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IEEE ELECTRON DEVICE LETTERS, VOL. 38, NO.

4, APRIL 2017 497

Al2O3/AlGaN Channel Normally-Off MOSFET on


Silicon With High Breakdown Voltage
Joseph J. Freedsman, Takeaki Hamada, Makato Miyoshi, and Takashi Egawa, Member, IEEE

Abstract — A normally-Off metal-oxide-semiconductor field locally underneath the ohmic contacts by using Schot-
field-effect transistor (MOS-FET) is proposed by using tky source/drain [9], or under the gate by fluoride plasma
AlInN/AlGaN heterostructure grown on silicon. The AlGaN treatment [10], as well as by using a thick and C-doped GaN
channel MOSFET with Al2 O3 layer as gate insulator
exhibits a drain current of 90 mA/mm at the gate bias of buffer [11].
+8 V, an ON/OFF drain-current ratio of 1.4 × 108 , a peak Nevertheless, most of the AlInN/GaN devices exhibited
field-effect mobility of 97 cm2 /V·s, and threshold voltage BVOFF values that are par below the existing AlGaN/GaN
of +2.4 V, respectively. With significant reduction in leakage counterparts [12]. This is possibly due to an improved carrier
currents, the MOS-FET with a gate-to-drain spacing of 20 µm properties such as higher 2-DEG density and/or mobility in
delivers a high breakdown of 993 V. The present results
AlInN/GaN devices which might cause a high off-state leakage
of Al2 O3 /AlGaN normally-Off MOSFET signifies promising
prospects for future high power and high voltage applica- current and therefore reduce the BVOFF .
tions. Meanwhile, Nanjo et al., employed AlGaN layer as chan-
Index Terms — AlGaN channel, normally-Off, MOS-FET, nel and showed remarkable enhancements in BVOFF with
buffer leakage, breakdown voltage (BV). increasing Al-mole fraction [13]. Likewise, an AlGaN-channel
MIS-FET with a higher Al-mole fraction of 0.75 delivered
I. I NTRODUCTION a high breakdown field of 200 V/μm [14]. Following works
on AlGaN-channel devices with AlN and AlInN as respective
T HE AlInN/GaN heterostructure based field-effect tran-
sistors (FETs) have recently emerged as excellent can-
didates for high frequency and high power applications.
barriers also indicates considerable improvements in BVOFF
[15], [16]. Recently, we have also demonstrated metalorganic
Its uniquely large built-in spontaneous polarization charges chemical vapor deposition (MOCVD) grown AlInN/AlGaN
provide high two-dimensional electron gas density (2-DEG), heterostructure based FET that exhibited a high 2-DEG as well
which brings superior on-current capabilities than AlGaN/GaN as high breakdown field [17], [18]. In fact, these encouraging
FETs [1]. Excellent direct current (DC) and radio-frequency results on emerging new class of ultra-wide bandgap (UBWG)
performances were demonstrated by using these devices AlGaN-channel devices with higher breakdown field suggest
[2], [3]. A high breakdown of 3 kV was achieved for they are suitable alternate to next-generation power electron-
AlInN/GaN metal-oxide-semiconductor (MOS)-device on SiC ics [19]. In addition, recent theoretical predictions indicate
with AlGaN as back barrier [4]. Normally-Off operation they are also potential candidates for normally-Off operation
was also realized in AlInN/GaN based MOS-FETs [5], [6]. with threshold voltage (VT H > 3 V) [20]. Moreover, all
Despite these improvements, a high off-state drain leak- the prior works on AlGaN-channel based devices are on
age is a persistent issue which often reduces the ON/OFF AlN/sapphire templates. Therefore, it is imperative to demon-
drain-current ratio (ION /IOFF ) and can induce premature strate AlGaN-channel device with such features on a low-cost
breakdown [2]–[7]. silicon substrate.
Kuzmik et al., proposed that the off-state breakdown voltage To make full advantage, we have used MOCVD grown
(BVOFF ) in AlInN/GaN devices is primarily governed by a AlInN/AlGaN/Si heterostructure and propose for the first
highly conductive GaN channel [8]. Subsequently, enhance- time an Al2 O3 /AlGaN channel normally-Off MOS-FET on
ments in BVOFF were suggested by lowering the electric Si. As fabricated Al2 O3 /AlGaN MOS-FET exhibits good DC
characteristics. Due to significant reduction in leakage currents
Manuscript received December 2, 2016; revised January 13, 2017 by using AlInN/AlGaN/SLS/Si heterostructure, the MOS-FET
and January 20, 2017; accepted January 30, 2017. Date of publication
February 1, 2017; date of current version March 22, 2017. This work with a gate-to-drain spacing (L G D ) of 20 μm delivers a
was supported by the Super Cluster Program of the Japan Science and remarkable BVOFF close to 1 kV.
Technology Agency. The review of this letter was arranged by Editor
T. Palacios. II. D EVICE S TRUCTURE AND E XPERIMENTS
J. J. Freedsman and T. Hamada are with the Research Center for
Nano-Devices and Advanced Materials, Nagoya Institute of Technology, The AlInN/AlGaN heterostructure used in this work was
Nagoya 466-8555, Japan (e-mail: freedy54@gmail.com). grown on Si by using Taiyo Nippon Sanso MOCVD
M. Miyoshi and T. Egawa are with the Research Center for Nano-
Devices and Advanced Materials, Nagoya Institute of Technology, SR-4000 system. The heterostructure consists of a
Nagoya, Japan, and also with the Innovation Center for Multi-Business of 100-nm-thick AlN nucleation layer, 3-μm-thick strained-layer-
Nitride Semiconductors, Nagoya Institute of Technology, Nagoya, Japan. super lattice (SLS), 1-μm-thick Al0.05 Ga0.95 N channel, and
Color versions of one or more of the figures in this letter are available
online at http://ieeexplore.ieee.org. 1-nm-thick AlN spacer and 10-nm-thick Al0.85 In0.15 N barrier,
Digital Object Identifier 10.1109/LED.2017.2662710 respectively. Room temperature Hall-effect measurements

0741-3106 © 2017 IEEE. Personal use is permitted, but republication/redistribution requires IEEE permission.
See http://www.ieee.org/publications_standards/publications/rights/index.html for more information.
498 IEEE ELECTRON DEVICE LETTERS, VOL. 38, NO. 4, APRIL 2017

Fig. 1. Schematic cross-section of the Al2 O3 /AlGaN channel


normally-Off MOS-FET on silicon.

yielded a 2-DEG density of 1.3 × 1013 cm−2 with a


mobility of 186 cm2 V−1 s−1 . The fabrication process for
the Al2 O3 /AlGaN channel MOS-FET commenced with the
mesa isolation by using BCl3 plasma based reactive ion
etching (RIE). Source/drain ohmic contacts were defined by
photolithography and then evaporation of Ti/Al/Ni/Au metal Fig. 2. (a) Typical DC output and (b) transfer characteristics of normally-
Off Al2 O3 /AlGaN MOS-FET. (c) IDS − VGS and IGS − VGS characteristics
stack followed by annealing at 800 ° C in N2 ambient. The of the device in semi-log scale. (d) Typical C-V curve measured at
contact and sheet resistances (RC andR S H ) measured from 100 kHz and the extracted field-effect mobility of a ‘FAT-FET’ with
the transmission line model were 1 ·mm and 939 /, 100-µm-long LG .
respectively. The recessed-gate structure was formed by
etching the barrier layer with a BCl3 gas based RIE and
at a low RF power of 5 W for 150 s. After the gate- characteristics [13]–[19]. The MOS-FET exhibited normally-
recess, a 20-nm-thick Al2 O3 layer was deposited at 300 ° C Off operation with a VT H of +2.4 V as extracted from the
by atomic layer deposition (ALD). In the ALD process, linear extrapolation of the transfer curve. The drain and gate
trimethyl-aluminum (TMA) was used as metal precursor currents (I D S , IG S )-VG S characteristics in semi-log scale are
and O3 and H2 O vapor in sequential pulses were used as shown in Fig. 2(c). The MOS-FET showed low subthreshold
oxidants. Post deposition annealing of the oxide was carried leakage current (∼10−10 A), which is at least 2 to 6 orders
at 600 ° C to improve the oxide/semiconductor interface. lower in magnitude compared to conventional AlInN/GaN
The use of a thick device grade Al2 O3 layer is to facilitate devices reported in literature [2]–[8]. The excellent insulating
normally-Off operation enabling a high positive gate swing property of the ALD-Al2 O3 layer was reflected from a low
and to reduce gate leakage, respectively [21]. The device IG S value of 17 nA/mm at a maximal VG S of +8 V. A high
fabrication was completed with the evaporation of gate and ION /IOFF of 1.4 × 108 was also realized for this device.
pad metals Pd/Ti/Au. Fig. 1 shows the schematic cross-section Fig. 2(d) shows the extracted μFE for the Al2 O3 /AlGaN MOS-
of the Al2 O3 /AlGaN normally-Off MOS-FET. The MOS-FET FET at a low drain bias (V D S ) of 0.1 V, by using μFE =
subjected to DC measurements features a gate length (L G ) G M L G /(WG C M O S V D S ). Corresponding C-V curve measured
of 2 μm, gate-to-source distance (L G S ) of 4 μm, and at 100 kHz is also shown. Considering the device geometry,
L G D of 20μm, respectively. The field-effect mobility (μFE ) an extracted peak μFE−peak of 97 cm2 /V·s indicates effective
was extracted by using ‘FAT-FET’ with 100-μm-long L G . modulation of the gate over Al2 O3 /AlGaN MOS-channel
The lateral and vertical buffer strengths were estimated by that can be competitive with some of the high-performance
using mesa-isolated ohmic contacts (10-μm inter-electrode Al2 O3 /GaN channel normally-Off MOS-FETs [22], [23].
spacing) and circular shaped diodes (100-μm in diameter), To gain insight of AlInN/AlGaN heterostructure on
respectively. During breakdown measurements, the devices breakdown characteristics, the vertical and lateral leakage
were immersed in an inert Flourinert (FC-40) solution to measurements were carried out in the first place. As refer-
avoid surface flashover. The criteria for lateral and vertical ence, conventional AlInN/GaN devices were also measured.
breakdowns are respective voltages at currents of 1 mA/mm Fig. 3(a) represents the comparison of vertical leakage cur-
and 1 A/cm2 . rents as a function of critical electric field (E C ). Assisted
by high quality SLS multi-pairs [12], the vertical leakage
III. R ESULTS AND D ISCUSSION currents are in proximity irrespective of the heterostructures
The Al2 O3 /AlGaN MOS-FET exhibited typical DC output and the E C was close to 2.3 MV/cm. The E C of present
and transfer characteristics as shown in Fig. 2(a) and 2(b). vertical diodes are consistent with our reported value for
A drain current maximum (I D S,max ) of 90 mA/mm accom- GaN-on-Si [24]. For the AlGaN-based vertical diode with
panied by a specific-on resistance of 22.5 m·cm2 was only 5 % of Al concentration, the E C is comparable to
observed at a gate bias (VG S ) of +8 V. With respect that of GaN-vertical diodes. Nevertheless, this could be
to AlGaN channel devices, the I D S,max is expected to be improved by growing thicker AlGaN layer with higher Al
low and can be further increased by improving the ohmic concentration [25].
FREEDSMAN et al.: Al2 O3 /AlGaN CHANNEL NORMALLY-OFF MOSFET ON SILICON 499

Fig. 3. (a) Two-terminal vertical, and (b) lateral breakdown char-


acteristics of MOCVD grown AlInN/AlGaN heterostructure on Silicon.
Insets: Illustration of cross-section of device structures and measurement
configuration.
Fig. 4. (a). Three-terminal BVOFF characteristics of the Al2 O3 /AlGaN
channel MOS-FET with an LGD of 20 mm. The dotted line represents
The lateral breakdown characteristics are shown in Fig. 3(b). the BVOFF of a typical AlInN/GaN device with similar dimensions. (b) EC
versus Al content in AlGaN channel from recent reports compared with
For AlInN/GaN structure, the lateral leakage increases expo- this work, (LGD was taken into account for EC ).
nentially with increase in V D S > 90 V and an E C
of 0.4 MV/cm was observed. Interestingly, unlike the vertical of 740 V. This device with an L G D of 20 μm delivered a high
breakdown characteristics, the influence of the AlGaN channel BVOFF of 993 V. For the conventional GaN-channel MOS-FET,
can be seen. The onset of exponential increase in leakage is the BVOFF was limited to 62 V as shown in Fig. 4(a). This
delayed to a V D S of 300 V. The corresponding E C for this is due to the high drain leakage caused by a higher 2-DEG
structure was enhanced by 140 % (E C = 1 MV/cm). The density (∼3 x 1013 cm−2 ). Fig. 4 (b) summarizes the EC as a
observed leakage between inter-electrodes is due to carrier function of Al composition in recent reports on AlGaN channel
injection from source-to-drain via respective channels. Further, devices in context to this work. It is worthy to mention, that
these results validates that the lateral transport mechanism the EC of our Al2 O3 /AlGaN normally-Off MOS-FET on Si is
is predominant for both the device and the parasitic leakage compatible with that of AlGaN channel normally-On devices
current was considerably suppressed due to a high resistive on AlN/sapphire templates [13], [14], [16], [18].
AlGaN channel. A similar source-injection induced buffer
leakage (SIBL) mechanism has been reported in AlGaN/GaN IV. C ONCLUSION
devices [26]. In brief, we have experimentally demonstrated Al2 O3 /
The three-terminal BVOFF characteristics of the MOS-FETs AlGaN channel normally-Off MOS-FET by using MOCVD
are shown in Fig. 4 (a). Our BVOFF is defined as V D S at grown AlInN/AlGaN heterostructure on Si. The MOS-FET
which a leakage current of 1 mA/mm was observed and shows prominent features of an I D S,max of 90 mA/mm,
the device subjected to measurement undergoes a permanent ION /IOFF of 108, and a VT H of +2.4 V, respectively. Owing
breakdown. With a high quality ALD-Al2 O3 as gate insulator to significant reduction in off-state leakage currents, this
the IG was 11 μA/mm until breakdown, and the I D was device with an L G D of 20 delivers a high BVOFF of 993 V.
found to be dominant and triggers the breakdown mecha- These results suggests that AlInN/AlGaN/Si devices are
nism as aforementioned. Although, the present Al2 O3 /AlGaN potential candidates for future high power and high voltage
MOS-FET could endure I D S as low as 5 μA/mm at high V D S applications.
500 IEEE ELECTRON DEVICE LETTERS, VOL. 38, NO. 4, APRIL 2017

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