshad Chughtai, who helped us throughout our research work and during
the compilation of this Design project. His motivation, guidance and kind words
always encouraged us to work with commitment. Whenever we found ourselves in any
sort of trouble, we always found him available to cater the issue. This sort of
generosity and favor is highly commendable.
We are grateful to our parents for their special prayers that helped us achieve this
tedious task in the compilation of this design project.
IV
ABSTRACT
Synthesis gas produced from wood feed stock usually contains gaseous impurities
such as carbon dioxide and hydrogen sulphide which are acids in aqueous solution
thus highly corrosive to the processing equipment and poisonous to Catalyst,
impurities laden-gas is also highly toxic and malodorous and is referred to as “sour
gas”.
The purpose of project is to design “Amine Treating Unit” (ATU). There are many
processes for the recovery of acid gas from Synthesis gas but we selected Absorption
Process by using Amine solvents (MDEA), because the design of the process is
economically most favorable. The economics of the plant also make balance with the
efficiency and is most suitable to the oil and gas reserves of Pakistan.
The process selected for this purpose is the Absorption Process by using Amine
solvents (MDEA) and the unit is designed to treat 208MMSCFD of Synthesis gas. This
Design Project includes introduction and processing of various methods employed for
the Acid gas recovery from Synthesis gas.
ChemCAD, Aspen HYSYS, MS Excel, and MS Visio are the softwares that has been
used for the calculations and designing of the project.
The details of this Project contains material and energy balances across the Amine
treating unit (ATU), individual equipments design, instrumentation and control, cost
estimation, and Operational Problems of Amine treating unit (ATU).
In summary, the focus on the future improvements in the Absorption process by using
Amine Solvents makes this project distinctive and particularly relevant for educating
present or perspective engineers. We worked very hard to complete this project. Our
aim is to stimulate young future engineers. We also strived to develop the design of the
Amine Treating unit (ATU) that will capture engineer’s attention and is easy for the
engineers to use and adapt.
V
Table of Contents
1. INTRODUCTION
1.1 Synthesis Gas 1
1.2 Synthesis Gas: A Historical Overview 1
1.2.1 Historical Terminology Related to Different types of Synthesis gas 2
1.2.2 From Feedstock to Synthesis Gas: A brief over view 3
1.3 Need of Purification of Synthesis Gas 3
1.4 Application of Synthesis Gas 6
1.5 Principal Gas Phase Impurities 9
1.6 Gas purification 10
1.6.1 Absorption 11
1.6.2 Adsorption 21
1.6.3 Membrane Permeation 22
1.6.4 Chemical conversion 24
1.6.5 Condensation 24
2. PROCESS SELECTION
2.1 Process Selection 25
2.2 Process Description 28
2.3 Equipments used in The Process 29
2.4 Process Flow Diagram for Amine Sweetening Process 33
3. MATERIAL BALANCE
3.1 Introduction 34
3.2 Synthesis Gas Composition 35
3.3 Inlet Gas Separator 36
3.4 Mass Balance on Absorber 41
3.5 Mass balance on Stripper 44
3.6 Balance across over-head separator 46
VI
3.7 Balance across the overhead reflux drum 47
3.8 Overall material balance 47
4. ENERGY BALANCE
4.1 Introduction 48
4.2 Conservation of Energy 48
4.3 Forms of Energy 49
4.4 Inlet Separator 50
4.5 Absorber 59
4.6 Lean Solvent Exchanger 69
4.7 Lean/Rich amine exchanger 70
4.8 Over head Stripper Condenser 71
4.9 Stripper 74
4.10 Energy Balance across Hydraulic Turbine 79
5. EQUIPMENT DESIGN
5.1 Inlet Separator 81
5.2 Plate Heat Exchanger 85
5.3 Absorber Design 96
5.4 Stripper Design 109
5.5 MDEA Surge Drum 119
7. COST ESTIMATION
7.1 Plant Cost Estimation 122
7.2 Capital Investment 122
7.2.1 Direct costs 122
VII
7.2.2 Indirect costs 123
7.3 Types of Cost Estimation 123
7.4 Methods of Estimating Capital Investment 123
7.5 Percentage of Delivered Equipment Cost 123
7.6 Direct Cost 126
7.7 In-Direct cost 127
8. HAZOP STTUDY
8.1 HAZOP study 128
8.1.1 Objectives of HAZOP study 129
8.1.2 HAZOP Team 129
8.1.3 Strength of HAZOP 129
8.1.4 Weakness of HAZOP 129
8.1.5 Responsibility of HAZOP Team Members 130
8.1.6 Guide Words 130
8.2 HAZOP Study of storage Tank for MDEA 131
9. OPERATIONAL PROBELMS
9.1 Problems occurring during operation 134
9.2 Foaming 134
9.3 Corrosion 135
VIII
Chapter 1 Introduction
Chapter 1 Introduction
Hard Coal
Brown Coal
Natural Gas
Mineral Oil Fractions
Petroleum Gas
Biomass
Heavy Oil
Light oil fractions and Natural gas is most suitable for production of synthesis gas since they
contain high fraction of H2.
Revival of coal gasification is in progress by now in some part of world due to increasing oil
crisis and shortage
Synthesis gas can also be made from plastics using chemical recycling process which are use
to convert plastics to gaseous raw material (synthesis gas ) and liquid
1
Chapter 1 Introduction
for lightening street lights and for industrial heating. With time the increasing demand for
chemicals and energy developed interest in field of synthesis gas technology. The main reason
for this was:
1. Due to high flexibility, synthesis gas can be used in variety of process like fuel
production, power generation, chemical manufacturing.
2. Synthesis gas provide better opening to use renewable fuels and low cost fuel as it
can be produce from multiple kind of solid fuel.
Below we will look into some historical development in the field of Synthesis gas:
1813: Westminster Bridge which is in London was first light up with use of town gas on the
eve of New Year with help of wooden pipe for delivery of gas.
1816: Town gas was use for first time to Light up streets light in Baltimore Maryland, US
1800s: Town gas was use to replaces lanterns and candle in factories which lead to
Producer gas: Reaction of coke with humid air produce syngas which contain nitrogen
diluent in significant amount, such gas is called producer gas
Town gas: It is a type of synthesis gas which is produced from coal. In 1800s it was basically
used for lighting. To create yellow flame for purpose of lighting, heavy hydrocarbons were
added.
Blast Furnace Gas: It is the product gas which is obtained from blast furnace where iron
oxide reduces using coke to produce iron. This process produces gas which contains
nitrogen in large amount.
2
Chapter 1 Introduction
The next stage in production of synthesis gas is the called as reaction phase. In this phase the
feed stock react with oxygen, water vapors and carbon dioxide in case of oxygen rich material
the reaction is initiated by thermal decomposition.
The next stage in processing of synthesis gas is the purification stage. The gas produce in
previous steps is raw synthesis gas which is not very clean to be use in further process. In
purification process impurities like carbon dioxide, tar, ash, sulfur compound, methane, water
vapors is removed. After completion of purification process the ratio of carbon monoxide and
hydrogen is also adjusted depending on the product for which production this synthesis gas will
be use further. This synthesis gas is now ready for further use
When synthesis gas is brought in contact with different catalyst which mostly contain
compound of metal like copper, iron, Manganese, cobalt then new complex molecules are
formed. Now a days scientist working on finding new ways of creating already discovered
molecular combination by experimenting synthesis gas with different catalysts This is how
environmental friendly fuel can be made now a days.
When synthesis gas is used for combustion process or applications then it should be purify to
meet the required standard of atmospheric emission by keeping emission like SOx and NOx in
control. To determine the amount of purity of synthesis gas required for combustion process
we take help of material balances involve in combustion and assuming in what way synthesis
3
Chapter 1 Introduction
gas will be oxidized in the furnace or combustor(for calculation and estimation is considered
appropriate to assume impurities like NH3 and H2S are all converted into NOx and SO2 stack
emission ). The process where flue gases are scrubbed with the help of selective catalytic
reduction the sulfur removal from synthesis gas is also required to keep NOx under control.
In the chemical or fuel production process the purity of synthesis gas is determined by catalyst
requirements. In some cases even small amount of impurities can damage or poison whole
catalyst so purification requirements in case of catalyst are quite strict and stringent. For
example Van Der Burgt and Higman (2003 ) showed that catalyst which is used in Fischer-
Tropsch(FT) for production of liquid fuel requires that the syn gas use as raw material should
contained combined HF+HCl+HBr less than 10 ppb. Now a day such techniques are use which
purify gas to such level that it can be used in FT process. So before using syngas as raw material
it is necessary to purify it to meet downstream applications. Below we will see in table the
purification level of synthesis gas required for different downstream applications
4
Chapter 1 Introduction
Produce in-situ;
Carbonyl
controlled to avoid turbine
material deposits
Fuel Cells: For molten carbonate fuel cells (MCFCs), earlier studies and requirements are
summarized by Thambimuthu (1993). For solid oxide fuel cells (SOFCs), recent studies have
established the required purity for multiple trace species; see papers by Gemmen and Trembly
(2006) and Trembly et al. (2007a, 2007b, 2007c).2
5
Chapter 1 Introduction
Synthesis gas is a combustible material and can be used in various combustion processes as
fuel. It can also be used to produce steam which in turn can be used to produce electricity from
steam cycle using prime mover, gas engines, turbine as well as fuel cell.
In the big scale project that used coal gasification for the operation of gas turbine to produce
electricity using combined cycle technology, it is possible to operate that gas turbines on syngas
with combined cycle. This will provide opportunity to implement the idea of large scale
electricity production using syngas (biomass) without actually employing much effort on small
scale technologies of biomass gasification. Eventually by using this idea we can convert coal
fired power plant into biomass plant (bio syngas) for short term, it will help us to produce large
amount of green (environmental friendly) electricity. Implementation of this short term
possibility is more beneficial to produce large amount of clean, environmental friendly
electricity than relying just on those small scale green electricity production facilities. In this
way national governments and environmental authorities stringent emission limits can also be
met. This idea is already implemented in many facilities around the world For example, 253
Mega Watt coal fired entrained flow (IGCC) plant in Netherlands (Buggenum) is about 18 % by
weight biomass (bio syngas ) co fired.
1. Automobile Fuels:
It is widely expected that in future syngas will be used to produce large amount of Ultra clean
Transportation duel from process like GTL. Methanol/ DME and Fischer-Tropsch Diesel are the
prominent example of this idea.
Methanol:
Methanol can be produce by using syngas. It can be produce by catalytic reaction of hydrogen
and carbon monoxide and some amount of carbon Dioxide. These reactions proceed with the
contraction of volume and both are exothermic in nature. This presence of small amount of
Carbon Dioxide keep the reaction in optimum zone in other words it enhance the reaction, As
these reaction are exothermic and proceed with reduction in volume so higher pressure and
lower temperature are favorable condition for reaction to occur.
It Important to keep an eye on side reaction of this process as those side reaction are also
highly exothermic and lead to the formation of many by product like that of methane DME
(Dimenthyl ether ) and higher alcohols. Now a days all over the world Methanol on Industrial
6
Chapter 1 Introduction
scale is produce by conversion of Syn Gas in the presence of desire catalyst. The process of
production of methanol is divided into three types on the basis of pressure used:
CO + 2H2 CH3OH
Optimum operating condition for Fischer-Tropsch Synthesis include pressure in range of 25-60
bar and temperature should be in range of 200-350oC. Almost 20% of chemical energy is
dissipated in form of heat due to exothermic nature of this reaction. Following chemical
reaction take place:
7
Chapter 1 Introduction
2. Chemical Synthesis:
Ammonia :
Large amount of ammonia (85% ) produce world wide is used in the synthesis of fertilizers
while the remaining amount of ammonia is use in other useful application. Every nitrogen
atom which is used in industry in various application is obtained somehow (indirectly or
directly) from ammonia or nitric acid (derivative of ammonia). NH3 is used in the synthesis of
plastics, explosives, fibers for used in polyamides, polyurethane, polyacronitril, fertilizers,
animal feed. Ammonia production process required two main thing firstly nitrogen
concentration should be high and secondly the amount of CO and CO 2 should be limited to less
than 20 ppmV.3 So before using synthesis gas amount of CO and CO2 should be controlled by
using various CO and CO2 removal process. Ammonia production is carried out at temperature
of 350-550oC and at a pressure of 100-250 bar in the presence of suitable catalyst. :
N2 + 3H2 2NH3
Hydroformylation of olefins :
This process is also called as Roelen reaction or oxo-synthesis process for the manufacturing
of aldehydes on commercial scale. It is a catalytic reaction in which reaction take place
between synthesis gas (containing hydrogen and carbon monoxide) and olefins to form
aldehydes. These aldehydes contains additional carbon atom. The reactions occur as shown
below. In this reaction CO and H2 is added catalytically into olefins which result in aldehydes.
Alcohols and aldehydes are produce on industrial scale through Hydroformylation reaction.
The most significant products of oxo synthesis are C3-C19. Out of these butanal is one of the
most important product. Most used olefin is propene. The Products of oxo-synthesis is further
converted into aldol-condensation products, carboxylic acid, alcohols, primary amine.
Hydrogen in refineries:
In refineries main source of hydrogen is synthesis gas. Synthesis gas is obtained from heavy oil
through gasification and mainly from natural gas through steam reforming. This hydrogen is
used in refinery for purpose of hydro-treating and in other hydro-processing process.
Hydrogenation of olefins and removal of impurities (nitrogen and desulphurization) is
accomplished by using hydro treating. There are many hydro-treating units in refinery for
hydro treatment of several product fractions which includes heating oil, gasoline, kerosene,
8
Chapter 1 Introduction
diesel etc and also for pretreatment of feedstock which is used in catalytic cracking process.
On the other hand transportation fuels can by produce from the products obtained as a result
of hydro processing operation. Hydro processing operation basically involves the production of
lighter products from heavy oil fractions. The feed stock requirement for hydro cracking is 4 :
sum of CO2 And CO should be less than or equal to 10-15ppmV, H2 should be more than or
equal to 98% by volume, O2 should be less than or equal to 100 ppmV, inert gas should be less
than 2% by volume.
Acid Gas:
It is a gas containing acidic components such as CO2, H2S,COS (carbonyl sulphide), CS2(carbon
sulphide) RSH that can form acidic solutions when mixed with water.
Composition:
Mainly contains of CO2 and H2S gases. Both gases can cause corrosion. These gases are obtained
after a sweetening process applied to a sour gas.
9
Chapter 1 Introduction
Chemical
Absorption in to a
liquid
Physical
Adsorption on a
solid
Gas Purification
Permeation through
a membrane
Chemical conversion
to another
compound
Condensation
10
Chapter 1 Introduction
1.6.1 Absorption:
It refers to the transfer of a component of a gas phase to a liquid phase in which it is soluble.
Stripping is exactly the reverse-the transfer of a component from a liquid phase in which it is
dissolved to a gas phase. Absorption is undoubtedly the single most important operation of
gas purification processes.
Chemical Absorption
It is a type of separation process in which absorbent solution (solvent) reacts chemically with
acid gases presence in natural gas to produce compounds. E.g. Gas Sweetening process
• The compounds can be dissociated by heating or operating at low pressure of stripping.
• Used solvent is regenerated and re-use again
I. Amine solutions
Amines are of three types.
Primary Amines:
Amines which have two hydrogen atoms directly attached to a nitrogen atom, such as
monoethanolamine(MEA) and 2-(2-aminoethoxy) ethanol (DGA), are called primary
amines and are generally the most alkaline.
Secondary Amines:
Diethanolamine(DEA) and Diisopropanolamine(DPA) have one hydrogen atom directly
attached to the nitrogen atom andarecalled secondary amines.
Primary and secondary amines are known for their non-selectivity, and can remove
comparatively more CO2than H2S from the feed syngas stream.
Tertiary Amines:
Triethanolamine (TEA) and Methyldiethanolamine (MDEA) represent completely substituted
ammonia molecules with no hydrogen atoms attached to the nitrogen, and are called tertiary
amines.
In comparison, a tertiary amine process such as MDEA and physical solvent systems of Selexol
and Rectisol can selectively remove first H2S then CO2
from a feed gas stream, and thus in principal, has a higher degree of control with meeting the
needed clean syngas specification. Also, MDEA has a lower circulation rate and regeneration
energy requirement than primary and secondary amine processes of MEA and DEA
respectively.
11
Chapter 1 Introduction
NOTES:
1. These data alone should not be used for specific design purposes. Many design factors must be considered for actual plant
design.
2. Dependent upon acid gas partial pressures and solution concentrations.
3. Dependent upon acid gas partial pressures and corrosiveness of solution. Might be only 60% or less of value shown for
corrosive systems.
4. Varies with stripper overhead reflux ratio. Low residual acid gas contents require more stripper trays and/or higher reflux
ratios yielding larger
reboiler duties.
5. Varies with stripper overhead reflux ratios, rich solution feed temperature to stripper and reboiler temperature.
6. Maximum point heat flux can reach 20,000–25,000 Btu/hr-ft2at highest flame temperature at the inlet of a direct fired fire
tube. The most satisfactorydesign of firetube heating elements employs a zone by zone calculation based on thermal efficiency
desired and limiting the maximum tube wall temperature as required by the solution to prevent thermal degradation. The
average heat flux, Q/A, is a result of these calculations.
7. Reclaimers are not used in DEA and MDEA systems.
8. Reboiler temperatures are dependent on solution conc. flare/vent line back pressure and/or residual CO2content required. It
is good practice to operatethe reboiler at as low a temperature as possible.
9. According to Total.
10. B.L. Crynes and R.N. Maddox, Oil Gas J., p. 65-67, Dec. 15 (1969). The heats of reaction vary with acid gas loading and
solution concentration. Thevalues shown are average
12
Chapter 1 Introduction
Advantages:
used in solution of 15-18 wt%, to avoid corrosion.
Low solvent cost.
Good thermal Stability.
reacts strongly with CO2 and H2S.
High solution capacity at moderate concentrations typically acid gas. Pickup 0.33–0.40,
mols/mol amine,
contaminated solution can be easily reclaimed.
recommended for treatment of natural gas with low acid gas content (<10%)
enables compliance with strict acid gas specifications.
Disadvantages:
Operation energy consuming.
Required very careful operation of unit.
High corrosion potential than any other alkanolamines.
Non selective removal in a mix acid gas system.
High vapor pressure causes high vaporization losses in low-pressure operation.
easily degraded.
by oxidation
by reaction of COS and CS
by overheating the solution
13
Chapter 1 Introduction
b) DEA
Advantages:
• used in 15-20 wt% solution but upgraded from 25-40 wt% solution
• reduced in solution circulation flow rate and energy consumption
• Greater resistance to degradation than MEA
• Low in vapor pressure make DEA losses are reduced
• Effective in simultaneously remove CO2 and H2S
• Preferable to replace MEA for treatment of natural gas with low acid gas
content
Disadvantages:
Operation energy consuming.
Required very careful operation of unit.
The reclaiming of contaminated solutions is more complex since vacuum distillation may
be required6
14
Chapter 1 Introduction
c) MDEA
Advantages:
used in 35 –50 wt% solution.
Selective removal of H2S
it can be partially regenerated ina simple flash
for extraction of H2S and leaving some CO2in treated gas
For production of CO2 with little H2S to enhance oil recovery fluid.
H2S enrichment of acid gas before treatment in Claus unit.
not behave in the same way as MEA and DEA
rate of reaction for MDEA-H2S extremely fast
rate of reaction for MDEA-CO2involves formation of carbonic acid and slow
Lower corrosion rates.
Lower heat of reaction results in lower regeneration energy.
It is more economical with respect to rates of solvent circulation and requirements for
energy7
Disadvantages:
Contact time is too short for absorption of all CO2.
For enhancing CO2 absorption some promoters should have to be added.
Cannot be reclaimed by conventional reclaiming techniques.
15
Chapter 1 Introduction
Reaction 2 is instantaneous; the rate of diffusion of H2S from vapor to liquid phase controls the
rate of absorption of H2S.
For CO2, rate of absorption proceeds by two parallel chemical reaction schemes.
16
Chapter 1 Introduction
The second mechanism consists of direct reaction of the amine and CO2 to form a
zwitterionic intermediate which reacts with a second mole of amine to form the amine
carbamate.Only primary and secondary amines such as MEA, DEA, and DGA can react
via the carbamate mechanism. With these classes of amines, carbamate formation is
rapid and the bulk of the CO2 is absorbed in this way.In the carbamate mechanism, two
moles of amine are consumed for each mole of CO2absorbed. Thus, primary and
secondary amines have a maximum practical CO2 loading of 0.5mole/mole.
17
Chapter 1 Introduction
18
Chapter 1 Introduction
PHYSICAL ABSORPTION:
In this process an organic solvent is used to remove the acid gases from syngas. The process is
carried out at low temperatures and high pressures. In physical absorption the loading capacity
of the solvent is mathematically described by Henry’s law which states that the absorption is
directly proportional to the partial pressure of the acid gas component in the syngas. Hence the
more the volume of the syngas to be processed, the more is the solvent rate required for the
desired absorption. This is shown in the fig below. During solvent regeneration reboiling is used
along with flashing and stripping which raises the temperature and reduces the solubility of
absorbed aid gases.
Characteristics:
Acid gases dissolve in the solution under pressure and temperature
Favoured by high acid gas partial pressure concentrations (contributed by both pressure
of CO2 and/or H2S) and low temperature
Use solvent is an operating parameter that will dictate the degree of efficiency of
absorption
Solvent is regenerated by low pressure expansion of solution rich in dissolved acid gases
Involves no chemical reaction between acid gases and the solvent
19
Chapter 1 Introduction
Properties of solvents:
For industrial used, properties of solvents should have:
• high solubility with respect to acid gases
• low viscosity at operating temperature to facilitate solvent circulation
• resistivity to corrosion of carbon steel
• high thermal stability, i.e. not degraded under operating conditions (T, P, reaction)
• low vapor pressure at operating conditions to minimize solvent loss
• reasonable price
20
Chapter 1 Introduction
1.6.2 Adsorption:
It is the selective concentration of one or more components of a gas at the surface of a micro
porous solid. The mixture of adsorbed components is called the adsorbate, and the micro
porous solid is the adsorbent. The attractive forces holding the adsorbate on the adsorbent are
weaker than those of chemical bonds, and the adsorbate can generally be released (desorbed)
by raising the temperature or reducing the partial pressure of the component in the gas phase
in a manner analogous to the stripping of an absorbed component from solution. When an
adsorbed component reacts chemically with the solid, the operation is called chemisorption
and desorption is generally not possible.
Although adsorption can be practiced with many solid compositions, the great majority ofgas-
purification and dehydration adsorbents are based on some
form of silica, alumina (including bauxite), carbon, or certain silicates, the so-called molecular
sieves. The silica and alumina-base adsorbents are primarily
used for dehydration, while activated carbon has the specific ability of adsorbing organic vapors
and is very important for this purpose. The molecular sieves have very unusual properties with
regard to both dehydration and the selective adsorption of other compounds.
21
Chapter 1 Introduction
22
Chapter 1 Introduction
Advantages:
Operational simplicity. The one-stage systems have no moving parts. For the two-stage
systems, the addition of the recycle adds some complexity.
Reduced space requirements
Ideal for remote locations
Can be used to debottleneck existing solvent-based plant. In such cases, the membrane
is used for bulk acid gas removal, and the existing solvent-based system is used for the
final cleanup.
contains little or no H2S.
in treating NG very rich in CO2(over 20%)
use lower CO2content to around 2%
Disadvantage:
cannot be widely used until improve in permeability and selectivity of membrane and
resistance to deterioration.
Because membranes use pressure as the driving force of the process, there may be a
considerable energy requirement for gas compression.
23
Chapter 1 Introduction
1.6.5 Condensation:
As a means of gas purification is of interest primarily for the removal of volatile organic
compounds(VOCs) from exhaust gases. This process consists of simply cooling the gas stream to
a temperature at which the Organic compound has a suitably low vapor pressure and collecting
the condensate.
24
Chapter 2 Process Selection
Chapter 2 Process Selection
Method used for gas treatment has various effects on the overall gas processing process and
facility. It usually affects the methods which are selected for various other processes like acid
gas removal, liquids fractionation, sulfur recovery, liquid product treatment and liquid recovery.
Following point’s designer must keep in mind while selecting any process for treatment of
gas13:
Selection of the process can be done quite easily by examining the chart below shown14:
In our process the the partial pressure of acid gas of the feed (syngas ) is 71.355 psia while
the partial pressure of acid gas in the product is 7.178 psia. By comparing these values on
the chart above shown we get the following result
25
Chapter 2 Process Selection
Our process lies in the region where physical or amine system is feasible. We have to make now
selection between the amine or physical system.
The physical absorption process has draw back compare to other process that it is economically
less feasible when partial pressure of acid gas is low because capacity of physical solvent is
function of partial pressure.
According to Stupin, partial pressure of acid gas above 200 psia is suitable for physical
absorption whereas low partial pressure of acid gas is suit able for alkaline solution absorption.
Schaaf and Tennyson (1977) indicated that chemical solvents are use at partial pressure
between (60-100psia)and above this pressure range physical solvent is used15
From the discussion above made, chemical absorption would be our choice. In chemical
absorption we have different types of amines. We have selected a tertiary amine (Methyl di
ethyl Amine) due to the following distinctions over primary and secondary amines 16.
MDEA serves saving of energy from reduced reboiler duties (reflux ratio 0.5 to 1.0) and
lower overhead condenser duties. Highly selective towards H2S when compared with
CO2, resulting in lower circulation rates and recycling higher quality of acid gas to
sulphur recovery unit.
MDEA can be used in greater concentration thus a greater capacity to react with acid
gas
26
Chapter 2 Process Selection
Usually the concentration 30-50% and 0.4-0.5 moles acid gas pick up per mole of MDEA
has increased the capacity of existing unit and allowed the equipment to be to be
considerably smaller for newer units. High pick up rate and high concentration reflects
lower solvent circulation rates for equivalent capacities
MDEA has less heat of reaction with CO2 and H2S as compared with DEA and MEA
27
Chapter 2 Process Selection
The synthesis gas first enters the knock out drum followed by absorber in which most of the
absorption takes place. The solvent which is used for extraction of acid gas enters from top of the
absorber.
After the absorption of acid gases in absorber the solvent leaves the absorber from the bottom
and this solvent is called as Rich solvent (contain absorbed acid gases). This rich solvent then
passes through heat exchanger after which its temperature raises. In heat exchanger this rich
solvent exchanges heat with lean solvent coming from the stripper.
This rich solvent then enters in stripper where acid gases and some amount of water vapors are
removed from it and this mixture of water vapor and acid gases passes through the condenser and
then enters separator where water vapors are separated from acid gases. The water which left the
separator from bottom is the pump back to top of stripper column
The solvent which leaves from bottom of stripper is now called as lean solvent as acid gases are
removed from it. This solvent then passes through the heat exchanger where heat exchange takes
place between lean and rich solvent. Then this solvent enters the absorber from its top at
temperature and pressure of 110oF and 432psia respectively.
The treated gas having H2S content of about 2ppmv is then sent to the ZnO bed to meet the
desired concentration of H2s of 10-5mol % to synthesize methanol
28
Chapter 2 Process Selection
I. Inlet Separator:
The characteristic, objective and alternative equipment of inlet separator are mentioned below :
Objectives:
The main objective of inlet separator is to prevent liquid contaminants from entering in amine
system. These liquid contaminates are mostly hydrogen condensate, water or mist.
Characteristic:
Inlet separator is basically employ demister pad which remove liquid contaminates from carrying
over to amine system. It is a demister containing vertical drum.
Alternatives Equipment:
The equipment which can be used as replacement of inlet separator is Cartridge filter separator
II. Absorber:
The characteristic, objective of Absorber are mentioned below:
Objective:
The main application of absorber is to remove acid gas from the feed.
Characteristic:
29
Chapter 2 Process Selection
Objective:
The primary objective of Amine flash drum is to remove entrained liquid hydrocarbon and
dissolved gas prior to sending them to amine/amine heat exchanger& stripper for recovery of
amine solution.
Characteristics:
Alternative Equipment:
Hydraulic turbine can be used in place of flash drum. Through the use of hydraulic turbine we can
produce power to drive circulation pumps.
Objective:
The function of amine/amine heat exchanger is to heat the rich solution ( acid gas containing
solution ) before sending it to stripper ( regenerator). This reduces the heating load on stripper to
some extent.
Characteristics:
It is shell and tube exchanger having lean solution on shell side whereas rich solution is in
tube side.
To minimize the chances of erosion or corrosion as a result of mix flow, vaporization
should be as minimum as possible in exchanger.
Maximum 1m/s velocity should be allowed.
If more than one exchanger is to be used then exchangers will be installed one above the
other vertically. Rich solution will then enter the bottom exchanger from its lower part
and any released gas will flow out by moving upward alone amine solution.
The inlet temperature of lean solution is about 110-130 degree C
The outlet temperature of rich solution is about 90-110 degree C
30
Chapter 2 Process Selection
Alternative:
The alternative equipment for this purpose is plate frame exchanger . This exchanger offer high
heat transfer rates and larger surface area but are more prone to fouling.
V. Regenerator:
The characteristic, objective of Regenerators are mentioned below:
Objective:
The function of regenerator is to remove acid gases from rich solution by stripping so that rich
amine solution is regenerated.
Characteristics:
VI. Reboiler:
The objectives, characteristics of Reboiler are shown below:
Objectives:
The main purpose of Reboiler is to add heat to the acid gases containing rich solution to generate
energy for moving the chemical reaction in backward direction which will result in stripping of acid
gases from rich solution and reboiler also produce steam required to remove acid gases. The
overhead reflux ratio governed the efficiency of stripping.
Characteristics:
The reboiler mostly use is kettle type. The recommended tube pitch is square.
The outlet temperature of the regenerated solution depends on amine strength and
operating pressure.
The heating medium rate controls the duty of reboiler.
The prevent amine degradation the temperature of less than 145 degree C is
recommended for tube skin.
31
Chapter 2 Process Selection
To enhance the good natural circulation, space should be left below the bundle. This space
will also provide place for sludge deposition.
To avoid overheating and localized drying the layer of liquid should be high enough that it
totally covers the tube bundle.
Vapor volume should be high enough to prevent solution entrainments.
Objective:
The purpose of refuel drum is to recover the condensed water in condenser as stripper reflux and
also to remove any condensed hydrocarbon.
Characteristics:
Objectives:
Surge tank has spare capacity equal to that of amine solution hold up for maintenance unloading
or emergency
Characteristics:
32
Chapter 2 Process Selection
33
Chapter 3 Material Balance
Chapter 3 Material Balance
3.1 Introduction:
A mass balance (also called material balance) is an application of law of conservation of mass to
the analysis of physical systems. By accounting for material entering and leaving the system,
mass flows c a n b e identified which might have been unknown or difficult to measure without
this technique. The exact conservation law used in the analysis of system depends on the
context of problem but all revolve around mass conservation. That is that matter cannot
disappear or be created spontaneously.
The general form quoted for a mass balance is the mass that enters a system must, by
conservation of mass, either leave the system or accumulate within the system.
Mathematically the mass balance for a system within the system without chemical reaction is
as follows.
34
Chapter 3 Material Balance
Here an assumption is taken that there is no chemical reaction is taking place and our system is
steady state process. Hence
35
Chapter 3 Material Balance
Vapor (V)
300
Feed (F)
205
301
Our inlet gas separator has a temperature of 110 °F, so those components which have critical
temperature less than 110 °F will remain in gas phase. Otherwise they will be in liquid phase.
36
Chapter 3 Material Balance
Hydrogen Sulfide has not critical temperature less than 110 °F but it has a very high vapor
pressure so that at this temperature of inlet gas separator, H2S will be present in gas phase.
Antoine Equation,
( )
T = Temperature in kelvin K
37
Chapter 3 Material Balance
P = 429.5psi
1. For Water:
YH2O = XH2O = 2.9406 x 10-3 XH2O (1)
2. For Ammonia:
YNH3 = XNH3 = 0.555 XNH3 (2)
3. For Benzene:
YC6H6 = XC6H6 = 9.35 x 10-3 XC6H6 (3)
4. For Naphthalene:
YC10H8 = XC10H8 = 4.23 x 10-5 XC10H8 (4)
I. For H2:
7089.5 = XH2L + YH2V
As it is only present in Vapor phase, so XH2L = 0
7089.5 = YH2V
YH2 = (5)
II. For CO2:
3674.73 = YCO2 V
YCO2 = (6)
III. For CO:
3241.36 = YCO V
YCO = (7)
IV. For CH4:
291.69 = YCH4 V
YCH4 = (8)
V. For C2H4:
1.86 = YC2H4 V
38
Chapter 3 Material Balance
YC2H4 = (9)
VI. For C2H6:
0.367 = YC2H6 V
YC2H6 = (10)
VII. For H2S:
7.44= YH2S V
YH2S = (11)
Viii. For N2:
8.39 = YN2 V
YN2 = (12)
IX. For H2O:
7849.39 = XH2O L + YH2O V
From Eq.1
7849.39 = YH2O/2.9406 x 10-3 L + YH2O V
7849.39 = YH2O { L (340.136) + V }
YH2O = ( )
(13)
X. For NH3:
1.706 = XNH3 L + YNH3 V
From Eq.2
1.706 = YNH3/0.555 L + YNH3 V
1.706 = YNH3 {1.80 L +V}
YNH3 = * (14)
+
XI. For C6H6:
2.44 = XC6H6 L + YC6H6 V
From Eq.3
2.44 = YC6H6/9.35 x 10-3 L + YC6H6 V
2.44 = YC6H6 {106.95 L + V}
YC6H6 = (15)
* +
XII. For C10H8:
0.0156 = X C10H8 L + YC10H8 V
From eq.4
0.0156 = YC10H8/4.23 x 10-5 L + YC10H8 V
0.0156 = YC10H8 {23640.6L + V}
YC10H8 = * +
(16)
39
Chapter 3 Material Balance
1= + + + + + + + + ( )
+
+* +*
* + + +
V=V[ + ( )
+* +* +* ]
+ + +
We know that
L = 22167 – V
Putting this value in above Equation and solving by computer program
V = 14358
L = 22167 – 14358
L = 7809
By putting the value of V in Eq. (5 to 16) , we get
Composition of stream 300:
YH2 0.494
YC02 0.256
YCO 0.2258
YCH4 0.0203
YC2H4 0.00013
YC2H6 0.000026
YH2S 0.00052
YN2 0.00058
YH2O 0.00294
YC6H6 2.87 x 10-6
YNH3 6.0 x 10-5
YC10H8 8.5 x 10-11
40
Chapter 3 Material Balance
311
Amine recirculation rate
300
V = 14358
303
E
For stream 300:
Component Mole % Molar Flow
H2 0.494 7092.852
CO2 0.256 3675.648
CO 0.2258 3242.0364
H2O 0.00294 42.21252
CH4 0.0203 291.4674
C2H4 0.00013 1.86654
C2H6 0.000026 0.373308
C6H6 0.00000287 0.04120746
C10H8 8.5E-11 1.22043E-06
NH3 0.00006 0.86148
H2S 0.00052 7.46616
N2 0.00058 8.32764
41
Chapter 3 Material Balance
So,
( )
GPM =
GPM = 3919
Then ,
Using recommended 15% safety factor, lean amine flow rate = 2041015.2 x 1.15
= 2347167.48
= 1173583.74
42
Chapter 3 Material Balance
= 9848.80
So,
= 2166.689
= 1173583.74
Moles of water =
= 65200
Lean amine re-circulation rate (including acid gas) = 65200 + 9848.589 + 49.24
= 75098
We can write,
D = 10680.037 + 0.0200D
D = 10898
In D stream,
In E stream,
43
Chapter 3 Material Balance
306
312
305 309
307
Inlet stream 305: Out Stream 307:
44
Chapter 3 Material Balance
CO2 = 154308
= 152141.32
= 254.218
CO2 = 152141.32
H2S = 254.218
H2O = 9388.66
45
Chapter 3 Material Balance
313
312
309
Our reflux drum has a temperature of 130 °F , so those components which have a critical
temperature less than 130 °F will remain in gaseous phase otherwise they would remain in
liquid phase.
CO2 H2O
H2S
So feed stream contain same CO2 and H2S as in the vapor phase.i-e
46
Chapter 3 Material Balance
It is reported that reflux ratios between to mole of water per mole of acid gas are generally
used to make the process work properly.19
= 3465.477
= 4366.501
= 78597 of water
AH2O = 78597
CO2 = 152141.31
H2S = 254.218
H2O = 78597
422595.66 = 422643.7
47
Chapter 4 Energy Balance
Chapter 4 Energy Balance
4.1 Introduction:
As with mass, energy can be considered to be separately conserved in all but nuclear process.
The conservation of energy, however differ from that of mass in that energy can be generated
(or consumed) in a chemical process. Material can change form, new molecular species can be
formed by chemical process, but total mass flow into a process unit must be equal to flow out
at the steady state. The same is not true of energy. The total enthalpy of outlet streams will not
equal to that of inlet streams if energy is generated or consumed in the process; such as that
due to heat of reaction. Energy can exist in several forms: heat, Mechanical energy, electrical
energy, and these are the total energy that is conserved. In process design, energy balance are
made to determine the energy requirements of the process: heating, cooling and power
required. In plant operation, energy balance (energy audit) on the plant will show the pattern
of the energy usage, suggest areas for conservation and savings.
It is the statement of first law of thermodynamics. An energy balance can be written for any
process step. Chemical reaction will evolve energy (exothermic) or consume energy
(endothermic). For steady state processes, the accumulation of both mass and energy will be
zero. Energy can exist in many forms and this, to some extent, makes an energy balance more
complex than material balance.
In our project we are using the steady state energy balance i.e
As we are using the relation given below for the calculation of heat
Q= m Cp ∆T
Where
Q = Amount of heat
M = mass
Cp = specific heat
48
Chapter 4 Energy Balance
Potential energy = gz
The energy associated with molecular motion. The temperature T of the material is a measure
of its internal energy U;
U = f(T)
iv. Work:
W = FD
Where F = force
D = Distance
v. Heat:
Energy is transferred either as heat or work. A system does not contain “ Heat” but the transfer
of heat or work to a system changes its internal energy. Heat taken in by a system from its
surrounding is conventionally taken as positive and that given out as negative.
Electrical and mechanical forms of energy are included in the work term in an energy balance.
Electrical energy will only be significant in an energy balance on electrochemical processes.
49
Chapter 4 Energy Balance
300
205
Syn gas
301
Q- Ẇs =ΔH+ΔEx+ΔEp (1)
Assumption:-
ΔEx=0 ; ΔEp=0
Ẇs=0
Q = ΔH (2)
50
Chapter 4 Energy Balance
I. Hydrogen:
Formula used is Q = oCpΔT
Q= o x Cp x ΔT
Q= 7093.44 x6.9x33
Q=1615176.288
Q= o x Cp x ΔT
Q=3657.555x9.12 x33
Q=1100777.753
Q= o x Cp x ΔT
Q=3236.382 x 6.97 x 33
Q=744400.2238
Q= o x Cp x ΔT
Q= 7862.6349 x 17.98 x33
Q=46611`5215.792
51
Chapter 4 Energy Balance
V. Methane CH4:
Formula used is Q = oCpΔT
Q= o x Cp x ΔT
Q= 288.171 x 8.7 x 33
Q= 82733.8941
Q= o x Cp x ΔT
Q= 1.8575 x 10.7 x 33
Q=655.91665
Q= o x Cp x ΔT
Q= 0.3657 x 13.09 x 33
Q= 157.9954
Q= o x Cp x ΔT
Q= 0.563 x 21.13 x 33
Q= 392.60
52
Chapter 4 Energy Balance
Q= o x Cp x ΔT
Q= 0.01562 x 33.88 x 33
Q= 17.47
X. Ammonia NH3:
Formula used is Q = oCpΔT
Q= o x Cp x ΔT
Q= 1.76 x 8.63 x 33
Q= 502.5100184
Q= o x Cp x ΔT
Q= 7.448112 x 8.63 x 33
Q= 2022.832738
XII. Nitrogen:
Formula used is Q = oCpΔT
Q= o x Cp x ΔT
Q= 8.401x 6.97 x 33
Q=1932.381403
53
Chapter 4 Energy Balance
Q= o x Cp x ΔT
Q= 7808.2191 x 17.98 x33
Q=4632928.721
Q= o x Cp x ΔT
Q= 0.05356974 x 21.13 x 33
Q= 37.353644
Q= o x Cp x ΔT
Q= 0.01562 x 33.88 x 33
Q= 17.47
54
Chapter 4 Energy Balance
Q= o x Cp x ΔT
Q= 0.843372 x 8.63 x 33
Q=240.1839119
Q= o x Cp x ΔT
Q= 7092.852 x6.9x33
Q=1615042.4
Q= o x Cp x ΔT
Q=3675.648 x 9.12 x33
Q=1106223.022
Q= o x Cp x ΔT
Q=3242.0364 x 6.97 x 33
Q=745700.7924
55
Chapter 4 Energy Balance
Q= o x Cp x ΔT
Q= 42.21252 x 17.98 x33
Q=25046.37662
V. Methane CH4:
Formula used is Q = oCpΔT
Q= o x Cp x ΔT
Q= 291.4674 x 8.7 x 33
Q= 83680.29054
Q= o x Cp x ΔT
Q= 1.86654 x 10.7 x 33
Q=659.075274
Q= o x Cp x ΔT
Q= 0.373308 x 13.09 x 33
Q= 161.2578568
56
Chapter 4 Energy Balance
Q= o x Cp x ΔT
Q= 0.041 x 21.13 x 33
Q= 28.73354978
Q= o x Cp x ΔT
Q= 1.22043E-06x 33.88 x 33
Q= 17.47
X. Ammonia NH3:
Formula used is Q = oCpΔT
Q= o x Cp x ΔT
Q= 0.86148 x 8.63 x 33
Q= 245.34
Q= o x Cp x ΔT
Q= 7.46616 x 8.63 x 33
Q= 2027.734394
57
Chapter 4 Energy Balance
XII. Nitrogen:
Formula used is Q = oCpΔT
Q= o x Cp x ΔT
Q= 8.32 x 6.97 x 33
Q=1915.440476
3580730.466 =(4633244.686+8213985.662)
58
Chapter 4 Energy Balance
4.5 Absorber:
302
311
300
303
Q- Ẇs =ΔH+ΔEx+ΔEp (1)
Assumption:-
ΔEx=0 ; ΔEp=0
Q = ΔH (2)
59
Chapter 4 Energy Balance
Q= o x Cp x ΔT
Q= 7092.852 x6.9x33
Q=1615042.4
Q= o x Cp x ΔT
Q=3675.648 x 9.12 x33
Q=1106223.022
Q= o x Cp x ΔT
Q=3242.0364 x 6.97 x 33
Q=745700.7924
60
Chapter 4 Energy Balance
Q= o x Cp x ΔT
Q= 42.21252 x 17.98 x33
Q=25046.37662
V. Methane CH4:
Formula used is Q = oCpΔT
Q= o x Cp x ΔT
Q= 291.4674 x 8.7 x 33
Q= 83680.29054
Q= o x Cp x ΔT
Q= 1.86654 x 10.7 x 33
Q=659.075274
Q= o x Cp x ΔT
Q= 0.373308 x 13.09 x 33
Q= 161.2578568
61
Chapter 4 Energy Balance
Q= o x Cp x ΔT
Q= 0.041 x 21.13 x 33
Q= 28.73354978
Q= o x Cp x ΔT
Q= 1.22043E-06x 33.88 x 33
Q= 0.00136449
X. Ammonia NH3:
Formula used is Q = oCpΔT
Q= o x Cp x ΔT
Q= 0.86148 x 8.63 x 33
Q= 245.34
Q= o x Cp x ΔT
Q= 7.46616 x 8.63 x 33
Q= 2027.734394
62
Chapter 4 Energy Balance
XII. Nitrogen:
Formula used is Q = oCpΔT
Q= o x Cp x ΔT
Q= 8.32 x 6.97 x 33
Q=1915.440476
Q= o x Cp x ΔT
Q= 7092.852 x6.9x33
Q=1615042.4
Q= o x Cp x ΔT
Q=217.96 x 9.12 x33
Q=655597.2416
63
Chapter 4 Energy Balance
Q= o x Cp x ΔT
Q=3242.0364 x 6.97 x 33
Q=745700.7924
Q= o x Cp x ΔT
Q= 42.21252 x 17.98 x33
Q=25046.37662
V. Methane CH4:
Formula used is Q = oCpΔT
Q= o x Cp x ΔT
Q= 291.4674 x 8.7 x 33
Q= 83680.29054
Q= o x Cp x ΔT
Q= 1.86654 x 10.7 x 33
Q=659.075274
Q= o x Cp x ΔT
64
Chapter 4 Energy Balance
Q= 0.373308 x 13.09 x 33
Q= 161.2578568
Q= o x Cp x ΔT
Q= 0.041 x 21.13 x 33
Q= 28.73354978
Q= o x Cp x ΔT
Q= 1.22043E-06x 33.88 x 33
Q= 0.00136449
X. Ammonia NH3:
Formula used is Q = oCpΔT
Q= o x Cp x ΔT
Q= 0.86148 x 8.63 x 33
Q= 245.34
Q= o x Cp x ΔT
65
Chapter 4 Energy Balance
Q= 0.0218 x 8.63 x 33
Q= 5.920662
XII. Nitrogen:
Formula used is Q = oCpΔT
Q= o x Cp x ΔT
Q= 8.32 x 6.97 x 33
Q=1915.440476
Q= o x Cp x ΔT
Q=3507 x 9.38 x75
Q=2467174.5
Q= o x Cp x ΔT
Q= 65602 x 18.02 x75
Q=88117800
66
Chapter 4 Energy Balance
Q= o x Cp x ΔT
Q= 7.477232968x 8.3 x 75
Q= 4654.577523
IV. MDEA:
Formula used is Q = oCpΔT
Q= o x Cp x ΔT
Q= 9849 x 69.04 x 75
Q= 50998122
Q= o x Cp x ΔT
Q=49.24 x9.12 x33
Q=`14819.2704
67
Chapter 4 Energy Balance
Q= o x Cp x ΔT
Q= 65602 x 18.02 x33
Q=38771832
III. MDEA:
Formula used is Q = oCpΔT
Q= o x Cp x ΔT
Q= 9849 x 65.33 x 33
Q= 21233360.61
For Absorber Heat of reaction = Heat out – Heat in= Stream(300 +306 )-
Stream (302-307)= -80525091.6
68
Chapter 4 Energy Balance
311 310
E-1
Heat in = 188037450.7
69
Chapter 4 Energy Balance
Q- Ẇs =ΔH+ΔEx+ΔEp (1)
Assumption:-
ΔEx=0 ; ΔEp=0
Q = ΔH (2)
70
Chapter 4 Energy Balance
Heat In = 130628533+213955756+160602.17
Heat in = 344744891
306 313
Q= o x Cp x ΔT
Q= 3457.757 x 9.67 x 126
Q= 4213000.284
71
Chapter 4 Energy Balance
Q= o x Cp x ΔT
Q= 7.477 x 8.4 x 126
Q=7913.6568
Q= o x Cp x ΔT
Q= 4366.5 x 18.14 x 126
Q= 9980247.06
Q= o x Cp x ΔT
Q= 3457.757 x 9.25 x 53
Q= 1695165
Q= o x Cp x ΔT
Q= 4366.5 x 17.99 x 53
Q=3273.281
72
Chapter 4 Energy Balance
Q= o x Cp x ΔT
Q= 7.477 x 8.26 x 53
Q= 4163327
73
Chapter 4 Energy Balance
4.9 Stripper:
306
309
305
307
Q- Ẇs =ΔH+ΔEx+ΔEp (1)
Assumption:-
ΔEx=0 ; ΔEp=0
Q = ΔH (2)
74
Chapter 4 Energy Balance
Q= o x Cp x ΔT
Q= 1173584 x 0.615 x 123
Q= 88775742
Q= o x Cp x ΔT
Q= 1173584 x 1.007 x 123
Q= 145361256
Q= o x Cp x ΔT
Q= 254.218 x 0.219 x 123
Q= 6847.8703
75
Chapter 4 Energy Balance
Q= o x Cp x ΔT
Q= 154308 x 0.246 x 123
Q= 238812897
Q= o x Cp x ΔT
Q= 1173584 x 0.658 x 181
Q= 139771476
Q= o x Cp x ΔT
Q= 1173584 x 1.018 x 181
Q= 216242193
Q= o x Cp x ΔT
Q= 2166.68 x 0.226 x 181
Q=356102299
76
Chapter 4 Energy Balance
Q= o x Cp x ΔT
Q= 152141.3 x 0.22 x 126
Q= 4217357.4
Q= o x Cp x ΔT
Q= 78597 x 1.007 x 126
Q=9972544.6
Q= o x Cp x ΔT
Q= 254.218 x 0.246 x 126
Q= 7879.7411
77
Chapter 4 Energy Balance
Components
I. Water H2O
Formula used is Q = oCpΔT
Q= o x Cp x ΔT
Q=78597 x 0.999 x 53
Q= 4161475
=207850800
78
Chapter 4 Energy Balance
152 F
445 Psia Ẇs
304
30 Psia
T= ?
Q- Ẇs =ΔH+ΔEx+ΔEp (1)
Assumption:-
ΔEx=0 ; ΔEp=0
- Ẇs = ΔH (2)
5. Assuming that the volume remain constant ( i.e process streams are liquid )
Calculation of the shaft work:-
W= v.dp + P.dv dv = 0 according to condition (3)
So
W= v(P2 – P1) (3)
79
Chapter 4 Energy Balance
= 6567347847
o= 78563.471
80
Chapter 5 Equipment Design
Chapter 5 Equipment Design
Basic Principle:
The main purpose of separator is to separator liquid from vapor and vice versa. This separation
is accomplished by providing velocity low enough so that vapor get separated from liquid.
Gravity plays vital role in this separation along with density difference.
c) Knock-out drums:
This type of separator is used when very low liquid content are present in inlet stream. Due to
this reason Knock out drum is mostly installed on compressor inlet stream to stop liquid from
going in the compressor and damaging it.
81
Chapter 5 Equipment Design
As far as vertical and horizontal separator are concerned both have same designing procedure
and have same design calculations but they only differ in one parameter that is value L/D ratio.
If L/D ratio is greater than 5 than Horizontal is use if it is between 5 and 3 than vertical is used .
20 ( )
= Liquid density,
= vapour density,
= settling velocity,
( )
= Maximum velocity
82
Chapter 5 Equipment Design
= Liquid density,
= vapour density,
√ = 1.97 or 0.602
= 2.06 m
= 1.928 m
83
Chapter 5 Equipment Design
22
Checking ratio:
84
Chapter 5 Equipment Design
The plate spacing in plate exchanger is normally in the range of 1.3 to 6.4 mm. There are certain
factors which determine the size and numbers of plates, these factors are pressure drop, fluid
physical properties, temperature program and flow rates. The main function of plate
corrugation is to give enough strength to plate to overcome differential pressure and also
introduce fluid turbulence. All plates are then composed in frame by using pressure
arrangement.
85
Chapter 5 Equipment Design
Unit Plates
2
Size 1540-2500m Thickness 0.5-1.2 mm
Number of plates Up to 700 Size 0.03-2.2 m
Port size Up to 39cm Spacing 1.5-5.0 mm
Corrugation depth 3-5 mm
86
Chapter 5 Equipment Design
87
Chapter 5 Equipment Design
88
Chapter 5 Equipment Design
Gasket selection:
The main points which should be consider while selecting any gasket are shape, good
sealing ability, temperature and chemical resistance. Different gaskets and their
28
respective operating temperature are shown in below:
Styrene butadiene rubber (80 oC)
Nitrile rubber ( 140 oC)
Ethylene propylene rubber (150 oC)
Resin- cured butyl rubber (140 oC)
Fluorocarbon rubbers (180 oC)
Fluoroelastomer (100 oC)
Compressed asbestos fiber (260 oC)
Silicon elastomers ( low temperature application )
Tie bolts:
The tie bolts use in PHE are mostly made from 0.5%Mo-1%Cr low alloy steel. Different
types of tightening devices (pneumatic, hydraulic or electric) can by use for packing
large units.
89
Chapter 5 Equipment Design
Comparison between Shell & tube heat exchanger and Plate heat exchanger:29
= 938.4618
=0.0003018 Pa-sec
K=0.3443
Cp=110684
90
Chapter 5 Equipment Design
= 921.3411
=0.0005557 Pa-sec
K=0.3350
Cp=101919
=156.231 or 45784.3 kW
( ) ( )
ΔTlm= ( ) = 38.6
( )
30
FT factor calculated from graph for 1:1 pass is =0.975
As in this exchanger both stream are light organic liquid so the value of overall coefficient (U)
31
taken from table is 2200
Q=UAΔT
91
Chapter 5 Equipment Design
Number of plates = =
= x( )
x =1.02
Re(Reynolds’s No)=
= = 31789
Pr (Prandtl No) =
= = 97
Hp = Nu x
= x( )
x =1.03
Re(Reynolds’s No)=
= = 17240
Pr (Prandtl No) =
92
Chapter 5 Equipment Design
= = 169
Hp = Nu x
4. Overall Coefficient:
33
Fouling factor for rich and lean amine (light organic) is = 10000 Wm-2 oC-1
We Take plate thickness as 0.75 mm and we use titanium material which has thermal
conductivity of 21 Wm-1 oC-1
= + + + +
( ) ( )
= + + + +
= 2.829x10-4
The value of overall coefficient is much above the supposed value so the calculated number of
plate per pass is satisfactory
5. Pressure Drop
For Lean amine
Jf = 0.60 x (Re)-0.3
= 0.60 x (31789)-0.3
= 0.0267
ΔPp=8 x Jf x x density x
93
Chapter 5 Equipment Design
= 15655
=2.67
ΔPpt= 1.3 x
= 4351
=0.2 bar
ΔPp=8 x Jf x x density x
= 18848
94
Chapter 5 Equipment Design
=2.72
ΔPpt= 1.3 x
= 4437
=0.23 bar
The pressure drop is well between the limits so the design of exchanger and number
of plates is good. So plate heat exchanger can be considered for this duty
95
Chapter 5 Equipment Design
1. Plate column are designed to handle wide range of liquid flow rates without flooding.
2. If a system contains solid contents; it will be handled in plate column, because solid will
accumulate in the voids, coating the packing materials and making it ineffective.
3. Dispersion difficulties are handled in plate column when flow rate of liquid are low as
compared to gases.
4. For large column heights, weight of the packed column is more than plate column.
5. If periodic cleaning is require, man holes will be provided for cleaning. In packed columns
packing must be removed before cleaning.
6. For non-foaming systems the plate column is preferred.
7. Design information for the plate column is more readily available and more reliable than
that for packed column.
8. Inter stage cooling can be provided to remove heat of reaction or solution in plate column.
9. When temperature change is involved, packing may be damaged.
1. They are lighter in weight and less expensive. It is easier and cheaper to install.
2. Pressure drop is low as compared to valve and bubble cap plates.
3. Peak efficiency is generally high.
4. Maintenance cost is reduced due to the ease of cleaning.
5. In case of capacity rating, sieve plate has high rank as compared to valve and bubble plates.
Sieve plate:
Sieve plate is simplest type of cross-flow plate. Vapor passes up through perforations in the
plate; and the liquid is retained on the plate by vapour flow. The perforations are usually small
96
Chapter 5 Equipment Design
holes, but larger holes and slots are used. The arrangement, number and size of the holes are
design parameters.
Because of their efficiency, wide operating range, ease of maintenance and cost factors, sieve
and valve trays have replaced the once highly thought of bubble cap trays in many applications.
Foaming:
Foaming refers to the expansion of liquid due to passage of vapor or gas. Although it provides
high interfacial liquid-vapor contact, excessive foaming often leads to liquid buildup on trays. In
some cases, foaming may be so bad that the foam mixes with liquid on the tray above.
Whether foaming will occur depends primarily on physical properties of the liquid mixtures, but
is sometimes due to tray designs and condition. Whatever the cause, separation efficiency is
always reduced.
Entrainment:
Entrainment refers to the liquid carried by vapor up to the tray above and is again caused by
high vapor flow rates. It is detrimental because tray efficiency is reduced: lower volatile
material is carried to a plate holding liquid of higher volatility. It could also contaminate high
purity distillate. Excessive entrainment can lead flooding.
Weeping/Dumping:
This phenomenon is caused by low vapor flow. The pressure exerted by the vapor is insufficient
to hold up the liquid on the tray. Therefore, liquid starts to leak through perforations. Excessive
weeping will lead to dumping. That is the liquid on all trays will crash (dump) through to the
base of the column (via a domino effect) and the column will have to be re-started. Weeping is
indicated by a sharp pressure drop in the column and reduced separation efficiency.
97
Chapter 5 Equipment Design
Flooding:
Flooding is brought about by excessive vapor flow, causing liquid to be entrained in the vapor
up the column. The increased pressure from excessive vapor also backs up the liquid in the
down comer, causing an increase in liquid holdup on the plate above. Depending on the degree
of flooding, the maximum capacity of the column may be severely reduced. Flooding is
detecting by sharp increases in column differential pressure and significant decrease in
separation efficiency.
Column Diameter:
Vapor flow velocity is dependent on column diameter. Weeping determines the minimum
vapor flow required while flooding determines the maximum vapor flow allowed, hence column
capacity. Thus, if the column diameter is not sized properly, the column will not perform well
98
Chapter 5 Equipment Design
ABSORBER DESIGN
Flow rate = 10898 Ibmole/hr
Pressure = 422 psia
Temperature = 110 F
Flow rate = 14358 Ibmole/hr 302 CO2 = 217.96 Ibmole/hr
Pressure = 429.5 psia H2S = 0.0218 Ibmole/hr
Temperature = 110 F H2 = 7092.85 Ibmole/hr
3
Density = 21.47 kg/m CO = 3242.036 Ibmole/hr
Avg. wt = 18.9985 Ib/Ibmole CH4 = 291.467 Ibmole/hr
CO2 = 3675.648 Ibmole/hr C2H4 = 1.866 Ibmole/hr
H2S = 7.46616 Ibmole/hr C2H6 = 0.373308 Ibmole/hr
H2 = 7092.85 Ibmole/hr C6H6 = 0.0412 Ibmole/hr
CO = 3242.036 Ib mole/hr C10H8 = 1.22 x 10-6 Ibmole/hr
CH4 = 291.467 Ibmole/hr NH3 = 0.8615 Ibmole/hr
C2H4 = 1.866 Ibmole/hr N2 = 8.3276 Ibmole/hr
300
C2H6 = 0.373308 Ibmole/hr H2O = 42.2125 Ibmole/hr
C6H6 = 0.0412 Ibmole/hr
C10H8 = 1.22 x 10-6 Ibmole/hr
NH3 = 0.8615 Ibmole/hr Flow rate = 75098 Ibmole/hr
N2 = 8.3276 Ibmole/hr Density = 1001.48 kg/m3
H2O = 42.2125 Ibmole/hr 311 Avg. wt = 31.2969 Ib/Ibmole
Pressure = 432 psia
Temperature = 110 F
CO2 = 49.24 Ibmole/hr
99
Chapter 5 Equipment Design
H2S:
In = 3.73
Out = .0109
Eai =
= 0.997 or 99.7%
( ) min = Ki Eai
T = 110 °F
P= = 433psia.
36
Ki = 1.6
= 1.5952.
= 1.994.
100
Chapter 5 Equipment Design
Aio = ( )○ .
= 1.246.
N = 19.09.
So,
Uf = K1
Where,
FLV =
101
Chapter 5 Equipment Design
Where,
In this Case,
Lw = 148.045
Vw = 17.18
Pv = 21.47 [ ]
PL = 1001.48
FLV =
= 1.26
Then, UF = 0.034
= 0.23
= 0.20
=0 .80
= 4 m2
102
Chapter 5 Equipment Design
= 4.55 m2
= 4.55 – 2(0.55)
= 3.45 m2
Column diameter = Dc =
= 2.40 m.
= 103.631
39
= 0.77
we know
103
Chapter 5 Equipment Design
Lw = weir length, m
= 109mm.
We take , hw = 50mm
Dh = hole diameter, mm
( )
Uh = ( )
]
Uh = 0.77m/s
= 1.62 m/s.
104
Chapter 5 Equipment Design
ht = hd + (hw + how) + hr
hr = residual head
hw = height of weir
hd = 51 [ ]2
Co = Orifice coefficient
Uh = = 2.32 m/s.
so,
41
Co = 0.84
hd = 51 [ ]2 [ ]
= 8.34 mm
hr =
= 12.48mm
105
Chapter 5 Equipment Design
= 179mm liquid
= 1757 Pa
Where,
hdc = 166 [ ]2
where,
Am = Either downcomer area or clearance area under the downcomer Aop which is smaller.
Aop = hop Lw
Lw = length of weir
hop = hw – 10
= 50 – 10 = 40mm
106
Chapter 5 Equipment Design
= 0.074m
hdc = 166 [ ]2
= 6.62mm
= 34..62mm = 0.33462m
7. Entrainment Calculation:
For checking entrainment , we calculate
Uv =
Uv = = 0.2 m/s
% flooding =
= = 86%
FLV = 1.26
42
107
Chapter 5 Equipment Design
Top clearance = 1m
Bottom clearance = 1m
108
Chapter 5 Equipment Design
Stripping Phenomenon:
Stripping is a mass transfer operation that involves the transfer of a solute (as H2S & CO2 in our
case) from the liquid phase to the gas phase.
Stripping Agents:
Air
Stream
Inert gas
Hydrocarbon gases
Reboiled vapors (as in our case)
Types of Stripper:
i. Refluxed Stripper:
It is employed if simple stripping is not sufficient to achieve the desired separation and
contacting trays are needed above the feed tray.
109
Chapter 5 Equipment Design
110
Chapter 5 Equipment Design
Let us suppose that 100% of H2S is not stripped and very minute quantities remains in the lean
MDEA coming back from Stripper.
T = 230 °F
P = 26psia.
36
Ki = 35
So, ( )min = =
= 0.0285
= 0.0356.
111
Chapter 5 Equipment Design
Si = ( )○ . Ki = 0.0356 x 35
= 1.246.
N = 20.78
So,
= 30 stages.
Uf = K1
Where,
FLV =
112
Chapter 5 Equipment Design
Where,
In this case,
In this Case,
Lw = 315
Vw = 20.38
Pv = 1.96 [ ]
PL = 935.24
FLV =
= 0.71
Then, UF = 0.054
= 1.18
= 1.00
=10.4
113
Chapter 5 Equipment Design
= 10.4 m2
= 11.82 m2
= 11.82 – 2(1.42)
= 8.98 m2
Column diameter = Dc =
= 3.88 m.
= 220.5
39
= 0.77
we know
114
Chapter 5 Equipment Design
Lw = weir length, m
= 138mm.
We take , hw = 50mm
Dh = hole diameter, mm
( )
Uh = ( )
]
Uh = 6.17m/s
= 8.11 m/s.
115
Chapter 5 Equipment Design
ht = hd + (hw + how) + hr
hr = residual head
hw = height of weir
hd = 51 [ ]2
Co = Orifice coefficient
Uh = = 11.6 m/s.
so,
41
Co = 0.84
hd = 51 [ ]2 [ ]
= 20 mm
hr =
= 13mm
116
Chapter 5 Equipment Design
ht = 188 + 13 + 20
= 221mm liquid
= 2027.6 Pa
6. Downcomer Design:
The downcomer area and the plate spacing must be such that the level of the liquid and froth in
the downcomer is well below the top of outlet weir on the plate above. If the liquid rises above
the outlet weir the column will flood.
Where,
hdc = 166 [ ]2
where,
Am = Either downcomer area or clearance area under the downcomer Aop which is smaller.
Aop = hop Lw
Lw = length of weir
hop = hw – 10
= 50 – 10 = 40mm
117
Chapter 5 Equipment Design
= 0.120m
hdc = 166 [ ]2
= 13.07mm
= 422.07mm = 0.422m
7. Entrainment Calculation:
For checking entrainment , we calculate
Uv =
Uv = = 1 m/s
% flooding =
= = 85%
FLV = 0.71
42
118
Chapter 5 Equipment Design
Top clearance = 1m
Bottom clearance = 1m
Basis 24 hours
Vol. of MDEA for 24 hr = 2349334.04 x 24/64.6 = 872817.6 ft3
Total vol. of vessel = vol. of MDEA + 10% allowance
= 872817.6 x 1.10 = 960099.36 ft3
Let us suppose that 0.3% of MDEA solution is slipped in the surge tank
=960099.36 *0.03=2858.29 ft3=81m3
V = d2h/4
[1]
Let, h/d = 3 or h = 3d
V = 3 d /4
3
Design Specifications
Time of operation = 24hr
Dia. Of vessel = 3.25m
Height of Vessel = 9.75m
Recommended material of instruction is carbon steel
119
Chapter 6 Instrumentation & Process Control
Chapter 6 Instrumentation & Process Control
In Amine contactor bottom section most of the heat of reaction44 is released. If there is high
amine loading then it will lead towards corrosion. In the following control scheme we have used
the temperature near the middle of the amine absorber to reset the control the amine flow. By
controlling the amine flow rate the chances of corrosion due to temporary overloading of rich
amine solution is reduced. Level is controlled in the absorber by using Proportional controller.
Sweet gas pressure is maintained by using Proportional Integral Controller.
In Regenerator section we have used flow ratio control45 to set the reboiler heat medium mass
flow at a fixed value in relation to the rich amine and second control method on regenerator
uses the temperature between the top tray and overhead condenser to reset the reboiler heat
medium flow.
In lean/rich MDEA Exchanger, the rich MDEA is more important because it after the exchanger
it leads to Regenerator column. Any change in its dynamic can alter the dynamics of the whole
column. Hence the lean MDEA stream is manipulated to keep the temperature of rich MDEA
constant.
Further in Lean MDEA cooler, the lean MDEA stream is the key stream because it then flows to
absorber and hence failure to meet the required temperature will affect the absorber
performance. Hence the speed of the fan of Air Fin Fan Cooler Is varied to meet the constant
lean MDEA temperature. The control action is simple, since the temperature usually has a
sluggish response so a PID controller is more suitable.
120
Chapter 6 Instrumentation & Process Control
121
Chapter 7 Cost Estimation
Chapter 7 Cost Estimation
The capital needed to supply the necessary manufacturing and plant facilities is called fixed
capital. Fixed cost capital investment while necessary for the operation of the plant termed
as Working Capital. The sum of fixed capital investment and the working capital is known as
total capital investment.
Direct costs
Indirect costs
Purchase equipment
Purchase equipment installation
Instrumentation
122
Chapter 7 Cost Estimation
Piping
Electrical Equipment and materials
Building (including services)
Service facilities
Taxes
Preliminary estimate
Definitive estimate
Detailed estimate
In choosing the method for cost estimation following factors are considered:
123
Chapter 7 Cost Estimation
The percentage used in making an estimation of this type should be determined on the basis
of type of process involved, design complexity required, material of construction, location of
the plant, past experiences, and other items depend on the particular unit under
consideration.
Ce= a + b (S)n
S = size parameter
(these all above values have been obtained from table # 6.6, Coulson vol.6, Ed.5. for year
2007 )
1. Cost of Absorber:
We know that
C= a+b(S)n
so,
C = 110+380(2.4)1.8
= $1947 ( Cost/Tray)
= $52569
124
Chapter 7 Cost Estimation
= $105138
This cost is for year 2007, so by applying inflation rate of 3.3% per year, we can find cost in
2013.
C = 105138(1.033)6 = $127750.21
2. Cost of Exchanger:
We know
C= a+b(S)n
so,
C = 1350+180(584)0.95
= $73313
This cost is for year 2007, so by applying inflation rate of 3.3% per year, we can find cost in
2013.
C = 73313(1.033)6 = $89080.
Length = L = 6.34 m
From Graph48
C = 22000
So,
This cost is for year 2004, so by applying inflation rate of 3.3% per year, we can find cost in
2013.
C = 30800(1.033)9 = $41253.
125
Chapter 7 Cost Estimation
From Graph
C = $25000
This cost is for year 1988, so by applying inflation rate of 3.3% per year, we can find cost in
2013.
C = 25000(1.033)21 = $49436.
We know that
C = C= a+b(S)n
so, C = 5000+1400(81)0.7
= $35343
This cost is for year 2004, so by applying inflation rate of 3.3% per year, we can find cost in
2013.
C = 35343(1.033)9 = $47337.
E = $354856
126
Chapter 7 Cost Estimation
= $503855
127
Chapter 8 HAZOP Study
Chapter 8 HAZOP Study
Specify the purpose, objective, and scope of the study. The purpose may be the analysis of a yet
to be built plant or a review of the risk of unexisting unit. The scope of the study is the
boundaries of the physical unit, and also the range of events and variables considered. The
initial establishment of purpose, objectives, and scope is very important and should be precisely
set down so that it will be clear, now and in the future, what was and was not included in the
study. These decisions need to be made by an appropriate level of responsible management.
HAZOP team is selected.
For the collection of data following materials are needed:
Process description
Process flow sheets
Data on the chemical, physical and toxicological properties of all raw materials,,
intermediates, and products.
Piping and instrument diagrams (P&IDs)
Equipment, piping, and instrument specifications
Process control logic diagrams
Layout drawings
Operating procedures
Maintenance procedures
Emergency response procedures
Safety and training manuals
128
Chapter 8 HAZOP Study
Team Secretary
Process Engineer
Mechanical Engineer
Commissioning/Operations
Engineer/Manager
Instrument Engineer
• The use of keywords is effective and the whole group is able to participate.
• HAZOP is an excellent well-proven method for studying large plant in a specific manner.
• HAZOP does not identify all causes of deviations and therefore omits many scenarios.
129
Chapter 8 HAZOP Study
• Control discussion
• Limit discussion
• Motivate members
• Discourage recriminations
130
Chapter 8 HAZOP Study
131
Chapter 8 HAZOP Study
Table 8.152
Equipment Deviations What event Consequences Additional Process Notes and questions
reference from operating could cause of implications of indications
and conditions conditions this this deviation this
operating deviation? on consequence
conditions item of
equipment
under
consideration
MDEA Level 1. Tank runs dry Pump Damage to LIA-1, Can reagent
Storage Less cavitates pump, FICA-1 react/explode if over-
tank heated in pump?
2. Rupture 4-in. Reagent Potential fire LIA-1, Estimate release
discharge released FICA-l quantity. Consider
second LAL
shutdown on pump.
3. V-3 open or Reagent Potential fire LIA-1 Estimate release
broken released quantity.
4. V-l open or Reagent Potential fire LIA-1 Consider V-l
broken released protection
5. Tank rupture Reagent Potential fire LIA-1 What external events
released can cause rupture
More 6. Unload too Tank overfills Reagent LIA-1 Is RV-1 designed to
much from tank released relieve liquid
truck via RV-1 atloading rate?
.Consider secondhigh
level shutoff.
7. Reverse flow Tank overfills Reagent LIA-1 Consider check
from process released valvein pump
via RV-1 discharge line.
Consider second LAH
shutdown on feed
lines.
Composition 8. Wrong Possible Possible tank Consider
Other than reagent reaction rupture samplingbefore
unloading.
As well as 9. Impurity in If volatile, Are other
reagent possible materialsdelivered in
overpressure trucks?
Pressure 10. Break l-in. Reagent Potential fire PICA-l Consider PAL to
Less line to flare or l- released PICA- 1. Consider
in nitrogen line independent
PAL.
11. Lose nitrogen Tank implodes Reagent PICA-l Consider vacuum-
released break
Valve.
12. PV-2 fails Tank implodes Reagent PICA-l consider PAL on
closed released PICA-l
13. PICA-1 fails, Tank implodes Reagent PICA-l Tank not designed
closing PV-2 released for vacuum.
132
Chapter 8 HAZOP Study
More 14. PICA-l fails Reagent Tank rupture if PICA-l What is capacity of
closing PV-1 released RV-1 fails PV-l? RV-l? Consider
via RV-1 independent PAH.
15. PV-1 Reagent Tank rupture if PICA-l Consider
failsclosed released RV-1 fails independent PAH.
via RV-1
16. V-7 closed Reagent Tank rupture if PICA-l Is V-7 locked open?
released RV-1 fails Is V-S locked open?
via RV-1 Consider
independent PAH.
17. Overfill tank See Event 6 Tank rupture if PICA-l Consider second
RV-1 fails High-level shutoff.
133
Chapter 9 Operational Problems
Chapter 9 Operational Problems
9.2 Foaming53:
Foaming of alkanolamine solution is probably the most common operating problem in amine
treating units. It is most frequently encountered in contractor, but may also occur in the
stripping column.
Causes of Foaming:
Specific cause of foaming includes the following:
Water soluble surfactants in the feed gas (e.g. well treating compounds, pipeline corrosion
inhibitors) which lowers the amine solutions surface tension. Excessive antifoam can also
cause foaming.
Liquid hydrocarbons e.g. entrained compressor lubricating oils in the feed gas or
hydrocarbons condensation within the amine absorber.
Particulate contaminants (e.g. mill scale, FeS correction products, rust contained in the feed
gas or produced within amine treating units. Solids such as FeS do not cause foaming but
concentrate at liquid/gas interface and stabilize the foam by increasing the surface viscosity
retarding film drainage.
Oxygen contamination of feed gas or amine unit (usually at the amine sump or amine
storage tank) and reaction of amine heat stable salts. Dissolved iron can catalyze the
reaction of amine with oxygen to foam carboxylic acid.
Feed gas contamination such as carboxylic acid, which react with amine to form heat stable
salts.
Contamination of amine unit with gases and oils during a turnaround.
Amines filter elements that have been washed with surfactants or contaminated with oils
during manufacture.
Contaminants in the amine plant makeup water such as boiler feed water treating
chemicals and corrosion inhibitors.
134
Chapter 9 Operational Problems
Prevention of Foaming:
Foaming can be reduced or controlled by proper care of the amine solution. The following
techniques reduce the amine solution contamination and minimize foaming:
A properly designed feed gas inlet separator and filter should be provided. A feed gas
coalscer should be considered for feed gas stream contaminated with compressor
lubricating oils and other finally dispersed aerosols. A properly size slug catcher should be
provided if slugs can accumulate in the feed gas line.
A feed gas water wash should be considered when the feed gas streams is severely
contaminated with carboxylic acid or water soluble, surface active contaminates. A feed gas
water wash can also remove aerosols and ultra fine chemicals.
Onsite of offsite amine solution reclaiming to remove heat stable salts and amine
degradation products. No more than 10% of the amine should be tied up as stable salts.
Caustic addition to neutralize heat stable salts to mitigate corrosion and thereby reduce
iron sulfite formation.
A properly sized rich amine flash drum remove entrained and dissolved hydrocarbons.
Liquid skimming facilitate in the absorber sump, the rich amine flash drum, the regenerator
sump and the amine regenerator overhead accumulator.
New plants and old plants that have undergone a major turnaround or often contaminated
with oils, greases welding fluxes and corrosion inhibitors. A hot caustic wash (2-5 wt%
caustic soda) followed by a hot condensate wash can remove these impurities and help to
prevent foaming.
Addition of antifoam is carried out.
9.3 Corrosion:
By far the most serious operating problem encountered with amine gas purification process
is corrosion as would be expected this problem has been given widest attention. Generally,
it occurs in regenerator heat exchanger and pumps. The extent and type of corrosion has
been observed to depend upon such factors as the amine used, the presence of
contaminants in the solution leading with acid gas, the temperature and pressure,
prevailing in various part of the plant, the velocity with which the solution flows and others.
However, it appears that the principal corroding agents are the add gases. The rate of
corrosion increases with increase acid gas concentration n solution.
Corrosion due to hydrogen sulfide and carbon dioxide is frequently observed a filter shell
and the hot end heat exchanger tubes. To minimize corrosion by hydrogen sulfide and
carbon dioxide, the acid gases must be held in a relatively corrosive form until regeneration
of amine solution is stripping still.
135
Chapter 9 Operational Problems
Overloading the amine solution will increase the chance for corrosion due to pressure
reduction or high temperature in the heat exchanger. This danger can be remedied
bymaintaining sufficient pressure on the foul amine solution and by operating the unit at as
low and acid gas alkanolamine ratio as possible. This ration should not exceed 0.05 moles of
acid gas per mole of alkanolamine and should be event less of condition permits.
Mechanism of Corrosion:
It is known that free or “aggressive” carbon dioxide causes severe corrosion particularly at
elevated temperature and in the presence of water.
It is believed that the metallic iron with carbonic acid which results in the formation of stable
iron bicarbonate. Further heating of solution may cause the release of carbon dioxide and the
precipitate of the iron as the relatively insoluble carbonate.
Hydrogen sulfide attacks steel as an acid with the subsequent formation of insoluble ferrous
sulfite. This compound forms a coating on the metal surface which does not adhere tightly and
therefore affords little protection from further corrosion. There is no satisfactory correlation
available for carbon dioxide, hydrogen sulfide mixture, which relates the corrosive attacks to be
expected with any given ratio of hydrogen sulfide to sulfur dioxide.
However, certain generalized observation has been made. It appears that in plant handling
predominantly carbon dioxide, very small quantity of hydrogen sulfide may actually reduce
corrosion. On the other hand, each of the acid gases increases the corrosive attacks of the
other.
The temperature of the solution in the reboiler and the temperature of the steam used in
the reboiler should be kept as low as possible.
Use of high temperature heat carrying media, such as oil, should be avoided to maintain the
lowest possible skin temperature of metal.
Pressure regenerator with its accompanying high temperatures results in severe corrosion
of reboiler tubes; it is, therefore, good practice to maintain the lowest possible pressure on
the stripping column and reboiler.
To prevent oxygen from entering the system, it is advisable to maintain a blanket of inlet
gas over all portion of the solution, which could be exposed to atmosphere and to ensure
the pressure the suction side of all pumps.
136
Chapter 9 Operational Problems
Continuous removal of suspended solids (by nitration) and the decomposition product (by
distillation of a side stream) generally helps to reduce corrosion.
9.6 Entrainment:
In many cases most of the glycol loss occurs as carry over of solution with the product gas.
Entrainment losses are caused either by inefficient mist extraction or by foaming and
subsequent carry over solution. Entrainment losses from glycol absorber vary considerably
depending on the mechanical design of both the upper solution of absorber and mist
elimination devices.
137
BIBLOGRAPHY
BIBLOGRAPHY
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Fundamentals and Applications”,Table 1.5
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14- TENNEYSON, R.N. & SCHAAF, R.P, "Guidelines Can Help Choose Proper Process for Gas
Treating Plants", Oil and Gas Journal, January 10, 1977, page 78.
138
BIBLOGRAPHY
15- ARTHUR KOHL & RICHARD NELSON , “ Gas Purification” , Page 4, Edition 5th. 1979
16- Amine & Plasticizers limited,AN ISO 9001:2008 CERTIFIED COMPANY.
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Programme”, ,page 7, Table 1.1
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Petroleum Refinery”, Page 155, May 1964.
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1&2, Edition 12th .
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139
BIBLOGRAPHY
34- R.K SINNOTT, “Coulson & Richardson’s Chemical Engineering” page 558-561, Volume 6,
Edition 4th.
35- ERNEST E. LUDWIG, “Applied Process Design for Chemical & Petrochemical Plants”, page
109, Volume 2, Edition 3rd.
36- GAS PROCESSORS SUPPLIERS ASSOCIATION, “Engineering Data Book”, page 25-23,
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37- R.K SINNOTT, “Coulson & Richardson’s Chemical Engineering” page 567-579, Volume 6,
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38- R.K SINNOTT, “Coulson & Richardson’s Chemical Engineering”, Figure 11.27, page 568,
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39- R.K SINNOTT, “Coulson & Richardson’s Chemical Engineering”, Figure 11.31, page 573,
Volume 6, Edition 4th.
40- R.K SINNOTT, “Coulson & Richardson’s Chemical Engineering”, Figure 11.30, page 571,
Volume 6, Edition 4th.
41- R.K SINNOTT, “Coulson & Richardson’s Chemical Engineering”, Figure 11.34, page 576,
Volume 6, Edition 4th.
42- R.K SINNOTT, “Coulson & Richardson’s Chemical Engineering”, Figure 11.29, page 570,
Volume 6, Edition 4th.
43- ERNEST E. LUDWIG, “Applied Process Design for chemical & petrochemical plants”, page
110, Volume 2, Edition 3rd.
44- APTHUR KOHL, “Gas Purification”. Page 205, Edition 5th.
45- APTHUR KOHL, “Gas Purification”. Page 204, Edition 5th.
46- RAY SINNOTT & CAVIN TOWLER, ”Chemical Engineering Design”, page 314, Table 6.6,
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47- RAY SINNOTT & CAVIN TOWLER, ”Chemical Engineering Design”, page 313, Table 6.6,
Volume 6, Edition 5th.
48- R.K SINNOTT, ”Chemical Engineering Design”, page 256, Figure 6.5a,b.
140
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49- RAY SINNOTT & CAVIN TOWLER, ”Chemical Engineering Design”, page 314, Table 6.6,
Volume 6, Edition 5th.
50- MAX S.PETERS & KLAUS D.TIMMERHAUS, ” Plant Design & Economics For Chemical
Engineer”, page 167, Table 4, Edition 4th.
51- MAX S.PETERS & KLAUS D.TIMMERHAUS , “Plant Design and Economics For Chemical
Engineers”, page 63, Edition 4th.
52- MAX S.PETERS & KLAUS D.TIMMERHAUS , “Plant Design and Economics For Chemical
Engineers”, page 64, Edition 4th.
53- APTHUR KOHL, “Gas Purification”. Page 224, Edition 5th.
54- ARTHUR KOHL, “Gas Purification”. Page 231, Edition 5th
141