Class 11th

Unit: 13 Hydrocarbons

Q.1. Write structural formula of the following:

(i) 3 – Ethyl – 2 – methyl pentene
(ii) 3, 4, 8 – trimethyl decyne
Q.2. Write short note on
(i) Kolbe’s electrolytic method
(ii) Conformations of Ethane
Q.3. Write IUPAC names of the following:
CH3
CH3 CH3
CH3
||||
(i) CH3 – C – CH2 – CH – CH3
(ii) CH3 – C – CH2 – C – CH3
|||
CH3 CH3
C2H5
Q.4. What is meant by linear polymerization of acetylene? Give chemical equation and
use of the product formed.
Q.5. Convert:
(i) Benzene to cyclohexane (ii) Benzene to Benzene hexachloride
Q.6. Complete the following reactions:
(i) CH3 – CH – CH2 – CH3 + KOH (alc) —>
|
Cl
(ii) CH3 – CH = CH2 + HBr —>

Q.7. Distinguish between:

(i) Ethane and Ethene
(ii) But-1-yne and But-2-yne
(iii) Ethene and Ethyne

Q.8. Convert
(i) Propene to Propan – I – ol
(ii) Ethyne to Benzene
(iii) Acetylene to acetadehyde

Q.9. What happens when

(i) Acetylene is passed over red hot tube.
(ii) But – l – ene reacts with O3 followed by Zn and H2O
(iii) Benzene reacts with CH3Cl in presence of AlCl3
Q.10. (i) A conjugated diene ‘A’ having formula C13H22 on ozonolysis gave ethyl
methyl ketone; cyclo haxanal and glyoxal. Identify ‘A’ and write reaction involved.
(ii) Define Huckel rule. How is cyclopentadienyl anion aromatic?
(iii) What happens when benzene reacts with conc. HNO3 and H2SO4 at 333 K?

Q.11. Why is rotation about carbon-carbon single bond free? What type of isomerism
does it lead to?

Q.12. Explain why the rotation about carbon-carbon double bond is hindered?

Q.13. Alkynes contain two pi bonds but still do not show geometrical isomerism whereas
alkenes contain only one π bond but show geometrical isomerism. Comment.

Q.14. Benzene contains three double bonds yet it behaves like a saturated compound.
Explain.

Q.15. Why is cyclopropane more reactive as compare to cyclohexane?

Q.16. Staggered conformation of ethane is

(i) more stable than eclipsed conformation
(ii) less stable than eclipsed conformation
(iii) Equally stable than eclipsed conformation
(iv) impossible to exist

Q.17. Which one of the following is the most reactive cycloalkane?

(i) Cyclopentane
(ii) Cyclobutane
(iii) Cyclopropane
(iv) Cyclohexane

Q.18. Which one of the following compounds had delocalized electrons?

(i) Methane
(ii) Ethane
(iii) Cyclohexane
(iv) Benzene

Q.19. Which of the following show position isomerism?

(i) Butane, isobutene
(ii) cis and trans-2-butnene
(iii) Chair and boat forms of cyclohexane
(iv) 1, 2 and 1, 3 and 1, 4 dimethyl benzene

Q.20. The state of hybridization of the asterisked carbon in CH3CH=C*=CH2 is

(i) sp
(ii) sp2
(iii) sp3
(iv) none

Q.21. Give two reactions of alkynes to show their acidic nature

Q.22. Wurtz reaction is a good method for the preparation of alkanes containing even
number of carbon atoms comment.

Q.23. Write equation for the following reactions:

(i) 2- butene and 2-butyne are treated with hot alkaline KMnO4 solution.
(ii) Propane reacts with HBr in the dark and in the absence of peroxides.
(iii) Ethyne reacts with water in presence of mercury ions and 60% H2SO4 at 333 K.
(iv) Benzene is treated with conc H2SO4.

Q.24. Write short notes on

(i) Friedel-Crafts reaction
(ii) Addition reactions
(iii) Markownikoff’s rule
(iv) Peroxide effect