Indus Group of Colleges

CHEMISTRY -HSSC-II
1st term Exam , 2018
Time Allowed: 2:35 Hours Total Marks Section B C & D: 34
Note: Sections 'B' , 'C' and D comprise of questions which are to be answered on the separately provided answer book. Use supplementary answer sheet i.e.
sheet-B if required. Write your answer neatly and legibly.

SECTION –B(Marks 12)

Q 2. Attempt any FOUR parts All parts carry equal marks (7×3=21)
i. What are alicyclic compounds?
ii. How nitogen can be detected in organic compounds?
iii. Define following.
a. Steric effect b. inductive effect
iv. When 2-methyl propene react with HBr what are possible products. Which one is not formed and why?
v. Define following.
a. conjugated alkene b. cumulated alkene c. isolated alkene
vi. How dehydration of alcohol give rise to alkene.Also mention reactivity order of different alcohols.
SECTION – C(Marks 12)
Q 3. Attempt any FOUR parts All parts carry equal marks (4×3=12)
i. How optical isomerism arises?
ii. Draw all possible stereoisomers of tartaric acid.Mention the optically active ones.
iii. what is Markovnikov’s rule. Explain with example?
iv. Why single bond in cycloalkane has restricted rotation and what are its consequences?
v. what are terminal alkynes. why they show acidic charachter?
SECTION –D ( Marks 14 )
Attempt any TWO questions in detail
Q.4. a. Draw structures of the following compounds 4
i. 1-pentene-4-yne ii. 2-methyl-1,3-butadiene
iii. 3-methyl-1-butene iv. acetylene
b. How to get sterospecefic alkene from alkyne. 3

Q.5. a. Describe isomerism in organic compounds in detail. 5

b. Write the free radical substitution reaction mechanism in alkanes. 3

Q.6 a. How alkenes react with following.

i. Bromine ii. Ozone iii. Epoxidation iv. Hydrogen 4
b. Define following terms.
i. Enantiomer ii. Recamic mixture iii. Plane of symmetry 4
 Indus Group of Colleges
Roll No/Sec. Name of Candidate.____________

CHEMISTRY -HSSC-II Group B

Pre-Board Exam, 2018
SECTION -A ( Marks 17)
Time Allowed: 25Minutes
Note: Section-A is compulsory and comprises page 1 All parts of this section are to be answered on OMR sheet . It should be completed in the first 25
minutes and handed over to the Centre Superintendent. Cutting/overwriting is not allowed. Do not use lead pencil.
Q 1: Fill the correct option a/b/c/d in OMR sheet. Each part carry one mark (8x1=08)
i. Double bond is formed as a result of
a). addition reaction b). substitution reaction
c). elimination reaction d). none of them
ii. Whuch object has no plane of symmetry
a). hand b). shoe
c). foot d). none of them
iii. Alkenes react with aq.solution of halogen acid to form alkyl halides.The order of reactivity of halogen acid is
a). HF<HCl<HBr<HI b). HI<HF>HBr>HCl
c). HI>HBr>HCl d). both a and c
iv. Which of the following compounds reacts with HBr obeying Markownikov’s rule?
a) Ethene b). Propene
c) Trans-2-butene d) Cis-2-butene
v. Catalyst used for dehydration of alcohol is
a). Al2O3 b). H2SO4
c). both a & b d).CCl4
vi. Radical substitution reaction occurs in presence of
a). heat b). uv light
c). both a & b d). none of these
vii. which is the correct order of stability
a). alkene>alkane>alkynes b). alkyne> alkane > alkene
c). alkane>alkyne>alkene d). none of them
viii. Hydration of alkene gives
a) a halo alkane b) an alcohol
c) an alkyne d) Both b and c