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Documente Cultură
CHEMISTRY PROJECT
(For the partial fullfillment of BOARD practical exam)
Academic Session:2019-20
Submitted to: Mrs.Vandana Pant
Submitted by:Anush Jain
Roll No. :12201
Class/Section :XIIB
Project Topic :Dyes
CERTIFICATE
This is to cerify that Anush Jain, a
student of class XII B has
successfully completed the project on
the topic :
' Dyes ' under the guidance of
Mrs.Vandana Pant mam (subject
teacher )during year 2019-20, in
partial fulfillment of Central Board
of Secondary Education(CBSE)
practical exam.
ACKNOWLEDGEMENT
First of all, I am immensely indebted to almighty god for his blessings and grace
without which I could not have undertaken this task and my efforts would never
have been a success.
I humbly consider a privilege and honor to express my heartiest and profound
gratitude to Sir Madhukar Pawar, Principal SICA 54, Indore for his
appropriate direction, valuable suggestion, under judging assistance so generously
extended to me.
I wish to express my deepest feelings of gratitude to Mr.Sunil Sharma sir,
Physics department.For her erudite involvement and sustained guidance which
has been pivotal in my project work. His minute observation, precious insights,
critical comments have indeed greatly helped to shape my ideas.
This guidance and support received from my entire classmates who contributed
and who are contributing to this project, is vital for the success of this project. I
am grateful for their constant support and help.
I also owe sense of gratitude to my parents for encouragement and support
throughout the project.
-Anush Jain
INDEX.
TOPICS PG.NO.
1. Introduction.
3. History.
5. Classification.
7. Dyeing.
9. Experiment.
11. Advantages.
12. Drawbacks.
14. Bibliography.
INTRODUCTION.
The art of dyeing is as old as our civilization.Natural Dyes were used only for
coloring of textiles from ancient time the nineteenth century.
As the name suggests,natural dyes are derived from natural
resources.Colouring materials obtained from natural resources of
plant,animal,mineral and microbial origins were used for colouration of various
textile materials.
Use of Natural Dyes started to decline after the invention of synthetic dyes
in the second half of the nineteenth century.Recent environmental awareness
has again revived interest in natural dyes mainly among environmentally
conscious people.Natural dyes are considered eco friendly as these are
renewable and biodegradable.
Apart from their application in textiles,natural dyes are also used in the
coloration of food,medicine etc.
Pg 1
HISTORY
It was in 2600 BC when earliest written records of the use of dyestuffs were
found in china.The preparation and application of dyestuffs is one of the
oldest forms of human activities,evident of which were found by excavation at
archeological sites where ancient fabrics were unearthed.
The real breakthroughs in the history of dyes came in 1856 when a teenager
who was experimenting at his makeshift laboratory in home made a certain
discovery that acted as a sort of launching pad for the modern chemicals
industry.
William Perkin,an 18 year old student was working on chemical synthesis of
natural products.In a classical case of serendipity ,the young William changed
upon his famous "Aniline Mauve" dye while he was attempting synthesize
quinine,the only cure for malaria.
Perkin named his colour Mauveine,after the French name of non fast colour
which was made of natural dyes.So "Mauve" was the first synthetic dye stuff
Mauve was a derivative of coal tar.
Pg 3
POTENTIAL SOURCES OF NATURAL
DYES.
Natural dyes are derived from natural resources and based upon their source
of origin,these are broadly classified as :-plant,animal,mineral and microbial
dyes,although plants are the major source of natural dyes.
Dye plants used for natural dyeing of textiles such
as,alkanet,annatto,chamomile,coreopsis,madder,safflower,indigo and so on.
Plants to use for Natural Dyes :-
(Following is the list of common dye plants and colour they yield)
* Blue- Red cabbage,blueberries,blackberries.
* Brown- Red beet skins.
* Green- Nettle,spinach.
* Purple- Elder berries,mulberries.
* Orange- Yellow onion,dandelion heads.
* Pink- Strawberries,cherries,roses.
* Red- Hibiscus or Sumac flowers.
* Creamy Brown- Ground coffee beans.
Pg 4
CLASSIFICATION.
Dyes can be classified in several ways; each class has a very unique chemistry,
structure and particular way of bonding.Some dyes can react chemically with
the substrate forming strong bonds in the process and others can be held by
physically forces.
Some of the prominent ways of classification are given below :-
* Natural-Synthetic.
* Organic-Inorganic.
* By area and method of application.
* Chemical classification-Based on the nature of their respective
chromospheres.
* By nature of the electronic excitation.
*According to dyeing method.
-Anionic.
-Direct.
-Dispersed.
Pg 5
PROTECTION TECHNIQUES FOR
NATURAL DYES.
Unlike synthetic dyes,which are synthesized from chemical precursors,natural
dyes are mostly obtained from various plants' parts.These dyes-bearing
materials contain only a small percentage of dye usually 0.5-5%.These plant
materials cannot be directly used for dyeing textiles.
Also,many plant materials such as flowers and fruits are seasonal and contain
a large amount of water and hence cannot be stored as such.Therefore,in
order to make them suitable for textile dyeing purposes and make them
available throughout the year,these are subjected to some processing
operations.Collected plant materials are first dried:either in shade or in a hot
air dryer at a low temperature about 313-323 K to reduce their water
content to about 10-15% or less.
Many materials can also be sun dried.Dried material is then powdered in a
pulverizes to reduce particle size and to facilitate better dye
extraction.These powdered and dried materials in most cases can be stored in
airtight bags and containers for at least a year and used for dyeing whenever
required.
Storage under nitrogen can further prolong their shelf life. Many natural dye
manufacturers sell such finally powdered materials and these are used by many
cottage-level dyers practicing hand-dyeing out cheaper.
However,these powders are unsuitable for use in various dyeing machine such
as a package dyeing machine as the textile material act as a filter and the
dye particles get trapped within it,resulting in patchy and uneven dyeing.
Therefore purified dye powders are required for use in dyeing machines.
For producing purified dye powders,dye has to be first extracted from
dye-bearing materials and the extract thus obtained is then concentrated or
dried to get liquid concentrates or purified ready-to-use powders.Various
extraction and dyeing process for production of purified natural dyes are
used.
The different methods for extraction of colouring materials are :
* Aqueous extraction.
* Alkali or acid extraction.
* Microwave and ultrasonic assisted extraction.
* Fermentation.
* Enzymatic extraction.
* Solvent extraction.
* Supercritical fluid extraction.
DYEING.
As for synthetic dyes,the amount of dye to be taken is given as '%shade'.It
denotes the amount of dye(in gms) to be taken for dyeing 100gm of textile
material.The terminology remains the same for the both crude dye material
and purified extracts.As the dye content of raw material is low,its common to
use 10-30%shade,whereas the amount can be reduced to 2-5% for the
purified dyed extracts.
A large quantity of mordants is needed for higher shades. As in the case
with the synthetic dyes,the amount of water to be taken in he dye bath is an
important parameter.In technical terms,it is given in the recipe as the
material-to-liquor ratio(MLR).The MLR denotes the amount of water in ml
required per gram of the fabric to be dyed.
As natural dyes differ in their chemical constituents,their dyeing procedures
also differ but their basic dyeing process is similar.Their may be different
optimum temperature,time and pH of dyeing,but the basic steps remain the
same.Many natural dyes are dyed at near boiling temperature on cotton.Wool
and silk are dyed at a lower temperature,although some dyes may dye cotton
also at low temperature.For dyeing, animal fibres wool,pashmina and
silk,generally 1-2% of acetic acid is used during dyeing.The material to be
dyed is introduced into the dyeing bath at room temperature and the
temperature is then increased slowly to ensure of dyeing.The movement of
textile material in bath tub is very important;otherwise the dyeing may not be
uniform.
After the dyeing is over,the dyed material is removed and allowed to cool
down for some time and then washed with water again.Some traditional dyers
have leaved the material in the dye bath itself to cool down a little and then
removed the material for washing.The washed dyed material is then soaped
with a hot soap or non-ionic detergent solution to remove loosely held dye and
i again rinsed with water and dried in shade.At industrial scale hydro
extractors are used to remove excess water during washing.
Preparing the fabric for natural dye:
Natural fabric such as cotton,silk and wool take better to natural dyes than
do synthesis.If we use cotton,make it hasn't been worn because colour won't
take it,the fabric may have any of body oil.With most dyes and materials we
have to prepare the fabric so that the colour will adhere to it and not run,a
process called fixing.Fixing requires a mordant or fixer;alum,lemon
juice,vinegar and baking soda are common mordants.
Start with white fabric,and wash it well.Add a small amount of mordant to one
quart of warm water in a large stainless steel pot.Add the fabric to the
pot,bring the liquid to the boil and then let it simmer for 45-60
minutes.Remove the pot from the stove to cool;then use the tongs to remove
the fabrics from the water.Rinse the fabric in cold water until it runs
clear;then blot out the extra water with the help of paper towels.
How to dye the fabric:
Take the wet fabric and put it into a stainless steel pot with the dye.Bring to
boil and simmer for about 30-40 minutes,stirring gently with a wooden spoon
or paddle to make sure the dye covers evenly.Some people leave the fabric in
the dye overnight without boiling it.Remove the fabric from the water with
tongs.Rinse it in cold water and hang it to dry it out in the sun.
EXPERIMENT.
AIM: To dye wool and cotton clothes with turmeric and malachite green.
REQUIREMENTS:500ml beaker,tripod,stand,wire gauze,wool cloth,sodium
carbonate,turmeric and malachite dye.
PROCEDURE:
1. Take about 0.5gm of solid sodium carbonate and dissolve it in 250ml of
water.
2. Take about 0.1gm of malachite green dye and add it to 400ml water.On
warming a clear solution of dye results.
3. Take about 2gm of turmeric powder and add 400ml of
water and on warming, a yellow solution is obtained which is further used for
dyeing.
4. Take about 200 ml of dye solution and in it dip the cloth to be dyed.
5. Boil the solution for 2 minutes.
6. After that remove the cloth and wash it with hot water 3-4 times,squeeze
and keep it for drying.
7. Take another piece of cotton cloth and put it directly into boiling solution
of the dye. Keep it dipped for 2 min. Remove the cloth and wash with water
and squeeze and keep it for drying.
8. Similarly dye the cloth with turmeric solution and keep it for drying.
9. Compare the colour of the wool cloth with that dyed directly.
OBSERVATION:
1. The colour of the wool cloth dyed directly by dipping in hot solution of
malachite green dye is fast.
2. The colour of the cloth dipped in the turmeric solution becomes permanent
yellow and is dyed.
APPLICATION OF NATURAL DYES
ON TEXTILE.
Natural dyes are mostly employed for dyeing of natural fiber textiles to
enhance their eco friendly characteristics. They are usually applied to textiles
by dyeing. Apart from indigo,other natural dyes are usually not used for
printing directly. For producing printed fabrics,the printing is usually done with
mordant and the whole material is dyed whereby only the area printed with
mordant's picks up the colour.
Natural dyes,like synthetic dyes,can also be used to dye textiles at all stages
such as fiber,yarn or fabric.Fiber dyeing has the advantage that any shade
variation can be easily adjusted by blending and therefore has been practiced
at industrial scale also.Wool is generally dyed in yarn dyeing for all materials
as it offers versatility in designing during weaving.
Dyeing in hank form is preferred by traditional dyers operating at the cottage
level due to its simplicity and low investment and also its compatibility with
their usage of crude dye-bearing natural resources for reasons of authenticity
as well as cost effectiveness.
Dyeing is normally carried out by these artisans by hand in large vessel.Iron,
stainless steel,copper and aluminium vessels are used. Dyeing in copper vessels
is considered to produced bright shades.Aluminium vessels are normally stained
with a particular dye hence should be used if only one type of dye is used.
Stainless steel vessels are most preferred for the natural dyeing process. On
a large scale,hank-dyeing machines have been successfully used.Fine purified
products or concentrates are needed for package dyeing as otherwise dyeing is
uneven.Fabric dyeing is also carried out in metal vessel at the cottage
level.Machines such as the Jigger and Winch have been employed for dyeing
larger lots.Suitable dyes or dye-bearing resources are selected based on the
colour requirement.Flowers and leaves containing flavonoids are used to
produce yellow colour shades.
If purified natural dyes are used,these can be directly used for during.The
process for the dyeing of textiles with natural dyes differs from the synthetic
dye application process because only some natural dyes can be applied directly
to textiles.In most of the cases the dye is not substantive to the fiber on
which it is being dyed therefore an additional step of mordanting is involved.
ADVANTAGES.
Natural dyes are considered to be eco-friendly as these are obtained from
renewable resources.These are biodegradable and the residual vegetal matter
left after extraction of dyes can be easily compressed and used as
fertilizer.They produce soft clothes soothing to the eye which are in harmony
with nature.
In addition to these environmental benefits,natural dyes also offer functional
benefits to the wearer and users of such textiles.Many of the natural dyes
absorb in the ultraviolet region and therefore fabrics dyed with such dyes
should offer good protection from ultraviolet light.Fabrics dyed with some
natural dyes have been reported by the wearers to be free of odour perhaps
due to the antibacterial or bacteriostatic properties of natural dye materials.
DRAWBACKS
# Dependence on chemicals :-There is still a reliance on chemicals for bonding
the colour to the fabric.
# Ecological aspects :-Just as the dye is natural that does no guarantee that
if it is also environmentally stable.
# Effluents :-Some of the effluents from the processes using natural dyes
can be harmful as the ones of the synthetic dyes.
# Inherent weakness :-Some uncomfortable questions regarding
permanency,application methods and colour fastness.
# Need for huge amount of water :-Huge amount of water is wasted.Typically
the dye material is put in a pot of water and then the textiles to be dyed are
added to the pot,which is heated and stirred until the colour is transferred.
FUTURE PROSPECTS AND
CONCLUSION.
Presently an approximately 1% share of textiles is only being dyed with
natural dyes mostly in the cottage sector by traditional artisans,enthusiasts
and small entrepreneurs. Selling of natural dye-bearing materials and their
purified extracts is,however,being done at a small industry level.
The tedious application process and non-reproducibility of shades and
insufficient availability are some of the factors responsible for their
non-adoption in mainstream textile processing.However, at the present level of
dye resource availability, their adoption by the textile industry is not
desirable also as that would result in an environmental disaster by way of loss
of biodiversity and depletion of forest cover in spite of the tremendous
environmental advantage offered by them in terms of the lower pollution of
the effluent if used properly.This advantage can be utilised by the traditional
artisans in preserving their surrounding from the ill effects of pollution caused
by synthetic dyes as they do not have access to expensive effluent treatment
plants needed for synthetic dyes.A clean production model offered by natural
dyes is a better alternative for them.
The benefits of research on the development of improved application
compliance should reach and the consumers also get the benefit of truly
environment friendly textiles.
The availability of natural dyes needs to be increased in a sustainable manner
by utilizing the by-products and wastes from agriculture and agro processing
industries and judicious collection of forest procedure.This may be
supplemented by growing important dye-bearing plants on wastelands and
marginal lands thus providing an alternative cas crop to
cultivators.Establishment of proper characterization and certification protocols
for natural dyes would definitely improve consumer confidence in natural dyed
textiles and would benefit both producers and users.If natural dye availability
can be increased by the above-described measures and the cost of purified
dyes can be brought down with a proper certification mechanism, there is a
huge scope for adoption of these dyes by small-scale dyeing units as they lack
the resources to install and operate expensive effluent treatment plants
needed to bring the synthetic dye effluent within the limits set by regulatory
authorities.
At the level where scientific development stand today,natural dyes are a
sustainable option only for small-scale application.
BIBLIOGRAPHY.
1. www.scribd.com
2. www.fabricnaturaldyes.com
3. www.yahooanswers.com
4. Chemistry lab manual class 12