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To cite this article: W.H. Pepys jun. Esq. P.R.I. (1803) XXXIII. On gems. Read in the Session
1802–3, Philosophical Magazine Series 1, 17:67, 193-203, DOI: 10.1080/14786440308676399
Article views: 6
before.
Several others were tried, with the same results: one,
which was accidentally thrown from the charcoal, was seen
distinctly burning during its passage through the air; the
flame was of a blueish pearl colour, and nearly s-4ths of an
inch in length.
Guyton has proved, by a series of experiments on the
diamond in oxygen gas, exposed to the action of the con-
centrated rays from the sun, that this substance is one of
the purest ibrms of carbon; and that the other known
classes of carbonaceous bodies are in intermediate states of
oxygenation, which to a certain degree increases their com-
bustibility, and power of decomposing the air.
The differencehetween the degrees of temperature neces-
sary for the combustion of the diamond and charcoal are
as 188 to e765 of a Wedgwood~s scale.
Charcoal set on fire in oxygen gas does itself maintain
the temperature necessary for its combustion ; but the com-
bustion of the diamond" ceases as soon as it is no longer
maintained by the heat of the fhrnac% or the concentration
of' the solar rays.
The diamond re.quires for its complete combustion a
much greater quantity of oxygen than charcoal does, and
likewise produces more carbonic acid; for one part of char-
coal absorbs ~'~'27 of oxygen, and produces 3"575 of car-
bonic acid. But one part of the diamond absorbs somewhat
more than four of oxygen~ and really produces five of car-
bonic acid.
The diamond is the pure state of carbon. Plumbago is
its first state of oxidationi charcoal its second; gaseous
oxide of" carbon its third ; and carbonic acid its eom~)letion.
Guvton, to prove the carbonaceous property of the dia-
molld~ converted soft iron into steel t)y cementation with
~ See Phihsophiczl M~g~zine,,~-ol.,/iiL
it,
On Gems. 199
~¢. Mushet converted the iron into the same state without
the diamond being present. Mackenzie supports Guyton,
and.denies that tlais could have been done without the pre-
sence of some carbonaceous matter in the crucibles. Musher
says that carbon penetrates the crucibles at these elevated
temperatures: and ehus the experimem rests.
The substance of diamonds is lameUatcd, consisting of
very thin plates like ~those ~ f talc, but extremely hard and
intimately united, whose direction lapidaries must fi~ad out,
not only to cleave the ill-shaped stones, but to cut and shape
them properly. This last operation is pertbrmed by rub-
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90"75~
The ,~pph~.
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The E,m~ald.
The emerald is a gem of a fine, f~lt, transparent green
colour, electrical by friction. It is next in hardness after
the topaz. The Peruvian emerald erystal~zes in hexa~dral
~risms truncated~ flat at each extxemity. Crystals of eme-
rald
90~ Or~ Ge,ms~.
raid are frequently found inserted in the gatigues of quartzs
mad even of fluor.
Its specific gravity compared with that of water is as
27"755 to lo'ooo.
The emeralds which come from America are called o c d -
dental : Peru and the Brasils afford the most beautiful.
The emerald melted in the furnace of Pott : it was spee-
dily fused by the mirror: oxygen gas fuses it in a white
milky bubble tinged with green.
The emerald analysed by Vauquelin afforded
Silex - - 64"60
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Alumirte - 14"00
Glucine - - 13"OO
Chrome - 3"50
Lime - - 2-56
94"60
w,,,
T:~e Topaz.
The topaz is a precious stone of a fine goIden yellow co-
|our. The oriental topaz takes the octa~dral form : the Bra-
zilian crystallizes in rhomboidal tetra~dral prisms, grooved
longitudinally: they are terminated by two tetra~dral py-
ramids with smooth triangular faces. The Saxon topaz
exhibits long subocta6dral prisms, terminated by hexa~dral
pyramids more or less terminated at their base.
The specific gravity of the oriental is as 40" 106 to 10"000 ;
that of tke Brasilian 35"365 to 10"000.
The topaz is not fused in the porcelain furnace ; but both
the Oriental and the Brasilian are fused, and losc their colour
for a white opake mass, by oxgen gas.
The topaz analysed by Vauquelin gave
- S i l e x - - -68
.Alumine - - 31
99
The ttffacinth.
The hyacinth is a stone of a fine reddish yelIow colou'r
it is usually crystallized in the form of a rectangular tetra-
&tral prism, terminated by two quadrangular pyramids with
rhombie faces.
Its specific gravity compared with water is as 36"873 tr~
I0'000,
It
On Gems., ~03
tt loses its colour in the fire : with oxyget~ gas it js fusext
into a globule resembling bottle glass.
Hyacinths are found in Poland, in Bohemia, in Saxony,
Velay, &c.
Modern analysis has classed the jargon of Ceylon with
this stone, the analysis of which is given by Klaproth and
Vauquelin
Hyacinth. Jargon of CeIlon.
Zirconia ; - 6s'o Zircoaia - 7o'o
Silex 31"5 Silex - - ~5"0
:Nickel and iron o'5 Oxide of iron o'5
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!oo'o ~5.~
99"5
The violet-coloured amethyst, the crimson gameI, the pale
blue water sapphire, the girasol, the jacinth, and the chry-
solite, do not offer us any thing new, considered in a che-
mical point of view : they are also stones of an inferior va-
lue to those we have spoken of, which by their lustre an~
superior hardness have obtained the first-ptice in the cablne~
0f the virtuoso.
XXXI¥. 0 /