Documente Academic
Documente Profesional
Documente Cultură
Advantages of Low
Volatile Coals for
PCI
Report No: 970005
Date: 2 August, 1997
Revision: May, 2000
Executive Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ii
Economic Impact . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
This report was prepared by Energy Tactics -trading name of CoalTech Pty Ltd. . Energy Tactics or any of its sub-
contrac tors do no t: a) ma ke an y warr anty, exp ressed or im plied, with respect to th e accu racy, co mpleten ess, or usefu lness
of the information contained in this re port, or that the u se of any informa tion, appar atus, metho d, or process disclosed in
this report may not infringe privately owned rights; or b) assum e any liabilities with respect to use of, or for damages
resulting from th e use of, any inform ation, appa ratus, meth od, or process disclosed in th is report.
Executive Summary
Pulverised coal injection has become a standard practice in most major steelworks with
injection rates varying from 100 to over 200 kg/tHM. The injection rates and number of
installations are expected to continue to increase resulting in a coal demand for injection
reaching around 55 million tonnes per year by the year 2005.
A major factor limiting PCI r ates, while maintaining stable blast furnace operation, is the
permeability of the coke bed surrounding the raceway. As injection rates increase the level
of unburnt char entering the raceway and the blast momentum both incr ease, leading to:
C changes in the size of the raceway,
C mechanical degradation of coke in the raceway,
C reduction of permeability of the coke surrounding the raceway, and
C changes in temperature distribution in the raceway.
All of these influence raceway stability and the distribution of gas flow through the lower
sections of the blast furnace, both of which impact on furnace stability and therefore blast
furnace productivity.
A general overview was developed showing how the volatile content of the injected coals
can impact on char formation, blast momentum and generation of coke fines in the raceway.
Although, this overview was based on the idealised properties of coal and individual coals
will vary from these properties. This overview does however highlight two important
aspects of how coal properties can influence blast furnace performance. These are:
C Coke replacement ratio increases with the dry ash free carbon content of the coal
up to approximately dry ash free carbon content of 91% where the replacement
ratio seems to level out.
C The blast momentum decreases with increasing carbon content of the coal when the
dry ash free carbon content is greater than 85%; the blast momentum directly
influences the raceway depth and coke degradation within the raceway.
At high injection rates and injecting a coal with a carbon content less tha n 85% daf, any
fluctuations in the coal rate delivered to a tuyere will result in fluctuations in the raceway
depth and the generation of coke fines. Fluctuations in raceway depth and the generation
rate of fines will reduce blast furnace stability and therefore pr oductivity. By choosing a
coal with a dry ash free carbon content greater than sa y 88%, the impact of variations in
coal feed rate on blast furnace stability will be reduced and furnace productivity will be
maintained.
The main economic benefit of coal injection is the replacement of high cost coking coals.
The coke replacement ratio of a coal can be shown to be dependent on the energy or carbon
content of that coal, with low volatile coals having the highest coke replacement ratio. This
is shown by steelworks tending to buy PCI coals based on cents per percent carbon which is
similar the purchase of iron at cents per % iron. At high injection rates and using low
volatile coals for injection the saving in total coal costs will be about US$8 per tonne of hot
metal produced.
Low volatile coals also generally are softer coa ls with Hardgrove Grindability Index around
80. As these coals are ver y easy to mill there will be sa vings fr om reduced mill power
consumption for a given coal throughput.
Low volatile coal also allows the mill capacity to be increased up to 40% above that of a 50
Hardgrove Grindability Index coal, thus allowing the steelworks to increase injection rates
without further capital expenditure in further milling capacity.
Pulverised Coal Injection (PCI) Technology
The past improvements in productivity, coke consumption and fuel use within the
steelworks have been hastened due to the steel industry being a very competitive global
industry. It can be expected that further improvements in these areas of operations to reduce
costs will continue, but the technological change within the integrated steelworks that is
having the largest impact on the costs is that of pulverised coal injection (PCI). It is for this
reason that PCI has become a standard practice in most major steelworks with injection
rates varying from 100 to over 200 kg/tHM. The injection rates and number of installations
are expected to continue to increase.
The use of PCI assists blast furnace operators through benefits such as:
C lower costs through the substitution for higher cost coking coals and energy
savings;
C marked increase in productivity;
C extended coke oven life due to decreased coke demand, and;
C consistent quality of hot metal with a relatively low silicon content.
Most injection systems use coal ground to appr oximately 75% minus 75µm, as coal milling
systems for this size are commonly used in power plants for electricity generation. A
granulated coal injection system has been developed by British Steel, though this system has
not been widely accepted by the international steel community. The main elements of a PCI
system are:
C a mill to pulverise the coal to around 70% minus 75µm. The mill is normally
swept with hot gases (low in oxygen) to dry and transport the coal to the storage
bins;
C a distribution system which meters and transports the coal from the storage hoppers
to the blast furnace and evenly distributes the coal to the 15 to 38 tuyeres,
depending on the size of the furnace.
Coal is injected directly into the raceway region through the tuyeres with the hot blast. The
hot blast can be enriched with oxygen to improve combustion efficiency or furnace stability.
Uniform distribution of the coal to each tuyere is important for effective operation of the
furnace and has been addressed by all suppliers of PCI systems.
The coal absor bs hea t, devolatilizes, the volatile matter combusts in approximate 10 ms
before exiting the blow pipe and the tuyere. The coal char starts to combust as soon as it
leaves the tuyere. At low injection rates the distance from the point of injection to the exit
of the tuyere is great enough to ensure almost complete combustion of the coal. At high
injection rates the combustion of the coal is not completed and some unburnt char enters the
coke bed. Some operators have decreased the distance from the injection point to the end of
the tuyere to reduce the pressure drop through the tuyere or to reduce ash build-up on the
inside surface of the tuyere (Yoshida and others, 1991). Figure 1 shows the important zones
around the tuyere.
The influence of the design of the lance on combustion of the coal has been investigated by
Thyssen Stahl (Joksch and others, 1993) and Japanese researchers (Mati and others, 1996).
They found that coaxial lances improve the mixing of coal and oxygen leading to better
combustion. Other means of enhancing combustion efficiency such as fuel blending,
Figure 2 Comparison of PCI rate and corrected coke rate for Japanese and European
blast furnaces (Holcombe & Coin, 1993)
Coke
kg/tHM 297 287 272 294 308
Consumption
Coal
kg/tHM 197 194 212 202 188
Consumption
Total Fuel
kg/tHM 494 481 484 496 496
Consumption
Sinter % 61 81 49 75 86.5
Volatile Matter % 20 10 35 22 35
Blast
°C 1230 1189 1183 1125 1185
Temp erature
Oxygen
Enrichment of % 3.3 2.2 5.6 8 3.1
Blast
Top Gas
°C 160 187 154 122 184
Temp erature
Table 2 : Changes in RAFT an d Replaceme nt Ratio with co al types (Hunty and others, 199 0).
Coal Type C/H C/O kg injected per Rep lacem ent Rat io
10 0 K cha nge in
RAFT
relationship between the calorific value of the injected coal and replacement ratio which is
given in Figure 3. More recently Brouwer and Toxopeus (1991) in summarising the PCI
operating results at Hoogovens IJmuiden blast furnace derived a relationship between
replacement ra tio and the properties of the coal injected. This relationship, based on the
dry carbon, hydrogen and ash content , is given below:
(1)
Figure 3 Variation in replacement ratio with the rank of the injected coals showing
correlations based on actual (*) and theoretical (**).
properties of the injected coal but also can be influence by other factors such as oxygen
enrichment. They showed that with oxygen enrichment the replacement ratio chnaged to
0.99 from 0.88.
Coal Ash Chemistry
Ash chemistry is important for PCI coals in terms of furnace operation and iron product
quality. Generally the same considerations apply as for coke ash chemistry.
Snyder and Fletcher (1991), based on experience at Armco Steel, suggested that 5.5
kilograms of extr a carbon must be injected to compensate for every kilogram of extra ash,
and it can be deduced that this would correspond to a reduction in replacement ratio by
approximately 0.05 per 1% absolute increase in ash. These authors acknowledged that this
carbon penalty was considerably higher than most would expect. Experience at British
Steel (Maldonado & others, 1985) on the other hand suggested that there was no carbon
penalty for extra ash, and allowing that this extra ash is inert there would therefore be a
reduction in replacement ratio of approximately 0.01.
High levels of sodium or potassium can cause coke degradation, while sulphur or
phosphorus impact on hot metal quality. Sulphur can be removed from the iron in the blast
furnace by the introduction of extra limestone flux, while phosphorus is removed in
processing of the product subsequent to the blast furnace, but in either case there are costs
involved. Absolute limits are not normally specified on the concentrations of these elements
in the ash, and a blast furnace operator would normally take into consideration the
combined quantities in coal and coke.
A low ash fusion temperature is favoura ble for slag fusibility, however the majority of
operators have favoured high ash fusion temperatures to avoid deposition of the ash in the
blowpipe or tuyere. There appears to be a trend for coal injection lances to be positioned
Combustibility
The role of PCI has traditionally been viewed as providing heat to drive the blast furnace
reactions. At moderate PCI rates, up to around 160 kg/tHM, there is sufficient oxygen in
the blast to consume all of the coal in the initial combustion reaction pr oducing carbon
dioxide and water. However, the coke in and around the raceway competes for the oxygen
and hence there may be coal remaining after the oxygen is consumed. The dust formed by
this unburnt char may lower the permeability of the coke bed to the movement of gases and
liquids, or the entrained dust containing unused carbon may exit the BF with the top gas.
This perceived need for rapid combustion of the injected coal has prompted blast furnace
operators in the past to pulverise the coal very fine and to choose highly reactive coals. It
is now recognised that complete combustion of the coal is not possible at high PCI rates,
and some operators are introducing practices which are counter-productive to good
burnout, such as the use of coarser pulverised coal (Kuwano, 1993) or of GCI (Jukes,
1993) to reduce milling costs and improve handling behaviour.
Based on the widely accepted assumption that the coal devolatilises in the tuyere then the
amount of char that enters the raceway depends on the amount of volatiles that are released
at the high temperature within the blow pipe. Several researchers have examined the
volatile release at high temperatures with most finding that the amount of volatiles released
depends on the temperature and the rank of the coal and var ies between 1.2 to 2.0 times the
volatile content as measured by the standard ASTM method. The ratio between the actual
volatiles and the ASTM volatiles is usually termed the “Q factor”.
Figure 4 summarizes the findings of some researchers relating the “Q factor ” to the rank of
the coal. Researchers evaluating the characteristics of low volatile coals (T romp and
others, 1992 & Wall and others, 1987) found the “Q factor” increased significantly with
the rank of the coal. This sharp increase in the “Q factor” with higher rank coals may be
due to some combustion of the char occurring in the favourable conditions of entrained
flow test furnances.
Standard correlations (Van Krevelen, 1961 & Callcott and others, 1990) relating specific
energy and volatile matter to carbon content of the coal were used in the construction of
Figure 4 and the best curves fitted to the data of the respective authors are given.
Soot Formation
The possibility of soot formation from injected coal was studied by de Lassat and others
(1990) through the recovery of pyrolysis products and separation of the char, mixed tars
and soot. T hey showed that the quantity of soot forming media produced at 1000 and
1200°C increases with the amount of volatile components up to a level of about 40%.
Although, it is expected that the soot yield will decrease for coals with a volatile content
greater than 30% daf, as a greater fraction of the volatile components released from the
coal are gases for these coals.
Based on the estimated volatile yield as determined by Tromp and others (1992) and
assuming 30% of the volatiles form soot then an estimate can be made of the char and soot
that enters the raceway. Figure 5 indicates how this cha r and soot will vary with the rank
of the coal.
Char Reactivity
Char reactivity does incr ease with the volatile content of the coal, however at the elevated
temperatures pertaining to char combustion in the raceway, chemical reactivity has very
little significance since combustion rates are limited by the rate of diffusion of oxygen to
the particle, and bur nout times depend more on particle size and oxygen concentration
(Field and others,1967). The particle size depends on the swelling and/or fracturing
behaviour of the char particles. This is supported by the work of Bachhofen and others
(1998) who found that the volatile matter of the injected coal had no influence on the extent
of coal conversion within the furnace.
Stanmore(1992) evaluated the impact of coal properties on the swelling characteristics and,
for the coals tested, he found that the particle diameter (dp ) could be related to the burnout
(u), the initial particle diameter (do ) and a swelling factor (") by the following equation:
(2)
Stanmore found that " increased linearly with increasing volatile content of the coal.
Using this relationship it can be shown that there is no significant swelling of the coal
particle in the early stages of combustion.
Therefore, since char combustion is diffusion controlled with a shor t residence time and
reduced oxygen level in the raceway, there will be no great differences in the rate of char
combustion for different coals. Steeghs and others (1994) using a coke filled test furnace
found for a low volatile coal approximately 10% less coal is combusted near the tuyere
than for a high volatile coal at the same injection rates. This agrees with the predicted char
and soot yields given in Figure 5.
(3)
Tamura and others cited their earlier work where, in a two-dimensional cold test rig, the
amount of coke fines increased sharply with raceway depth, see Figure 6. They postulated
that the sharp incr ease in -1mm fine coke was due to the increase in the amount and the
velocity of the coke circulating in the raceway, which in turn increases the frequency at
which coke particles collide and the energy involved in those collisions.
Figure 6 Effect of raceway depth on fine coke deposit near core surface,
(Tamura and others, 1991)
Blast velocity, and therefore ra ceway depth, depends on the tuyere diameter, blast volume,
blast temperature, blast pressure and the amount of the coal combusted within the tuyere.
The fraction of coal combusted within the raceway will be the volatile content of the coal,
after allowing for any soot formation, as the residence time within the raceway is
insufficient for any significant char or soot combustion to occur. The heat liberated from
the combustion of the volatiles can be approximated using the correlations developed by
Figure 8: Variation of coke fines with the rank of the coal injected
Figure 11: Variation in mill specific power with Hardgrove Grindability Index
(Bennett & Holcombe, 1994)
Blockages
The usual places where blockages occur in a PC I system are:
C in the injection lance where the coal enters the blow pipe, and
C the transport lines and storage bins.
Blockages that occur in the injection lance are due to the coal being heated to a temperature
where it can become sticky. A coal propensity to form these blockages can be related to the
Crucible Swelling Number of the coal. These problems ca n be overcome by ensuring the
temperature of the coal in the injection lance does not exceed 300°C by cooling the lance or
shortening the length of the lance that protrudes into the blow pipe.
Handling problems of pulverised coal both in bulk storage bins and pneumatic transport
systems can be related to some extent to the amount of very fine material and moisture in
the product.
The moisture content of pulverised coal mill product is normally assumed to be a fraction
of the inher ent moisture level of the coal. This implies that mill product moisture level
would be relatively independent of the total moisture in the mill feed coal, which is a
reasonable assumption provided the mill outlet temperature is able to be mainta ined at the
required value of around 70-90°C. Fur ther drying of the coal has been reported to occur in
the storage tanks when these are swept with inert gas to prevent fires. Based on these
considerations, moisture should not be a cause for poor handling of pulverised coal.
In colder climates where there may be condensation on the inside of bin walls, external
heaters and/or insulation may be required to reduce the likelihood of bin blockages. This is
especially important when the hot gas fr om the mill enters the bin.
In bulk storage bins the Ha usner Ratio, the ratio between the compacted and uncompacted
bulk density, is used to indicate possible onset of bridging in bins. The Hausner Ratio does
increase when the amount of minus 5.8 µm material increases above around 12%.
Studies were carried out into the dense and dilute phase handling characteristics of PCI
coals in a pilot scale loop at Wollongong University (Holcombe & others, 1994). The
pressure drop along the pipe versus the air flow rate for a given solids flow rate typically
Figure 12: Savings in total coal costs from the replacement of coking coals