National Standard Examination in Chemistry 27 11 2016 PDF

CHEMISTRY NSEC 2016-2017 EXAMINATION CAREER POINT
ASSOCIATION OF CHEMISTRY TEACHERS

NATIONAL STANDARD EXAMINATION IN CHEMISTRY 2016-2017
Date of Examination 27th November 2016
[Ques. Paper Code : C323]
1. The kinetic energy of an electron that has a wavelength of 10 nm is
(a) 2.4 × 10–21 J (b) 4.8 × 10–21 J (c) 2.4 × 10–29 J (d) 4.8 × 10–29 J
Ans. [a]
Sol. According to debroglie
h

mv
h

m
1
Kinetic energy = mv 2
2
1 h2
 m 2 2
2 m 
1 h2

2 m2
1 (6.626  10 34 ) 2
 
2 9.1  10  27  (10) 2
= 2.4 × 10–21 Joules
2. Which of the following compounds contain 3-centered 2-electron bonding ?

(i) [BeF2]n (ii) [Be(CH3)3]n (iii) [BeCl2]n (iv) [BeH2]n
(a) (i) and (ii) (b) (ii) and (iii) (c) (ii) and (iv) (d) (iii) and (iv)
Ans. [c]
Sol. (i) [BeF2]n (ii) [Be(CH3)3]n (iii) [BeCl2]n (iv) [BeH2]n
F:
F:
F
(i) [F – Be – F]n  Be Be Be (3c–4e–)
F
:F :F
CH3 CH3
[Be(CH3)2]n  Be Be Be (3c – 2e–)
CH3 CH3
CAREER POINT, CP Tower, Road No.1, IPIA, Kota (Raj.) Ph.: 0744-5151200
1 / 35
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Cl
Cl
Cl
Be Be
[BeCl2]n Cl
Be (3c–4e–)
Cl Cl
H
Be Be (3c–2e–)
H
[BeH2]n 
Banana bonding
3. 3-Methypentane on monochlorination gives four possible products. The reaction follows free radical
mechanism. The relative reactivities for replacement of –H are 3°:2°:1° = 6:4:1.
Cl
Cl2
light A + B
3-Methyl pentane
Cl Cl
C +
Cl D
Relative amounts of A, B, C and D formed are

(a) 6/31, 16/31, 6/31, 3/31 (b) 16/31, 6/31, 6/31, 3/31
(c) 6/31, 16/31, 3/31, 6/31 (d) 6/31, 3/31, 6/31, 16/31
Ans. [c]
Sol.
C
(1) C–C–C–C–C
Cl
C
(2) C–C–C–C–C
Cl2 Cl
C
3-Methyl pentane
1°H = 9 (3) C–C–C–C–C
2°H = 4
3°H = 1 Cl
(4) C–C–C–C–C
C–Cl
1  x 9 1 9
 
2  y 4  4 16
2  y 4  4 16
 
3  z 1 6 6
9 16 6
% of x =  100 % of y =  100 % of z =  100
9  16  6 31 31
2 / 35
Relative amounts
6 16 3 6
of A,B,C,D are  , , ,
31 31 31 31
(A) (B) (C) (D) 
4. White phosphorous on reaction with NaOH gives PH3 and

(a) Na2HPO3 (b) NaH2PO2 (c) NaH2PO3 (d) Na3PO4
Ans. [b]
Sol. P4 + NaOH  NaH2PO2 + PH3
Phosphene
5. Given the E0 values for the half reactions :

Sn4+ + 2 e–  Sn2+, 0.15 V
2Hg2+ + 2 e–  Hg 22 , 0.92 V
PbO2 + 4 H+ + 2 e–  Pb2+ + 2 H2O, 1.45 V
Which of the following statements is true ?
(a) Sn2+ is a stronger oxidizing agent than Pb4+ (b) Sn2+ is a stronger reducing agent than Hg 22
(c) Hg2+ is a stronger oxidizing agent than Pb4+ (d) Pb2+ is a stronger reducing agent than Sn2+
Ans. [b]
Sol. Lower the value of Reduction Potential Higher will be it oxidizing nature i.e. strong Reducing Agent.
6 For the conversion CCl4() CCl4(g) at 1 bar and 350 K, the correct set of thermodynamic parameters is
(Boiling point of CCl4 is 77 °C)
(a) G = 0, S = +ve (b) G = 0, S = – ve (c) G = – ve, S = 0 (d) G = – ve, S = +ve
Ans. [a]
Sol. CCl4)()  CCl4(g)
P = 1 bar ; T = 350 K; Boiling point of CCl4 = 77ºC = 350 K
G = 0
G = H – TS
0 = H – TS
TS = H
H
S =
T
= +ve
7. How many isomers are possible for complex [Co(ox)2Cl2]+ ?

(a) 1 (b) 3 (c) 2 (d) 4
Ans. [b]
Sol.
3 / 35
O
C
O C O
+ Cl O
[Co(ox)2Cl2]  (Cis) Optically Active (2)
Co
Cl O C O
[M(AA)2a2]n±type O
C
component
O
Cl
O O
O C C O
Co
O C (Trans) Optically Inactive (1)
O O C O
O (3)
8. The compound that will not react with silver perchlorate under normal conditions is
(a) 3-bromocyclopropene (b) tetraethyl ammonium chloride
(c) tetramethylammonium hydroxide (d) polyvinyl chloride
Ans. [d]
AgClO4
(a) Br  + AgCl
Sol.
+ – AgClO4 +
(b) [(Et)4N] Cl [(Et)4N] + AgCl
+ – AgClO4 +
(c) [(Me)4N] OH [(Me)4N]ClO4 + AgOH (Acid base reaction)
(d) CH2=CH–Cl [CH2–CH]n
Cl
AgClO4
No reaction
9. The conductivity of 0.10 M KCl solution at 298 K is 1.29 × 10–2 S cm–1. The resistance of this solution is
found to be 28.44 . Using the same cell, the resistance of 0.10 M NH4Cl solution is found to be 28.50 .
The molar conductivity of NH4Cl solution is S cm2 mol–1 is
(a) 0.130 (b) 13 (c) 130 (d) 1300
Ans. [c]

Sol. K= G
a
1 
1.29 × 10–2 = 
2.8.44 a

0.367 =
a
Cell constant = 0.367
k
m = × 1000
c
4 / 35
1
0.367
 .50
28 × 1000
0.10
m = 130 Scm2 mol–1
10. Consider a compound CsXY2 where X and Y are halogens. Which of the following statement/s is/are correct ?
(i) X and Y have different oxidation states.
(ii) For Y with lower atomic number than X, X can assume oxidation states higher than normal.
(iii) Such compounds exist because Cs+ has a high charge to size ratio.
(a) Only (i) (b) (i) and (ii) (c) Only (ii) (d) (i) and (iii)
Ans. [b]
Sol. Cs XY2 where X and Y are halogens
O.S of Cs is + 1
Cs+ (XY2)–
O.S of X is + 1
O.S of Y is –1
XY2 = –1
x + (–1)2 = –1
x = + 2 –1
=+1
11. Match the compounds given in list I with their characteristic reactions in list II
List I (Compound) List II (Reaction)
1 Tertbutyl amine a Liberation of ammonia on heating with aq NaOH
2 2-methyl-2-pentanol b Effervescence with NaHCO3
3 2,4,6-trinitrophenol c Foul smell with chloroform in alkaline condition
4 Cyclohexane carboxamide d Formation of an water insoluble compounds on treatment with conc. HCl and ZnCl2
(a) 1-a, 2-c, 3-d, 4-b (b) 1-c, 2-d, 3-b, 4-a (c) 1-a, 2-b, 3-c, 4-d (d) 1-d, 2-a, 3-b, 4-c
Ans. [b]
Sol. (1) Tert. butyl amine  (c)
C C
CHCl3
C–C–NH2 C–C–N==C

C OH C
foul smell with
chloro form & base
C
Conc. HCl Write turbidity
(2) H3C–C–CH2–CH2–CH3 (d) produce with in
ZnCl2
seconds (lucas test)
OH
(3
)
5 / 35
OH
O2N NO2
NaHCO3
(b) gives effervescence
of CO2 gases

NO2 O Na
Picric acid O2N NO2
+ H2O + CO2
NO2
aq. NaOH (a)
C–NH2 C–OH + NH3
(4) Ammonia
O O
gas
Cyclohexane Carboxamide
12. Which of the following statements is not correct regarding the galvanic cells ?
(a) Oxidation occurs at the anode.
(b) Ions carry current inside the cell
(c) Electrons flow in the external circuit from cathode to anode
(d) When the cell potential is positive, the cell reaction is spontaneous
Ans. [c]
Sol. Electrons flow in the external circuit from anode to cathode
Anode to cathode
G
ne
Mn+
Anode Cathode
oxidation Reduction
half cell half cell
13. L-Fucose with the following planar representation is a sugar component of the determinants of the A, B, O
blood group typing
H
5 O
H OH
CH3
4 1
H OH
HO H
3 2
OH H
The open chain structure of L-Fucose can be represented as
6 / 35
CHO CHO CHO CHO

HO H H OH HO H H OH
H OH HO H H OH H OH
(a) H OH (b) HO H (c) H OH (d) H OH
H OH HO H HO H HO H
CH3 CH3 CH3 CH3
Ans. [c]
Sol.
H
5 O CHO
H OH HO H
CH3
4 1 H OH
H OH H OH
HO H
3 2 HO H
OH H CH3
L-Fucose L-Fucose
14. In ammonia the bond angle is 107º 48º while in SbH3 the bond angle is about 91º 18'. The correct explanation
among the followings is /are
(a) The orbitals of Sb used for the formation of Sb-H bond are almost pure p-orbitals.
(b) Sb has larger size compared to N.
(c) Sb has more metallic character than N.
(d) All the statements are correct.
Ans. [a]
Sol. Given  Bond angle of ammonia is 105°, 48' while SbH3 is 91°, 18'
According to DRAGO's Rule down the group after 3rd period bond angle almost equal approx 90° surround.
We know that bond angle decrease.
Then % of p-character increases 
s
cos  = cos 90° = 0
s–I
Then % of s = 0
Then meaning   = 91°, 18'
per % of s
almost negligible
Hence % of p is pure
15. Equal masses of ethane and hydrogen gas are present in a container at 25ºC. The fraction of the total pressure
exerted by ethane gas is
(a) 11.2 dm3 (b) 5.6 dm3 (c) 4.48 dm3 (d) 22.4 dm3
Ans. [b]
W W
Sol. Number of moles of C2H6 & H2 are and respectively
30 2
7 / 35
W
30 1
Mole fraction of C2H6( X C 2 H 6 ) = =
W W 16

30 2
If total pressure in container is P then
P
Fraction of the total pressure exerted by C2H6 =
16
16. The volume of nitrogen evolved on complete reaction of 9 g of ethylamine with a mixture of NaNO2 and
HCl at 2.73ºC and 1 atm pressure is
(a) 11.2 dm3 (b) 5.6 dm3 (c) 4.48 dm3 (d) 22.4 dm3
Ans. [Bonus ]
Sol. CH3 –CH2 –NH2 NaNO
 2  CH3–CH2OH + N2
HCl
9 9 9
mole
45 45 45
mole mole
nRT 0.2  .0821  546
v= = = 8.96L
p 1
Ans. is wrong
correct ans is 8.96L, Not given in option
If temperature consider as 273K. Then volume liberated is 4.48 dm3
17. The electrons identified by quantum numbers n and l, (i) n = 4, l = 1, (ii) n = 4, l = 0, (iii) n = 3, l = 2, (iv) n =
3, l = 1 can be placed in order of increasing energy from lowest to highest as
(a) (iv) < (ii) < (iii) < (i) (b) (ii) < (iv) < (i) < (iii)
(c) (i) < (iii) < (ii) < (vi) (d) (iii) < (i) < (iv) < (ii)
Ans. [a]
Sol. value of (n + )
(i) n = 4,  = 1  4p 5
(ii) n = 4,  = 0  4s 4
(iii) n = 3,  = 2  3d 5
(iv) n = 3,  = 1  3p 4
According to (n + ) rule lowest value of (n + ) is in 4s & 3p but 3p has lower value of 'n' so it has lowest
energy so (i) > (iii) > (ii) > (iv)
18. Spodoptol, a sex attractant, produced by a female fall armyworm moth, can be prepared as follows.
The structure of Spodoptol is (pka : terminal alkynes ~ 25, alcohols ~ 17)
i. NaNH2 (excess)
ii. n–C4H9Br (1 eq)
iii. H2/Lindlar cat
HO CH2 (CH2)7 C CH Spodoptol
8 / 35
(a) n – C4H9 – O – CH2 – (CH2)7  HC CH2
H H
(b)
HO–CH2–(CH2)7 n–C4H9
H n–C4H9
(c)
HO–CH2–(CH2)7 H
(d) HO – CH2 – (CH2)12 – CH3
Ans. [b]
Sol.
NaNH2(excess)
HO–CH2–(CH2—
)7 CCH
   
aNO – CH2–(CH2—
)7 CC Na
–Br CH3–CH2 –CH2–CH2

| (1eq)
Br
 
NaO–CH2–(CH2—
)7 CC–CH2–CH2–CH2–CH3
H2 Lindlar catalyst
 
NaO–CH2–(CH2)7 nC4H9
C=C
H H
Or H
HO–CH2 –(CH2)7 nC4H9

C=C
H H
19. Passing H2S gas into a mixture of Mn2+, Ni2+, Cu2+ and Hg2+ in an acidified aqueous solution precipitates
(a) CuS and HgS (b) MnS and CuS (c) MnS and NiS (d) NiS and HgS
Ans. [a]
Sol.
9 / 35
Mn2+ or Ni2+ or Cu2+ or Hg2+

H2S gas eu dks tkuk ugha
OH–
MnS MnS CuS NiS
Basic medium
Puff Blue white Blue
But H2S in acidic aq solution  Pb+2 Cu2+ Cd2+ Bi+3 Hg+2 Cd+2  Hence ans. is CuS and HgS
20. Battery acid (H2SO4) has density 1.285 g cm–3. 10.0 cm3 of this acid is diluted to 1 L. 25.0 cm3 of this diluted
solution requires 25.0 cm3 of 0.1 N sodium hydroxide solution for neutralization. The percentage of sulphuric
acid by mass in the battery acid is
(a) 98 (b) 38 (c) 19 (d) 49
Ans. [b]
Sol. density = 1.285
mass mass
d= = = 1.285
vol 10
w = 12.85 gm
H2SO4 + 2NaOH  Na2SO4 + 2H2O
25mL 25mL
0.1 N
Number of milli equivalents = Number of milli equivalents of NaOH
of H2SO4
= 25 × 0.1
milliequivalents = 2.5
millimoles × 2 = 2.5
2 .5
millimoles of H2SO4 =
2
= 1.25
WH 2SO 4 = 1.25 × 10–3 × 10–3 × 98 × 40
= 4.9g
4 .9
% H2SO4 = × 100
12.85
= 38.13 %
21. The compound that reacts fastest with methylamine is

CH2Br Br Br
Br
(a) (b) (c) (d)
Br
Br Br
Ans. [b]
Sol. React faster with methyl amine
Br NHCH3
| |

NH2 – CH3
SN1
| |
Br NHCH3
10 / 35
22. HgO is prepared by two different methods : one shows yellow colour while the other shows red colour. The
difference in colour is due to difference in
(a) electronic d–d transitions (b) particle size
(c) Frenkel defect (d) Schottkey defect
Ans. [b]
Sol.
23. The pH of a 1.0 × 10–3 mol L–1 solution of a weak acid HA is 3.60. The dissociation constant of the acid is
(a) 8.4 × 10–8 (b) 8.4 × 10–6 (c) 8.4 × 10–5 (d) 8.4 × 10–2
Ans. [c]
Sol. HA H+ + A–
t=0 C 0 0
teq C–C C C
pH = 3.60
10 3
[H+] =
4
[H+] = C
10 3
  1  10 3  
4
= 0.25
C 2
Ka =
1 
1  10 3  (0.25) 2

1  0.25
= 8.4 × 10–5
24. The best sequence of reactions for preparation of the following compound from benzene is
(H3C)2HC COCH3
HO3S
(a) (i) CH3COCl/AlCl3 (ii) Oleum (iii) (CH3)2CH-Cl (1 mole)/AlCl3
(b) (i) (CH3)2CH-Cl (1 mole)/AlCl3 (ii) CH3COCl/AlCl3 (iii) Oleum
(c) (i) Oleum (ii) CH3COCl/AlCl3 (iii) (CH3)2CH-Cl (1 mole)/AlCl3
(d) (i) (CH3)2CH-Cl (1 mole)/AlCl3 (ii) Oleum (iii) CH3COCl/AlCl3
Ans. [b]
Sol.
11 / 35
(1)(CH3)2CH–Cl/AlCl3
COCH3
(2) CH3–C–Cl/AlCl3
O
(3) Oleum
SO3H
1Mole (CH3)2CH–Cl/AlCl3
H2S2O7/
O
(Oleum)
CH3 – C – Cl
AlCl3
C – CH3
25. Which reaction is spontaneous at all temperatures at standard pressure and concentration?
(a) exothermic reaction with a decrease in entropy.
(b) exothermic reaction with an increase in entropy
(c) endothermic reaction with a decrease in entropy
(d) endothermic reaction with an increase in entropy
Ans. [b]
Sol. G = H – TS
Reaction is spontaneous at all temperature when
G < 0
G is always negative at
H < 0  Exothermic Reaction
S > 0  Increase in Entropy
26. The IUPAC name of the following compound is
CONH2
(a) 3-Aminocarbonylpent-1-en-4-yne
(b) 2-Ethenylbut-3-yn-1-amide
(c) 2-Ethynylbut-3-en-1-amide
(d) 3-Aminocarbonylpent-4-en-1-yne
Ans. [c]
Sol.
12 / 35
3 4
CH = CH2
2 1
H – C C – CH – C – NH2
O
2- Ethynyl but – 3 – en- 1 - amide
27. NaOH solution is added dropwise to HCl solution and the conductance of the mixture is measured after
addition of each drop. The variation of conductance with volume of NaOH added is as shown below.
The statement that is not true for the above is
Conductance
Z
Y
Volume of base added
(a) decrease in conductance from XY is due to decrease in [H+].
(b) point Y represents the equivalence point of titration.
(c) Na+ has the higher equivalence conductance than H3O+.
(d) segment YZ represents the conductance due to ions from NaCl and NaOH in solution.
Ans. [c]
Sol.
28. A colorless water-soluble compound on strong heating liberates a brown colored gas and leaves a yellow
residue that turns white on cooling. An aqueous solution of the original solid gives a white precipitate with
(NH4)2S. The original solid is
(a) Zn(NO3)2 (b) Ca(NO3)2 (c) Al(NO3)3 (d) NaNO3
Ans. [a]
Sol. NaNO3 NaNO2 + O2
Ca(NO3)2 NO2+ CaO + O2 (NH4)2S
ZnS
Zn(NO3)2 ZnO + 2NO2O2 White ppt

Al(NO3)2  Al2O3 + O2
29. The following compounds are heated (i) KNO3, (ii) Cu(NO3)2, (iii) Pb(NO3)2, (iv) NH4NO3
Which of the following statement/s is/are correct ?
(a) (ii) and (iii) liberate NO2 (b) (iv) liberates N2O
(c) (i), (ii) and (iii) liberate O2 (d) All statements are correct.
Ans. [d]

Sol. KNO3  KNO2 + O2

Cu(NO3)2  NO2+ CuO + O2
Pb(NO3)2 PbO + NO2 + O2
NH4NO3 N2O + H2O
13 / 35
30. The diastereoisomer (stereoisomer that is not a mirror image) of 'X' is

COOCH3
HO H
H OH
COOH
'X'
COOH
HO H OH
HO H H
(a) (b)
HO H
COOH
COOCH3
COOCH3
HO H
H
OH
COOCH3
(c) (d) HOOC H
COOCH3
HOOC
HO H OH
Ans. [c]
Sol.
COOCH3
OH H
H OH
COOH
(X)
COOCH3 COOCH3
HO H HO H
(A)
HO COOH H OH
H COOH
( Identical )
14 / 35
COOCH3
H OH
(B) ( Enantiomer)
HO H
H
OH COOCH3
H3COOC H H OH
(C)
H OH H OH
COOH COOH
( Diastereomer )
COOH H HO H COOCH3 COOCH3
HO H HO H
(D)
HO H H OH
OH COOCH3
H COOH
( Identical )
31. Given rHº = –54.08 kJ mol–1 and rSº = 10.0 J mol–1 at 25ºC, the value of log10K for the reaction A B is
(a) 3.4 (b) 10 (c) 0.53 (d) 113
Ans. [b]
Sol. G0 = H0 – TS0 = –2.303 RT log10 k
32. Which of the complexes has the magnetic moment of 3.87 B.M.?
(a) [Co(NH3)6]3+
(b) [CoF6]3–
(c) [CoCl4]2–
(d) [Co(dmg)2] square planar complex (dmg = dimethyl glyoxime)
Ans. [c]
Sol. (a) [Co(NH3)6]3+ (b) [CoF6]3–
(c) [CoCl4]2– (d) [Co(fmg)2] square planer cample
3+
(a) [Co(NH3)6]
x + 0 × 6 = +3
x = +3
15 / 35
Co 4s2 3d7
27
C63 4s0 3d6

3d6 4s2 4p
G.S.       = 0
NH3 is strong field ligand
NH3 NH3 NH3 NH3 NH3 NH3
Hybridization is d2sp3
Eos    Dia magnetic
Similar  In[Co F6]3–  paramagnetic (4)
 
Co+3 WFL n = 4  = 24
and  In[CoCl4]2– Co+  4sº3d7
Cl– in WFL
3d 3d 3d
G.S.
3d 3d 3d
× × × ×
E.S. × × × ×  = 15
– – – –
n=3 Cl Cl Cl Cl = 3.87 BM  paramagnetic
3
sp
(d) [Co(dmg)2]
x + (–1) ×2 = 0
n = +2 dmg in SFL
27Co  4s 3d
2 7
Co+2  4s05d7

 pairing 

dsp2
n=1
= 3 = 1.732 BM
33. For a gaseous reaction, A + B  Products, the energy of activation was found to be 2.27 kJ mol–1 at 273 K.
The ratio of the rate constant (k) to the frequency factor (A) at 273 K is
(a) 0.368 (b) 3.68 (c) 4.34 (d) 0.434
Ans. [a]
Sol. K = Ae–Ea/RT
K
 e  Ea / RT
A
2270
K
 e 8.314273
A
16 / 35
K
 e 1
A
K 1

A e
K 1

A 2.718
K
 0.3679
A
34. In the case of dibromo derivatives of the following compound, the derivative having highest energy has the
bromo substituents in positions
2
3 1
10
4
9
5 8
6 7
(a) 1,2 (b) 2,3 (c) 4,5 (d) 1,10
Ans. [d]
Sol.
2
3 1 For electrophillic attack (Br+)
4 10
9
5 8
6 7
35. The ionization energy of a certain element is 412 kJ mol–1. When the atoms of this element are in the first
excited state, however, the ionization energy is only 126 kJ mol–1. The region of the electromagnetic
spectrum in which the wavelength of light emitted in a transition from the first excited state to the ground
state is
(a) Visible (b) UV (c) IR (d) X-ray
Ans. [a]
Sol.
n=
126 kJ/ mole
n = 2 (1st excited level-1)
412 kJ/mole 286 kJ/ mole

n = 1(ground stale)
when electron jump from 1st excited state to ground state then 286 KJ/mole energy is released which is
released with visible range So ans is A
17 / 35
hc
E =

l = 4.15 × 10–7 m visible range.
36. The reaction of an olefin with HBr can proceed by ionic as well as radical mechanism. The reaction in the
presence of light takes place by radical mechanism, as
(a) the free energy of the reaction in radical mechanism is higher than in ionic mechanism
(b) ionic mechanism requires a catalyst while radical mechanism does not.
(c) in the presence of light the activation energy of the reaction is lower than that for ionic mechanism.
(d) a radical reaction has very low activation energy as compared to that for the corresponding ionic reaction.
Ans. [c]
Sol. A
37. The correct statement/s is/are

I. Soap is excellent for cleaning, 100 % broken down by bacteria in rivers and hence has no further
environmental damaging repercussions.
II. Soap forms an insoluble precipitate/scum when hard water containing calcium and magnesium ion is
used.
III. Soaps can be used for cleansing under acidic solutions.
(a) Only I (b) Only II (c) only III (d) I and III
Ans. [b]
Sol.
38. The kinetic data recorded at 278 K for the reaction

NH 4 (aq) + NO 2– (aq)  N2(g) + 2H2O (l) is
Set No. [ NH 4 ] /M [ NO 2– ] /M Rate of reaction/Ms–1
1
(a) 0.24 (b)0.10 7.2 × 10–6 (c) (d)
–6
2 0.12 0.10 3.6 × 10
3 0.12 0.15 5.4 × 10–6
The kinetic rate expression and the unit of rate constant (k) of the above reaction are respectively
(a) k [ NH 4 ] [ NO 2– ] and Ms–1 (b) k [ NH 4 ] and s–1
(c) k [ NH 4 ] [ NO 2– ] and M–1s–1 (d) k [ NO 2– ] and s–1

Ans. [c]
Sol. K [0.24]x [0.10]y = 7.2 × 10–6 –––––––(1)
K [0.12] x [0.10]y = 3.6 × 10–6 –––––––(2)
K [0.12] x [0.15]y = 5.4 × 10–6 –––––––(3)
Dividing 1 by 2
2x = 2
x=1
Dividing 3 by 2
(0.15) y 5.4  10 6
=
0.10 y
3.6  10 6
18 / 35

3
  = 3/2
2
So order of reaction is 2
unit (M sec–1) 1–2
= M–1 sec–1
39. Which of the following statements is not true for Ce 3 and Yb 3 ?

(a) Both absorb in UV region (b) Both show f–f transition
(c) Both show 4f to 5d transition (d) Both ions are colorless
Ans. [b]
Sol.
cerium-ion Ytterbium-ion
3+ 3+
Ce and Yb
Lanthanide-Series
La Ce Pr Nd Pm 
 57 58
Ac Th 
89 90
Statement (a) Correct and also (d) adsorb light in the near infrared region -
58Ce 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6
Similar  Yb3+ 6s2 4f2 5d0 / 6s2 4f1 5d1  similar for Yb+3 both show 4f to 5d transition but not
show f-f-transition. 
40. Complete catalytic hydrogenation of naphthalene gives decalin (C10H18). The number of isomer of decalin
formed and the total number of isomers of decalin possible are respectively
(a) 1,2 (b) 2,2 (c) 2,4 (d) 3,4
Ans. [b]
Sol.
H
H2/Pt
H Cis decalin
H
H2/Pt
H trans decalin
19 / 35
41. The mass of argon adsorbed per unit mass of carbon surface is plotted against pressure. Which of the
following plots is correct if x and m represent the masses of argon and carbon respectively ? (----- represents
extrapolated data)
x/m x/m
(a) (b)
P P
x/m x/m
(c) (d)
P P
Ans. [d]
Sol. Fact
42. In a process n-propyl chloride is reacted with sodium butanoate in an aqueous medium. After the reaction
diethyl ether is added and the solution is shaken. The two layer are separated. The incorrect statement with
respect to this procedure is
(a) The reaction gives a solid product which precipitates in the aqueous solutions.
(b) The reaction takes place in the aqueous medium.
(c) The product is extracted in diethyl ether and the organic layer is the upper layer.
(d) The salt formed in the reaction remains in aqueous medium.
Ans. [a]
Sol.
 
CH3 – CH2 – CH2–Cl + Na O – C – CH2 – CH2 – CH3
n– propyl chloride O Sod. Butanoate
NaCl + CH3 – CH2 – CH2 – O – C– CH2 – CH2 – CH3
O
Soluble in Aq . n – propyl Butanoate [Ester]
medium
organic comp present in upper
layer. Salt formed in reaction
remain in aq. medium
43. Which of the following statements about ammonium cerium (IV) nitrate, (NH4)2[Ce(NO3)6] is false ?
(a) NO 3– acts as a monodentate ligand
(b) The Ce atom has a coordination number of 12
20 / 35
(c) The shape of the complex ion is icosahedron.

(d) The solution is used as oxidizing agent.
Ans. [a]
Sol. (NH4)2 [Ce(NO3)6] Ammonium Cerium nitrate  2NH4+ + [Ce(NO3)6]–2
+1 × 2 + x + (–1) 6 = 0 
x = + 6 – 2 = +4
O
N
O N
O O O
O O N O
O Ce O
N
O O O
O N O
 NO3 acts as bidentate ligand
The cehas co-ordination number is 12.

This is oxidizing agent inorganic synthesis
And shape is icosheedral
44. The correct order of the magnitude of bound energy (kJ/mol) of the central C-C bond in the following
compounds is
(i) CH2=CH–CH=CH2 (j) Me3C–CPh3 (k) MeCO–CO–Me (l) CH ≡C–C≡CH
(a) k > i > l > j (b) j > k > l > i (c) i > j > k > 1 (d) 1 > i > k > j
Ans. [d]
Sol. Bond Energy order for C – C central Bond
CH C – C CH > CH2 = CH – CH = CH2 > Me – C – C – Me > Me3C – CMe3
|| ||
O O
l>i>k>j
45. Which one of the following information about the compounds is correct ?
Compounds Oxidation No. of P–OH No. of P–H No. of P = O

state of P bonds bonds bonds
[I] H3PO2 1+ 2 1 0
Hypophosphorous acid
[II] H4P2O5 3+ 2 2 2
Pyropophosphorous acid
[III] H4P2O6 4+ 2 2 2
Hypophosphoric acid
[IV] H4P2O` 5+ 3 1 4
pyrophosphoric acid
21 / 35
(a) I (b) III (c) IV (d) II

Ans. [d]
Sol.
No. of P-OH No. of P-H No. of P = O bent
H
+1
H3PO2 H–P–O–H 1 2 1
O
H H
+3
H4P2O5 H–O–P–O–P–O–H 2 2 2
O O
O–H O–H
+4
H4P2O6 H–O–P – P–O–H 4 0 2
O O
O–H O–H
+5
H4P2O7 H–O–P–O–P–O–H 4 0 2
O O
46. The method of preparation of 2-benzyloxynaphthalene is a base catalysed reaction of -

(a) benzyl chloride and 1-naphthol (b) 1-chloromethylnaphthalene and phenol
(c) 1-chloronaphthalene and benzyl alcohol (d) benzyl alcohol and 1-naphthol
Ans. [NA]
Sol.
47. The pair that is isostructural (i.e. having the same shape and hybridization) is
(a) NF3 and BF3 (b) BF4 and NH 4 (c) BCl3 and BrCl3 (d) NH3 and NO 3
Ans. [b]
Sol. Pair of isostructural
(a) NF3 and BF3 Not isostructural
sp3 sp2
(b) BF4 and NH 4 Same hybridisation and same bond pair and no-lone pair
Hence same shape (isostructural)
(c) BCl3 and BrCl3 Not isostructural
sp2 B.P. = 3
plane L.P. = 2
5 = sp3d
T-shape
22 / 35
(d) NH3 and NO 3 Not isostructural
sp3 O=N=O
B.P. = 3
O
L.P. = 1
sp2
48. A group which departs from the substrate in a a nucleophilic substitution reaction is called a leaving group.
The case of departure is determined by the acidity of the conjugate acid of the leaving group; higher the
acidity better is the leaving group. The correct order of the reactivity of the following compounds in a given
nucleophilic reaction is -
(a) R-Cl > R-OCOCH3 > R-OSO2CH3 > RI (b) R-OSO2CH3 > R-Cl > R-OCOCH3 > ROH
(c) R-I > RNH2 > R-OCOCH3 > R-OSO2CH3 (d) R-Br > R-OSO2CH3 > R-OCOCH3 > ROCH3
Ans. [b]
Sol. Leaving group ability
O –
– – –
O–S–CH3 > Cl > O –C–CH3 > OH
O O
Acidic strength :
O
CH3–S–OH > H Br > CH3–C–OH > H–O–H
O O
49. Compound 'X' in the following reaction is -

i. Ozonolysis CH3
ii. aq. KOH, heat
X
COCH3
H3C
CH2CH3 CH2CH3
(a) (b)
CH3
CH3
(c) (d)
CH3 CH2CH3
Ans. [c]
Sol.
23 / 35
O
CH3
O3|Zn|HO
Ozonolysis
CH3
O
KOH
O O
– O
–H2O
 CH3
OH Intra molecular
O
Aldol
50. A toxic element is to be removed from drinking water by adsorption on activated charcoal. At low
concentrations, the rate constant for adsorption is 1.8 × 10–5 s–1. The time required to reduce the
concentration of the toxic element to 10% of its initial concentration is
(a) 1.28 × 105 s (b) 5.85 × 103 s
(c) 1.28 × 106 s (d) cannot be calculated from the given data.
Ans. [a]
2.303 C0
Sol. K= log
t Ct
2.303 a
k= log
t 0.1a
2.303
t= log 10
1.8  10 – 5
5
t = 1.28 × 10
51. Assuming that Hund's rule is violated by the diatomic molecule B2, its bond order and magnetic nature will
be respectively
(a) 1, diamagnetic (b) 1, paramagnetic
(c) 2, diamagnetic (d) 2, paramagnetic
Ans. [a]
Sol. B2  5 × 2 = 10 e–
Case – I
N  14 * 1s2  1s2 * 2s2 2p1x = 2p1y  2pz
But in given question Hund's Rule is voleted
Then configuration is
 1s2 * 1s2  2s2 * 2s2 2p2x = 2p0y  2p0z
Hence B2 is Diamagnetic
1
But B.O. is = (Nb – Na)
2
1
= (6 – 4)
2
=1
24 / 35
52. In a cubic crystal structure, divalent metal-ion is located at the body-centered position, the smaller tetravalent
metal ions are located at each corner and the O2– ions are located half way along each of the edges of the
cube. The number of nearest neighbors for oxygen is
(a) 4 (b) 6 (c) 2 (d) 8
Ans. [b]
Sol. Since the nearest distance is a/2 so the No. of nearest atom will be six
53. Organic compounds sometimes adjust their electronic as well as steric structures to attain stability. Among
the following, the compound having highest dipole dipole moment is
Br
(a) (b) (c) (d)

Br
Br Br
Ans. [d]
Sol.
ionisation
+ Br
6 e–
+
Br Aromatic
Higher cyclic delocalisation
Dipole moment of (4n +2)  e–.
So more ionic nature
54. Cyanide ion is a very good complexing agent and also functions as a reducing agent. Hence many cyanide
complexes of metals are known. Addition of an aqueous solution of KCN to a solution of copper sulphate
yields a white precipitate which is soluble in excess of aqueous of aqueous KCN to form the complex :
(a) [Cu(CN)4]1– (b) [Cu(CN)4]2– (c) [Cu(CN)4]3– (d) [Cu(CN)4]4–
Ans. [c]
2
Sol. CuSO4 + 2 KCN  K2SO4 + Cu (CN) 2 Cu2 (CN)2 + (CN)2
or or
1
K 3 [Cu (CN) 4 ]  
3KCN
Cu CN NC – CN
55. When a certain metal was irradiated with light of frequency 3.2 × 1016 Hz, the photoelectrons emitted had
twice the kinetic energy as did the photoelectrons emitted when the same metal was irradiated with light of
frequency 2.0 × 1016 Hz. The 0 of the metal is
(a) 2.4 × 1016 Hz (b) 8.0 × 1016 Hz (c) 8.0 × 1015 Hz (d) 7.2 × 1016 Hz
Ans. [c]
Sol. h1 = h0 – K.E1 1 = 3.2 × 1016
h2 = h0 – K.E2 2 = 2 × 1016
 K.E1 = 2 × K.E1
K.E1  h (1 –  0 )
K.E 2  h ( 2 –  0 )
25 / 35
2 ( –  0 )
= 1
1 ( 2 –  0 )
22 – 20 = 1 – 0
22 –1 = 0
2 × 2 × 1016 – 3.2 × 1016 = 0
0 = 8 × 1015 Hz
56. The major product 'S' of the following reaction sequence is

NO2
i. NaNO2-H2SO4/0ºC
Br2/Fe Sn/HCl excess Br2/H2O ii. CuBr,HBr
P Q R S
Br Br Br Br
Br Br Br Br
(a) (b) (c) (d)

Br Br Br Br Br Br Br
Br Br Br Br
Ans. [b]
Sol.
NO2 NO2 NH2
Br2/Fe Sn./HCl
Br Br
Br NH2
Br Br Br Br
(i) NaNO2–H2SO4/0°C
(ii) Cu–Br,HBr
Br Br
Br Br
57. 1.250 g of metal carbonate (MCO3) was treated with 500 mL of 0.1 M HCl solution. The unreacted HCl
required 50.0 mL of 0.500 M NaOH solution for neutralization. Identify the metal M
(a) Mg (b) Ca (c) Sr (d) Br
Ans. [b]
Sol. MCO3 + HCl 
1.250 gm 0.1 m
500mL
Excess
HCl + NaOH O + NaCl
Remaining 0.5
50 mL
No. of equivalents of HCl = No. of equaivalents of NaOH
n×1 = 0.5 × 1 × 50
nHCl = 25 milli moles
26 / 35
Remaining.
nHCl (Actual) = 0.1 × 500
= 50 millimol
nHCl reacted with MCO3 = (50 – 25) millimoles
= 25 millimoles
Number of equilivalents of MCO3 = Number of equivalents of HCl
1.250
= 25 × 10–3 × 1
E
1.25
E=  1000
25
= 50
Mol. wt = E × Af = E × 2 = 50 × 2 = 100 (So CaCO3)
58. An electron beam can undergo diffraction by crystals which proves the wave nature of electrons. The
potential required for a beam of electrons to be accelerated so that its wavelength becomes equal to 0.154 nm
is
(a) 63.5 V (b) 31.75 V (c) 635 V (d) 127 V
Ans. [a]
150
Sol.  =  in Aº
V
150
1.54 × 1.54 =
V
V = 63.5V
59. A biodegradable alternating coploymer of L-alanine and glycolic acid (HO–CH2-COOH) is

o H H o o
HO N H3C o H
H3C
o N
o o o
(a) (b) o (c) N (d) o
N H CH3 o H H3C H
o H n n n n
Ans. [a]
Sol.
CH3 O
H
HO NH2 + HO – C O H
CH2
O
CH3 O
H O
NH – C
CH2
O n
60. In which of the following complexes the metal ion has the lowest ionic radius ?
(a) [Ti(H2O)6]2+ (b) [V(H2O)6]2+ (c) [Cr(H2O)6]2+ (d) [Mn(H2O)6]2+
Ans. [b]
27 / 35
Sol. In all four complex 3d metals are in +2 state like Ti2+ , V2+, Cr2+ and Mn2+ So there ionic radius trends as
follow
110
Ca2+
Ionic radius (pm)
100
90
Ti,2+ Mn2+
80 Zn2+
2+ 2+
Cr Co +
V2+ Fe2+ Cu2+
70
Ni2+
60
increasing atomic No
Lowest ionic radius = V2+
complex is  V(H 2 O) 6 2
61. In cold climate, the water in a radiator of a car gets frozen causing damage to the radiator. Ethylene glycol is
used as an antifreezing agent. The amount of ethylene glycol that should be added to 5 kg of water to prevent
it from freezing at –7 ºC is
(Given) Kf for water = 1.86 K mol–1 kg ; Molar mass of ethylene glycol = 62 g mol–1)
(a) 1165 g (b) 46.7 g (c) 116.7 g (d) 93.4 g
Ans. [a]
Sol. Tf = i × kf × m
n
7 = 1× 1.86
5
75
nethylene glycol =
1.86
w 75
=
62 1.86
w = 1165 gm
62. The ratio of the energy of the electron in ground state of hydrogen atom to that of the electron in the first
exited state of Be3+ is
(a) 1:4 (b) 1 : 8 (c) 1: 16 (d) 4 :1
Ans. [a]
z2 ( 4) 2
Sol. E =  E0 E Be3   E 0
n2 22
(1) 2
E H  E 0 = – 4E0
12
= – E0
EH  E0 1
 
E Be3  4E 0 4
28 / 35
63. Water insoluble, but organic solvent soluble, dye is dissolved in three organic solvents and taken in three
separating funnels, a, b and c. To each solution, water is added, shaken, and kept undisturbed. The solvents in
separating funnels a, b and c form the following figures are respectively
Organic solvent
a b c
(a) a: EtOH; b: CCl4 ; c: EtOAc (b) a: CCl4 ; b: EtOH ; c EtOAc;

(c) a : EtOAc; b: CCl4; c: EtOH (d) a : CCl4; EtOAc; c ; EtOH
Ans. [b]
Sol. (i) In picture a both are Immiscible and organic solvent is heavier So it should be CCl4
(ii) In picture b organic solvent is soluble So organic solvent should be alcohol
(iii) In picture c ester is present because it is insoluble and less dense than water
64. P,Q R and S are four metals whose typical reactions are given below ;
(I) Only Q and R react with dilute HCl to give H2 gas.
(II) When Q is added to a solution containing the ions of the other metals, metallic P,R and S are formed.
(III) P reacts with concentrated HNO3 but S does not
The correct order of their reducing character is -
(a) S< P< R<Q (b) S< R <P < Q (c) R< Q < P < S (d) Q < P < S < R
Ans. [a]
Sol. According of obove given statements Q is best
Reducing Agent then that of P.R and S
Hence [Ans is S<P<R<Q]
65. If a dilute solution of aqueous NH3 is saturated with H2S then the product formed is
(a) (NH4)2S (b) NH4HS (c) (NH4)2Sx (d) NH4OH + S
Ans. [b]
Sol. Dilute solution of aqueous NH3 is saturated with H2S
NH3 + H2O  NH4OH
NH4OH + H2S  NH4HS + H2O
66. Three Faradays of electricity are passed through aqueous solution of AgNO3, NiSO4 and CrCl3 kept in three
vessels using inert electrodes. The ratio (in moles) in which the metals Ag, Ni and Cr are deposited is
(a) 1: 2 : 3 (b) 3: 2 : 1 (c) 6: 3 : 2 (d) 2: 3 : 6
Ans. [c]
29 / 35
Q
Sol. Number of moles =
F  nf
Q
n
np
1 1 1
So. n AgNO3 : n NiSO 4 : n CrCl3 : : :
n f ( AgNO3 ) n f ( NiSO 4 ) n f ( CrCl3 )
1 1 1
n AgNO3 : n NiSO 4 : n CrCl3 = : :
1 2 3
=6:3:2
67. Nepetalactone (X) is isolated as an oil from Catnip.

O CH3
(X)
The number of chiral carbon atoms and the amount of KOH consumed by 83 mg of Nepatalactone are
respectively
(a) 3, 50 mg (b) 2, 56mg (c) 3, 56 mg (d) 3, 28 mg
Ans. [d]
Sol.
O
HO
HC
O O CH3
CH3
HO
* OH
O * 3 chiral centre
KOH
*
83  10 –3
= 0.5 × 10–3 mole
166
5 × 10–4 mole of molecule require 5 × 10–4 mole of KOH
So WKOH = 5 × 10–4 × 56 = 28 × 10–3 g
moles mole wt = 28 mg
So Ans. is (d) 3. chiral centre and 28 mg of KOH
68. Number of P-S single bonds and P-S double bonds (P=S) in P4S10 are respectively
30 / 35
(a) 10, 6 (b) 16, 0 (c) 14, 2 (d) 12, 4

Ans. [d]
Sol. P4S10
S
||
P
S S
S
S=P P=S
S S S
P
||
S
Number of P-S Single bond is = (12)
and P-S Double bond is = (4)
69. If the solubility product of iron(III) hydroxide is 1.8 × 10–37, the pH of a saturated solution of iron(III)
hydroxide in distilled water is close to
(a) 4 (b) 5 (c) 7 (d) 9
Ans. [b]
Sol. Fe(OH)3  Fe3+ + 3OH
s 3s
Ksp = 11 × 33 s s1 + 3
Ksp = 27s4
1.8 × 10–37 = 27 s4
S4 = 66.66 × 10– 40
S = 2.85 × 10–10
[OH–] = 3s
= 3× 2.85× 10–10
= 8.55 × 10–10
pOH= 10– log 8.55
= 10– 0.9319
pOH = 9
pH = 14 – 9 = 5
70. An alkyl halide (X) on reaction with ethanolic sodium hydroxide forms an alkene (Y) which on further
reaction with HBr gives the same alkyl halide . The alkene (Y) on reaction with HBr / peroxide followed by
reaction with Mg metal; followed by reaction with HCN produces an aldehyde(Z). Z is.
CHO
CHO CHO
(a) (b) (c) (d) CHO
Ans. [b,c]
Sol.
31 / 35
– +
EtO Na HBr
(B) CH3 – CH – CH3 CH3 – CH = CH2 CH3 – CH – CH3

Br Y Br
X X
HBr/R2O2
Mg
CH3 – CH2 – CH2 CH3 – CH2 – CH2
Br MgBr
(1) HCN
(2) H3O
CH3 – CH2 – CH2 – CHO

Br Br
– +
EtO Na HBr
(C) CH3 – C – CH3 CH3 – C – CH3 CH3 – C – CH3

CH3 CH2 CH3
X Y
HBr/R2O2
Mg
H3C – CH – CH3 CH3 – CH – CH2
CH2 – Br CH2MgBr
(1) HCN
(2) H3O+
CH3 – CH – CH3
CH2–CHO
71. HClO4 is a stronger acid than HClO. The correct statement is

(a) ClO 4 ion is more stabilized than ClO 
(b) ClO 4 ion has higher hydration energy than ClO 
(c) HClO 4 is better solvated in water than HClO

(d) In HClO4, H is attached to Cl, while in HClO it is attached to O
Ans. [a]
Sol. HClO4 is a strongest acid than HClO
correct statement are 
O–
 HClO4  H+ + ClO4–  O = Cl = O  four R.S.
O
H – O – Cl  H + OCl
+ –
Hence  Statement (a) is correct 

72. For an elementary rearrangement reaction A P, the following data were recorded at 303 K, when
32 / 35
[P]0 = 0 :
Set No. [A]0/mol L–1 Rate of conversion of A / mol L–1 min–1
1. 0.340 0.100
2. 0.170 0.050
3 0.085 0.025
If the equilibrium constant of the reaction is 1.12 at 303 K, the rate constant for the reaction P  A is -
(a) 0.263 min–1 (b) 0.294 min–1 (c) 0.526 min–1 (d) 0.588 min–1
Ans. [a]
Kf
Sol. A P
Kb
k
Kc = f
kb
Order of reaction is 1
Rate = kf [A] Rate = kf [A]
0.100 = kf (0.34) 0.50 = kf (10.170)
kf = 0.29 kf =0.29
kf
kc =
kb
0.29
1.12 =
kb
kb = 0.2626
73. Compound P on treatment with CH2N2 (diazomethane) produces compound Q. Compound Q on reaction
with HI produces two alkyl iodides R and S. Alkyl iodide S with higher number of carbon atoms on reaction
with KCN followed by hydrolysis gives 3-methylbutanoic acid. The compound P is
(a) 2-butanol (b) 1-butanol (c) 2-methyl-2-propanol (d) 2-methyl-1-propanol
Ans. [d]
Sol.
CH3–I
P Q
CH2N2 HI
CH3–CH–CH2–OH CH3–CH–CH2–O–CH3

CH3 CH3
2-methyl-1-propouol CH3–CH–CH2–I
CH3
Mg / Dry ether
(1)HCN
H3C–CH–CH2–C–OH H3C–CH–CH2MgI
(2) H3O+
CH3 O CH3
74. I2 reacts with aqueous Na2S2O3 to give Na2S4O6 and NaI. The products of reaction of Cl2 with aqueous
Na2S2O3 are
33 / 35
(a) Na2S4O6 + NaCl (b) NaHSO4 + HCl (c) NaHSO3 + HCl (d) NaHSO3 + NaCl
Ans. [b]
Sol. Na2S2O3 + I2  Na2S4O6 + 2NaI
(aq)
Cl2 Water

NaHSO4 + HCl
75. The standard potentials (Eº) of MnO 4 / Mn 2 and MnO 2 / Mn 2 half cells in acidic medium are 1.51 V and
1.23 V respectively at 298 K. The standard potential of MnO 4 / MnO 2 half-cell in acidic medium at the
same temperature is
(a) 5.09 V (b) 1.70 V (c) 0.28 V (d) 3.34 V
Ans. [b]
+7 E1= ?
+4
1.23
MnO4 MnO2 Mn2+
Sol.
E1 n 1  E 2 n 2
E=
n1  n 2
E  3  1.23  2
1.51 = 1
5
7.55 – 2.46 = 3E1
E1 = 1.69V
76. Aspartame (X) is an artificial sweetening agent and is 200 times sweeter than sugar. It is an ester of the
dipeptide of
COOH
O
H M
N e OMe
H2N
O
M
e (X)
(a) Alanine and phenylalanine (b) Aspartic acid and alanine

(c) Phenylalanine and glycine (d) aspartic acid and phenylalanine
Ans. [d]
Sol. Aspartame is an artificial sweetening agent formed by aspartic acid and phenylalanine
77. Which one of the following reactions is correct ?

(a) [Fe(CO)5] + 2NO  [Fe(CO)2(NO)2] + 3CO (b) [Fe(CO)5] + 2NO  [Fe(CO)3(NO)2] + 2CO
(c) [Fe(CO)5] + 3NO  [Fe(CO)2(NO)3] + 3CO (d) [Fe(CO)5] + 3NO  [Fe(CO)3(NO)3] + 2CO
Ans. [a]
Sol. Fe(CO)5 + NO  [Fe(CO)2 (NO)2] + 3 CO
W
e know
34 / 35
that C=O N=O

–
2e– Donar 3e Donar
3 × 2  6e– 2 × 3e–  6e–
Donar Donar
This meaning 3CO replaced by 2NO
Hence Ans. is (a)
78. Standard molar enthalpy of formation of CO2(g) is equal to

(a) Zero
(b) The standard molar enthalpy of combustion of carbon (graphite)
(c) The standard molar enthalpy of combustion of C(g)
(d) The standard molar enthalpy of combustion of CO(g)
Ans. [b]
Sol. C(s) + O2 CO2(g)
Formation of CO2 = combustion of C(s) graphite
79. The reaction of 1-phenylpropane with limited amount of chlorine in the presence of light gives mainly
(a) 4-chloropropylbenzene (b) 1-chloro-1-phenylpropane
(c) 3-chloro-1-phenylpropane (d) 2-chloro-1-phenylpropane
Ans. [b]
Sol.
Cl
Cl2 (less)
CH3–CH2–CH2–Ph CH3–CH2–CH–Ph
h
CH3–CH2–CH–Ph
It is example of photo monohalogenation by free radical mechanism. So reaction occur through benzylic free
radical.
80. An ionic solid LaI2 shows electrical conduction due to presence of

(a) La2+ and 2I– (b) La3+, 2I– and e– (c) La2+, I2 and 2e– (d) La3+, I2 and 3e–
Ans. [b]
Sol. LaI2  La 2  + 2I
La3+ + e–
35 / 35

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CHEMISTRY NSEC 2016-2017 EXAMINATION CAREER POINT

ASSOCIATION OF CHEMISTRY TEACHERS

= 2.4 × 10–21 Joules

2. Which of the following compounds contain 3-centered 2-electron bonding ?

Relative amounts of A, B, C and D formed are

4. White phosphorous on reaction with NaOH gives PH3 and

5. Given the E0 values for the half reactions :

7. How many isomers are possible for complex [Co(ox)2Cl2]+ ?

CHO CHO CHO CHO

(a) n – C4H9 – O – CH2 – (CH2)7  HC CH2

–Br CH3–CH2 –CH2–CH2

HO–CH2 –(CH2)7 nC4H9

Mn2+ or Ni2+ or Cu2+ or Hg2+

21. The compound that reacts fastest with methylamine is

26. The IUPAC name of the following compound is

30. The diastereoisomer (stereoisomer that is not a mirror image) of 'X' is

C63 4s0 3d6

412 kJ/mole 286 kJ/ mole

37. The correct statement/s is/are

38. The kinetic data recorded at 278 K for the reaction

Set No. [ NH 4 ] /M [ NO 2– ] /M Rate of reaction/Ms–1

(c) k [ NH 4 ] [ NO 2– ] and M–1s–1 (d) k [ NO 2– ] and s–1

39. Which of the following statements is not true for Ce 3 and Yb 3 ?

n– propyl chloride O Sod. Butanoate

NaCl + CH3 – CH2 – CH2 – O – C– CH2 – CH2 – CH3

(c) The shape of the complex ion is icosahedron.

 NO3 acts as bidentate ligand

The cehas co-ordination number is 12.

Compounds Oxidation No. of P–OH No. of P–H No. of P = O

(a) I (b) III (c) IV (d) II

46. The method of preparation of 2-benzyloxynaphthalene is a base catalysed reaction of -

(c) BCl3 and BrCl3 Not isostructural

(d) NH3 and NO 3 Not isostructural

49. Compound 'X' in the following reaction is -

(a) (b) (c) (d)

56. The major product 'S' of the following reaction sequence is

(a) (b) (c) (d)

nHCl = 25 milli moles

59. A biodegradable alternating coploymer of L-alanine and glycolic acid (HO–CH2-COOH) is

(a) a: EtOH; b: CCl4 ; c: EtOAc (b) a: CCl4 ; b: EtOH ; c EtOAc;

67. Nepetalactone (X) is isolated as an oil from Catnip.

(a) 10, 6 (b) 16, 0 (c) 14, 2 (d) 12, 4

CH3 – CH2 – CH2 – CHO

71. HClO4 is a stronger acid than HClO. The correct statement is

(b) ClO 4 ion has higher hydration energy than ClO 

(c) HClO 4 is better solvated in water than HClO

 HClO4  H+ + ClO4–  O = Cl = O  four R.S.

Hence  Statement (a) is correct 

(a) Alanine and phenylalanine (b) Aspartic acid and alanine

77. Which one of the following reactions is correct ?

that C=O N=O

78. Standard molar enthalpy of formation of CO2(g) is equal to

80. An ionic solid LaI2 shows electrical conduction due to presence of

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