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Answer Key

41/75 Questions
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Physics

Q. 1

For two masses following measurment are taken

What is the percentage error in

Option 1:
3.8 %

Option 2:
1.6 %

Option 3:
2.5 %

Option 4:
3.5 %

Correct Answer:
1.6 %

Solution:
As we have learned

Percentage error in the value of x -

- wherein

= absolute error in measurement of a

= absolute error in measurement of b


= absolute error in measurement of x

% error in M=

Incorrect
Q. 2
The diameter and height of a cylinder are measured by a meter scale to
be and , respectively. What will be the value of its volume in
appropriate significant figure ?

Your Answer:

Option 1:

Option 2:
Option 3:

Option 4:

Correct Answer:

Solution:

All non zero digits are significant -

42.3 -Three significant figure

238.4 -four significant figure

33.123 -five significant figure

A zero becomes significant figure if it exists between two non zero digits -

2.09 - Three significant figures

8.206 -four significant figures

6.002 -four significant figures

For addition or subtraction, the final result should retain as many decimal places as there in the
number with the least decimal places

for multiplication or division, the final result should retain as many significant figures as there in the
original number with the least significant figures

The number of significant figures in diameter and height is 3. Error have one significant figure

Only option 4260 80cm3 have three significant figures.


Error =

Correct
Q. 3
Time (T), velocity (C) and angular momentum (h) are chosen as fundamental quantities instead of
mass, length and time. In terms of these, the dimensions of mass would be :

Your Answer:

[ M ]=[ T−1 C−2 h ]

Option 1:
[ M ]=[ T−1 C−2 h ]

Option 2:
[ M ]=[ T−1 C2 h ]

Option 3:
[ M ]=[ T−1 C−2 h−1 ]

Option 4:
[ M ]=[ T C−2 h ]

Correct Answer:
[ M ]=[ T−1 C−2 h ]

Solution:
As we have learnt in

Plank's Constant (h) -

- wherein

Joule-sec
Dimension of length

Correct Answer is 1

And other options are incorrect

Incorrect
Q. 4
The dimensions of angular momentum, latent heat and capacitance are, respectively.

Your Answer:

Option 1:

Option 2:

Option 3:

Option 4:

Correct Answer:
Correct
Q. 5
Choose the correct pair (A,B) showing A as scalar quantity and B as vector quantity

Your Answer:

(Speed,Velocity)

Option 1:
(Time,Work)

Option 2:
(Force,Current)

Option 3:
(Length, Mass)

Option 4:
(Speed,Velocity)

Correct Answer:
(Speed,Velocity)

Solution:

As we learned that

1) Scalar Quantity

The quantities having magnitude only are known as scalar quantity.

Examples-Distance, time, work, energy, etc......

2) Vector Quantity

The quantities having both directions as well as magnitude are known as vector quantities.

Examples - Displacement , force ,velocity, acceleration, momentum ....etc.

In opt 1-(Time,Work)- Both are scalar quantities. So it is incorrect

In opt 2-(Force,Current)- Force is vector quantity.So it is incorrect


In opt 3- (Length, Mass)- Both are scalar quantities. So it is incorrect

In opt. 4- (Speed,Velocity)- Speed is scalar quantity and Velocity is vector quantity. So it is correct
option.

Incorrect
Q. 6
Which of the following is not a fundamental quantity?

Your Answer:

current

Option 1:
mass

Option 2:
time

Option 3:
charge

Option 4:
current

Correct Answer:
charge

Solution:
As we have learnt,

The fundamental quantities are length, mass, time, electric current, temperature, luminous intensity,
amount of substance

unit of charge is a derived quantity. so option 3 is right

Correct
Q. 7

Which one of the following represents the correct dimensions of the coefficient of viscosity?

Your Answer:
ML-1T -1

Option 1:
ML-1T-2

Option 2:
MLT-1

Option 3:
ML-1T -1

Option 4:
ML-2T-2

Correct Answer:
ML-1T -1

Solution:
Viscous force

or

As we learnt in

Dimension -

The power to which fundamental quantities must be raised in order to express the given physical
quantities.

or

or
Incorrect
Q. 8
Strain has same dimension as that of:

Your Answer:

Stress

Option 1:
Stress

Option 2:
Power

Option 3:
Relative density

Option 4:
Relative velocity

Correct Answer:
Relative density

Solution:
As we learn

Strain, refractive index, relative density, Poisson's ratio etc -

- wherein

unitless

Strain is unitless and relative density is also unitless.


Incorrect
Q. 9
The value of absolute error of first measurement in a measured value a1,a2..............am is equal to

[am is the true value]

Your Answer:

Option 1:

Option 2:

Option 3:

Option 4:

Correct Answer:

Solution:
As we learnt in

Errors of measurements -

It is the magnitude of the difference between the true value and the measured value of the quantity.

It may be positive in certain cases and negative in certain other cases

If are a measured value

then

where = true value


Q. 10

Which one of these groups shows the scalar physical quantity

Option 1:
displacement , speed , work

Option 2:
current , force , work

Option 3:
mass , charge , volume , electric potential

Option 4:
charge , electric field , speed , work

Correct Answer:
mass , charge , volume , electric potential

Solution:
As we have learned

Scalar Quantity -

Scalar Quantity can be added or subtracted by the laws of addition or subtraction

- wherein

It does not specify the direction

displacement , force , electric field are vector quantities

Q. 11

In an experiment , the value of refractive index of glass was found to be 1.54 , 1.53 1.44 , 1.54 , 1.56
and 1.45 in successive measurment

What is absolute error in the measurment of third reading


Option 1:
+ 0.06

Option 2:
-0.06

Option 3:
+0.07

Option 4:
+0.05

Correct Answer:
+0.07

Solution:
As we have learned

Absolute Error -

It is the magnitude of the difference between the true value and the measured value of the quantity.

- wherein

where am = true value

be measured value

= true value - measured value

Absolute Errors -
It may be positive in certain cases and negative in certain other cases

absolute error in third reading

Incorrect
Q. 12
A vector quantity

1) have magnitude direction

2) electric potential and Area are example for vector quantity

3) have direction

Which is true

Your Answer:

only 1

Option 1:
only 1

Option 2:
2 and 3

Option 3:
1 and 3

Option 4:
only 2

Correct Answer:
1 and 3

Solution:
As we have learned

Vector Quantity -

Those quantities having both direction as well as magnitude

- wherein

force ,velocity, acceleration, momentum ....etc.

electric potential is a scalar quantity

Q. 13

The speed of light (c), gravitational constant (G) and Plank's constant (h) are taken as fundamental
units in a system. The dimensions of the time in the new system should be

Option 1:

Option 2:

Option 3:

Option 4:

Correct Answer:

Solution:
By comparing the power of M, L & T.

By solving (1), (2) and (3)

Q. 14

If a tuning fork of frequency 340Hz tolerance is used in resonance column


method the first and the second resonance are measured
at The max. permissible error in speed of sound is :

Option 1:

Option 2:

Option 3:

Option 4:

Correct Answer:

Solution:

Error in division x = a/b -


( maximum fractional error in )

- wherein

= absolute error in measurement of a

= absolute error in measurement of b

= absolute error in measurement of x

Q. 15

Joule's law of heating gives us where I is current R is resistance and t is time . If the
error in measurment I , R and t are 5 % , 4 % and 8 % respectively then error in measurment of H
is

Option 1:

Option 2:

Option 3:

Option 4:

Correct Answer:

Solution:
As we have learned

Percentage error in the value of x -


(% error in value of a + % error in value of b)

- wherein

= absolute error in measurement of a

= absolute error in measurement of b

= absolute error in measurement of x

Incorrect
Q. 16
For a physical quantity which of the following relation is true [n- numerical value , u - unit ]

Your Answer:

Option 1:

Option 2:

Option 3:

Option 4:

Correct Answer:

Solution:
As we have learned

Physical quantity -

- wherein

(Magnitude)

For any physical quantity

Q=nu

(numerical) * (unit)

Incorrect
Q. 17

Which of the following has maximum no. of significant figure

Your Answer:

Option 1:
234.000

Option 2:
0.000303

Option 3:

Option 4:
Correct Answer:
234.000

Solution:
As we have learned

Trailing Zeros -

4.330- four significant figures

433.00- five significant figures

343.000- six significant figures

All zeros to the right of a decimal point are significant

So 234.000 has 6 significant figure

Incorrect
Q. 18
What is true for significant figure

Your Answer:

All non zero digits are significant

Option 1:
Higher no. of significant figure , higher is the accuracy

Option 2:
All non zero digits are significant

Option 3:
Both A and B

Option 4:
only B

Correct Answer:
Both A and B

Solution:
As we have learned

Significant figures -

The figures of a number that express a magnitude to a specified degree of accuracy

higher accuracy means there are higher no of S.F

Correct
Q. 19
What is true for ratio physical quantity

Your Answer:

All of the above

Option 1:
It is ratio of two similar quantity

Option 2:
It has no unit

Option 3:
Example is relative density

Option 4:
All of the above

Correct Answer:
All of the above

Solution:
As we have learned

Ratio Quantity -
When a physical quantity is the ratio of two similar quantities

- wherein

Ratio is a physical quantity which is ratio of two similar quantity . It is unit less

Incorrect
Q. 20
Dimensional formula is equal to dimensional formula of

Your Answer:

latent heat

Option 1:
Electric Potential

Option 2:
gravitational potential

Option 3:
latent heat

Option 4:
Both B and C

Correct Answer:
Both B and C

Solution:
As we have learnt,

Latent heat and gravitational potential -


- wherein

Electrical Potential

Gravitational potential

Latent Heat (L)

Q. 21

For a measurement of a length of cylinder by vernier callipers following reading are taken

3.29 cm 3.28 cm 3.29 cm 3.31 cm 3.28 cm 3.27 cm 3..29cm 3.30cm

Absolute error in measurement for 5th reading is -

Correct Answer:
-0.01

Solution:

mean value
=

Absolute error in measurement for 5th reading is=

Incorrect
Q. 22
For measurement of the diameter of a hollow cylinder following calculation are obtained for the
absolute error of different measurement

What will be the mean absolute error for the measurement

Your Answer:0.01

Correct Answer:
0.022

Solution:
As we learnt in

Errors of measurements -

It is the magnitude of the difference between the true value and the measured value of the quantity.

It may be positive in certain cases and negative in certain other cases

If are a measured value

then

where am = true value

then Absolute Error for nth reading = = true value - measured value
So

2) Mean absolute error

absolute error

(0.01+0.02+.06+.01+.01)/ 5

= 0.11/5=0.022

Q. 23

The length of a cylinder is measured with a meter rod having least count 0.1 cm. Its diameter is
measured with vernier calipers having least count 0.01 cm. Given that length is 5.0 cm. and the
radius is 2.0 cm. The percentage error in the calculated value of the volume will be

Correct Answer:
3

Solution:
The volume of a cylinder,

The percentage error in volume=

Q. 24

In a simple pendulum experiment for determination of acceleration due to gravity (g), time taken for
20 oscillation is measured by using a watch of 1 second least count. The mean value of time taken
comes out to be 30 s. The length of pendulum is measured by using a meter scale of least count 1
mm and the value obtained is 55.0 cm. The percentage error in the determination of g is close to:

Correct Answer:
6.8

Solution:

Q. 25

If percentage error in measurement of resistance R is 5% and that of in a measurement of current I


is 2% , then maximum fractional error in voltage V will be :

Correct Answer:
7

Solution:
V= IR

Chemistry

Incorrect
Q. 1
What is the ratio of masses of oxygen that combine with a fixed mass of Hydrogen in water and
Hydrogen Peroxide?

Your Answer:

2:1

Option 1:
1:2

Option 2:
2:1

Option 3:
2:3

Option 4:
3:2

Correct Answer:
1:2

Solution:
As we learnt in

Law of multiple proportion -

If two elements can combine to form more than one compund, the masses of one element that
combines with a fixed mass of other element are in ratio of small whole numbers.

- wherein

One mole of water has 2g hydrogen & 16g oxygen.

Similarly, one mole of hydrogen peroxide has 2g of hydrogen and 32 g of oxygen

Therefore, masses of oxygen combining with a fixed mass of hydrogen in water and hydrogen
peroxide have ratio 16:32 = 1:2

the ratio =

Therefore, Option (1) is correct


Incorrect
Q. 2
Which of the following has maximum number of molecules?

Your Answer:

11.2L of NH3 at STP

Option 1:
100g CaCO3

Option 2:
1.1 moles of H2O

Option 3:
11.2L of NH3 at STP

Option 4:
14g of N2

Correct Answer:
1.1 moles of H2O

Solution:
As we learnt.

Dimensional Analysis -

While calculating, the units should be the same all across the equation

- wherein

The units for each physical quantity should be the same throughout th equation. eg. If temperature is
involved, the units should be kelvin on both sides

Lets express all the entities in same physical quantities and same units
Therefore, Option(2) is correct

Correct
Q. 3
Which of the following exists as a moleclue ?

Your Answer:

Carbon dioxide

Option 1:
Argon

Option 2:
Carbon dioxide

Option 3:
Krypton

Option 4:
Neon

Correct Answer:
Carbon dioxide

Solution:
As we learnt in

Concept of moleclue -

Two or more atoms combine to give a moleclue

- wherein
Atom Molecule

In carbon dioxide, an atom of carbon combines with 2 atoms of oxygen to form a moleclue (CO2) of
carbon dioxide.

Therefore, Option(2) is correct

Incorrect
Q. 4
What is the ratio of the masses of the Oxygen that combine with a fixed value of Nitrogen in the
compounds Nitrogen monoxide and Nitrogen dioxide?

Your Answer:

2:3

Option 1:
2:3

Option 2:
2:1

Option 3:
3:2

Option 4:
1:2

Correct Answer:
1:2

Solution:
As we learnt,

Law of multiple proportion -

If two elements can combine to form more than one compund, the masses of one element that
combines with a fixed mass of other element are in ratio of small whole numbers.

- wherein
masses of oxygen combining with a fixed mass of hydrogen have ratio 16:32 => 1:2

Lets take NO first, the chemcial reaction is follows:

in NO2,

Therefore, Option (4) is correct

Incorrect
Q. 5
Classify the following as pure substances :

Your Answer:

Petrol

Option 1:
Petrol

Option 2:
Tap water

Option 3:
Distilled water

Option 4:
Milk

Correct Answer:
Distilled water

Solution:

As we have learnt,

Classification of Matter -

Chemical Classification :

1. Pure Substance: A material containing only one type of substance. Pure Substance can not be
separated into simpler substances by physical methods.

 e.g.: Element = Na, Mg, Ca .................. etc.

Compound = HCl, H2O, CO2, HNO3 .......... etc.

1. Element: The pure substance containing only one kind of atoms. 3 types (depend on the
physical and chemical property)
1. Metal
2. Non-metal
3. Metalloids
2. Compound: It is defined as a pure substance containing more than one kind of atoms that are
combined together in a fixed ratio by weight and which can be decomposed into simpler
substances by the suitable chemical method. The properties of a compound are different from
those of its components.
o e.g.: H2O, HCl, HNO3 .......... etc.
1. Organic compound
2. Inorganic compound

Distilled water does not contain any impurity mixed with it.

Therefore, Option(3) is correct

Incorrect
Q. 6
Which of the following can be considered an element ?

Your Answer:

Rubber

Option 1:
Limestone

Option 2:
Diamond

Option 3:
Rubber

Option 4:
Marble

Correct Answer:
Diamond

Solution:
As we learnt in

Concept of Element. -

Pure substances can be classified into elements or compunds

- wherein

Elements consists of only one type of particles.

eg: H2, O2

Diamond is pure carbon, The rest are not element.

Therefore, Option(2) is correct

Q. 7
The volume of 0.1N dibasic acid sufficient to neutralize 1g of a base that furnishes 0.04 mole of
OH− in aqueous solution is:

Option 1:
200 mL

Option 2:
400 mL

Option 3:
600 mL

Option 4:
800 mL

Correct Answer:
200 mL

Solution:

Reactions in Solutions -

Concentration :
It is the amount of solute present in one litre of solution. It is denoted by C or S.

Mole Fraction:
It is the ratio of moles of one component to the total number of moles present In the solution. It is
expressed by X for example, for a binary solution with two components A and B.

Here nA and nB represent moles of solvent and solute respectively. Mole fraction does not depend
upon temperature as both solute and solvent are expressed by weight.
Molarity:
It is the number of moles or gram moles of solute dissolved per litre of the solution. Molarity is
denoted by 'M'.

 When molarity of a solution is one, it is called a molar solution and when it is 0.1, solution
is called decimolar solution.
 Molarity depends upon temperature and its unit is mol/litre.
M1V1 = M2V2
 On dilution water added = V2 - V1
 When the solution of two different substances react together then

Here M, V, n are molarity, volume and number of molecules taking part in a reaction
respectively.
 When a mixture of different solutions having different concentrations are taken the molarity of
the mixture is calculated as follows:

 When density and % by weight of a substance in a solution are given, molarity is find as
follows:

Here d = density

Molality
It is the number of moles or gram moles of solute dissolved per kilogram of the solvent. It is
denoted by 'm'.

 If molality is one solution, it is called molal solution.


 One molal solution is less than one molar solution.
 Molality is preferred over molarity during experiments as molality is temperature
independent while molarity is temperature-dependent.

Normality
It is the number of gram equivalents of solute present in one litre of the solution and it is denoted by
'N'.

 When normality of a solution is one, the solution is called normal solution and when it is 0.1, the
solution is called deci-normal solution.
Normality Equation:

 Volume Of water added = V2 - V1


Here V2 = volume after dilution
V1 = volume before dilution
 When density and % by weight of a substance in a solution are given, normality is find as
follows:

Here d = density of solution


 When a mixture of different solutions having different concentrations are taken the normality of
the mixture is calculated as follows:

• In case of acid-base neutralization the normality of the resulting solution

• To find weight of substance

Relation between Normality and Molarity :


N x Eq wt. = molarity x molar mass
N = molarity x valency
N = molarity x number of H+ or OH- ion

Dibasic acids has two ionizable hydrogens.


Therefore the equation can be given as follows:

V x 0.1 x 2 = 0.04
v = 200ml

Therefore, Option(1) is correct

Q. 8
Number of atoms in 558.5 gram Fe (at. wt.of Fe = 55.85 g mol-1) is:

Option 1:
twice that in 60 g carbon

Option 2:
6.023 × 1022

Option 3:
half that in 8 g He

Option 4:
558.5 × 6.023 × 1023

Correct Answer:
twice that in 60 g carbon

Solution:
As we learnt in

Mole Concept -

One mole is the amount of a substance that contains as many particles or entities as there are
atoms in exactly 12 g (or 0.012 kg) of the 12C isotope.

- wherein

one mole = 6.0221367 X 1023

Number of moles of Fe atom

Total number of atom

no. of atoms found in 120 gm carbon.

Therefore, Option (1) is correct

Q. 9

A gaseous compound of nitrogen and hydrogen contains 12.5%(by mass) of hydrogen. The density
of the compound relative to hydrogen is 16. The molecular formula of the compound is :
Option 1:

Option 2:

Option 3:

Option 4:

Correct Answer:

Solution:
In the given compound, let the total weighht of the compound is 100g.
Therefore, the weigght of hydrogen = 12.5g and weight of nitrogen = 87.5g.

Now, moles of hydrogen = 12.5 /1 = 12.5 moles


moles of nitrogen = 87.5 / 14 = 6.25 moles

Now the atomic ratio of hydrogen to nitrogen = 12.5 / 6.25


= 2:1

According ot question, vapour density of the compound = 16


Therefore, molecular weight = 2 x vapour density
= 32g

Now, from atomic ratio, we can say that the empirical formula of the compound is NH2.
Thus, the molecular formula of the compound = n x empirical formula
Now, molecular mass = 32g and empirical mass = 16g
Thus, molecular formula of the compound = 2 x NH2
= N2H4

Therefore, Option (4) is correct

Incorrect
Q. 10
The ratio of masses of oxygen and nitrogen in a particular gaseous mixture is 1:4. The ratio of
number of their molecule is :
Your Answer:

1:8

Option 1:
1:4

Option 2:
7 : 32

Option 3:
1:8

Option 4:
3 : 16

Correct Answer:
7 : 32

Solution:
As we learnt ,

Gay Lussac's law of Gaseous Volumes -

When gases combine or are poduced in a chemical reaction, they do so in a simple ratio by volume
provided all gases are at the same temperature and pressure.

- wherein

100 ml 50ml 100ml


Avogadro's number is defined as the number of elementary particles (molecules, atoms,
compounds, etc.) per mole of a substance. It is equal to 6.022×1023 mol-1 and is expressed as the
symbol NA.

Now let the ratiio be m, therefore, mass of O2 is m and mass of N2 is 4m.


Therefore, moles of O2 = m/32 and moles of N2 = 4m/28
Thus,

Therefore, Option (2) is correct

Incorrect
Q. 11
Permanent hardness in water cannot be cured by:

Your Answer:

Treatment with washing soda

Option 1:
Boiling

Option 2:
Ion exchange method

Option 3:
Calgon's method

Option 4:
Treatment with washing soda

Correct Answer:
Boiling

Solution:

Volume Strength of H2O2 Solution and Hardness of Water -

Volume Strength of H2O2 Solution :

The concentration of H2O2 is usually represented in terms of volume, if a sample of H2O2 is labeled
as 'X' volume, it means that 1 volume of H2O2 solution gives 'X' volumes of O2 gas at STP on
complete decomposition. Consider the decomposition of H2O2 as:

As 22400 ml of O2 gas is liberated by 68 g of H2O2 solution. So X ml of O2 gas will be liberated by:


It means that (17X / 5600) g of H2O2 will be present in 1 ml of solution.
1000 ml of solution contains H2O2

Strength (g L-1) = Normality x Equivalent wt.

that is, Volume strength of H2O2 = 5.6 x Normality

Hardness of Water :
The hardness of water is due to the presence of bicarbonates, chlorides and sulphates of calcium
and magnesium bicarbonates causes temporary hardness while chlorides and sulphates
cause permanent hardness. The extent of hardness is called degree of hardness. It is defined as the
number of parts by weight of calcium carbonate present In one million parts by weight of water that
is, in ppm (milligrams per litre) of CaCO3

As we have learnt,

The hardness of water cannot be cured simply by boiling. It needs extra treatment for purification like
Calgon's method.

Therefore, Option(1) is correct

Q. 12

The density of a solution prepared by dissolving 120 g of urea (mol. Mass = 60u) in 1000g of water is
1.15 g/mL. The molarity of this solution is:

Option 1:
0.50 M

Option 2:
1.78 M
Option 3:
1.02 M

Option 4:
2.05 M

Correct Answer:
2.05 M

Solution:
Mass of solute taken = 120 g

Molecular mass of solute = 60 u

Mass of solvent = 1000 g

Density of solution =1.15 g/mL

Total mass of solution = 1000 +120 + =1120 g

Moles of solute = 120g / 60g


= 2 moles

Now, molarity of solution = (2 / 973.066) x 1000


= 2.05M

Threfore, Option (4) is correct

Incorrect
Q. 13
If the true value of a quantity is 5g, which of the following measurements are both precise and
accurate?

Your Answer:

4.84g, 4.86g

Option 1:
4.90g, 4.89g

Option 2:
4.99g, 5.01g

Option 3:
4.84g, 4.86g

Option 4:
5.03g, 5.05g

Correct Answer:
4.99g, 5.01g

Solution:
As we learnt,

Precision refers to the closeness of various measurements for the same quantity.
Accuracy is the agreement of particular value to the true value of the result.

True value of a quantity is 5g. A student measures it twice and gets 4.99g and 5.01g.

4.99g & 5.01g are accurate because they are the closest to the true value. They are precise
because they are close to each other.

Therefore, Option(2) is correct

Incorrect
Q. 14
What is the number of molecules in 16g of Oxygen?

Your Answer:

Option 1:

Option 2:
Option 3:

Option 4:

Correct Answer:

Solution:
As we have learnt

MOLE CONCEPT AND MOLAR MASS -


Mole:

 A mole is a unit that represents 6.023 x 1023 particles, atoms, molecules or ions, etc.,
irrespective of their nature.
 Mole is related to the mass of the substance, the volume of gaseous substance and the
number of particles

Here G.m.m. = Gram molecular mass


 Volume of one mole of any gas is equal to 22.4 litres of dm3 at STP. It is known as molar
volume.

Here P= Pressure in atmosphere, V = Volume in litre, T = Temperature in Kelvin, R = Universal


gas constant
Relationship of Mole:

A mole of any substance (like O2) stands for:

 6.023 x 1023 molecules of O2


 2 x 6.023 x 1023 atoms of Oxygen
 32 gm of Oxygen
 22.4 litre of O2 at STP.

To Find the Total Number of Identities:

1. Total number of Molecule = mole(n) x NA


2. Total number of Atoms = mole (n) x NA x No. of atoms present in one molecule
3. Total number of Electrons = mole (n) x NA x No. of electron present in one electron
4. Total charge on any ion = mole (n) x NA x charge on one ion x 1.6 x 10-19 C

one mole = 6.0221367 X 1023

Mass of one mole of oxygen = 32 g

Thus moles of oxygen = 16/32


= 1/2 moles

Thus, number of molecules =

Therefore, Option(4) is correct

Q. 15

6 litres of an alkene require 27 litre of oxygen at constant temperature and pressure for complete
combustion . The alkene is:

Option 1:
Ethene

Option 2:
Propene

Option 3:
1-Butene

Option 4:
2-Butene

Correct Answer:
Propene

Solution:

Reactions in Solutions -

Concentration :
It is the amount of solute present in one litre of solution. It is denoted by C or S.

Mole Fraction:
It is the ratio of moles of one component to the total number of moles present In the solution. It is
expressed by X for example, for a binary solution with two components A and B.

Here nA and nB represent moles of solvent and solute respectively. Mole fraction does not depend
upon temperature as both solute and solvent are expressed by weight.

Molarity:
It is the number of moles or gram moles of solute dissolved per litre of the solution. Molarity is
denoted by 'M'.
 When molarity of a solution is one, it is called a molar solution and when it is 0.1, solution
is called decimolar solution.
 Molarity depends upon temperature and its unit is mol/litre.
M1V1 = M2V2
 On dilution water added = V2 - V1
 When the solution of two different substances react together then

Here M, V, n are molarity, volume and number of molecules taking part in a reaction
respectively.
 When a mixture of different solutions having different concentrations are taken the molarity of
the mixture is calculated as follows:

 When density and % by weight of a substance in a solution are given, molarity is find as
follows:

Here d = density

Molality
It is the number of moles or gram moles of solute dissolved per kilogram of the solvent. It is
denoted by 'm'.

 If molality is one solution, it is called molal solution.


 One molal solution is less than one molar solution.
 Molality is preferred over molarity during experiments as molality is temperature
independent while molarity is temperature-dependent.

Normality
It is the number of gram equivalents of solute present in one litre of the solution and it is denoted by
'N'.

 When normality of a solution is one, the solution is called normal solution and when it is 0.1, the
solution is called deci-normal solution.

Normality Equation:

 Volume Of water added = V2 - V1


Here V2 = volume after dilution
V1 = volume before dilution
 When density and % by weight of a substance in a solution are given, normality is find as
follows:

Here d = density of solution


 When a mixture of different solutions having different concentrations are taken the normality of
the mixture is calculated as follows:

• In case of acid-base neutralization the normality of the resulting solution

• To find weight of substance

Relation between Normality and Molarity :


N x Eq wt. = molarity x molar mass
N = molarity x valency
N = molarity x number of H+ or OH- ion

the formula of Alkene is CxH2x

making the general equation--

now,

for one mole or 1 litre of alkene the equation

for 6 litre of alkene the equation


Incorrect
Q. 16
Which of the following is a heterogenous mixture?

Your Answer:

Methyl alcohol in water

Option 1:
Methyl alcohol in water

Option 2:
Ethanol

Option 3:
Soil

Option 4:
Steel

Correct Answer:
Soil

Solution:
As we learnt in

Matter and its nature -

Classification of Matter

- wherein

At microscopic level matter can be classified as mixture or pure substances


Soil is the only heterogenous mixture here. Ethanol is pure substance. Methyl acohol in water and
steel are homogenous mixtures.

Therefore, Option(3) is correct

Correct
Q. 17
For a reaction,

identify dihydrogen as a limiting reagent in the following reaction mixtures.

Your Answer:
Option 1:

Option 2:

Option 3:

Option 4:

Correct Answer:

Solution:

Concept of limiting reagent and excess reagent -

The reactant which gets consumed and thus limits the amount of product formed is called the limiting
reagent.

- wherein

CH4 (g) + 2O2 (g) → CO2 (g) + 2 H2O (g) ;

In this reaction, if 1 mole of methane and 1 mole of oxygen are taken then oxygen would be limiting
reagent.

For :-

Identifying as a limiting reagent


Thus, in this case, 2 moles of N2 will react with 6 moles of H2, but only 5 moles of H2 are available.
Hence dihydrogen is the limiting reagent.

(LR)

:- Reaction gets completed here

(LR)

Therefore, Option(1) is correct

Q. 18

At 300 K and 1 atmsopheric pressure, 10 mL of a hydrocarbon required 55 mL of

for complete combustion, and 40 mL of is formed. The formula of the hydrocarbon is:

Option 1:

Option 2:

Option 3:
Option 4:

Correct Answer:

Solution:

Mole Concept -

One mole is the amount of a substance that contains as many particles or entities as there are
atoms in exactly 12 g (or 0.012 kg) of the 12C isotope.

- wherein

one mole = 6.0221367 X 1023

Law of Definite Proportions -

A compound always contains exactly the same propotion of elements by weight

- wherein

CaCO3 contains 40% Ca, 12% C and 48% O by weight irrespective of the source.

Law of conservation of mass -

Matter can neither be created nor destroyed.

- wherein
Mass is balanced on both sides

The equation of hydrocarbon can be written as :

Since , 10mL of produces 40mL of &

1mL of produces mL of

Now,

10mL of requires 55mL of

1mL of requires mL of

=>

=>

=>

=>
So, option (2) is correct.

Q. 19

The ratio of mass percent of C and H of an organic compound (CXHYOZ) is 6 : 1. If one molecule of
the above compound
(CXHYOZ) contains half as much oxygen as required to burn one molecule of compound
CXHY completely to CO2 and
H2O. The empirical formula of compound CXHYOZ is :

Option 1:
C2H4O3

Option 2:
C3H6O3

Option 3:
C2H4O

Option 4:
C3H4O2

Correct Answer:
C2H4O3

Solution:
As we learnt in

Empirical formula -

An Empirical formula represents the simplest whole number ratio of various atoms present in a
compound.

- wherein

for glucose, empirical formula is CH2O


Mass ratio of C & H is 6 : 1

So mole ratio of C & H is 1 : 2

X:Y=1:2

To burn one molecule of

molecule of is required i.e. 3 atoms of O are required

so

So empirical formula is

Q. 20

The amount of arsenic pentasulphide that can be obtained when 35.5 g arsenic acid is treated with
excess H2S in the presence of conc. HCl ( assuming 100% conversion) is :

Option 1:
0.50 mol

Option 2:
0.25 mol

Option 3:
0.125 mol

Option 4:
0.333 mol

Correct Answer:
0.125 mol

Solution:

Reactions in Solutions -
Concentration :
It is the amount of solute present in one litre of solution. It is denoted by C or S.

Mole Fraction:
It is the ratio of moles of one component to the total number of moles present In the solution. It is
expressed by X for example, for a binary solution with two components A and B.

Here nA and nB represent moles of solvent and solute respectively. Mole fraction does not depend
upon temperature as both solute and solvent are expressed by weight.

Molarity:
It is the number of moles or gram moles of solute dissolved per litre of the solution. Molarity is
denoted by 'M'.

 When molarity of a solution is one, it is called a molar solution and when it is 0.1, solution
is called decimolar solution.
 Molarity depends upon temperature and its unit is mol/litre.
M1V1 = M2V2
 On dilution water added = V2 - V1
 When the solution of two different substances react together then

Here M, V, n are molarity, volume and number of molecules taking part in a reaction
respectively.
 When a mixture of different solutions having different concentrations are taken the molarity of
the mixture is calculated as follows:

 When density and % by weight of a substance in a solution are given, molarity is find as
follows:
Here d = density

Molality
It is the number of moles or gram moles of solute dissolved per kilogram of the solvent. It is
denoted by 'm'.

 If molality is one solution, it is called molal solution.


 One molal solution is less than one molar solution.
 Molality is preferred over molarity during experiments as molality is temperature
independent while molarity is temperature-dependent.

Normality
It is the number of gram equivalents of solute present in one litre of the solution and it is denoted by
'N'.

 When normality of a solution is one, the solution is called normal solution and when it is 0.1, the
solution is called deci-normal solution.

Normality Equation:

 Volume Of water added = V2 - V1


Here V2 = volume after dilution
V1 = volume before dilution
 When density and % by weight of a substance in a solution are given, normality is find as
follows:

Here d = density of solution


 When a mixture of different solutions having different concentrations are taken the normality of
the mixture is calculated as follows:

• In case of acid-base neutralization the normality of the resulting solution


• To find weight of substance

Relation between Normality and Molarity :


N x Eq wt. = molarity x molar mass
N = molarity x valency
N = molarity x number of H+ or OH- ion

The chemical equation is as follows:

Thus 2 moles of arsenic acid produce one mole of arsenic pentasulphide.


Therefore, moles of arsenic acid = 35.5/142
= 0.25 moles

Thus, moles of arsenic pentasulphide produced = 0.25 / 2


= 0.125 moles

Therefore, Option(3) is correct

Q. 21

How PCl5 needs to be heated to give 22.4 L of Cl2? (in moles)

Correct Answer:
1

Solution:
As we learnt in

Stoichiometry -

Stoichiometry deals with measurements of reactants and products in a chemical reaction.

- wherein
aA (g) + bB (g) → cC (g) + dD (g)

Here, ‘a’ moles of A(g) reacts with ‘b’ moles of B(g) to give ‘c’ mole of C(g) and ‘d’ moles of D(g)

Now, we have:

Now, moles of Cl2 = 22.4 / 22.4


Thus, moles of Cl2 = 1 mole

1 mole of PCl5 gives 1 mole of Cl2.

Therefore, Option(3) is correct

Q. 22

The mole fraction of a solvent in aqueous solution of a solute is The


molality of the aqueous solution is :

Correct Answer:

Solution:

Mole Fraction -

It is ratio of moles of solute or moles of solvent to moles of solution.

- wherein

If a substance ‘A’ dissolves in substance ‘B’ and their number of moles are and respectively;
then the mole fractions of A and B are given as

Mole fraction of A = (number of moles of A)/(number of moles of solution ) = /( + )


We have,

Incorrect
Q. 23
How many significant digits does have?

Your Answer:1

Correct Answer:
3

Solution:
As we learnt in

Rules for significant figures -

In numbers written in scientific notation, all digits are significant e.g., 6.0 x 102 has two significant
figures, and 8.656 × 10–3 has four significant figures.

-
In numbers written in scientific notation, all digits are significant. So in , we have
3 significant digits.

Therefore, Option (1) is correct

Q. 24

50 mL of 0.5 M oxalic acid is needed to neutralize 25 mL of sodium hydroxide solution. The amount
(in g) of in 50 mL of the given sodium hydroxide solution is :

Correct Answer:
4

Solution:

Molar Mass -

The mass of one mole of a substance in grams is called its molar mass.

- wherein

Molar mass of water = 18 g mol-1

Molarity -

Molarity (M) = (Number of moles of solute)/(volume of solution in litres)

- wherein

It is defined as the number of moles of the solute in 1 litre of the solution.


Stoichiometry -

Stoichiometry deals with measurements of reactants and products in a chemical reaction.

- wherein

aA (g) + bB (g) → cC (g) + dD (g)

Here, ‘a’ moles of A(g) reacts with ‘b’ moles of B(g) to give ‘c’ mole of C(g) and ‘d’ moles of D(g)

As we have learned from mole concept

Q. 25

We have a substance . What is the molar mass (in g) of if 2 moles of it weigh 196g?

Correct Answer:
98

Solution:
As we learnt in

Number of Moles -

No of moles = given mass of substance / molar mass of substance


-

Molar mass of

Therefore, Option (3) is correct

Maths

Q. 1

The domain of the function

Option 1:

Option 2:

Option 3:

Option 4:

Correct Answer:

Solution:
As we learnt in

DOMAIN -

The domain of R is the set of all first elements of the ordered pairs in a relation R.

- wherein

eg. R={(a,b),(c,d)}, then domain is {a,c}


, |x| - x > 0

x < |x| it is only for -ve number. So that

Correct option is 1.

Incorrect
Q. 2
If A is a proper subset of B, we write

Your Answer:

Option 1:

Option 2:

Option 3:

Option 4:

Correct Answer:

Solution:
As we learnt

SUBSETS -

A set A is said to be a subset of a set B if every element of A is also an element of B.


- wherein

It is represented by . eg. A B if A={2,4} and B= {1,2,3,4,5}

for proper subset

Incorrect
Q. 3
Which of the following are equal sets?

Your Answer:

A={5} and B={x: }

Option 1:
A={1,2,3,4} and B={natural numbers less than 6}

Option 2:
A={prime numbers less than 6} and B={prime factors of 30}

Option 3:
A={0} and B={x:x>15 and x<5}

Option 4:
A={5} and B={x: }

Correct Answer:
A={prime numbers less than 6} and B={prime factors of 30}

Solution:
As we learnt

EQUAL SETS -

Two sets A and B are said to be equal iff they have exactly the same elements and we write A = B.
Otherwise, the sets are said to be unequal and we write A ≠ B.
- wherein

eg. A= {3,2,1,4} and B= {2,3,4,1}

Prime factors of 30 are 2,3,5 which are all prime numbers less than 6.

While in (4) which is not same as x=5.

Incorrect
Q. 4
If U = {1, 3, 5, 7, 9, 11, 13}, then which of the following is subsets of U?

Your Answer:

{2,4,6,8}

Option 1:
{5,11,1}

Option 2:
{0,6,9}

Option 3:
{2,4,6,8}

Option 4:
{2,1,4,5,6}

Correct Answer:
{5,11,1}

Solution:
As we have learnt in

Subsets, Proper Subset, Improper Subset, Intervals -

A set A is said to be a subset of a set B if all elements of A present in B.


It is represented by ⊂ .

A = {1, 2, 3} , B = {1, 2, 3, 4, 5} , C = {3, 2, 1}

A is a subset of B or A ⊂ B

C is a subset of A or C ⊂ A

we can see in option every element of option (a) belongs to U while in other option all elements of
the set do not belong to U, so (a) is the only subset of U

Correct
Q. 5
For function from

The Co - domain of function is

Your Answer:

Option 1:

Option 2:

Option 3:
R
Option 4:

Correct Answer:
R

Solution:
As we learned

Co - Domain of function -

All possible outcomes for the function f(x) is known as co - domain unless not specified in question.

When we write f : R

Co - domain = R ; Domain = R.

Incorrect
Q. 6
The graph of the function is symmetrical about the line ,then

Your Answer:

Option 1:

Option 2:

Option 3:

Option 4:
Correct Answer:

Solution:
As we learnt in

Even Function -

- wherein

Symmetric about Y - axis

Since a graph symmetric about y-axis

means x = 0 then it is even function and f(-x) = f(x)

f(0 - x) = f(0 + x) (b < z it is symmetric about v = 0 )

But in question it is symmetric about x = 2

then f(2-x) = f(2+x)

Correct option is 2.

Q. 7

If f(x) and g(x) are two functions . are domains and range of f(x) , g(x) . Then
which of the following is the there if fog exists?

Option 1:

Option 2:

Option 3:
Option 4:

Correct Answer:

Solution:
As we have learned

Condition for composite function -

go f is defined only if for each is an element of g.

- wherein

The range of f must be a subset of the domain of g.

For fog to exsits , Range of inner function is a subset of domain of outter function

Q. 8

Which of the following binary operations are not commutative?

Option 1:
a*b=a+b

Option 2:
a*b=ab

Option 3:
a*b*c=a+b+c

Option 4:
a*b*c=ab+c

Correct Answer:
a*b*c=ab+c

Solution:
As we learnt
Commutative Binary operation -

a*b=b*a

- wherein

A binary operation * on a set A is a function * : A × A → A. It is called commutative, if a * b = b * a,


for every a, b ∈ A.

This operator is not commutative.

Incorrect
Q. 9
Which of the following functions are injective functions ?

Your Answer:
Option 1:
Option 2:
Option 3:
Option 4:
none of these.

Correct Answer:
none of these.

Solution:
As we learned

One - One or Injective function -

A function in which every element of range of function corresponds to exactly one elements.

- wherein

A line parallel to x - axis cut the curve at most one point.

All of the following functions are many one functions, since if there is a line drawn parallel x - axis. It
cuts at multiple points.

Q. 10

if and

Option 1:
is an empty set.

Option 2:
contains exactly one element.

Option 3:
contains exactly two elements.

Option 4:
contains more than two elements.
Correct Answer:
contains exactly two elements.

Solution:
As we learnt in

FUNCTIONS -

A relation f from a set A to a set B is said to be a function if every element of set A has one and only one
image in set B.

Put at the place of

(i)

(ii)

Multiplying (i) by 2
and

Correct option is 3.

Correct
Q. 11
Then which of the following is
true?

Your Answer:

Q=R

Option 1:
P=R

Option 2:
Q=R

Option 3:
Q=S

Option 4:
P=Q

Correct Answer:
Q=R

Solution:
As we learnt

COMMUTATIVE PROPERTY OF INTERSECTION -

A∩B=B∩A

According to property

A∩B=B∩A

Q=R

Incorrect
Q. 12
If then is a subset of

Your Answer:

Option 1:

Option 2:

Option 3:

Option 4:
Correct Answer:

Solution:
As we have learnt,

Theorem of Cartesian Product -

As explained in the property,

Q. 13

Which of the following binary operation is not associative?

Option 1:
Addition

Option 2:
Subtraction

Option 3:
Multiplication

Option 4:
Union of 3 sets

Correct Answer:
Subtraction

Solution:
As we learnt

Associative Binary operation -


(a * b) * c = a * (b * c)

- wherein

A binary operation * on a set A is a function * : A × A → A, such that, A × A → A is said to be


associative, if(a * b) * c = a * (b * c), for every a, b, c ∈ A

Subtraction is not associative since (a-b)-c a-(b-c)

Q. 14

Which of the following relations is antisymmetric ?

Option 1:

Option 2:

Option 3:

Option 4:
none of these

Correct Answer:
none of these

Solution:
As we learned

Anti - Symmetric Relation -

Here, R is relation in A
-

in option (3)

since (1,2) is present (2,1) should not be present.

Incorrect
Q. 15
Which of the following is not a set?

Your Answer:

The collection of all students with names starting from 'A'.

Option 1:
The collection of all licensed drives in the class

Option 2:
The collection of students in class above the age 15.

Option 3:
The collection of all the young students in the class.

Option 4:
The collection of all students with names starting from 'A'.

Correct Answer:
The collection of all the young students in the class.

Solution:
As we learnt

SETS -

A set is a well-defined collection of objects. There are two methods of representing a set -Roster or
Tabular form & Set-builder form.

- wherein
eg. A={1,2,3}

"The collection of young students" is not a set because the term young is not well defined.

Incorrect
Q. 16
Which of the following function is an even function ?

Your Answer:

Option 1:

Option 2:

Option 3:

Option 4:

Correct Answer:

Solution:
As we have learned

Even Function -

- wherein

Symmetric about Y - axis


If f(x)= cos x

then f(-x)= cos (-x)= cos x

Correct
Q. 17
Given n(U)=150,n(A)=60,n(B)=50 and . Find the shaded portion.
Your Answer:

40

Option 1:
20

Option 2:
40

Option 3:
60

Option 4:
80

Correct Answer:
40

Solution:
As we learnt

Number of Element in Union A & B -

If (A ∩ B) = φ,then n (A ∪ B) = n (A) + n (B)

- wherein

Given A and B be any finite sets. then Number of Elements in intersection A & B is given by this formula.

n (A ∪ B) = n (A) + n (B)- n(A ∩ B)

n (A ∪ B) = 60+50-0=110

Thus Shaded region = n(U)-n (A ∪ B)=150-110=40


Correct
Q. 18
If set A={1,3,5} and B={3,5,7}. Alse and . Then which of the following is
true?

Your Answer:

Option 1:

Option 2:

Option 3:

Option 4:

Correct Answer:

Solution:
As we learnt

COMMUTATIVE PROPERTY OF UNION -

A∪B=B∪A

For two set A and B

A ∪ B = B ∪ A Because of the commutative property of th given sets.


Q. 19

Let L denote the set of all the straight lines in a plane. Let a relation R be defined
by . Then R is

Option 1:
Reflexive

Option 2:
Symmetric

Option 3:
Transitive

Option 4:
none of these

Correct Answer:
Symmetric

Solution:
As we learnt

TRANSITIVE RELATION -

A relation R in A is said to be transitive, if a R b and b R c ⇒ a R c ∀ a,b,c ∈ A

Here,

Hence R is symmetric.

But it is not transitive.

Q. 20
Consider the following two binary relations on the set

and

Then :

Option 1:
both R1 and R2 are not symmetric.

Option 2:
R1 is not symmetric but it is transitive.

Option 3:
R2 is symmetric but it is not transitive.

Option 4:
both R1 and R2 are transitive.

Correct Answer:
R2 is symmetric but it is not transitive.

Solution:
As we learned

REFLEXIVE RELATION -

A relation R in A is said to be reflexive, if a R a ,∀ a ∈ A

SYMMETRIC RELATION -

A relation R in A is said to be symmetric, if a R b ⇒ b R a,∀ a,b ∈ A

-
TRANSITIVE RELATION -

A relation R in A is said to be transitive, if a R b and b R c ⇒ a R c ∀ a,b,c ∈ A

R1 is reflexive since (b,b) is present.

(c,a) and (a,c) are present ;

(a,b) is here but (b,a). So R1 is not symmetric.

Also, it is not transitive.

similarlly, R2 is symmetric and not transitive.

Q. 21

If n(A) = 4 and n(B) = 4 . Then how many bijective functions can be formed from A to B?

Correct Answer:
24

Solution:
As we have learned

Number of Bijective Function -


If A & B are Bijective then

So number of Bijective functions= m!

number of bijective function = 4!

Q. 22

In a class of 140 students numbered 1 to 140, all even numbered students opted Mathematics
course, those whose number is divisible by 3 opted Physics course and those whose number is
divisible by 5 opted Chemistry course. Then the number of students who did not opt for any of the
three courses is;

Correct Answer:
38

Solution:

Number of Elements in Union A , B & C -

n (A ∪ B ∪ C) = n (A) + n (B) + n (C) – n (A ∩ B) – n (A ∩ C) – n (B ∩ C) + n (A ∩ B ∩ C)

- wherein

Given A, B and C be any finite sets. then Number of Elements in union A , B & C is given by this formula.

From the concept,

Let n(M) = no. of students opted maths = 70

n(P) = student opted physics = 40

n(C) = student opted chemistry = 28


n(M ∩ P) = number of students opted for physics and maths = 23

n(M ∩ C) = number of students opted for maths and chemistry = 14

n(P ∩ C) = number of students opted for physics and chemistry = 9

n(M ∩ P ∩ C) = number of students opted for all three students = 4

So the total number of students who opted for at least one subject =

n(M ⋃ P ⋃ C) = n(M) + n(P) + n(C) - n(M ∩ P) - n(M ∩ C) - n(P ∩ C) + n(M ∩ P ∩ C)

So putting the values, we have

n(M ⋃ P ⋃ C) = 70+46+28-23-14-9+4 = 102

Hence total no. of students who not adopted for any course = total number of students -total number
of students who opted for at least one course = 140 - 102 = 38

Incorrect
Q. 23
If a set has 20 elements.How many ordered pairs having distinct elements can be formed?

Your Answer:10

Correct Answer:
190

Solution:
As we learnt

ORDERED PAIR -

A pair of elements grouped together in a particular order.

- wherein

eg. (a,b),
The number of ordered pairs = =190

Q. 24

Greatest integer less than or equal to the number is

Correct Answer:
2

Solution:
As we have learnt in

Q. 25

If n(A) = 5 and n(B) = 3 . Find the number of onto function A to B

Correct Answer:
150

Solution:
As we have learned

Number of Onto function -

&

Number of onto functions

-
= 150

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