SPHOORTHY ENGINEERING COLLEGE

Nadergul (Vill), Saroornagar(M), R.R.Dist-501 510.

BTL QUESTION BANK-2019
NAME OF THE PROGRAM: I B.Tech. – I Semester
BRANCH: COMPUTER SCIENCE AND ENGINEERING
COURSE NAME: CHEMISTRY COURSE CODE:CH102BS

Unit -3
Q.No Questions Month- year (reg/Supply Marks CO BL PO
1 Summarize eletroless May– 2019 5 L2 PO1,PO2,PO6
C102.3
plating of Nickel
2 Discuss about sacrificial May– 2019 5 L2 PO1,PO2
anodic method to control C102.3
the corrosion.
3 Write a note on Aug– 2019 5 L2 PO2,PO6
Tinning process give C102.3
its applications
4 Describe the factors Jun– 2019 5 C102.3 L1 PO1
affecting rate of
corrosion
5 Illustrate the wet / electro May– 2019 5 L2 PO1,PO2
C102.3
chemical corrosion
6 Write a note on oxidation Jun– 2019 5 C102.3 L1 PO1
corrosion

BL –Bloom’s Taxonomy Levels:

(1-Remembering, 2-Understanding, 3–Applying, 4–Analysing, 5–valuating, 6-Creating)

CO–Course Outcomes PO –Program Outcomes

 20 Fill in the blank questions with answer

1. Corrosion is a process of---------reaction. ( oxidation)

2. Which one of the following causes corrosion of iron ---------------
(moisture and oxygen)
3.The method to prevent corrosion of iron by zinc coating is called
galvanization
4. Rusting of iron is catalyzed by H2O
5. A substance which allows the electric current to pass through it is called------------
Conductor
6. Coating of Tin on Iron metal is called ----------
7. The rate of corrosion increases with -----------in pH
increases
8. During wet corrosion ---------------part undergoes corrosion
anodic
9. During galvanic corrosion the more noble metal acts as ----------
Cathode
10. The process in which metal is protected from corrosion by keeping it in molten zinc is known as
galvanisation
11. When zinc and copper alloy is placed in moisture environment ----------------metal undergoes corrosion
Zn
12. Any metal above hydrogen in electro chemical series can be easily oxidized. Hence they undergo-----------
Corossion
13. One of the common sacrificial anodic metal is
Magnesium
 SPHOORTHY ENGINEERING COLLEGE
Nadergul (Vill), Saroornagar(M), R.R.Dist-501 510.

BTL QUESTION BANK-2019

NAME OF THE PROGRAM: I B.Tech. – I Semester
BRANCH: COMPUTER SCIENCE AND ENGINEERING
COURSE NAME: CHEMISTRY COURSE CODE:CH102BS
Part –A
Each question carries 5 marks (previous questions from last five years)
Q.No Questions Month- year Marks CO BL
PO
(reg/Supply)
Unit -IV
1 2
1 Write a note on SN and SN reaction
December-2018 PO1 &
mechanism with suitable examples. Give 5 3
(Regular)
CH102.4 PO2
their stereochemistry.
2 Explain different confirmations of n-
December-2018 PO1 &
butane with the potential energy 5 2
(Regular)
CH102.4 PO2
diagram.
3 What is isomerism? How its classified? December-2018 PO1 &
(Regular) 5 CH102.4 2 PO2
Explain with suitable examples.
4 Explain Markovnikoff’s rule with
suitable example. Why this rule is failed May-2019 5 2 PO1 &
(Regular)
CH102.4 PO2
during addition of HBr in presence of
peroxides.
5 Write the synthetic methods for Aspirin
May-2019 PO1 &
and Paracetamol. Give their 5 3
(Regular)
CH102.4 PO2
pharmaceutical applications.
6 Discuss the mechanism of reduction of May-2019 PO1 &
(Regular) 5 CH102.4 2 PO2
carbonyl compounds with NaBH4
7 Write the product when HBr added May-2019 PO1 &
(Regular) 5 CH102.4 3 PO2
propene under thermal conditions.
2
8 Explain Why do SN reactions give rise August-2019 PO1 &
(Supply) 5 CH102.4 2 PO2
to inverted product? Explain.
9 Write Grignard addition reactions on August-2019 PO1 &
(Supply) 5 CH102.4 3 PO2
carbonyl compounds.
10 Discuss the mechanism involved in August-2019 PO1 &
(Supply) 5 CH102.4 2 PO2
oxidation of alcohols using KMnO4

BL –Bloom’s Taxonomy Levels (1-Remembering, 2-Understanding, 3–Applying, 4–Analysing, 5–

valuating, 6-Creating)
CO–Course Outcomes PO –Program Outcomes;
2. 20 multiple choice questions with answers

1. Which of the following is an incorrect statement about the nucleophile? (b)

a) They are electron rich
b) They possess an empty orbital to receive the electron pair
c) They attack on electron deficient centers
d) Examples are: OH–, NH3, H2O etc

2. Compounds which have different arrangements of atoms in space while having same atoms bonded to
each other are said to have (d)
a) position isomerism b) functional group isomerism
c) chain isomerism d) stereoisomerism

3. Which of the following can make difference in optical isomers? (c)

a) heat b) temperature c) polarized light d) pressure

4. Which of the following is an alkane which can exhibit optical activity?

a) Neopentane b) Isopentane c) 3–Methylpentane d) 3–Methylhexane

5. Which of the following groups has the highest priority according to the Cahn-Ingold-Prelog sequence
rules? (c)

a) −CH3 b) −CH2Cl c) −CH2OH d) −CHO

6. Which of the following groups has the highest priority according to the Cahn-Ingold-Prelog sequence
rules? (c)

a) −C≡CH b) −CH=CH2 c) −CH(OH)CH3 d) −CH2CH2OH

7. Which of the following conformations of n-butane is the least stable? (c)

a) Gauche b) Anti c) Eclipsed d) Semi eclipsed

8. The functional isomers of ethers are (b)

a) Ketones b) Alcohols c) Esters d) Aldehydes

9. A recemic mixture contains equal ........ of dextrorotatory and laevorotatory isomers. (b)

a) Number of grams b) Number of moles

c) Number of electrons d) None of the above

10. Geometric isomerism will be exhibited by (a)

a) Alkenes b) Alkanes c) Alkynes d) All of the above

11. Which of the following conditions favor the anti Markovnikoff’s product in addition reactions (d)

a) UV radiation b) High temperatures c) Peroxides d) All of the abve

12. Which of the following is cation (b)

a) CH3− b) C2H5+ c) C2H5• d) All
13. Which one of the following is alkane (b)
a) Pentyne b) Butane c) Hexene d) Pentene
14. What is hybridization of carbon in ethane? (c)
a) sp b) sp2 c) sp3 d) sp3d
15. Functional group present in alcohols (c)
a) – NO2 b) –Cl c) –OH d) -COOH
16. Functional group present in carboxylic acids (d)
a) – NO2 b) –Cl c) –OH d) –COOH
17. Which of the following is weak acid? (b)
a) HNO3 b) CH3COOH c) H2SO4 d) HCl

18. The minimum requirement organic compounds to form Cis-trans isomerism only (b)
a) Having only single bonds b) Having at least one double bond
c) Having only triple bond d) Having only double bonds
19. Number double bonds present in 1,3 butadiene (a)
a) 2 b) 3 c) 4 d) 1
20. The hemolytic fission of a hydrocarbon results in the formation of (c)
a) Carbocations b) Carbane anions c) Free radicals d) Carbenes

3. 20 Fill in the blank questions with answer

1. Compounds having same molecular formula but possesses different properties are known
as___________ (Isomers)
2. Isomers which are mirror images but not super imposable are called as___________
(Enantiomers)
3. Isomers which are non-mirror images and not super imposable are called as____________
(Diastereomers)
4. Geometrical isomer in which similar groups are arranged in same side of double bond carbon
is__________________ (Cis)
5. ……………….. Isomerism arises due to the different in nature of carbon chain (Chain)
6. Geometrical isomer in which similar groups are arranged in opposite side of double bond
carbon is__________________ (Trans)
7. Conformational isomer of n-butane with lowest energy is ………………….. (Anti or
staggered)
8. A reaction in which the substrate and the reagent add up to form a product is called
……………………. Reaction. (Addition)
9. …………………………… reaction is the one in which an atom or a group in a molecule is
replaced by atom or group. (Substitution)
10. …………………………… reactions involve of two atoms or groups from the same
molecule resulting in double bond. (Elimination)
11. Equimolar mixure of enantiomers is called as …………………….. (Recemic mixure)
12. The general formula of Grignard reagent is………………………. (R-Mg-X)
13. Thick lines and dot lines are used in ………………………… representation of three
dimensional structures. (Wedge)
14. The nearer carbon and rear carbons can be seen in …………….. representation of molecules.
(Newman projection)
15. The molecules are capable of rotating plane light either towards right or left are called
as……………………. compounds. (Optical active)
16. The compounds which can rotate light towards right are called as ……………….rotatory.
(Dextro)
17. The compounds which can rotate light towards left are called as ……………….rotatory.
(Leavo)
18. The basic compounds required in the preparation of aspirin are ………………………….
(Salicylic acid and Acetic anhydride)
19. The conformational isomers formed when staggered form rotate by 60o is …………………..
(Semi eclipsed)
20. The number of steps involved in SN1 reactions are ……………… (Two)
 Part –A
Each question carries 5 marks (previous questions from last five years)
Q.No Questions Month- year Marks CO
BL PO
(reg/Supply
Unit -5
1 Define and explain Beer-lamberts law give
its limitations CH102.5 L2 PO1
December -2018 5
(regular)
2 Explain about the selection rules for uv-
visible spectroscopy CH102.5 L3 PO1
December -2018 5
(regular)
3 Explain various electronic transitions with
suitable examples
May -2019 (regular) 5 CH102.5 L3 PO1

4 Give an account of various fundamental

vibrations CH102.5 L2 PO1
May -2019 (regular) 5
5 Explain the principle involved in NMR
PO1
spectroscopy CH102.5 L3
May -2019 (regular) 5
6 Give selection rules for IR-spectroscopy
CH102.5 L3 PO1
(Dec-2018) 5
7 Write a note on chemical shift 5
CH102.5 L3 PO1
May 2019 (supply)
8 Discuss about the selection rules for NMR
Spectroscopy CH102.5 L3 PO1
May 2019 (supply) 5
9 Discuss about applications of UV-Visible
spectroscopy CH102.5 L2 PO1
(Dec-2018) 5
10 Write the basic principle involved in IR- 5
spectroscopy CH102.5 L2 PO1
(Dec-2018)

BL –Bloom’s Taxonomy Levels (1-Remembering, 2-Understanding, 3–Applying, 4–Analysing, 5–

valuating, 6-Creating)

CO–Course Outcomes PO –Program Outcomes

 20 Multiple choice questions with answers

1. The different types of energies associated with a molecule are

a) Electronic energy b) Vibrational energy c) Rotational energy d) All the above
2. The region of the electromagnetic spectrum for nuclear magnetic resonance is
a)Microwave b) Radio freaquency c) Infrared(IR) d) UV-rays
3. The energy of a photon is given by
a)h/v b) v/h c) 1/hv d) hv
4. The energy level with lower energy is called
a)Ground state energy level b) Initial state energy level
c) Excited state energy level d) All the above
5. Absorption spectrum results when an electron in an atom undergoes a transition from
a)Higher energy level to a lower one b) lower energy level to a higher one
c) Intermediate levels d) All the above

6. The light source used in UV spectroscopy

a) Halogen lamp b)Helium lamp c) hydrogen lamp d) Na-vapour lamp
7. Electronic transition occurs by absorption of -------- radiation
a) Infra-red b) Microwave c) visible d) UV
8. Presence of functional group in a compound can be established by using
a) Chromatography b) IR-Spectroscopy c) Mass spectroscopy d) X-ray
diffraction

9. Which of the following transitions are of weak intensities and lie in the visible region

a) n→π* b) σ→σ* c) π→π* d) n→σ*

10. Electronic transition possible for CH4 molecule

a) σ→σ* b) σ→n* c) π→π* d) π→σ*

11. Increasing order of wavelength is

a) x-ray, UV, IR, microwave b) microwave, IR, UV, x-ray

c) UV, IR, x-ray, microwave d) microwave, UV, IR, x-ray

12. The correct order of different types of energies is

a)E >> E >> E >> E

el vib rot tr b) E >> E >> E >> E
el rot vib tr
 c) E >> E >> E >> E
el vib tr rot d) E >> E >> E >> E
tr vib rot el

13. Which of the following molecules will not give rotational spectra

a) CO b) HCl c) HBr d) N2

14. In NMR spectroscopy, the radiation used for nuclear excitation

a) Microwave b) IR-waves c) Radio waves d) UV-rays

15. A group of atoms in a molecule responsible for imparting colour to the compound is

called

a) Chromophores b) auxochrome c) chromosome d) perent molecule

16. What is the reference solvent used in NMR spectroscopy

a) KBR b) TMS(tetra methyl silane) c) ether d) ketones

17. Monochromator used in uv-spectroscopy

a) Gratting b) Glass cube c) laser d) glassplate

18. Chromophore is a functional group containing multiple bond capable of absorbing

radiation

a) below 200nm b) at 200nm c) above 200nm d) above 800nm

19. Which of the following is not an IR vibrational mode

a) Stretching b) Scissoring c) Rocking d) Rolling

20. Wavelength of UV radiation is in the range of

a) 1cm-10m b) 400-800nm c) 150-400 nm d) 100-1000nm

2. 20 Fill in the blank questions with answer
21. One micron is equal to ———————— meter ( 10-6 m)

22. What is the full form of TMS———————- (Tetramethylsilane)

23. The analysis of electromagnetic radiation scattered, absorbed or emitted by the molecule

is called ———————————- (Spectroscopy)

24. The radiation source in UV visible spectroscopy _______ (Deuterium lamp or xenon lamp)

25. The fingerprint region in IR-spectra ranges from—————————-(1500-700cm ) -1

26 The value of TMS proton in 𝛿 scale is ——————————-( 0)

27. The radiation source in IR spectroscopy _________________ (Nernst glower lamp)

28. Which spectroscopic study is used to identify the functional groups of the compounds——
————————— (IR-Spectroscopy)

29. Example for chromophore———————— (-C=C-, -C=O, N=O, C-X)

30. Example for Auxochrome ————————- (−NH2, −NHR, −OH, −OR, , SO H etc) 3

31. —————————— Organic compounds shows transition due to conjugation

(Conjugated dienes)

32. The representation of Beer Lambert’s law is given as A = abc. If ‘b’ represents distance,

‘c’ represents concentration and ‘A’ represents absorption, what does ‘a’ represent? ——
————————— (Absorptivity)

33. When there are n-protons adjacent to a given proton, the multiplying of its NMR peak is
given by————————- (n+1)

34. The absorption of IR radiation is accompanied by transition involving———————-

(Vibrational levels)

35. The source of light for UV-region——————————- (Deuterium lamp)

36. Full form of MRI———————————( Magnetic resonance imaging)

37. What is the unit for magnetic field—————————— (Tesla)

38. What is IR value for ketone functional group———————————-(1700 cm -1

39. Which spectroscopy is used to detect carbon-hydrogen framework———————-

(NMR spectroscopy)

40. The instrument which is used to record the spectrum is called——————————-

(Spectrophotometer)