Acs

2013F - CHEM126-Petrova: ACS Chem 125-126 Review II http://njit.mrooms.net/mod/quiz/review.php?
q=17626&attempt=878728
You are logged in as Daniel Nowak (Logout)
NJIT ► 2013F - CHEM126-Petrova ► Quizzes ► ACS Chem 125-126 Review II ► Review of

attempt 4
ACS Chem 125-126 Review II
Review of attempt 4
Started on Wednesday, 11 December 2013, 10:57 PM

Completed on Wednesday, 11 December 2013, 11:02 PM
Time taken 5 mins 42 secs
Marks 50/51
Grade 6.86 out of a maximum of 7 (98%)
1 Antimony reacts with sulfur according to the following reaction:

Marks: 1
2Sb(s) + 3S(s) → Sb2S3(s)
What is the mass percent yield from 2.30 g of Sb in excess S, if 1.01 g of

Sb2S3 is obtained?
Sb2S3 is 340. g/mol
Answer:
Correct
Marks for this submission: 1/1.
2 For the following reaction at 25 oC, ∆Ho = (-1827) kJ and ∆So = 330 J/K
Marks: 1
A +4B → 3C + 3D
1 of 21 1/30/2014 11:47 AM
2013F - CHEM126-Petrova: ACS Chem 125-126 Review II http://njit.mrooms.net/mod/quiz/review.php?q=17626&attempt=878728
What is ∆Go at 279 oC in kJ?
Answer:
Did you change to K and use consistent units?

Correct
3 What is the oxidation state of Mn in KMnO4?

Marks: 1
Answer:
Correct
4 Balance the following half-reaction in base, using smallest whole number

Marks: 1 coefficients. What is the coefficient for OH- in the balanced equation?
CrO42-(aq) → Cr(OH)3(s)
(Hint, technically only H2O and OH- are available. However, you may first
balance using H2O and H+ and then convert to only H2O and OH-. . .)
Answer:
Correct
5 Balance the following reaction in acid, using smallest whole number

Marks: 1
coefficients. What is the coefficient for H2O in the balanced equation?
Ga(s) + MnO4-(aq) → Ga3+(aq) + Mn2+(aq)
(Hint, first balance each half-reaction separately.)
2 of 21 1/30/2014 11:47 AM
Answer: Correct
6 A stock solution of NaOH is 0.800 M. What volume of this solution (in mL) is
Marks: 1
needed to prepare 2.00 L of 0.079 M NaOH?
Answer:
Correct
7 What mass of copper (in mg) could be plated on an electrode from the
Marks: 1
electrolysis of a Cu(N03)2 solution with a current of 0.800 A for 45.7 min?
Answer:
Correct
8
Marks: 1
Consider the following half-reaction.
4H+(aq) + O2(g) + 4e- → 2H2O(l) Eo = 1.23 V
What is E, if the pressure of oxygen gas is 1.0 atmosphere and the pH is

9.82?
USE 2 DECIMAL PLACES. (Hint, are solids and pure liquids included in Q?
Using LeChatelier's principle is E going to be larger or smaller?)
Answer:
Correct
3 of 21 1/30/2014 11:47 AM
9 The activation energy for a particular reaction is 49 kJ/mol. By what factor will
Marks: 1 the rate constant increase when the temperature is increased from 50 oC to
66 oC?
Answer:
Correct
10 What is Kc for the reaction:2NO2(g) → N2O4(g)?

Marks: 1
Answer:
Correct
11 Mg2C2O4(s) → 2Mg2+(aq) +C2O42-(aq) Ksp = 8.6 x 10-5

Marks: 1
What is Qsp if 100 mL of 0.084 M Mg(N03)2 is added to 50 mL of 0.025 M
Na2C2O4?
This problem had an error it was corrected 5/7/2010 at 8:17 pm.
Answer:
Recall that if Qsp is greater than Ksp, a precipitate forms.
4 of 21 1/30/2014 11:47 AM
Incorrect
12 Pb(OH)2(s) → Pb2+(aq) + 2OH-(aq) Ksp = 1.4 x 10-20

Marks: 1
What is the solubility of lead hydroxide in pure water? (Simplify by neglecting
the OH- from water.)
Answer:
Correct
13 2 L of an unknown concentration of the weak base ammonia are standardized.

Marks: 1
50.0 mL of the basic solution are titrated with 0.200 M HCl. The end point
occurs after 82.2 mL of acid are added. What is the concentration of
ammonia in the 2 L flask?
Answer:
Correct
14
Marks: 1
These experiments were preformed:
I. A copper wire was placed in a solution of AgNO3(aq). The copper dissolved

and filments of silver metal grew on the remaining copper wire.
II. A copper wire was placed in a solution of Zn(NO3)2(aq). No reaction was
detected.
III. An aluminum wire was placed in a solution of Zn(NO3)2(aq). The aluminum
dissolved and Zn metal formed.
Rank the activity of these metal.
Cu
Al
5 of 21 1/30/2014 11:47 AM
Correct
15
Marks: 1
Match Correctly
AgNO3(aq) + NaOH(aq) → AgOH(s) + NaNO3(aq)
Ag+(aq) + OH-(aq) → AgOH(s)
NO3-(aq). Na+
AgNO3(aq), NaOH(aq)
Correct
16
Marks: 1
Match the type of reaction
AgNO3(aq) + NaOH(aq) →
AgOH(s) + NaNO3(aq)
C3H7OH(l) + 4.5O2(g) → 3CO2(g)
+ 4H2O(g)
H2SO4 + 2NaOH(aq) → H2O(l) +
Na2SO4(aq)
AgNO3(aq) + Cu(s) → Ag(s) +
Cu(NO3)3(aq)
Correct
17
Marks: 1
Which of the relationships is true for the transition from ice to water for an ice
water mixture at 0 oC and 1 atm?
Choose a. ∆G < 0, ∆H > 0, ∆S > 0

one b. ∆G = 0, ∆H > 0, ∆S > 0
answer.
c. ∆G = 0, ∆H = 0, ∆S = 0
d. ∆G = 0, ∆H < 0, ∆S > 0
6 of 21 1/30/2014 11:47 AM
Correct
18
Marks: 1
A particular chemical reaction has a positive ∆H and a positive ∆S. Which
statement is correct?
Choose a. The reaction is spontaneous at all temperatures.

one b. The reaction is nonspontaneous at all temperatures.
answer.
c. The reaction becomes spontaneous as temperature
increases.
d. The reaction becomes spontaneous as temperature
decreases.
Correct
19
Marks: 1
For which of these processes is the value of ∆S expected to be negative?
Choose a. Sugar is dissolved in water.

one b. Ice melts.
answer.
c. CaCO3(s) is decomposed into CaO(s) and CO2(g).
d. CH3OH(l) +1.5O2(g) → CO2(g) + 2H2O(l)
The side with more moles of gas has the greater entropy.
Correct
20 In which process is entropy decreased?

Marks: 1
Choose a. dissolving KCl in water
one b. heat flowing from a hot to a cold object
answer.
c. expanding a gas at constant T
d. freezing a liquid
Correct
7 of 21 1/30/2014 11:47 AM
21
Marks: 1
For an endothemic process to be spontaneous which of the following
conditions is correct?
Choose a. Low T, ∆S is positive

one b. High T, ∆S is positive
answer.
c. Low T, ∆S is negative
d. High T, ∆S is negative
Correct
22
Marks: 1
Which laboratory measurement is expressed to the appropriate number of
significant figures?
Choose a. 6.1 oC on a thermometer graduated in degrees

one b. 78.2 cm on a meter stick graduated in millimeter
answer.
c. 35.42 mL in a buret graduated in milliliters
d. 35.6 g on a scale graduated to tenths of a gram
Correct
8 of 21 1/30/2014 11:47 AM
23
Marks: 1
Which statement is true for the following unbalanced reaction?
Cu1+(aq) + MnO4-(aq) → Cu2+(aq) + Mn2+(aq)
Choose a. Cu1+ is reduced.

one
b. MnO4- is oxidized.
answer.
c. MnO4- is reduced.
d. Mn2+ is reduced.
Correct
24 Which change requires a reducing agent to produce the indicated product in

Marks: 1
an acidic solution? (Half-reactions not balanced.)
Choose a. MnO2(s) → Mn2+(aq)

one
b. MnO2(s) → MnO4-(aq)
answer.
c. Fe(s) → Fe2+(aq)
d. Fe2+(aq) → Fe3+(aq)
A reducing agent allows something to be reduced, that is, it provides electrons.

Correct
25
Marks: 1
A student wanted to make compound D using the following reaction which
takes place in water:
A(s) +O2(g) → D(s) + H+(aq)
The student used atomsperic air (0.21 atm oxygen) and 1.0 M HCl (the
presence of the acid increases the rate of the reaction). Unfortunately, the
equilibrium yield of D was too low to be useful. Which of the following changes
will improve the yield of D?
Choose a. Increasing the concentration of the acid

one b. Decreasing the concentration of the acid
answer.
9 of 21 1/30/2014 11:47 AM
(This is easy if you remember LeChatelier's principle.)

Correct
26
Marks: 1
Under certain conditions some substances, like MnO2, can act as an oxidizing
agent; under other conditions, as a reducing agent. What is true for these
substances?
Choose a. One of the elements must have multiple oxidation states and
one be in an intermediate oxidation state. (It can't be the largest or
answer. smallest.)
b. One of the elements must be a transition metal.
c. The substance must be a stronger oxidizing agent than a

reducing agent.
d. All of the above
Correct
27
Marks: 1
Standard reduction potentials, Eo
Fe3+(aq) + e- → Fe2+(aq) +0.77 V

2+ - 1+
Cu (aq) + e → Cu (aq) -0.15 V
Which of these ions is the best oxidizing agent?
Choose a. Fe3+
one
b. Fe2+
answer.
c. Cu2+
d. Cu1+
Correct
10 of 21 1/30/2014 11:47 AM
28
Marks: 1
Cu2+(aq) + 2e- → Cu(s) +0.34 V

Cu2+(aq) + e- → Cu1+(aq) -0.15 V
2+ -
Ni (aq) + 2e → Ni(s) -0.25 V
A quantity of a powdered mixture of copper and nickel is added to a solution

containing Cu2+ and Ni2+ ions, each at unit activity (1 M). What reaction will
occur?
Choose a. Nickel metal reduces Cu2+ ions to Cu(s).

one
b. Ni2+ ions are reduced to Ni metal.
answer.
c. Cu2+ ions are reduced to Cu+
d. Ni2+ ions oxidize Cu metal to Cu2+ ions.
The reaction giving the largest voltage occurs.

Correct
29
Marks: 1
Al3+(aq) + 3e- → Al(s) -1.66 V

2+ -
Ni (aq) + 2e → Ni(s) -0.25 V
What is the standard electrode potential for a voltaic cell constructed in the
appropriate way from the above two half-cells?
Choose a. 1.41 V
one b. 2.57 V
answer.
c. -1.91 V
d. -1.41 V
e. 4.23 V
11 of 21 1/30/2014 11:47 AM
Voltage gives tendency for something to occur and is independent of the

number of electrons (doubling the number of electrons, that is doubling each
half-reaction and adding gives the same voltage). This is not true about
energy or enthalpy. Twice as much material, doubles the energy produced or
the enthalpy change.
Correct
30
Marks: 1
What is the correct procedure for diluting an acid?
Choose a. Add the acid to water.

one b. Add the water to the acid.
answer.
c. It is OK to add the acid to the water or the water to the acid.
Acid is added to water to avoid splattering. More dense acid sinks as it is

diluted and as heat is released. Less dense water stays on top, is less
dispersed, and may end up boiling and causing splattering.
Correct
31
Marks: 1
Under certain conditions, the average rate of appearance of the metal oxide
in the reaction 4M(s) +3O2(g) → 2M2O3((s) is 0.20 mol/s. What is the
average rate for the disappearance of O2? (Hint, for some of you it may be
easier to start by writing the rate of reaction in terms of oxygen and the metal
oxide.)
Choose a. 0.20 mol/s

one b. 0.30 mol/s
answer.
c. 0.13 mol/s
d. 0.4 mol/s
Correct
12 of 21 1/30/2014 11:47 AM
32
Marks: 1
What is a correct description of chemical equilibrium?
Choose a. The frequencies of reactant and of product collisions are

one identical.
answer. b. The concentrations of products and reactants are identical.
c. The velocities of product and reactant molecules are

identical.
d. The rate of reaction of reactant molecules to form product is
the same as the rate of reaction of product molecules to form
reactants.
Correct
33
Marks: 1
A gas-phase reaction, A + B +M → AB + M, proceeds by a rare trimolecular
collision between A, B, and M where M is a second A or B which takes away
excess energy. If the concentrations of both A and B are doubled, the reaction
rate will change by a factor of? (Hint, when A goes from 1 to 2 and B goes
from 1 to 2, what happens to M?)
Choose a. 2
one b. 4
answer.
c. 8
d. 16
M doubles (goes from 2 to 4). Rate increases by 2x2x2.

Correct
34
Marks: 1
The value of an equilibrium constant can be used to predict each of these
except the
Choose a. direction of a reaction.

one b. extent of a reaction.
answer.
c. quantity of reactant(s) remaining at equilibrium.
13 of 21 1/30/2014 11:47 AM
Correct
35
Marks: 1
Consider the reaction: 2KClO3(s) → KClO4(s) + KCl(s) + O2(g)
What is the correct expression for Kc?
Choose a. Kc = [KClO4][KCl][O2]/[KClO3]2
one b. Kc = [KClO4][KCl][O2]/[KClO3]
answer.
c. Kc = [KClO3]2/([KClO4][KCl][O2])
d. Kc = [O2]
Correct
36
Marks: 1
Consider the reaction: 2CO(g)+ O2(g) → 2CO2(g)
What is the correct expression for Kp?
Choose a. Kp = PCO22/(PCO2PO2)
one
b. Kp = PCO2/(PCO2PO2)
answer.
c. Kp = 2PCO22/(2PCO2PO2)
d. Kp = (2PCO2)2/((2PCO)2PO2)
Correct
37
Marks: 1
For the reaction: 2NO2(g) → N2O4(g), ∆H = -57 kJ. Which reaction
characteristics will be affected by a change in temperature?
1. Value of equilibrium constant 2. Equilibrium concentrations
Choose a. 1 only
one b. 2 only
answer.
14 of 21 1/30/2014 11:47 AM
Correct
38
Marks: 1
For the reaction: A +2B +2C → 2D +E, the following table gives the initial rates
of reactions for various concentrations. What is the experimental rate law?
Choose a. rate = k[A]1[B]1[C]0

one
b. rate = k[A]1[B]1[C]1
answer.
c. rate = k[A]1[B]2[C]2
d. rate = k[A]1[B]0.5[C]0
e. rate = k[A]2[B]1[C]0
Correct
39
Marks: 1
Consider this reaction, carried out at constant volume.
SO2(g) + O2(g) → 2SO3(g) ∆H =-198 kJ
The concentration of SO2(g) at equilibrium increases if
Choose a. O2 is added to the system.

one b. the temperature of the system is lowered.
answer.
c. SO3 is added to the system.
d. an inert gas is added to the system.
LeChatelier's Principle (easy). The ACS Guide had many questions of this
type.
15 of 21 1/30/2014 11:47 AM
Correct
40
Marks: 1
The reversible reaction:2H2(g) + CO(g) → CH3OH(g) + heat
is carried out by mixing carbon monoxide and hydrogen gases in a closed

vessel under high pressure with a small amount of a suitable catalyst. After
equilibrium is established at high temperature, all three substances are
present. Which of the following will increase the yield of product?
Choose a. Increasing the temperature

one b. Increasing the amount of catalyst
answer.
c. Increasing the size of the containing without changing the
amount of reactants and products
d. All of the above
e. None of the above
LeChatelier's Principle (medium hard).

Correct
41
Marks: 1
Consider the reaction: AB2 → A + 2B
What is the equilibrium constant expression if the initial concentration of AB2
is 1.0 M, the initial product concentrations are 0, and the equilibrium
concentration of A is represented by x?
Choose a. x(2x)2/(1-x)
one
b. x2x2/(1-x)
answer.
c. x(2x)2/(1-2x)
d. x(2x)/(1-3x)
Correct
42
16 of 21 1/30/2014 11:47 AM
Marks: 1 What is the intermediate, if any, for the following proposed mechanism?
Choose a. NO
one b. N2O2
answer.
c. Cl2
d. There is none.
Correct
43 What is the rate law for the above proposed mechanism? (Remember,
Marks: 1
intermediates are not included in the final rate law.)
Choose a. rate = k[NO]2[Cl2]

one b. rate = k[N2O2][Cl2]
answer.
c. rate = k[NO][Cl2]2
d. rate = k[NO][Cl2]
Correct
44 Which of the following has an effect on the rate constant?

Marks: 1
Choose a. Increasing the pressure of gaseous reactants.
one b. Increasing or decreasing the concentrations of reactants
answer.
c. Increasing the area of a catalytic surface.
d. All of the above
17 of 21 1/30/2014 11:47 AM
The above change the rate, but not the rate constant. The rate constant is
independent of amounts of reactant.
Correct
45
Marks: 1
Two reactions with different activation energies have the same rate at 1000
o
C. Whic statement correctly describes the rates of these two reactions at the
950 oC?
Choose a. The reaction with the larger activation energy will be faster.
one b. The reaction with the smaller activation energy will be faster.
answer.
c. The two reactions will continue to occur at the same rates.
d. A prediction cannot be made without additional information.
The larger the Ea the faster the rate constant increases as T increases.
Conversely, the larger the Ea the faster it decreases as T decreases.
Correct
46 The reaction rate is k[Ce4+][Mn2+] for the following reaction:

Marks: 1
2Ce4+(aq) + Tl+(aq) + Mn2+(aq) → 2Ce3+(aq) + Tl3+(aq) + Mn2+(aq
What is the catalyst?
Choose a. Ce4+
one
b. Ce3+
answer.
c. Mn2+
d. Tl+

Correct
47
18 of 21 1/30/2014 11:47 AM
Marks: 1 What is the overall reaction order for the above reaction?
Choose a. 1
one b. 2
answer.
c. 3
d. 4

Correct
48
Marks: 1
What is activation energy for the following reaction? Is it exothermic or
endothermic?
Choose at a. D-A
least one b. B
answer.
c. C
d. D
e. Exothermic
f. Endothermic
Correct
49
Marks: 1
For the reaction: A + 2B → C if the concentration of A is doubled the rate
increases by a factor of 4. If the concentration of both A and B are doubled,
the rate increases by a factor of 4.
19 of 21 1/30/2014 11:47 AM
Choose a. The reaction is second order with respect to A, and zero

one order with respect to B.
answer. b. The reaction is first order with respect to A, and first order
with respect to B.
c. The reaction is first order with respect to A, and second order
with respect to B.
d. The reaction is second order with respect to A, and second
order with respect to B.

Correct
50
Marks: 1
A plot of the log of the reactant concentration as a function of time gives a
straight line. What is the order of the reaction for this reactant?
Choose a. 0
one b. 1
answer.
c. 2
d. 3
Plotting using log or ln both give a straight line (different slope).

Correct
51
Marks: 1
Which molecule has the greatest entropy?
Choose a. C2H6
one b. C2H5Cl
answer.
c. C2H5I
d. C2H4I2
Correct
20 of 21 1/30/2014 11:47 AM
You are logged in as Daniel Nowak (Logout)
2013F - CHEM126-Petrova
1.307965 secs
RAM: 28.3MB
RAM peak: 28.6MB
Included 86 files
DB queries 701
Log writes 1
ticks: 131 user: 36 sys: 7 cuser: 0 csys: 0
Load average: 5.11
Record cache hit/miss ratio : 0/0
21 of 21 1/30/2014 11:47 AM

Acs

Încărcat de

Informații document

Titlu original

Drepturi de autor

Formate disponibile

Partajați acest document

Partajați sau inserați document

Opțiuni de partajare

Vi se pare util acest document?

Este necorespunzător acest conținut?

Drepturi de autor:

Formate disponibile

Acs

Încărcat de

Drepturi de autor:

Formate disponibile

2013F - CHEM126-Petrova: ACS Chem 125-126 Review II http://njit.mrooms.net/mod/quiz/review.php?

You are logged in as Daniel Nowak (Logout)

NJIT ► 2013F - CHEM126-Petrova ► Quizzes ► ACS Chem 125-126 Review II ► Review of

ACS Chem 125-126 Review II

Started on Wednesday, 11 December 2013, 10:57 PM

1 Antimony reacts with sulfur according to the following reaction:

What is the mass percent yield from 2.30 g of Sb in excess S, if 1.01 g of

Sb2S3 is 340. g/mol

What is ∆Go at 279 oC in kJ?

Did you change to K and use consistent units?

3 What is the oxidation state of Mn in KMnO4?

4 Balance the following half-reaction in base, using smallest whole number

5 Balance the following reaction in acid, using smallest whole number

Ga(s) + MnO4-(aq) → Ga3+(aq) + Mn2+(aq)

(Hint, first balance each half-reaction separately.)

Marks for this submission: 1/1.

4H+(aq) + O2(g) + 4e- → 2H2O(l) Eo = 1.23 V

What is E, if the pressure of oxygen gas is 1.0 atmosphere and the pH is

10 What is Kc for the reaction:2NO2(g) → N2O4(g)?

11 Mg2C2O4(s) → 2Mg2+(aq) +C2O42-(aq) Ksp = 8.6 x 10-5

This problem had an error it was corrected 5/7/2010 at 8:17 pm.

Recall that if Qsp is greater than Ksp, a precipitate forms.

12 Pb(OH)2(s) → Pb2+(aq) + 2OH-(aq) Ksp = 1.4 x 10-20

13 2 L of an unknown concentration of the weak base ammonia are standardized.

I. A copper wire was placed in a solution of AgNO3(aq). The copper dissolved

Rank the activity of these metal.

AgNO3(aq) + NaOH(aq) → AgOH(s) + NaNO3(aq)

Ag+(aq) + OH-(aq) → AgOH(s)

Choose a. ∆G < 0, ∆H > 0, ∆S > 0

Choose a. The reaction is spontaneous at all temperatures.

Choose a. Sugar is dissolved in water.

d. CH3OH(l) +1.5O2(g) → CO2(g) + 2H2O(l)

20 In which process is entropy decreased?

Marks for this submission: 1/1.

Choose a. Low T, ∆S is positive

Choose a. 6.1 oC on a thermometer graduated in degrees

d. 35.6 g on a scale graduated to tenths of a gram

Cu1+(aq) + MnO4-(aq) → Cu2+(aq) + Mn2+(aq)

Choose a. Cu1+ is reduced.

24 Which change requires a reducing agent to produce the indicated product in

Choose a. MnO2(s) → Mn2+(aq)

A reducing agent allows something to be reduced, that is, it provides electrons.

A(s) +O2(g) → D(s) + H+(aq)

Choose a. Increasing the concentration of the acid

(This is easy if you remember LeChatelier's principle.)

c. The substance must be a stronger oxidizing agent than a

Fe3+(aq) + e- → Fe2+(aq) +0.77 V

Which of these ions is the best oxidizing agent?

Cu2+(aq) + 2e- → Cu(s) +0.34 V

A quantity of a powdered mixture of copper and nickel is added to a solution

Choose a. Nickel metal reduces Cu2+ ions to Cu(s).

d. Ni2+ ions oxidize Cu metal to Cu2+ ions.

The reaction giving the largest voltage occurs.

Al3+(aq) + 3e- → Al(s) -1.66 V

Voltage gives tendency for something to occur and is independent of the

Choose a. Add the acid to water.

Acid is added to water to avoid splattering. More dense acid sinks as it is

Choose a. 0.20 mol/s

Choose a. The frequencies of reactant and of product collisions are

c. The velocities of product and reactant molecules are

M doubles (goes from 2 to 4). Rate increases by 2x2x2.

Choose a. direction of a reaction.

What is the correct expression for Kc?