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1. Calculate the number of oxygen atoms required to combine with 7g of N2 to form N2O3 when only
80% of N2 reacts to form N2O3.
(1) 2.3 1023 (2) 3.6 1023 (3) 1.8 1021 (4) 5.4 1021
2. If half mole of oxygen combine with Al to from Al2O3, the weight of Al used in the reaction is:
(Al = 27)
(1) 27g (2) 40.5g (3) 54g (4) 18 g
4. Calculate number of lines emitted in IR region when electron in H atom make transition from n2 = 5
to n1 = 1.
(1) 6 (2) 7 (3) 8 (4) 3
5. A light source of wavelength illuminates a metal and ejects photo-electrons with (K.E.)Max = 1 eV
Another light source of wavelength , ejects photo-electrons from same metal with K.E.Max 4 eV
3
Find the value of work function?
(1) 1 Ev (2) 2eV (3) 0.5 eV (4) None of these
6. Which of the following atomic orbital representation violates the Pauli’s exclusion principle, Hund’s
rule as well as Aufbau’s principle simultaneously?
2s 2p 4s 3d 4p
(i) (ii)
4f 5d
3p 4s
(iii) (iv)
10. What is the radius ratio for 2nd orbit of Li+2 ion and 3rd orbit of Be+3 ion?
(1) 3 : 1 (2) 16 : 27 (3) 4 : 9 (4) 3 : 4
11. The difference between nth and (n + 1)th Bohr’s radius of H–atom is equal to its (n – 1)th Bohr’s
radius. The value of n is
(1) 3 (2) 4 (3) 5 (4) 6
12. The radius of which of the following orbit is same as that of the first Bohr’s orbit of hydrogen atom:
(1) He+ (n = 2) (2) Li2+ (n = 2) (3) Li2+ (n = 3) (4) Be3+ (n = 2)
13. Consider the ground state of Cu atom (z = 29). The number of electrons with the azimuthal quantum
numbers l = 1 and 2 are respectively
(1) 16 and 6 (2) 12 and 10 (3) 12 and 9 (4) 16 and 5
14. Splitting of spectral lines when atoms are subjected to strong electric field is called:
(1) Zeeman effect (2) Stark effect
(3) Decay (4) Disintegration
15. The ionization energy of hydrogen atom in the ground state is x kJ. The energy required for an
electron to jump for 2 nd orbit to 3rd orbit is
5x x
(1) (2) 5x (3) 7.2x (4)
36 6
18. How many moles of NaOH are contained in 27 cm3 of 0.15 M NaOH?
(1) 0.2 (2) 4.05 × 103 (3) 4.05 × 103 (4) 0.2 × 10 3
19. 0.1g of an Organic compound containing phosphorus gave 0.222g of Mg2 P2 O 7 . The % of
Phosphorus in it will be: (Mg – 24; P – 31)
(1) 62 (2) 6.2 (3) 31 (4) 13
20. Sodium nitrate, heated in the presence of an excess of hydrogen, forms water according to the two-
step process.
2NaNO3 2NaNO2 + O2
2H2 + O2 2H2O.
How many grams of sodium nitrate are required to form 9 grams of water?
(1) 21.3 (2) 42.5 (3) 69.0 (4) 85.0
22. 1 g of Mg is burnt in a closed vessel which contains 0.5 g of O2. Which reactant is left in excess?
(1) Mg (2) O2
(3) Both the reactants are consumed (4) Mg and O2 are left in excess
23. The mass of chromium atoms in 85 g of Cr2S3 is (atomic mass of S = 32, Cr = 52)
(1) 22.1 g (2) 85 g (3) 44.2 g (4) 50 g
24. The ratio of energy of photon having wavelength 4000 A0 & 2000 A0 will be
(1) 2 : 1 (2) 1 : 2 (3) 3 : 1 (4) 1 : 1
o
25. In an atom of hydrogen, the atom is exposed to a radiation of wave length 970.58 A and atom got
excited, find out the maximum number of waves can be obtained during de excitation
(1) 3 (2) 6 (3) 4 (4) 10
26. Following figure shows a radial probability curve for an atomic orbital without specifying the name
of orbital. The orbital can be
r
27. Which of the following represents the De Broglie wavelength of electron if it’s kinetic energy is E.
6.12 0 12.24 0 3.06 0 1 0
(1) A (2) A (3) A (4) A
E E E E
28. The ratio between kinetic energy and total energy of electron in hydrogen atom will be
(1) 1 (2) 2 (3) –1 (4) –2
29. Calculate the number of oxygen atoms required to combine with 7g of N2 to form N2O3 when only
80% of N2 reacts to form N2O3.
(1) 2.3 1023 (2) 3.6 1023 (3) 1.8 1021 (4) 5.4 1021
32. The mole fraction of ethanol (C2H5OH) in water is 0.08. Its molality will be
(1) 2.41 mol/kg (2) 4.83 mol/kg (3) 3.33 mol/kg (4) 6.41 mol/ kg
CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 3
33. Calculate no lines emitted in IR region when Bohr electron make transition from n2 = 5 to n1 = 1.
(1) 6 (2) 7 (3) 8 (4) 3
34. A light source of wavelength illuminates a metal and ejects photo-electrons with (K.E.)Max = 1 eV
Another light source of wavelength , ejects photo-electrons from same metal with K.E.Max 4 eV
3
Find the value of work function?
(1) 1 Ev (2) 2eV (3) 0.5 eV (4) None of these
35. Which of the following atomic orbital representation violates the Pauli’s exclusion principle, Hund’s
rule as well as Aufbau’s principle simultaneously?
2s 2p 4s 3d 4p
(i) (ii)
4f 5d
3p 4s
(iii) (iv)
38. Select the correct combination of four quantum number for the outermost electron of Na atom
(1) n 4 l 0 ml 0 s 1 2 (2) n 3 l 1 ml 0 s 1 2
(3) n 3 l 1 ml 0 s 1 2 (4) n 3 l0 ml 0 s 1 2
39. If uncertainity in the momentrum of electron is zero. It’s uncertainity in the position is
(1) 0 (2) 1 (3) infinity (4) –1
41. Splitting of spectral lines when atoms are subjected to strong electric field is called
(1) zeeman effect (2) stark effect (3) decay (4) Integration
43. If uncertainity in position and momentum are equal than uncertainity in velocity is
h 1 h h 1 h
(1) (2) (3) (4)
2 m 2m
44. The quantum numbers for the last electron in an atom n = 3, l = 1 and m = –1. The atom is
(1) Al (2) Ti (3) Mg (4) C
46. An organic dye absorbs a photo of wavelength and re-emits the same energy into two photons of
wavelengths 1 and 2 respectively. The wave length is related to the wavelength 1 and 2 as :
1 1 1 1 1 1
(1) 1 2 (2) (3) (4) 1 2
1 2 1 2
47. Which of the following sets of quantum numbers represent an impossible arrangement?
n m s
(1) 3 2 –2 1
2
(2) 4 0 0 1
2
(3) 3 2 –3 1
2
(4) 5 3 0 1
2
(1) (2)
(3) (4)
50. The ratio of velocity of the electron in 4th and 5th orbit of Be3+ would be –
(1) 5 : 4 (2) 4 : 5 (3) 25 : 16 (4) 16 : 25
R2
Where R 2 Radical probability density r = distance from the nucleus. If there as no nodal plane in
the given orbital. The orbital is
(1) 3 s (2) 4 s (3) 5 dz 2 (4) 6 dz 2
54. According to Bohr model ,If the kinetic energy of electron in hydrogen atom in first excited state is
X then if the mass of electron is double then the magnitude of potential energy of electron in ground
state of that hypothetical hydrogen atom will be N times X . Then N is?
(1) 8 (2) 16 (3) 3 (4) 2
55. Calculate the atomic weight of a metal that forms an oxide having empirical formula M2O3 and
contains 70% metal by weight.
(1) 52 (2) 56 (3) 27 (4) 75
56. A mixture of 1 mole of Al and 3 mole of Cl2 are allowed to react as:
2Al (s) + 3Cl2(g) → 2AlCl3(s)
Then limiting reagent and moles of AlCl3 formed are:
(1) Al, 2 (2) Cl2,1 (3) Al,1 (4) Al, 1.5
57. 3.68 g of a mixture of CaCO3 and MgCO3 is heated to liberate 0.04 mole of CO2. The mole % of
CaCO3 and MgCO3 in the mixture is respectively;
(1) 50%, 50% (2) 60%, 40% (3) 40%, 60% (4) 30%, 70%
58. Assuming that petrol is iso-octane (C8H18) and has a density 0.8g mL–1; 1.425 L of petrol on
complete combustion will consume what amount of oxygen:
(1) 250 L (2) 125 L (3) 125 mole (4) 250 mole
59. An alloy of iron and carbon is treated with sulphuric acid, in which only iron reacts as:
2Fe(s) + 3H2SO4(aq) → Fe2(SO4)3 + 3H2(g)
If a sample of alloy weighing 140g gave 6g of Hydrogen, what is the % by weight of iron in alloy?
(1) 40% (2) 60% (3) 80% (4) 30%
60. A mixture of CO and CO2 has vapour density 20 at STP. 100 g of this mixture contains:
(1) 0.40 moles of CO (2) 0.20 moles of CO
(3) 0.625 moles of CO (4) 0.375 moles of CO
61. Suppose elements X and Y combine to form two compounds XY2 and X 3Y2 when 0.1 mole of
former weight 10 g while 0.05 mole of the letter weight 9 g. What are the atomic weight of X and Y.
(1) 40, 30 (2) 60, 40 (3) 20 , 30 (4) 30, 20
62. What is molarity of H2SO4 solution that has a density 1.84g/cc at 35o C and contains 98% by weight?
(1) 4.18 M (2) 8.14 M (3) 18.4 M (4) 18 M
63. A certain compound has the molecular formula X4O6 . If 10g of X 4O6 has 5.72g X , the atomic mass
of X is
(1) 32 amu (2) 37 amu (3) 42 amu (4) 98 amu
64. Calculate the number of oxygen atoms required to combine with 7g of N2 to form N2O3 when only
80% of N2 reacts to form N2O3.
(1) 2.3 1023 (2) 3.6 1023 (3) 1.8 1021 (4) 5.4 1021
66. 10 mL of oxygen and 60 mL of H2 is sparked till reaction is complete to form H2O(l). After attaining
the initial condition of P and T, the reduction in volume (in mL) of gases after reaction is:
(1) 30 (2) 40 (3) 20 (4) 10
1 2
(1) 3 = 1 + 2 (2) 3 = (3) 1 + 2 + 3 = 0 (4) 32 12 22
1 2
69. An excited electron of H-atom emit photon of wavelength and return in the ground state the
principal quantum number of excited state is given by
R 1 R 1
(1) R R 1 (2) (3) (4)
R 1 R R 1 R
70. The total number of nodes for 4d orbital will be (excluding the node at infinity)
(1) 2 (2) 3 (3) 0 (4) 1
71. The minimum frequency of photon needed to break bond in x 2 g having bond energy 158.4 kJ/mol
is a 1014 Hz. Find 'a'. (Take h = 6.6 1034 J s,1eV / atom = 96 KJ/mol)
(1) 8 (2) 6 (3) 4 (4) 2
72. Number of waves made by a Bohr electron during its one complete revolution in an orbit of a H-like
species :
(1) is only dependent on the atomic number of H-like species.
(2) is only dependent on the orbit number in which electron is revolving.
(3) is dependent on both the orbit number in which electron is revolving and the atomic number of
H-like species.
(4) is independent of both the orbit number in which electron is revolving and the atomic number of
H-like species.
73. Which of the following matter waves will have the longest wavelength, if travelling with same
kinetic energy?
(1) Proton (2) Alpha particle (3) Neutron (4) Electron