FIITJEE AITS-PT-II (Paper-2)-PCM-JEE(Advanced)/19 Test

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FIITJEE
ALL INDIA TEST SERIES
PART TEST – II
JEE (Advanced)-2018-19
PAPER – 2
TEST DATE: 18-11-2018

Time Allotted: 3 Hours Maximum Marks: 231
General Instructions:
 The test consists of total 69 questions.
 Each subject (PCM) has 23 questions.
 This question paper contains Three Parts.
 Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
 Each Part is further divided into Three Sections: Section-A, Section-C & Section-D.
Section-A (01 – 03, 24 – 26, 47 – 49) contains 9 multiple choice questions which have only one
correct answer. Each question carries +3 marks for correct answer and –1 mark for wrong
answer.
Section-A (04 – 08, 27 – 31, 50 – 54) contains 15 multiple choice questions which have one or
more than one correct answer. Each question carries +4 marks for correct answer and –2 mark
for wrong answer.
Partial Marks +1 for each correct option provided no incorrect options is selected.
Section-A (09 – 10, 32 – 33, 55 – 56) contains 3 paragraphs. Based upon paragraph, 2 multiple
choice questions have to be answered. Each question has only one correct answer and carries +3
marks for correct answer. There is no negative marking.
Section-C (11 – 20, 34 – 43, 57 – 66) contains 30 Numerical based questions with answer as
numerical value from 0 to 9 and each question carries +3 marks for correct answer. There is no
negative marking.
Section-D (21 – 23, 44 – 46, 67 – 69) contains 9 Numerical answer type questions with answer
XXXXX.XX and each question carries +4 marks for correct answer and –1 mark for wrong answer.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
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AITS-PT-II (Paper-2)-PCM-JEE(Advanced)/19 2
Physics PART – I
SECTION – A
Single Correct Choice Type
This section contains 3 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.

1. A conducting disc of conductivity  has radius a and thickness . A uniform magnetic field B is
applied in a direction perpendicular to the plane of the disc. If the magnetic field changes with
time at the rate of dB/dt, then the power dissipated in the disc due to the induced current.
2
a4  dB 
(A)  
8  dt 
2
a4  dB 
(B)  
12  dt 
2
a4  dB 
(C)  
4  dt 
2
a4  dB 
(D)  
6  dt 
Ans. A
Sol. Consider two circles of radii r and r + dr concentric with the disc
(0 < r < a) (figure). The induced e.m.f. in the circular path of 
radius r is a
d dB O r

dt

r 2B  r 2 
dt
. dr B
The resistance of the circular path between radii r and r + dr is
1 2r
R ,
 dr B
The length of the path being 2r and the cross sectional area of
current flow being dr. The power dissipated inside this path is
2
 2   dB  3
dP     r dr.
R 2  dt 
The total dissipated power P is
2 a 2
  dB  3 a 4  dB 
P    r dr    .
2  dt  0
8  dt 
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3 AITS-PT-II (Paper-2)-PCM-JEE(Advanced)/19
2. In the circuit shown in figure, the switch ‘S’ is closed L1 R1

at t = 0. The value of current in the resistor R3, when it
becomes steady (as compared to the steady current R2
R3
E
before closing the switch S)
L2
(A) Increases
(B) Decreases
(C) Remains constant
(D) Becomes zero
Ans. B
E
Sol. Initial current in R3, ii 
R1  R3
E R2 R2E
Final current if   =
R 2R 3 R2  R3 R1(R2  R3 )  R2R3
R1 
R 2  R3
E
If =
R1R 3
 R1  R3
R2
As if < ii, so current in the resistor R3 will decrease.
3. A straight segment OP of length L of a circuit carrying current I ampere is placed along x-axis.
Two infinitely long straight wires A and B each extending from z =  to + are fixed at y = 
meter to y = + meter respectively. Wires A and B, each carry current I ampere along positive z-
axis. Given that O is origin of the coordinate system. The magnitude of force on segment OP is
0 2  L2 
(A) I n 1  2 
   
 
0 2  L2 
(B) I n  1  2 
2   
0 2   2 
(C) I n 1  2 
  L 
0 2  2 
(D) I n  1  2 
2  L 
Ans. B
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Sol. Net B at distance x from O along x-axis A Y

 I
= 0 2cos  X
2 r 
r O
 I
 F   dF   I 0 2cos dx x 
2 r O
 P
  L2 
 0 I2 n  1  2  
2   
B
(One or More than one correct type)

This section contains 5 questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four options is(are) correct.
4. Logarithms of reading of pressure and volume for an log P(kPa)

ideal gas were plotted in the graph. By measuring
the gradient it can be shown that 5.38
5.10
3.10 3.30 logV (dm3)
(A) The gas may be Mono-atomic
(B) The gas may be Diatomic
(C) The process is an adiabatic change
(D) The process is an isothermal change.
Ans. B, C
Sol. log P = m log V + C …(i)

Where C is constant and m is slope
 5.38  5.10 
m   1.4
 3.10  3.30 
1.4
So, from (i) PV = K (constant)
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5. In a RLC series circuit shown in the figure, the V2

readings of voltmeters V1 and V2 are 100 V and 120 C
R L
V respectively. The source voltage (V) of
alternating source is 130 V. Mark the correct
option(s).
V1
V
~
(A) Voltage across resistor, inductor and capacitor are 50 V, 86.6 V and 186.6 V respectively.
(B) Voltage across resistor, inductor and capacitor are 50 V, 86.6, 206.6V respectively.
5
(C) Circuit is capacitive and power factor is .
13
5
(D) Circuit is inducting and power factor is .
13
Ans. B, C
Sol. Let voltage across resistor, inductor and capacitor be VR , VL and VC . Also since V2  V1 so
VC  VL .
2
 VR2  VL2  V12  1002 and VC  VL  120 and VR2   VC  VL   130 2
Solving VR  50V, VL  86.6 V, VC  206.6 V
VR 50 5
Power factor = cos    
VZ 130 13
6. An electrical circuit is shown in the R V

figure. It has two conducting spheres A
and B of radii 3a and 6a respectively.
When the inductor of inductance L is in
its steady state the switch is shifted
from position-1 to position-2. Now 1
choose the correct option(s)
3a
6a
L 2
A B
V
(A) Maximum charge on the sphere A is 80 aL .
R
V
(B) Maximum charge on the sphere B is 40 aL .
R
(C) The circuit contains only magnetic energy at time t  83 0 aL .
(D) The circuit contains only electrical energy at time t  23 0 aL .
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Ans. A, C, D
V 3C I L 6C
Sol. I0  , 3C  4 0 a  3  C  40 a
R
dI –q q –q q
0
dt
q q dI
 L 0
3C 6C dt
d2 q q d2 q q
 L 2
  0  2
 0
dt 2C dt 2LC
1
 q  q0 sin t, I  q0  cos t,  
2LC
I0
At t  0, I  I0  q0   I0 2LC

V
q0  80 aL
R
2
T  2 80 aL

T
 23 0 aL
4
7. Three small metallic charged balls (radius tends to v

zero) have equal charges q and masses m, 4m and m
as shown in the figure. The balls are connected by light
string (Non-conducting) of length  each, and placed
on horizontal frictionless, non-conducting table. Initially  
m, q 4m, q m, q
balls are at rest and form a straight line. A sharp
horizontal impulse gives the central ball a speed v
directed perpendicular to strings connecting the balls.
Choose correct option(s):
(A) The minimum distance during subsequent motion between the balls of mass m is
6q2 
3q  16m 0 v 2 
2
(B) The minimum distance during subsequent motion between the balls of mass m is
3q2 
3q2  16m 0 v 2 
(C) The maximum difference in electrostatic potential energy of the system during
2mv 2
subsequent motion is
3
(D) The maximum difference in electrostatic potential energy of the system during
4mv 2
subsequent motion is
3
Ans. A, C
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4mv 2v
Sol. v CM  
6m 3
In centre of mass frame
Gain in P.E. = Loss in KE
q2  1 1  2 4mv 2
  2mv 
40  D 2  3
6q2 
 D
3q2  16m0 v 2 
8. The figure shows the variation of electrostatic potential V in volt with the distance of position of
point along x-axis from origin due to continuous volume charge distribution. In the region x = – 1m
2
to x = + 1m, the graph is parabolic (V = 15 – 5x ) and rest portion of graph is straight line. Choose

the correct option(s) (0  permittivity of free space = 8.85 × 10–12 N–1 m–2C2). The direction of E
along positive x-axis is considered as positive.
V (in volt)
2
15 V = 15 – 5x
B
A 10
5
(in metre)
–3 –2 –1 0 +1 +2 +3 X
(A) This graph of potential may be due to a thick sheet of infinite dimension (– 1m  x  1, –
 < y <  and –  < z < ) with constant volume charge density 1.77 × 10–10 C/m3.
(B) This graph of potential may be due to a thick sheet of infinite dimension (– 1m  x  1, –
 < y <  and –  < z < ) with constant volume charge density 0.885 × 10–10 C/m3.
(C) E (electric field)
X
O
(D) E (electric field)
X
O
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Ans. A, C

Sol. dV  Edx  xdx
20
V x
  2
 dv  20 0
xdx  V  V0 
40
x , so
V0
V0  15 volt

 5    200  20  8.85  10 12  1.77  10 10 C / m3
40
E y xS
E  2S 
0
10 x
E
20
x X
O x = 1m
x
–10
Paragraph type (One Option Correct)

This section contains 1 paragraph each describing theory, experiment, data etc. Two questions relate to
the paragraph. Each question of a paragraph has Only One correct answer among the four choices (A),
(B), (C) and (D).
Paragraph for Questions 9 & 10
The melting point of wax is measured by using a thermometer
which is not exact, and it indicates a temperature of 50°C as shown
Thermometer 50°C
in figure-I.
Just melted
Wax-Box
Figure-I
A Wheatstone bridge is used to measure this melting point exactly.

The deviation from 50°C is being measured by observing the 50
variation of the resistance of a coil embedded in wax. 50
The Wheatstone bridge is setup so that the resistance of G

each arm is 50 exactly at 50°C, and there is no current in the 50
galvanometer as shown in figure-II. The resistance of the Ig = 0
galvanometer is 50. 50
50
2.5V
Figure-II
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One arm of the bridge containing the coil of resistance 50 is now
50 Wax-Box
immersed in a wax-box. The wax is just melted as shown in the figure-
III. It is now observed that the current through the galvanometer is 0.1
A.
G
–3 50
Given, temperature coefficient of resistance is 10 per °C.
Resistances other than inside wax-box are assumed to be constant Ig  0
50
and are exactly 50 while the resistance of wax box is very close to 50
50.
2.5V
Figure-III
9. The variation in the resistance inside the wax-box from its initial value of 50 is
(A) 1 104 
(B) 2  104 
(C) 4  10 4 
(D) 8  104 
Ans. D
10. Calculate the deviation in the melting point from 50°C.
(A) 0.004C
(B) 0.008C
(C) 0.016C
(D) 0.036C
Ans. C
Sol. 9-10.
When the four arms have equal resistances, the off-
balance galvanometer current for a small change R in the 50 Wax-Box
resistance of the third arm is
V R
IG  B 2 .
8R G
50
Here IG  107 A, R  50, and VB  2.5V. Hence
8  107  25  102 50
R   8  10 4  . 50
2.5
2.5V
If the corresponding change in temperature is T, we have
RT  R3 ,
–3
Where  = temperature coefficient of resistance = 10 /°C.
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8  104
Therefore, T   1.6  10 2  0.016C .
50  103
SECTION – C
(Single digit integer type)
This section contains 10 questions. The answer to each question is a Single Digit Integer ranging from
0 to 9, both inclusive.
11. An air-filled capacitor of capacitance 50 pF is charged to a voltage V and connected across

another uncharged capacitor of capacitance 100 pF, the final voltage across each capacitor is V1
volt. Now an identical air-filled capacitor of capacitance 50 pF is totally filled with a solid dielectric
of dielectric constant 2n & again charged to the same voltage V as before. It is now connected
across another uncharged capacitor of capacitance 100 pF, the final voltage across each
V 2
capacitor is V2 volt. If 1 is then find the value of n.
V2 5
Ans. 5
Sol. In the first case,

Charge = CV = (C + Ce)V1, …(i)
Where C = 50 pF, Ce = 100 pF
In the second case,
Charge = KCV = (KC + Ce)V2, …(ii)
Dividing (ii) by (i) we obtain
KC  Ce V2 KC  Ce 2.5KC  2.5Ce
K .   2.5 
C  Ce V1 C  Ce C  Ce
Ce
 1.5KC  K  2.5  Ce  1.5K  K  2.5   2 K  2.5 
C
 0.5 K = 5  K = 10  n = 5.
12. A long thin copper wire of the radius 2mm, carries a time-varying current I = t ampere (uniformly
distributed), then the induced electric field on its surface is equal to k X10–7 Vm–1. Find the value
of k. Take the induced field along the axis of the wire to be zero.
Ans. 1
Sol. Let the radius of the wire be R. Consider a rectangle abcd in

the wire with the side ab along the axis. The magnetic dr
a d
 Ir
induction at a distance r from the axis (r < R) is B  0 2 I=t
2R Es
ampere r
The flux through the elementary shaded area within abcd is
Bldr, where  = ab = cd. The flux  through abcd is
R c
 Ir  I b
   0 2 dr  0 .
0 2 R
4 R
R
The induced emf along the curve abcd is
d 0  dI 0 
    …(i)
dt 4  dt 4
The wire being thin, cd >> da. If Es is the induced electric field at the surface and E0 that along
the axis, then   Es  E0  . Since E0 = 0, we obtain from (i)
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0
Es   107 Vm1 .
4
Clearly, Es is independent of the radius of the wire.
0 0
13. A conducting ring of radius R & mass 300 g, carrying current I 30 30
ampere as shown in the figure. A bar magnet with its north
pole up is placed along the symmetric axis below the
conducting ring at a distance of 2m from the centre of ring. At
the location of ring, the magnetic field makes an angle 300 2m
1
with vertical and its magnitude is Tesla. If ring remains at
3π N
rest in its position, find the product of current I in the ring and
radius R of ring in ampere-meter. g  10 m / s  2

Ans. 9

Sol. 
Fmag  mg  B sin 30   I   2 R   mg
mg 0.3  10  3  2
 IR     9 A-m
2 B sin 30 2
14. A neutral metal sphere is placed at a large distance from a point charge. The magnitude of
Coulomb electrostatic interaction force between the charge and sphere is F0 . If the distance
between them is doubled, the new magnitude of Coulomb electrostatic interaction force between
n
the charge and sphere is 2 F0 . Find the value of n. (Assuming that the radius of sphere is very
small as compared to the distance between them)
Ans. 5
Sol. Due to induction, the sphere behaves as dipole whose dipole moment is directly proportional to
inducing field generated by point charge. So
a
p  2 , a is a constant and r is the distance between them.
r
bqp baq baq baq 5
p q
F0  3  5  F  5
 5 5
 2 F0
r r  2r  2 r r
15. On a sunny day, the temperature and pressure of atmosphere varying with height z from sea
level as

 z   z 
T  T0 1   , and P  P0  1  
 z0   z0 
Where T0 and z0, are 25°C and 25 km. The temperature A
pressure and density of air at sea level is T0 = 25°C, P0 =
1 atm and 1.2 kg/m3 respectively. Assume that air follows
T z
ideal gas law in the given condition, i.e.,  cons tan t.
P
Find the value of . Sea level
5 2 2
1 atm = 10 N/m and g = 10 m/s (g is uniform)
Ans. 3
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Sol. dp  gdz A
dp  gT P
  0 0
dz P0 T dz
PA
P z
dP g dz
   0 
P0
P P0 0 z 
1  
 z0 
z
P  0 gz0  z  (P+dp)A
 n   n 1  
 P0  P 0  z 0 
(Adz)g Sea level

 Z 
 P  P0  1   , where
 Z0 
 gz 1.2  10  25  10 3
 0 0  3
p0 105
16. In the circuit shown, all capacitors are identical. Initially,

the switch is open and capacitor-C1 is the only charged
capacitor. After the switch is closed, the equilibrium is
re-established and the charge on the capacitor – C1 is C1
a
Q. If initial charge on the capacitor – C1 was Q0  Q,
b C6
where a and b are positive integer, lying between 0 to 9.
C3
Find the value a – b.
C2 C4
C5
Ans. 3
Q Q 0  Q 8Q
Sol.   0  3Q  5Q0  5Q  0  Q0 
C 3C 5
5
Q0 – Q
+Q0 3C +Q 3C
–Q0 5 –Q 5
–Q0 + Q
Just before closing the switch Just after closing the switch
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
17. A point charge Q = 500 mC and mass B N
m = 10–6 kg is moving in a uniform magnetic I T


field B  1 tesla kˆ with speed v = 10 m/s and
6 M
follows path as shown in figure-1. If a wire with T

shape same as the trajectory of charged
particle carrying current I = 2A is kept in same Figure-1 Figure-2
magnetic field, each point of the wire
experiences a tension T (in newton) in
magnitude. Find the value of T.
Ans. 4
mv T mvI
Sol. R1  R 2    T
qB BI Q
10 6  106  2
 T  4 newton
500  103
18. Four resistance R, 3R, R and 3R are connected

as shown in figure. The two real voltmeters are
identical and Ammeter is ideal. If the value of R is V 0.5 V
25N  , find the value of N. You decide
arrangement of the resistances so that the given
conditions are satisfied.
V A
3V 6 mA
Ans. 5
Sol. x  y  6  x  3.5 mA X R B 3R Y
x  1  y y  2.5mA A C
KVL:
V I=x–y
3.5R  500  2.5  3R  0
3R
 4R = 500R = 125  A C
0.5 Y D X
R v  3  500  R
10
V A C
A
E C
3V
19. Particle A with charge 2q and mass mA, and particle B with charge 4q and mass m B are
accelerated with potential difference of V & 4 V respectively. Both particles are deflected by a
uniform magnetic field into semicircular paths. The radius of trajectories of particle A and B are R
and 2R respectively. The direction of magnetic field is perpendicular to the velocity. Find value of
mB
.
mA
Ans. 2
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1
Sol. qV  mv 2  mv  2qm V
2
mv 2qmV m V
R   R 
Bq Bq q
m A V mB 4V 1
R , & 2R  
2q 4q 2
m A 1 1 m A 1 1 mA 1
 .   .   
mB 2 2 mB 2 4 mB 2
20. Two point charges +Q and –Q are kept at points (a, 0) y

and (–a, 0). P(0, y0)
A dipole of dipole strength p and mass m is released + –
from point P(0, y0), where y0 >>> a; as shown in the
5Qp
figure. If the maximum speed of dipole is ,
0ma2
(–a, 0)A B(a, 0)
find the value of  X
–Q O +Q
Ans. 5
Sol. The force acting on the dipole is along negative y-axis.

1   1 2KQ
2 2 a
 
Ei  0, E f  mv 2  p.E  mv 2  p  ˆi . 2  ˆi  
Using COME, we have
1 Qp Qp
mv 2  v 
2 20 a 2
0ma2
SECTION – D
(Numerical Answer Type)
This section contains 3 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the second
decimal place; e.g. xxxxx.xx).
21. Consider the circuit shown in the figure. E1, E2 are sources of emf R1 = 3 E1 = 10 V
and R1, R2 are fixed resistances. E1 = 10V, E2 = 20V while R1 =
3, R2 = 2. The inductance L = 5 mH.
Take n 2  0.7, n3  1.1, n10  2.3.
The switch S is closed for a long time. The energy stored (in joule)
in the inductor is R2=2 L = 5 mH
S
E2=20V
Ans. 00000.25
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Sol. After the switch S, has been closed for a long time, the current R1 E1
through the inductor L can be found using Kirchoff’s Law:
2
1 E 
E2/R2 = I2. The stored energy is: L  2  . R2 L
2  R2 
After the switch S is opened, the current through the inductor
L is given by:
 
 
i  I1 1  eR t /L  I2 e R t /L
where R  R1  R 2 , E2 S
I1  E1 /  R1  R2 ,
I2  E2 / R2 .
22. Two solenoids, each of radius 2 cm are placed

coaxially with a gap of 1 cm between them. 2
Determine the magnetic field (in Gauss) at the 2 2 cm
centre of the gap if a current of 2 A flows through 1 1
z-axis
the two solenoids in series. Assume that each P
solenoid contains 40 turns per cm.
22
cos 1  0.907 , cos 2  0.242 ,   .
7
S1 1 cm S2
Ans. 00066.88
Sol. Let the two solenoids be S1 and S2, as shown in figure. The magnetic field at the centre-point p of
the gap due to the solenoid S1 is
 NI  NI
B1  0 [cos 1  cos    2 ]  0 cos 1  cos 2  ,
2L 2L
Where the angles 1 and 2 are as shown in figure. The field B1 is along the z-axis. By symmetry,
the field at p due to the solenoid S2 has the same magnitude and direction as B1. Thus the net
magnetic field at P is
 NI
B  2B1  0  cos 1  cos 2  .
L
N/L = 40 cm1  4  103 m1, 0  4  107 Henry / m, and I  2A.
Therefore, B  4  107  4  103  2   0.907  .242  = 66.88 Gauss.
23. A semi-circular conducting wire of radius 2m is rotated in a O



uniform magnetic field B  0.1 Tesla k̂ about point O with 
angular speed  = 10 rad/s as shown in the figure. The axis


of rotation is parallel to B. Find the potential difference (in M 53°
4 N

volt) between point M and point N.  tan53   .
 3
Ans. 00004.80
B 2 B22 B 2
Sol. e1 
2
, e2 
2
 VN  VM  e2  e1 
2
 
 2  12  2BR 2 cos   4.8 volt
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O
 
1  2R sin    2  2Rcos  
2 2

M N M 1 O 2 N
1 2

M O
N
Second Method v N   2

1  
v  VN  VM  Rcos  2R
2
M
e  Bv  B  2R  Rcos  
 2BR 2 cos 
v M   1
3
 2  0.1 10  4   4.8 Volt
5
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Chemistry PART – II
SECTION – A
Straight Objective Type
This section contains 3 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for
its answer, out of which Only One is correct.
24. In the following reaction sequence the correct structure for the major products X & Y are
NO2
K 2CO 3 Sn HCl
   X 
 Y
O
(A) O
X Y
NO2
Me N Et
H
(B) O
X Y OH
NO2 Me N Et
H
(C) HO Et HO Et
X Y
NO2 NH2
(D) HO Et HO Et
Y Y
NO2 NO2
Ans. B
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Sol. O
NO2
 OH  C 2H 5
 
O
NO2
Sn  HCl
O
C
OH OH C2 H5

Me Et Me Et NH2
N N
H H
 O
||
25. Compound A, C5H10O5 gives a tetraacetate with CH3  C  O and oxidation of A with Br2 – H2O

 
 2
gives an acid, C5H10O6. Reduction of A with red P and HI gives iso-pentane, there are two
possible structures for compound A which can be distinguished by using
(A) HIO4
(B) Red P + HI
(C) Phenyl hydrazine
(D) Tollen’s reagent
Ans. C
Sol. H OH
CH2OH CHO
O OH
HO HO
OH
OH HO
(i) (ii)
(i) will form osazone derivatives whereas (ii) will not.
26. The major product formed in the following reaction is:

O
MeMgCl, CuCl
 
Cl
(A) O
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(B)
O Me
(C)
O
CH3
(D) O
CH3
Ans. D
Sol. O O O
Cl
MeMgCl, CuCl
 
CH3 CH3
(More Than One Correct Type)
its answer, out of which MORE THAN ONE is/are correct.
OH OH
OH
i CHCl
3 ,NaOH

ii  H O
A 
2 2
27.
CH3 CH3
(A) A will give +ve test with Tollen’s reagent
(B) A is a weak organic monobasic acid
(C) A is a aldehyde
(D) A on reaction with conc. H2SO4 produces a neutral gas which is a very good reducing
agent.
Ans. A, B, D
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Sol. OH O OH O
OH O
C CH O
H O CH
O H
OOH
 
CH3 CH3
CH3
CHCl3 / OH
OH
OH
OH
OH
 HCOOH
CH3
CH3
Hence A will be HCOOH.
HCOOH + conc. H2SO4  CO
CO is a neutral gas as well as very good reducing agent.
28. An organic compound contains C, H, S, N and Cl, for detection of chlorine, the sodium extract of
compound is first heated with a few drop of conc. HNO3, and than AgNO3 is added to get a white
ppt. of AgCl, why was HNO3 added before the addition of AgNO3.
(A) To prevent the formation of NO2.
(B) To create a common ion effect.
(C) To convert CN – and S-2 to volatile HCN and H2S, else they will interfere with the test
forming AgCN and Ag2S.
(D) To prevent the hydrolysis to NaCN and Na2S.
Ans. C
29. Br
MgEther  NaNH
 A 
 NH     B
2
3
Cl
CH3
(A) Both A and B are aromatic in nature.
(B) Product A can show nucleophilic addition reaction.
(C) If potential nucleophile is not present then A will form dimer.
(D) B is a mixture of two structural isomers.
Ans. A, B, C, D
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Sol. Br MgBr
Mg

 

Cl Cl
CH3 CH3 CH3
NaNH2
CH3 NH3   
CH3
NH2 CH3 CH3
NH2
Dimer 
Sn HCl
30. CH3  CH2  NO 2  X    K  Organic compound  , then which of the following is/are
true for K?
(A) K (form solid oxamide) with diethyl oxalate.
(B) K (form liquid oxamide) with diethyl oxalate.
(C) K will not give Liberman nitroso test.
(D) K will form blue colour complex with Cu+2 salt.
Ans. A, C, D
SnHCl
Sol. CH3  CH2  NO2   CH3  CH2  NH2 K 
1o amine form solid oxamide
2o amine form liquid oxamide
Liberman Nitroso test is given by 2o amine
2
Cu2  4C2H5NH2   Cu  C 2H5NH2  4 
Blue 
31. In which case charge in transition state is more dispersed than starting material?
(A) CH3 X  NaNH2
(B) CH3 X  NH3
(C)  CH3 4 N X  OH
(D)  CH3 4 N X  RSH

Ans. A, C, D
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(B), (C) and (D).
Paragraph for Question Nos. 32 to 33
Hg2 ,H O/HNO2 BF4  


2
  A    B 
NH2  NH2 / OH
CH3 2 NH 1equivalent  Cl2 /AlCl3 ICl

F  
 E  D   C 
32. The compound (D) is
(A)
I NO 2
(B) Me
I
NO2
(C)
Me
I
NO2
(D)
NO 2
I
Ans. C
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33. The compound F is
(A) Cl
N
Me
O 2N
NO 2 Cl
(B) H3C CH3

N
I
NO2
(C)
N
H3C CH3
NO2
(D) NO 2
N Cl
H3C CH2
Ans. B
Solution for the Q. No. 32 and 33.

O
O
Hg2 , H /H O

2
 NOBF
4

2
A  B 
NO 2
NH2  NH2 / OH
C
NO 2
ICl
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H3C CH3
N Cl
Cl2 / AlCl3
CH3 2 NH
 
I I I
F 
NO2 NO2 NO2
E D
Single Integer Answer Type
This section contains 10 questions. Each question, when worked out will result in one integer from 0 to
9 (both inclusive).
34. 2.79 gm of nitrogenous compound on reaction with CS2 and HgCl2 forms a black ppt. of 0.09 mol.
If same amount of nitrogenous compound is reacted with HNO2. How many litres of gas at STP
would be formed.
Ans. 2
Sol. RNH2  CS 2  HgCl2 

 RNCS  HgS 
0.09 0.09
RNH2  HNO2 
 ROH  N2 
0.09 0.09
Volume in litres at STP = 0.09 × 22.4 = 2.016  2
O3 , CH3 2 S Tollen's reagent NaBH4

35. C6H8  anti aromatic    B  C   D
Only product Optically active
D on heating gives a major product having x number of stereoisomer, x is:
Ans. 3
Sol. O O O O
O
 3
 CH3 2 S
 H3C C C H 
 Tollen's reagent
H3C C C OH C
B  NaBH4

trans lactide  cis lactide   H3C CH C OH
 d 
OH O
D
36. Cl
H3C CH 2 CH 2 Cl2 , h
CH3 
Monochlorination 
If x = maximum number of monochloroisomer possible
y = Monochloro isomer on fractional distillation will separate. Then find

x  y
2
Ans. 5
Sol. x=6
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y=4
x  y = 5
2
37. CH3
NaOEt i Sn  HCl
  COOEt 2   X 
ii 
Y
NO2
Find the number of -bond in the Y?
Ans. 5
Sol. O
C OEt
CH3 CH2
EtO 
 C OEt
NO2 NO2 O
O
O CH2 C
OH
Sn  HCl

 COOEt
NH COOEt COOEt
NH2 NO2

H2O
COOEt
N
Y  H
38. How many of the following are cross-linked polymer?

Bakelite, Urea-formaldehyde, Melamine-formaldehyde, Nylon-6,6, Terylene.
Ans. 3
Sol. Bakelite, Urea-formaldehyde, Melamine-formaldehyde.
39. O
Br
NaOMe 
  A  
i aq. NaOH
ii NaOHCaO  
  B
The number of -bond in product (B) is:
Ans. 1
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Sol. O O COOMe
Br
NaOMe
  NaOMe
 
NaOH
COOH
NaOH/CaO
 
40. 1.2 gram of acetophenone on reaction with 76.2 gram of I2 in presence of NaOH give solid
iodoform with 75% yield. Find the weight of iodoform formed in gram.
Ans. 3
O O
|| ||
Sol. Ph  C CH3  3I2  4NaOH 
 CHI3  Ph  C ONa
O
||
1 mole of Ph  C CH3 will give 1 mole of CHI3
120 gram will give  394 g CHI3
1.2 gram will give  3.94 g CHI3
75
Hence, with 75% yield  3.94   2.955 gram
100
 3 gram.
41. In the following sequence of reaction the degree of unsaturation in the (B) is
CO2 Et
CO2 Et Tautomerise
HCl, 
 

 A  
 B  An aromatic compound 
H3C O
Ans. 4
Sol. CH3
CH3
CO2Et CH3
CO2Et HCl,  Tautomerise

 
O  
 OH
H3C O O
O
A B 
Degree of unsaturation = 4
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42. How many will liberates CO2 gas on reaction with NaHCO3?
O O C
H3C C CH2 C CH3, H

, CH3  SO2CHSO2CH3 ,
SO 3H
, CN – CH2 – CN
Ans. 1
Sol. SO 3H
, Re st all have pK a value greater than H2CO 3 .
43. NH2
CH3Br Moist Ag2 O Hot alkaline KMnO 4 Ba OH 


Excess
 A  
 B   C  
2
D
If number of carbon atom in D is x and -bond is y.

Find x + y?
Ans. 6
Sol. CH3
H3C CH3
+
NH2 N O
COOH
Ag O Hot KMnO4 Ba OH 
CH Br
3 
2
  (H2C) 4
Excess   2
 

COOH
SECTION – D
44. 2.25 g of a nitrogenous compound having molecular formula (C2H7N) is reacted with 11.95 g of
CHCl3 in presence of alc. KOH to form a bad smelling gas. One of the remaining reactant after
some times becomes poisonous due to aerial oxidation. This poisonous gas is now removed by
C2H5OH to form a precipitate. Find the weight of precipitate (in gram).
Ans. 00005.90
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alc KOH
Sol. C2H5NH2  CHCl3   C2H5NC
1 1 0
20 10 1
0 1 20
20
O , h
CHCl3 
2
 COCl2
COCl2  2C2H5 OH   C2H5  2 CO3
1
Hence precipitate =  118  5.9 gram
20
45. O O
CH3
i H3O
ii   B    C 
O O 
O CH3
O
A 
1.1 mole of (A) was reacted according to above reaction. ‘C’ is the gas produced which turns lime
water milky. The amount of C formed in gram will be? (Given At. Wt. of C, O, H are 12, 16, 1 gm
respectively).
Ans. 00096.80
Sol. O
CH3
HOOC COOH H3C

HO 
O
 A   3 
  2CO 2
HOOC COOH
C
CH3 H3C O
B 
1.1 mole of (A) produce 2.2 mole of CO2(g)
 wt. of CO2 = 2.2 × 44 = 96.8 gm.
 O i H
46. A  C4H6  3
CH  S
 B 
 ii   C
3 2 Aromatic compound
6.75 gram
A is a cyclic isomer having molecular formula C4H6. How many gram of C would be formed if 6.75
g of A was taken?
Ans. 00008.50
Sol. O O

O3 H
 H C CH2 CH2 C H 
CH3 2 S
A O
B   C
6.75 1
Moles of A   mole
54 8
1
Hence, mole of C would be formed
8
1
Wt. of C =  68  8.5 gm
8
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Mathematics PART – III
SECTION – A
Straight Objective Type
This section contains 3 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D),
out of which only one is correct
47. The length of medians of a triangle are 3, 4 and 5 cm. The area (in square cm) of the triangle is
(A) 8
(B) 12
(C) 24
(D) 32
Ans. A
4 1
Sol. A  34  8
3 2
48. The number of right-angled ABC (A = 90º) with integers side length whose inradius is 3 are
(A) 3
(B) 4
(C) 5
(D) 8
Ans. A
A
Sol.   s  a  tan    r (A = 90º)
2
(s – a) = r, 2s – 2a = 2r, b + c – a = 2r, a = (b + c – 2r)
(b – 6)(c – 6) = 2  32
49. P is a point inside an equilateral triangle ABC such that PA = 9, PB = 12 and PC = 15, then side
length of the ABC is
(A) 225  108 5
(B) 225  33
(C) 49  5 2
(D) none of these
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Ans. A
152  92   AC 
2 A(B)
Sol. cos    60º   ..... (1)
2.15.9 12 B
9 90º P
9 3
Also, cos   
15 5  15 60º
P 60º 15
So, a  225  108 5
60º
15
B C
One OR More Than One Choice Type
its answer, out of which only one or more than one is/are correct
50. Which of the following are INCORRECT?
 
(A) (sin x)sin x > (cos x)cos x  x   0, 
 4
  
(B) (cos x)sin x < (sin x)cos x  x   0, 
 12 
3  
(C) x cot x <  x   0, 
  3
 
(D) sin x  cos2x  sin x  cos2x  x   0, 
 4
Ans. A, B, C
Sol. (A) Use Jensen’s inequality for sin x < cos x < sin x + cos x with weights
1 = tan x and 2 = 1 – tan x ( 0 < x < /4), 1 and 2 are positive)
So, log(cos x) = log(tan x sin x + (1 – tan x)(sin x + cos x))
> tan x log(sin x) + (1 – tan x)log(sin x + cos x)
 sin x + cos x > 1 and tan x < 1. So, log(cos x) > tan x log(sin x)
    cos x   sin x 
(B) For x   0,  ; cos x > sin x. So, ln  ln
 12  cos x sin x
(C) Shown in the figure
m(OP) > m(OQ)
P
Q
x  
3 2
(D)  (a + b)p  ab + bp for a, b > 0 and 0  p  1
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51. Which of the following are INCORRECT?
1 7
(A)  sin20º 
3 20
x2 x4  
(B) cos x  1    x   0, 
2 16  2
x3 2x 5  
(C) tan x  x   x  0, 
3 15  2
(D) cos 2º and cos 7º are irrational
Ans. A, C
3
Sol. Use sin 3t = 3 sin t – 4 sin t
Let t = 20º
52. Let x – 2y – 5 = 0 be the directrix of a parabola and x – y – 7 = 0 be the tangent drawn to the
parabola at the point P(4, –3), then which of the following are INCORRECT?
16
(A) length of latus rectum =
5
8
(B) harmonic mean of length of segments of the focal chord =
5
(C) intersection point of the directrix and the given tangent is (9, 2)
(D) circle drawn on assuming P(4, –3) and Q as diameter, always passes through focus of
the parabola (where Q is the intersection point of tangent and directrix)
Ans. A, B
Sol. Foot of perpendicular P(4, –3) to the directrix is (3, –1)

  3   1 2  3  1  7 
Now, find its image about the tangent  
1 1 2
 = 6,  = –4. So, focus  (6, –4)
685 9
Now, distance of focus from the directrix = 
5 5
53. Let ABCD be a quadrilateral inscribed in a circle. Suppose AB  2  2 and AB subtends 135º
at the centre of the circle, the maximum possible area of ABCD is
53 3
(A)
4 2
8 7
(B)
3
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19  3
(C)
2
(D) none of these
Ans. A
Sol.  , ,  <  and y = sin x is concave downward on (0, ) C

sin   sin   sin  
So,  sin    sin75º
3  3 

1 1 D 
So, area of ABCD  sin 135º    sin   sin   sin  
2 2 
135 B
53 3
=
4 2
Equality holds if  =  =  = 75º A
54. If the vertices of an equilateral  lies on the curve 8x3 + y3 + 6xy = 1, then
6
(A) side length of the triangle is
15
3
(B) side length of the triangle is
2
3 3
(C) area of the triangle is
5
3 3
(D) area of the triangle is
16
Ans. A, C
6
Sol. (2x + y – 1)(4x2 + y2 + 1 – 2xy + y + 2x) = 0 and side length of the  =
15
3 3
So, area =
5

(B), (C) and (D).
Paragraph for Question Nos. 55 to 56
Read the following write up carefully and answer the following questions:
Diameter of ellipse is a line passing through the centre of the ellipse. Consider the set of parabola(s)
having common chord of minimum length with the diameter of the ellipse x 2 + y2 + xy = 8 and the line
mx – y + 4 = 0 as directrix
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55. The set of value(s) of m for which only one parabola is possible is
(A)  2, 2 
(B)  5, 3 
(C) {–2, 2}
(D) none of these
Ans. A
56. The range of value(s) of m for which two parabola(s) are possible is
(A)  ,  2    2,  
(B) (–, –2)  (2, )
(C)  ,  3    3,  
(D) none of these
Ans. A
Sol. (55.-56.)
For the ellipse x2 + y2 + xy = 8, c  (0, 0)
8 8 r2
For one parabola  : ( C1C2 = r1 + r2)
2 3
m 1
For two parabola(s) : C1C2 < r1 + r2  4 4 
c2  , 
r1  6 6
 4 4 
c1   , 
 6 6
SECTION – C
(One Integer Value Correct Type)
This section contains 10 questions. Each question, when worked out will result in one integer from 0 to
9 (both inclusive).
57. Consider the ellipse 4x2 + y2 – 8x + 4y + 4 = 0. Pair of tangents PT1 and PT2 are drawn to the
ellipse from P(–8, –2). Let S1' be the image of S1 about PT1 and S'2 be the image of S2 about

PT2, then if PS1S 2'   and PS1' S 2   , then is equal to _____

Ans. 1
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Sol. PS1' S 2 and PS1S'2 are similar
58. If tangents drawn to the parabola at A(1, 2) and B(5, 8) intersect at (–1, 8), then slope of directrix
a
is where gcd(a, b) = 1, then a + b is _____
b
Ans. 7
3
Sol. Q = mid-point of AB = (3, 5), let P  (–1, 8), m(PQ) = 
4
4
Slope of directrix =
3
59. Given a point (3, 2), then the minimum perimeter of a triangle with one vertex at (3, 2) one on the
x-axis and one on the line y = x (you may assume that a triangle with minimum perimeter exists)
is  , then sum of digits of  is _____
Ans. 8
Sol. For minimum perimeters (2, 3), (d, d) (c, 0), (3, –2) are collinear
Hence, mini perimeter = 26
60. If focus of the parabola which touches x = 0, y = 0, x – y + 1 = 0 and –2x – y – 8 = 0 is (, ), then

is _____

Ans. 3
Sol. Focus is intersection point of circles x(x + 1) + y(y – 1) = 0 and (x)(x + 4) + (y)(y + 8) = 0
 6 2
  , 
 5 5
12
61. If 3 2 , 4 2 and 2 be the altitudes of a triangle, then r 2 (r is inradius of the triangle) is
5
equal to _____
Ans. 2
Sol.  Harmonic mean of the altitudes of a triangle is 3 times its inradius

1  5 1 1 
So, r     
19  12 2 4 2 3 2 
62. Let ABC be a triangle (with A = /3) and a circle C1 be drawn lying in side the triangle, touching
its in-circle externally and also touching the two sides AB and AC, then ratio of the radii of the
circles C1 and C is k, then 3k is equal to _____
Ans. 1
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Sol. In triangle II1K A A/2

A r1
1  sin   M
 A  IK
sin    
r  r1
  2   r  r1  r  r1 I
1
 2  II1 r  r1  A  r  r1  r  r1
1  sin   r N
2
K
   A  r1 r1 1 I
tan2  2
  . So,  tan  30º  
 4  r r 3 B C
63. Let BD be the internal angle bisectors of angle B in triangle ABC with D on side AC. The
circumcircle of triangle BDC meets AB at E, while the circumcircle of triangle ABD meets BC at F.
if AE = 3, then CF is equal to
Ans. 3
Sol. Let circumcircle of triangle BDC be S1 and the circumcircle of triangle A

ABD be S2
E D
AD AB
So,  ..... (1)
CD BC
B C
Now, for circle S1: F
AE  AB = AD  AC S1
AD  AC
 AE  ..... (2) S2
AB
For circle S2:
CF  CB = CD  CA
CD  CA
 CF  ..... (3)
CB
From equation (2) and (3), we get
AE AD  CB
 ..... (4)
CF AB  CD
From equation (1) and (4), AE = CF
So, CF = 3
64. In an isosceles right angled triangle ABC, CA = CB = 1, and P is an arbitrary point on the
perimeter of ABC, then if maximum value of PA·PB·PC is , then 6 2 is _____
Ans. 3
Sol. (I): Let P  AC C

1
PA·PC  and PB  2
4
2 P
Thus PA·PC·PB 
4
The two equality sign can not be valid at the same time
2 A B
So, PA  PC  PB 
4
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(II): P  AB C

AP  x  0, 2 
So, let f(x) = (PA)2(PB)2)PC)2
2
 2  x  1  x
= x2 2
x 2 
 1
Let t  x  2  x  : t  0, 
 2 A P B
2
So, f(x) = g(t) = t (1 – t)
 1 1
 f  x  gt   g  
 2 8
1
PA  PB  PC  . Clearly P is the mid-point of AB
2 2
3
  1  4x 2  4
65. Number of solution of the equation  cos1  2
   x  x sin x  cos x is
 2
  1  4x 
Ans. 2
Sol. Shown in the figure
(0, –1)
1 2
66. Two circles C1, C2 of radii and touch each other externally and they both touch a unit circle
3 7
C internally. A circle C3 of radius R is inscribed to touch the circles C1, C2 externally and the circle
C internally, then 19R is equal to _____
Ans. 2
1 2

2
Sol. R 3 7 
1 2 19
1 
3 7
SECTION – D
67. If the exhaustive set of x  (0, 2) for which  n the inequality sin x + sin 2x + sin 3x + ..... +
3 3 1   2
sin(nx)  is valid 1  x   2 , k  I, then is _____
2 2
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Ans. 00002.00
2 2
Sol. Clearly, 0 < x < not valid, for  x  2
3 3
x  2x  1  x x
cos    cos  x cos    1 cot  
sin x   2   2 

2
   4  3
x x 2 2
2 sin   2 sin  
2 2
 
68. The least numbers A such that for any two squares of combined area 1 and a rectangle, of area A
exists such that the two squares can be packed in the rectangle (without interior overlap). You
may assume that the sides of the squares are parallel to the sides of the rectangle, is _____
Ans. 00001.20
Sol. If x and y are the sides of two squares then x 2 + y2 = 1

Let without loss of generality x  y
So, shorter side of the rectangle should be at least x
Longer side at least and (x + y)
So, A  x(x + y)
 
Put x = cos , y = sin ,   0, 
 4
1 2    1 2 
A  cos  2    equality holds if  
2 2  4  2 8
69. The least possible area of a convex set in plane that intersects both branches of the hyperbola
xy = 1 and both branches of the hyperbola xy = –1 is _____
Ans. 00004.00
Sol. For minimum area x = y = z = w

Amin = 4  1 
 y,   1
 y   x, 
 x
 1 
 1  w, 
 z,   w
 z

FIITJEE AITS-PT-II (Paper-2)-PCM-JEE(Advanced)/19 Test

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TEST DATE: 18-11-2018

 The test consists of total 69 questions.

 Each subject (PCM) has 23 questions.

 This question paper contains Three Parts.

 Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.

2. In the circuit shown in figure, the switch ‘S’ is closed L1 R1

(C) Remains constant

(D) Becomes zero

Sol. Net B at distance x from O along x-axis A Y

(One or More than one correct type)

4. Logarithms of reading of pressure and volume for an log P(kPa)

3.10 3.30 logV (dm3)

(A) The gas may be Mono-atomic

(B) The gas may be Diatomic

(C) The process is an adiabatic change

(D) The process is an isothermal change.

Sol. log P = m log V + C …(i)

5. In a RLC series circuit shown in the figure, the V2

6. An electrical circuit is shown in the R V

(C) The circuit contains only magnetic energy at time t  83 0 aL .

(D) The circuit contains only electrical energy at time t  23 0 aL .

7. Three small metallic charged balls (radius tends to v

(C) E (electric field)

(D) E (electric field)

Paragraph type (One Option Correct)

A Wheatstone bridge is used to measure this melting point exactly.

The Wheatstone bridge is setup so that the resistance of G

10. Calculate the deviation in the melting point from 50°C.

11. An air-filled capacitor of capacitance 50 pF is charged to a voltage V and connected across

Sol. In the first case,

Sol. Let the radius of the wire be R. Consider a rectangle abcd in

16. In the circuit shown, all capacitors are identical. Initially,

follows path as shown in figure-1. If a wire with T

18. Four resistance R, 3R, R and 3R are connected

20. Two point charges +Q and –Q are kept at points (a, 0) y

Sol. The force acting on the dipole is along negative y-axis.

22. Two solenoids, each of radius 2 cm are placed

23. A semi-circular conducting wire of radius 2m is rotated in a O

angular speed  = 10 rad/s as shown in the figure. The axis

(C) Phenyl hydrazine

(D) Tollen’s reagent

26. The major product formed in the following reaction is:

(More Than One Correct Type)

(A) A will give +ve test with Tollen’s reagent

(B) A is a weak organic monobasic acid

(A) To prevent the formation of NO2.

(B) To create a common ion effect.

(D) To prevent the hydrolysis to NaCN and Na2S.

(A) Both A and B are aromatic in nature.

(B) Product A can show nucleophilic addition reaction.

(C) If potential nucleophile is not present then A will form dimer.

(D) B is a mixture of two structural isomers.

(A) K (form solid oxamide) with diethyl oxalate.

(B) K (form liquid oxamide) with diethyl oxalate.

(C) K will not give Liberman nitroso test.

(D) K will form blue colour complex with Cu+2 salt.

(A) CH3 X  NaNH2

(B) CH3 X  NH3

(C)  CH3 4 N X  OH

(D)  CH3 4 N X  RSH

Paragraph type (One Option Correct)

Paragraph for Question Nos. 32 to 33