Chem 16 WFQR2 & WFUV2

Reviewer for 2ND Long Exam

1. Balance the following redox reactions:

a. MnO− 4 + Ce
3+
→ Mn2+ + Ce4+ (acidic)
b. S2 O3 + VO4 → VO2+ + SO2−
2− 3−
4 (acidic)
c. Al(s) + Hg 2+ −
2 → Al(OH)4 + Hg (l) (basic)
d. HNO3 + UO2+ → NO2(g) + UO2+ 2 (acidic)
e. S8(s) → S 2− + S2 O2−
3 (basic)

2. A. Hemoglobin is a protein that carries O2 and contains 4 Fe atoms. If hemoglobin contains 0.34%
Fe, calculate the molar mass of hemoglobin.

B. Calculate the molarity of (a) Ba(NO3)2, (b) Ba2+, and (c) NO3- of a solution prepared by dissolving
2.6132 g of Ba(NO3)2 in 50.00 ml of water.

C. If the solution in (B) was diluted to 125.0 ml, what would be the new molarity of Ba(NO3)2?

D. Consider the following reaction:

Al(s) + HNO3(aq) + HCl(aq) → AlCl3(aq) + NO(g) + H2 O(l)

a. Balance the chemical equation.

b. If 2.7 g Al, 100.0 ml of 0.300 M HNO3, and 200.0 ml of 0.600 M HCl were used, determine
which of the 3 is the limiting reactant.
c. How much Al remained unreacted? If Al is the limiting reactant, you may write 0.
d. What is the maximum NO(g) yield (in grams)?

3. Ef is a Chem 16 student and was given a colorless solution containing 4 unknown cations and anions.
Using the elimination tests he learned in the lab, he was able to get the following results:

· Formation of a white precipitate upon addition of NaOH with no change in color of red litmus paper.
Addition of excess NaOH seem to have little effect on the precipitate
· Yellow coloration of toluene layer after addition of KMnO4 and HNO3

All other elimination tests yielded negative results. However, Ef was playing around and
“accidentally” added K4Fe(CN)6 to his solution. The formation of a white precipitate was observed.
What are the 4 unknown ions present in Ef’s solution? Why was the positive confirmatory result for
the one of the ions not observed?

4. A. Combustion of 1.50 g of an unknown compound containing only C, H, and O yielded 3.78 g CO2 and
0.669 g H2O. Determine the empirical formula of the unknown compound.

B. Mass spectrometry analysis revealed that the molar mass of the compound is 122.13 g/mol.
Determine the molecular formula of the compound.

C. Write the balanced equation for the combustion reaction (without fractions).

DE GUZMAN, 1st Semester A. Y. 2015-2016 | 1

Chem 16 WFQR2 & WFUV2

D. The combustion experiment was done using a bomb calorimeter with a heat capacity of 6.62
kJ/mol. An 11.5ºC increase in temperature was observed. Assuming that the combustion was done
O
in standard temperature and pressure, calculate ΔHcombustion .

E. Given the following data:

ΔHfO (kJ/mol) SfO (J/mol ºC)

CO2(g) -393.5 213.7
H2 O(g) -241.8 188.8
O2(g) 0 205.1
Compound 167.6

Calculate ΔHfO for the unknown compound.

O
F. Calculate ΔGcombustion . Is the process spontaneous?

DE GUZMAN, 1st Semester A. Y. 2015-2016 | 2