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Index
Mathematical formulation
• Governing equations:
– Conservation of mass ∇ ⋅ ( ρ u) = 0
– Conservation of momentum
⎣ (
∇ ⋅ ( ρ u ⊗ u) = −∇P + ∇ ⋅ ⎡⎢ μ ∇u + ( ∇u ) ⎤⎥
Τ
⎦ )
– Conservation of energy ρ c p u ⋅∇T = k ∇ 2T
σΩ (T )
,
– Dynamic viscosity RspecificT
– Thermal conductivity 15 R ⎡ 4 c p M 1 ⎤ R
k= μ⎢ + ⎥ , cp = .
– Specific heat 4 M ⎣15 R 3⎦ M
Nomenclature:
u, v, w = component velocity C1ε = 1.44
μt= turbulent viscosity C2ε = 1.92
k = turbulent kinetic energy Cμ = 0.09
ε = turbulent dissipation
3
σk = 1.0
G = turbulent generation rate σε = 1.0
Mathematical Formulation
• Nusselt number calculation
1
Tmean =
VAc ∫ TudA ,
Ac
c
1
V=
Ac ∫ udA ,
Ac
c
Q&
h= ,
Tsurface − Tmean
hD
Nu =
k
Nomenclature:
Tmean = mixed mean temperature Nu = Nusselt number
Tsurface = surface temperature D = Hydraulic diameter
Ac = cross-section area
h k = Conductive heat transfer 4
= convective heat transfer
Q& = heat flux
V = mixed mean velocity
Geometry
• The flow configuration considered is full tube
flow inside square duct, as illustrated in figure
Numerics
6
LAMINAR FLOW
7
Boundary condition
Air Water
• Case 1: Constant heat flux at • Case 3: Constant heat flux at
wall wall
– Inlet: air velocity = 1.6 m/s; T – Inlet: water velocity = 0.1 m/s;
air = 25 °C. T water = 25 °C.
– Wall: no-slip; Q = 30 watt/m2. – Wall: no-slip; Q = 2870
– Outlet: Pout = 1 atm; ∇⋅Q=0. watt/m2.
– Re ≈ 1000. – Outlet: Pout = 1 atm; ∇⋅Q=0.
• Case 2: Constant wall – Re ≈ 1000.
temperature • Case 4: Constant wall
– Inlet: air velocity = 1.6 m/s; T temperature
air = 25 °C. – Inlet: water velocity = 0.1 m/s;
– Wall: no-slip; T wall = 50 °C. T water = 25 °C.
– Outlet: Pout = 1 atm; ∇⋅Q=0. – Wall: no-slip; T wall = 50 °C.
– Re ≈ 1000. – Outlet: Pout = 1 atm; ∇⋅Q=0.
– Re ≈ 1000.
8
Velocity in the middle channel
Air (Case 1)
Water (Case 3)
11
Air (Case 2)
Water (Case 4)
12
Nusselt Number
15
Boundary condition
Air Water
• Case 1: Constant heat flux at • Case 3: Constant heat flux at
wall wall
– Inlet: air velocity = 30 m/s; T – Inlet: water velocity = 2 m/s; T
air = 25 °C. water = 25 °C.
– Wall: no-slip; Q = 497 watt/m2. – Wall: no-slip; Q = 170370
– Outlet: Pout = 1 atm; ∇⋅Q=0. watt/m2.
– Re ≈ 20000. – Outlet: Pout = 1 atm; ∇⋅Q=0.
• Case 2: Constant wall – Re ≈ 20000.
temperature • Case 4: Constant wall
– Inlet: air velocity = 30 m/s; T temperature
air = 25 °C. – Inlet: water velocity = 2 m/s; T
– Wall: no-slip; T wall = 50 °C. water = 25 °C.
– Outlet: Pout = 1 atm; ∇⋅Q=0. – Wall: no-slip; T wall = 50 °C.
– Re ≈ 20000. – Outlet: Pout = 1 atm; ∇⋅Q=0.
– Re ≈ 20000.
16
Velocity in the middle channel
17
Air (Cases 1)
Water (Cases 3)
19
Air (Cases 2)
Water (Cases 4)
20
Nusselt Number
23
Boundary condition
Air Water
• Case 1: Constant heat flux at • Case 3: Constant heat flux at
wall wall
– Inlet: air velocity = 80 m/s; T – Inlet: water velocity = 6 m/s; T
air = 25 °C. water = 25 °C.
– Wall: no-slip; Q = 1272 – Wall: no-slip; Q = 433879
watt/m2. watt/m2.
– Outlet: Pout = 1 atm; ∇⋅Q=0. – Outlet: Pout = 1 atm; ∇⋅Q=0.
– Re ≈ 60000. – Re ≈ 60000.
• Case 2: Constant wall • Case 4: Constant wall
temperature temperature
– Inlet: air velocity = 80 m/s; T – Inlet: water velocity = 6 m/s; T
air = 25 °C. water = 25 °C.
– Wall: no-slip; T wall = 50 °C. – Wall: no-slip; T wall = 50 °C.
– Outlet: Pout = 1 atm; ∇⋅Q=0. – Outlet: Pout = 1 atm; ∇⋅Q=0.
– Re ≈ 60000. – Re ≈ 60000.
24
Velocity in the middle channel
25
Air (Cases 1)
Water (Cases 3)
27
Air (Cases 2)
Water (Cases 4)
28
Nusselt Number
32
Boundary conditions-Variable T,Q
Air
• Constant heat flux at wall
– Inlet: air velocity = 1.6 m/s; T
air = 25 °C.
– Wall: no-slip; Q = 30 watt/m2.
– Outlet: Pout = 1 atm; ∇⋅Q=0.
– Re ≈ 1000.
• Constant wall temperature
– Inlet: air velocity = 1.6 m/s; T
air = 25 °C.
– Wall: no-slip; T wall = 50 °C.
– Outlet: Pout = 1 atm; ∇⋅Q=0.
– Re ≈ 1000.
33
Temperature distribution
34
Temperature distribution
35
• Case 1: Heating
– Inlet: air velocity = 1.6 m/s; T air = 25 °C.
– Wall: no-slip; T wall = 50 °C, 100 °C, 200 °C.
– Outlet: Pout = 1 atm; ∇⋅Q=0.
– Re ≈ 1000.
• Case 2: Cooling
– Inlet: air velocity = 1.6 m/s; T air = 50 °C, 100 °C,
200 °C.
– Wall: no-slip; T wall = 25 °C.
– Outlet: Pout = 1 atm; ∇⋅Q=0.
– Re ≈ 1000.
37
Heating Cooling
38
LAMINAR FLOW WITH BOUYANCY
39
Boundary condition
Laminar flow (Air)
• Boundary conditions
– Inlet: air velocity = 0.15 m/s;
T air = 25 °C.
– Wall: no-slip; T wall = 200 °C.
– Outlet: Pout = 1 atm; ∇⋅Q=0.
– Re ≈ 100.
• Case 1: No gravity force
• Case 2: Horizontal placement
• Case 3: Tilted 45°
• Case 4: Vertical placement
• Gravity force is applied for
case 2, 3 and 4.
40
Velocity at entry region (z=2.5 cm)
Case 1 Case 2
41
Case 3 Case 4
Case 1 Case 2
42
Case 3 Case 4
Velocity at z= first 10 cm
Case 1
Case 2
Case 3
Case 4
43
Temperature at z= first 10 cm
Case 1
Case 2
Case 3
Case 4
44
Nusselt number
45
TAPERED DUCT 46
Boundary condition
Laminar flow (Air)
Case 1: Divergent duct
• Inlet: air velocity = 16
m/s;
T air = 25 °C.
• Wall: no-slip; T wall = 50
°C.
• Outlet: Pout = 1 atm;
∇⋅Q=0.
• Re ≈ 1000.
Case 2: Convergent duct
• Inlet: air velocity = 0.16
m/s; T air = 25 °C.
• Wall: no-slip; T wall = 50
°C.
• Outlet: Pout = 1 atm;
∇⋅Q=0. 47
• Re ≈ 1000.
48
Temperature in the middle channel
49
Nusselt number
50
POWER LAW FLUID
51
Boundary condition
Power law fluid Laminar flow (Air)
⎛ ∂u ⎞
n • Case 1 (Pseudoplastic n=0.5)
τ =K⎜ ⎟ – Inlet: air velocity = 1.6 m/s; T
⎝ ∂y ⎠
air = 25 °C.
where:
– Wall: no-slip; T wall = 50 °C.
K = flow consistency index (Pa s n )
– Outlet: Pout = 1 atm; ∇⋅Q=0.
∂u
= shear rate or the velocity gradient (s −1 )
∂y
• Case 2 (Dilatant n=1.5)
n = flow behaviour index
n −1
– Inlet: air velocity = 1.6 m/s; T
⎛ ∂u ⎞ air = 25 °C.
μeff = K ⎜ ⎟
⎝ ∂y ⎠ – Wall: no-slip; T wall = 50 °C.
μeff = apparent or effective viscosity (Pa s ) – Outlet: Pout = 1 atm; ∇⋅Q=0.
n Type of fluid
<1 Pseudoplastic
1 Newtonian
52
>1 Dilatant
Velocity in the middle channel
Pseudoplastic (Case1)
Dilatant (Case 2)
53
Pseudoplastic (Case1)
Dilatant (Case 2)
54
Nusselt number
55
PULSATING FLOW
56
Boundary condition
57
0s 0.05 s
0.1 s 0.15 s
58
Case 1 (frequency 5 Hz)
Temperature in the middle channel
0s 0.05 s
0.1 s 0.15 s
59
Case 1 (frequency 5 Hz)
0s 0.01 s
0.02 s 0.03 s
60
Case 2 (frequency 20 Hz)
Velocity in the middle channel
0.04 s 0.05 s
61
Case 2 (frequency 20 Hz)
0s 0.01 s
0.02 s 0.03 s
62
Case 2 (frequency 20 Hz)
Temperature in the middle channel
0.04 s 0.05 s
63
Case 2 (frequency 20 Hz)
64
Summary
• Flow inside square duct has been simulated for variety of
BCs and for buoyancy effect.
• Several cases - laminar and turbulent flow are
considered
• Cooling/heating, buoyancy effect, power law fluid,
tapered duct and pulsating inlet flow have also been
simulated; no analytical solution possible
• Heat transfer distributions are calculated
65
References
Guest lecturer
Jundika Candra Kurnia
Department of Mechanical Engineering
National University of Singapore
Outline
• Overview of drying
• Physical model
– Problem description
– Key assumptions
• Numerical methodology
• Selected results
– Case study
– Velocity
y contours
– Temperature contours
– Drying kinetics
• Summary
• Q&A 2
1
Overview
• Drying
– Widely known as the most common way to preserve food
– Essential operation in chemical, agricultural, biotechnology, food,
polymer ceramics,
polymer, ceramics pharmaceutical,
pharmaceutical pulp and paper
paper, mineral
processing and wood processing industries
– Involves simultaneous transport process
• Transport processes in drying:
– Mass transfer
– Heat transfer
– Flow
Occur simultaneously both internally and externally
• Induces deformation:
– Shrinkage
– Cracking
(Not modeled here) 3
2
Physical Model
An orifice nozzle is used in this study- Axisymmetric case
Physical model
The aforementioned condition can be brought into computational domain as follows
3
What phenomena occur during drying?
7
Transport mechanism of mass? Energy?
Physical model
Basic mechanisms
• moisture diffusion from the inner drying
substrate towards its surface,
surface where it
evaporates
• conductive heat transfer within the drying
substrate
• evaporation and convection of the vapor
from the surface of the drying substrate
into the drying air
• convection heat transfer from drying air to
the surface of the drying substrate 8
4
Why do we need assumptions?
What are the key assumptions?
Comment on validityy of assumptions?
p
Assumptions
In developing the mathematical model, several assumptions are
made- some for simplicity
• The drying substrate is compact and homogeneous with uniform
initial temperature and moisture content.
• Within the drying substrate, the diffusivity of water vapor is 100
times larger than the diffusivity of liquid water.
• The thermophysiscal properties of the drying substrate are
temperature and moisture content-dependent and isotropic (equal in
all directions).
• Variations in dependent variables in span wise direction are
negligible since width of the drying substrate is much larger than its
negligible,
height (reduction in dimensionality from three to two dimensions).
• The shape of the drying substrate remains constant. No shrinkage
or deformation is accounted for.
• Newtonian fluid
10
5
• How to translate these physical phenomena into
mathematical model?
• What conservation equations do we need to model
th physical
the h i l phenomena?
h ?
• Do we need more information?
11
Conservation equations
For drying substrate (chip) Transient term (time dependent)
Diffusion
• Conservation of
cl
mass: Dlbcl Kcl ,
t
– Liquid water
cv
– Water vapor Dvb cv Kcl ,
t Evaporation
Diffusion
Transient term (time dependent)
• Conservation of
energy Transient term (time dependence; heat capacity)
Conduction
T
b c pb kbT q
Cooling due to
evaporation
t 12
6
Conservation equation
For drying air (Impinging jet) unsteady case
u
• Momentum a
t
u u p u - a u ' ,
Pressure gradient
• Energy T
a c pa
t
uT ka T a c pa u ' T ' ,
• Mass
M off Advection/bulk motion Conduction Turbulent
T b l t
heating
cv
water vapor Dva cv u cv ,
t
Convection
Transient term (storage) 13
Diffusion
14
7
Turbulence model
• A turbulence model is a model which is used to approximates the
physical behavior of turbulent flows*
• Turbulence model are necessary in numerical simulation due to
impracticality in computing all scales of turbulent motion. Therefore,
approximate
i t methodsth d (turbulence
(t b l models)
d l ) are introduced
i t d d to
t simplify
i lif
and reduce computational cost.
• Reynolds averaging refers to the process of averaging a variable or
an equation in time. For example, if we have time dependent
variable , we can decompose this variable into an average part
and fluctuating part in the following way:
1
TT (t )dt , ' .
where T has to be long enough to phase out fluctuation part on (t).
• Aside from time averaging, Reynolds averaging also deals with
space averaging and Ensemble averaging**
*J.J. Bertin, J. Periaux, J. Ballmann, 1992, Advances in hypersonics v2: Modeling hypersonic flows, Birkhauser, Cambridge 15
**J. Sodja, 2007, Turbulence model in CFD, Ljubljana, Slovenia (http://www-f1.ijs.si/~rudi/sola/Turbulence-models-in-CFD.pdf)
Turbulence model
8
Turbulence model for impinging jet drying
Reynolds stress model (5 equations)
Rij
Cij Pij Dij ij ij ij
t
• Accumulation
A l ti Rij
ui'u 'j
t t
• Convective
Cij a ui' u 'j U
U j U i
• Production Pij Rim R jm
xm xm
• Rotation
ij 2k u 'j um' eikm ui' um' e jkm
k2
• Diffusion Dij t Rij with t C , C 0.09 and k 1.0
k
2
• Dissipation ij ij
3
2 2
• Pressure –strain ij C1 Rij k ij C2 Pij P ij
k 3 3
interaction with C1 1.8 and C2 0.6
To solve this model, k- turbulence model is required 17
Governing equations
Nomenclature:
u, v, w = component velocity C1 = 1.44
t= turbulent viscosity C2 = 1.92
k = turbulent kinetic energy C = 0.09 18
= turbulent dissipation k = 1.0
G = turbulent generation rate = 1.0
9
Constitutive relations
• Density air air 1.076 105 Tair2 1.039 102 Tair 3.326
• Dynamic viscosity of air air 5.211015 Tair3 4.077 1011Tair2 7.039 108 Tair 9.19 107
• Conductivity of air kair 4.084 1010 Tair3 4.519 107 Tair2 2.35 104 Tair 0.0147
• Specific heat of air c p , air 4.647 106 Tair3 4.837 103 Tair2 1.599Tair 1175
Constitutive relations
• Heat of wetting (heat to evaporate H w 8.207 106 X 4 4.000 106 X 3 6.161105 X 2
bound water) 2.368 104 X 1163 for 0.01 X 0.2
10
Constitutive relations
• Relation of moisture content to concentration of water inside substrate
w W b ,
X b ,ref 1 X
w ,
1 X 1 SbX
b ,ref X X 2
M w cw ,
1 SbX X SbX 2
b,ref
SbX 2 Sb 1 X 1
M w cw
X X ,
2
b,ref 2 b ,ref
Sb X Sb 1 X 1 0,
M w cw M wcw
can be solved analytically for X and by neglecting wrong root the solution is
b b 2 4ac
X ,
2a
where
b ,ref
a Sb ,
M wcw
b,ref
b Sb 1 ,
M w cw 21
c 1.
Correlations
Calculation of h, Nu, Nu distributions in impinging jets
• Local Nusselt number hx D jet
Nu ( x, t )
k fluid
along the target surface
• Time
Ti averaged
d llocall 1
t
t 0
Nuavg ( x) Nu ( x, t )dt
Nusselt number
x t
1 1
x 0 t 0
• Time averaged Nusselt Nuavg Nu ( x, t )dtdx
number 22
11
Nomenclature
cv concentration of water vapor [mol m-3] Dva diffusivity of vapor on the drying air [m2 s]
Dlb diffusivity of liquid inside the drying substrate [m2 s] μ dynamic viscosity of the drying air [Pa s]
Dvb diffusivity of vapor inside the drying substrate [m2 s] ρa density of the drying air [kg m-3]
T temperature [K] cpa specific heat of the drying air [J kg-1 K-1]
q cooling rate due to evaporation [W m-3] ka thermal conductivity of the drying air [W m-2 K-1]
K production of water vapor mass per unit volume Ea activation energy [kJ mol-1]
-3
ρb density of the drying substrate [kg m ] R universal gas constant [J K−1 mol−1]
cpb specific heat of the drying substrate [J kg-1 K-1] Ml molecular weight of water [kg kmol-1]
kb thermal
h l conductivity
d i i off the
h drying
d i substrate
b [W m-22 K-11] Δhhevap totall heat
h off evaporation k -11]
i [J kg
-1
u mean velocity [m s ] X moisture content (dry basis) [kg kg-1]
23
12
Boundary conditions and parameters
Inlet velocity for various cases • Parameters needed to solve
• Steady laminar jet the model are
– vin = 2 m s-1 b ,ref 1420 kg m 3 ,
• Pulsating
g laminar jjet Tin 45C ,
– vin = 1+1sin(2ft) m s-1
Ml 0.018 kg mol 1 ,
• Intermitent laminar jet
X0 4.6,
– vin= 2 m s-1(on),0 m s-1(off)
• Steady turbulent jet a ,45C 1.110 kg m 3 ,
– vin = 20 m s-1 a ,45C 1.934 105 kg m 1 s 1
• Pulsating turbulent jet
R 8.314 J K 1 mol 1 ,
– vin = 10+10sin(2ft)
10+10 i (2 ft) m s-11
• Intermitent laminar jet Ea 48.7 kJ mol 1 ,
– vin= 2 m s-1(on),0 m s-1(off) Sb 1.4
1
f Hz
120
25
Numerics
• Gambit: creating geometry, meshing,
labeling boundary condition
• Fluent: solver based on finite volume
method
– Domain is discretized onto a finite set of
control volumes (or cells).
– General conservation (transport)equations
for mass, momentum, energy, species, etc.
are solved on this set of control volumes.
t V
dV V dA dA S dV
A
A
V
Unsteady Convection Diffusion Generation
13
Numerics
Flow chart of computational fluid dynamics (CFD)*
27
*http://progdata.umflint.edu/MAZUMDER/Fluent/Intro%20Training/L-1%20Introduction%20to%20CFD.pdf
Numerics
14
SELECTED RESULTS
29
Contours of velocity
Laminar steady jet
30
15
Contours of temperature
Laminar steady jet
31
32
16
Moisture profile in substrate
33
17
Drying kinetics (5 mm substrate)
35
Conclusion
18
References
For Self-Study
38
19
Mass transport in a micro-
channel T-Junction with
coiled-base channel design
ME 6203 Mass Transport Guest Lecture
Guest lecturer
Agus Pulung SASMITO
Minerals Metals Materials Technology Center
National University of Singapore
2011
Outline
• Overview of micro-channel T-Junction
• Physical model
– Problem description
– Key assumptions
• Numerical methodology
• Selected results
• Mass transport enhancement
• Concluding remarks
2
Overview
• Micro-channel T-Junction
– Widely used in industry, especially pharmaceutical, for mixing
and reaction processes
– Relatively easy to control the reactions, especially for highly
exothermic reaction
– Involves simultaneous transport process
• Transport process in T-Junction:
– Momentum transfer
– Mass transfer
– Heat transfer
Occur simultaneously
• Main phenomena:
– Mixing
– Surface reactions
Micro-Channel T-Junction
• Passive mixing for various chemical reaction; it
does not require additional energy for mixing
processes
• Micro-channel T-Junction, however, has several
drawbacks
– Poor mixing, especially at short channel and high
Reynolds number
– High pressure drop due to impingement effect
• Various innovative designs are proposed to
improve mixing and reactions
– Coiled channel
– Channel with fins
4
– Impinging jet channel
Typical geometry
Example case of mixing and reaction of A typical micro-channel T-
methane oxidation in platinum surface junction is used to mix methane
and air; the channel surface is
O2 coated with catalyst (platinum)
N2 Inlet
T = 300K
Tin = 300 K
Vin ≈ Re 500
Pt surface; T 1290K
Micro-channel T-junction
CO L = 120 mm
h CO2
H2O h = 1 mm
Pt surface; T 1290K
Gas species: CH 4 , O 2 , H 2 , H 2 O,
CO 2 , HO 2 , N 2
Surface species: Pt(s), H(s), O(s),
CH4
H2 OH(s), H 2 O(s), H3 (s),
T = 300K CH 2 (s), CH(s), C(s),
L
CO(s), CO 2 (s)
Solid species: Pt(b) 5
Assumptions
In developing the mathematical model, several assumptions are
taken:
• The flow is steady-state, laminar, newtonian flow and
species mixture is follows ideal gas law.
• There are three types of species: gas, surface (site) and
solid species. The model treats chemical species
deposited on surfaces as distinct from the same
chemical species in the gas
• Thermo-physical properties of species mixture follows
mixing law of ideal gas with temperature dependent
effect.
• Gas phase reaction are closely coupled with surface
reactions.
8
• How to translate this physical phenomena into a
mathematical model?
• What conservation equations do we need to interpret
the physical phenomena?
Conservation equations
• Mass ∇ ⋅ ρu = 0
Compressible
flow
• Momentum viscous Effect of volume
dillatation
⎛
( ⎞
)
Inertia/net rate
2
∇ ⋅ ρ u ⊗ u = −∇p + ∇ ⋅ ⎜ ⎡ μ ∇u + ( ∇u ) ⎤ − μ ( ∇ ⋅ u ) I ⎟
T
Pressure ⎝⎣ ⎦ 3 ⎠
• Species gradient
∇ ⋅ ( ρ uωi ) = −∇ ⋅ ( ρ Di∇ωi ) + Ri
convective diffusive reaction
i: CH 4 , O 2 , H 2 , H 2 O, CO 2 , HO 2
• Energy
∇ ⋅ ( ρ cpuT ) = ∇ ⋅ ( keff ∇T ) + S temp
convective conductive Heat due to
reactions
Detailed reactions
• Theory: consider the rth wall surface reaction written in general forms
Ng Nb Ns Ng Nb Ns
∑ g Gi + ∑ b Bi + ∑ s Gi ←⎯
⎯⎯ → ∑ gi'',r Gi + ∑ bi'', r Bi + ∑ si'',r Gi
' Kr ' '
i ,r ⎯i ,r i ,r
i =1 i =1 i =1 i =1 i =1 i =1
where Gi, Bi, and Si represents the gas phase species, the solid species, and the
surface-adsorbed (or site) species, respectively. g’, b’, s’ are the stoichiometric
coefficients for each reactant species; g’’, b’’, and s’’ are the stoichiometric coefficients
for each product species; and Kr is the overallNreaction rate constant.
g
Rˆ = g '' − g ' ℜ
i ,gas i = 1, 2,3,..., N
i ,r i ,r r g
r =1
N rxn
Rˆi ,bulk = ∑ ( bi'',r − bi',r )ℜr i = 1, 2,3,..., N b
r =1
N rxn
Rˆi ,site = ∑ ( si'',r − si' ,r )ℜr i = 1, 2,3,..., N s
r =1
• Reaction rate constant is computed using Arrhenius expresion
k f , r = Ar T β r e − Er / RT
Constitutive relations
• Mixture density
ρ = pM / RT
• Mean molecular mass
( )
−1
M = ωCH4 / M CH4 + ωH2 / M H2 + ωO2 / M O2 + ωH2O / M H2O + ωOH / M OH + ωCO2 / M CO2 + ωCO / M CO + ωN2 / M N2
• Mixture viscosity
xα μα
μ =∑ with α , β = CH 4 , H 2 , O 2 , H 2 O, OH, CO, CO 2 , N 2
α ∑ xα Φ α,β
β
2
−1/ 2 ⎡ 1 1
⎤
1 ⎛ Mα ⎞ ⎢1 + ⎛ μα ⎞ ⎛ M β ⎞ 4 ⎥
(g) 2
Φ α,β = ⎜1 + ⎟⎟ ⎢ ⎜⎜ μ (g) ⎟⎟ ⎜ M ⎟ ⎥
8 ⎜⎝ M β ⎠ ⎝ β ⎠ ⎝ α⎠ ⎥
⎣⎢ ⎦
• Effective thermal conductivity; heat capacity
keff = ∑ ki ωi cp = ∑ ωi cp,i
i
Constitutive relations (Cont’d)
1
∫ TudA ,
• Mixed-mean temperature
Tmean = c
VAc Ac
1
• Mixed-mean mass fraction ωi ,mean =
VAc ∫ ω udA
Ac
i c
Boundary conditions
0.14
0.12
0.1
0.08
0.06
0 20 40 60 80 100 120
Length / mm
• Helical coil gives the best conversion rate among other designs.
• Straight T-junction yields the lowest conversion rate due to poor
mixing.
Mixed mean temperature along channel
1300
1200
1100
1000
Temperature / K
900
800
700
conical
600 in plane spiral
500 helical
straight
400
300
0 20 40 60 80 100 120
Length / mm
0.13
0.11
0.09
0.07
0.05
0.03
0 20 40 60 80 100 120
Length / mm
• Lower mass flow rate performs better conversion rate
• This is due to longer residence time of the species
Effect of coil diameter
0.18
r4
r3
0.16
r5
Oxygen mass fraction
0.14
diameter increasing
0.12
0.1
0.08
0.06
0 20 40 60 80 100 120
Length / mm
Pressure drop
20000
straight
18000
conical
16000 in-plane
14000 helical
12000
p / pa
10000
8000
6000
4000
2000
0
0 200 400 600 800 1000
Reynolds
2.00E-04
1.50E-04
1.00E-04
5.00E-05
0.00E+00
100 500 1000
Reynolds
• Straight channel has the highest figure of merit among other
designs; however, for industrial application where space is limited
and pumping power is not an issue, such as in pharmaceutical
industry, coiled base channel design can be a desirable choice
Concluding remarks
References
[1] O. Deutschmann, L.i. Maier, U. Riedel, A.H. Stroemman, R.W. Dibble,
Hydrogen Assisted Catalytic Combustion of Methane on Platinum,
Catalysis Today 59,141--150 (2000).
[2] V. Kumar, M. Paraschivoiu, K.D.P. Nigam, Single phase fluid flow and
mixing in microchannel, Chemical Engineering Science, 2011, in press.
[3] S. Vatisth, V. Kumar, K.D.P. Nigam, A review on the potential application
of curved geometries in process industry, Industrial Engineering Chemistry
Research 47, 3291-3337 (2008).
[4] J.C. Kurnia, A.P. Sasmito, A.S. Mujumdar, Evaluation of heat transfer
performance of helical coils of non-circular tubes, J. Zhejiang University
Science: A, 2011, in press.
[5] J.C. Kurnia, A.P. Sasmito, A.S. Mujumdar, Laminar convective heat
transfer in coils of non-circular cross-section tube: a computational fluid
dynamics study, Thermal Science, 2011, accepted.
[6] J.C. Kurnia, A.P. Sasmito, A.S. Mujumdar, Numerical investigation of
laminar heat transfer performance of various cooling channel designs,
Applied Thermal Engineering, 2011, in press.
[7] Fluent user guide documentation, http://www.fluent.com
30
For Self Study
March 2010
1
1
Why PEMFC Modeling in Mass
Transport course?
• Fuel cells are becoming important in academic
and industrial R&D. Some already
commercialized. Much more development is
needed to enhance performance cost-effectively
• Excellent industrial illustration of a case where
math modeling of transport phenomena-
including mass transport is critically important
• It is an excellent illustration of how very complex
transport processes can be modeled and what
are the different levels of math models which are
possible
3
2
Mass Transport and PEMFC
• Whenever there is species movement causing
concentration changes –there is mass transport
• Mechanisms are: diffusion, convection, electro-osmosis
etc
• PEMFC includes flow in channels, flow in porous media
• Involves proton and electron transfer, catalytic chemical
reactions, heat transfer etc
• An excellent-but complex-example for study of transport
phenomena
• Here, please focus on the technique of math modeling
rather than the complex details which are beyond the
scope of this course.
• Suitable for Term Paper Projects e.g. 1D analytical
modeling of different types of fuel cells
5
Preamble
• With this preamble , let us proceed to fuel cells..
• Numerous resources are available on the web for
self-study
• Advanced models are being worked on at hundreds
of labs around the world-useful for innovation!
• Several excellent textbooks available as well
• No need to go beyond what is in this PPT-except for
those who choose to work on term papers on this
subject.
• Poh Hee Joo will be happy to provide relevant
resources and ideas to those interested
• Caution: Some aspects are complex and are
included only for completeness of coverage. You do
not need to get into those details.
6
3
What is a Fuel Cell ?
A fuel cell is a device that generates electricity by a chemical
reaction taking place at two electrodes (anode and cathode)
Membrane
4
Basic Fuel Cell Operation
1. Reactant transport
•Efficient delivery of reactants by using flow field plates in
combination with porous electrode structures.
2. Electrochemical reaction
•Choosing right catalyst and carefully designing reaction
zones
3. Ionic (and Electronic) Conduction
•Thin electrolyte for ionic conduction, without fuel cross over
4. Product Removal
•“Flooding” by product water can be major issue in PEMFC
9
• Transportation
• Stationary Power Generation
• Residential
• Portable Power Generation
• Space and Defense
10
5
Fuel Cells: Classification
PEM fuel cell Solid oxide fuel cell
At Anode At Cathode
Characterized by
PEM Fuel Cell 2H2 → 4H+ + 4e O2 + 4e + 4H+ → 2H2O
•Electrolyte materials H2 + O2-→CO2 + H2O + 2e ½ O2 + 2e → O2-
Solid Oxide Fuel Cell
•Operating temperature Direct Methanol Fuel Cell CH3OH + H2O →CO2 + 6H+ + 6e 3/2O2 + 6H+ + 6e →3H2O
•Fuel used 11
6
Fuel Cells: Some Limitations
• High cost of fuel cell
• Low volumetric power density comparing to I.C.
engines and batteries
• Safety, Availability, Storage and Distribution of
pure hydrogen fuel
• Alternative fuels (e.g. methanol, gasoline)
difficult to use directly and require reforming
• Susceptibility to environmental poisons
• Operational temperature compatibility concerns
13
14
7
Fuel cells: Interdisciplinary field of
science and engineering:
• Thermodynamics
• Electrochemistry
• Chemistry and Chemical Engineering
• Fluid Mechanics
• Heat and Mass Transfer
• Material Science (metallurgy) and materials engineering
• Polymer Science and specifically ionomer chemistry
• Design, manufacturing and engineering optimization
• Solid mechanics and mechanical engineering
• Electromagnetism and electrical engineering
• Etc etc
15
PEMFC (Interdisciplinary!)
Catalysis Thermofluids
Membrane Science and and System Integration
Electrochemistry Component Design
Alternative catalyst
High temperature Transport phenomena System design & configuration
(reduce cost)
cation membrane (molecular diffusion, (reduce cost, improved efficient)
Reduce CO poisoning ion migration,
High catalyst utilization
of catalyst) convection) Interconnection
(reduce catalyst loading)
(increase power o/p)
Membrane for DMFC Multi-phase physics
Improved performance
(prevent methanol crossover) (water management) Heat and water management
(electro-oxidation/Reduction)
(operational stability)
Anion membrane Heat transfer
Measurement and
(use of low cost catalyst) (performance stability)
Characterization
(relate performance to
Fluid dynamics
electrochemical processes)
(flow channel design)
8
Schematic of a cross sectional view of PEM
Fuel Cell unit
Load
e-
Cathode Anode
Catalyst Catalyst
Cathode Cathode Membrane Anode Anode
Bipolar Plate Electrode Electrode Bipolar Plate
(GDL) (GDL)
Air O2 H+ H2 H2
channel channel
17
18
9
Water Management in PEMFC
Electrolyte
Cathode Anode
membrane
Water produced
within cathode
20
10
Fuel Cell : Mass Transport
• To produce electricity, fuel cell must be continually
supplied with fuel and oxidant. At the same time,
products must be continuously removed so as to
avoid “strangling” the cell. The process of
supplying reactants and removing products is
termed fuel cell mass transport.
11
Transport in Electrodes: Diffusive
Transport
Flow Flow Anode Catalyst Electrolyte
Structure channel Electrode Layer
Reactants (R) In
An electrochemical JR
JP
side of an electrode and Products (P) Out
Faraday’s Law
• From Faraday’s Law : current i evolved by an
electrochemical reaction is a direct measure of
the rate of electrochemical reaction i = dQ = nF dN
dt dt
i 1 dN
• *The current density j=
A
= nF = nFJ
A dt
12
Transport in Electrode: Diffusive Transport
• At steady state, the diffusion flux of reactants and
products down the concentration gradient across the
electrode (diffusion layer) will exactly match the
consumption/production rate of reactants and products
at the catalyst layer.
• Diffusion flux (kmol/m2s) of reactants to the catalyst
layer may be described by dc J = − D eff c *R − c Ro
J diff = − D
dx
diff
δ
eff c R − c R
* o
13
Question 1
1. Discuss the factors that determine jL,
limiting current density. List three ways to
increase jL.
27
28
14
Typical process of reactant
transport to reactant sites
• If considering the convection mass transfer across electrode surface,
how is the limiting current density being derived?
x=H
Diffusion and
Convection, hm Diffusion reaction
o
c R
c Rs
x HE
x=0
15
Transport in Electrode: Diffusive
Transport
• Concentration affects fuel cell performance through reaction
kinetics.
• This is because reaction kinetics also depend on the reactant and
product concentration at the reaction sites.
• Reactant depletion/product accumulation in the catalyst layers
lead to fuel cell performance loss.
• This is called fuel cell concentration (or mass transport) loss.
RT 1 jL
ηconc = 1 +
nF α jL − j
• ηconc - Voltage loss due to reactant depletion in the catalyst layer
• Increasing jL can greatly extend a fuel cell’s potential operating
range; therefore mass transport design is an active area of
current fuel cell research.
31
Question 2
2. Using the limiting current density equation, calculate
the limiting current density for a fuel cell cathode
running on air at 1 Atm and 25°C. Assume only O2 and
N2 and ignore the presence of water vapor. Mass
fraction of O2 in air is 0.23. Assume the diffusion layer
is 500µm and has a porosity of 40%.
16
Answer for Question 2
• In the H2-O2 fuel cell, the electrochemical reaction at
the cathode is given by O2 + 4H+ + 4e → H2O. Hence
n = 4. F is the Faraday constant, 96,485 C/mol. The
binary diffusion coefficient is given by Chapman-
Enskog theory.σO2 = 3.467. σN2 = 3.798. σO2-N2 =
3.6325. From the necessary calculation, Ω = 0.9186.
Therefore, Dij = 2x10-5 m2/s. From Bruggemann
correction Dij,eff = 5.06 x 10-6 m2/s. From the ideal gas
equation, total molar concentration for the mixture is =
40.9 mol/m3. Molecular weight for the mixture O2-N2 is
= 28.92. Mole faction of O2 = = 0.20786. Therefore,
molar concentration of O2 = 8.5015 mol/m3. Limiting
current density = 33,204 A/m2 = 3.32A/cm2
33
34
17
Convective Transport Contd
• Analyzing convective gas transport in the
complex real world flow structures is only really
possible with numerical methods. A common
technique is to use CFD modeling
35
y JC
Convection transfer at surface
JD
Diffusion Electrode
Membrane
• Pressure difference between inlet and outlet drives the fluid flow.
• Although gas flowing in stream-wise direction along flow channel,
convective mass transport can also occur in transverse direction from
flow channel into (or out of) electrode. This happens when
concentration of species i is different at the electrode surface versus
the flow channel bulk.
36
18
Transport in Flow Structure:
Convective Transport
• Mass flux (kg/m2s) due to convective mass transfer
may be estimated by
(
J C ,i = hm ρi , s − ρi )
• Mass transfer convection coefficient, hm, is dependent
on the channel geometry, the physical properties of
species i and j, and the wall conditions. It can be found
from the nondimensional Sherwood number
Dij
hm = Sh
Dh
37
19
Transport in Flow Structure: Convective
Transport
y Gas is depleted along flow channel
E CONV
uin J O2
y=E
ρO ρO HC
2 2
39
20
Transport in Flow Structure:
Convective Transport
From Faraday’s Law, if fuel cell is producing a current density at location X,
then the O2 mass flux (kg/cm2s) that is consuming is given by
j( X )
^ rxn
J O2 = M O2 (1)
x = X , y =C 4F
The O2 flux consumed by the electrochemical reaction must be provided by
diffusion in the gas diffusion layer, described by Fick’s law
^ diff ρO x = X , y =C
− ρ O2
x= X , y=E
= − DOeff2
2
J O2 (2)
x= X , y=E HE
O2 mass flux due to mass transport through the gas diffusion layer is provided
by convective mass transport between the flow channel and gas diffusion layer
conv
= − hm ρ O2
^
J O2 − ρ O2
x= X , y=E x= X , y=E x = X , y = channel (3)
41
21
Transport in Flow Structure:
Convective Transport
To maintain the flux balance, O2 mass flux in equations 1, 2 & 3 must be same
^ rxn ^ diff ^ conv
J O2 = J O2 = J O2 (4)
x = X , y =C x= X , y= E x= X , y= E
J O2 = M O2 (5)
x= X , y=E 4F
j( X ) H E
ρO x = X , y =C
= ρO2
x= X , y=E
− M O2 (6)
2
4 F DOeff2
j(X ) 1
ρO = ρ O2 − M O2 (7)
2 x= X , y=E x = X , y = channel 4 F hm 43
O2 leaving out of the top of the control volume can be related to the current
density produced by fuel cell.
j (x )
conv
^
∫
X
dx = ∫ M O2
X
J O2 dx (9)
0
y=E
0 4F
M O2 j ( X ) H E j ( X ) X j (x )
ρO = ρ O2 − + +∫ dx (10)
2 x = X , y =C x = X , y = channel
4 F hm eff
DO2 0 u in H C 44
22
Transport in Flow Structure:
Convective Transport
Assume current density is constant along the x direction
j 1 H X
ρO = ρ O2 − M O2 + E +
2 x = X , y =C x = X , y = channel 4 F hm DOeff2 u in H C
(11)
ShF DO2
hm =
HC (12)
Final expression for oxygen concentration profile along the catalyst layer
j H C H X
ρO = ρ O2 − M O2 + E +
2 x = X , y =C x = X , y = channel 4 F ShF DO2 DOeff2 u in H C
(13)
45
Linear profile
23
Transport in Flow Structure:
Convective Transport
• Flow Structure Pattern
• Flow plate typically contain dozen or even
hundreds of fine channels (or groves) to
homogenously distribute gas flow over the fuel
cell surface. The shape, size and pattern of
flow channels can significantly affect fuel cell
performance.
• In PEMFCs, flow field design effort often focus
on the water removal capability of cathode
side.
47
Outlet
2. Serpentine flow
Excellent water removal capability, as only one flow
path exists in the pattern and liquid water is forced to
exit the channel
However, in large area cell, serpentine design leads
to large pressure drop Inlet
24
Analytical Modelling with MATLAB
• Motivation
• Shorter turnaround time
• Accessibility
• Working with basics: enhancing understanding
Issues:
• Oversimplification
• Disregard for physical factors
• Incapable of complex reality simulations
Way out:
• Compare results with numerical methods
49
50
25
Modelling different components
51
(b)
(c)
Charge Conductor Gas Diffusion Layer
Figure 6 (a): PEM Fuel Cell Structure; (b): GDL and Current Conductor assembly;
(c): Flow Channel dimensions – w=width, d=depth, L=length
52
26
Limiting current density
Di , j 4⋅d ⋅w
hm = Sh Dh = [ ]
Dh 2( d + w)
53
Assumptions
• The fuel cell system is assumed to be operating at a constant temperature
• Fuel cell operating pressure is assumed to be constant
• Velocity in the gas flow channel is assumed to be constant
• The cell is in steady state operation
• The current density is assumed to be constant on the electrode surface
• Chamber gases are assumed to be of uniform composition
• Ideal gas properties are observed by all gases
• Incompressible and laminar flow in flow channel
• Isotropic and homogeneous membrane and electrode structures
• Negligible ohmic potential drop in solid components
• The mass and energy transport is modeled from macro-perspective using volume-
averaged conservation equations
Any model is only as good as the assumptions it is based upon are valid – Franco Barbir
54
27
(Analytical) Procedure
(C m ,in − C m ,out )
• Eqn in question: i L = nFhm [ C m ,in
]
ln( )
C m ,out
• Two cases: Square and Rectangular cross section
• Range: L – 10cm-30cm; w – 1mm-5mm; d – 1mm-5mm
• ‘for’ loop and data point for iL for every 10μm of channel
depth/width, and for every 100μmm of channel length
55
56
28
Square cross section
Channel Lenght/Channel Depth (L/d) 90 10
9
80
8.5
(iLmax) / Acm-2
75
8
70
7.5
65
7
60
6.5
55
6
50 5.5
45 5 L/d
0 0.05 0.1 0.15 0.2 0.25 0.3 0.35
57
58
29
Rectangular cross section
14 80
13
Maximum Limiting Current Density
70
11
(iLmax) / Acm-2
50
10
iLmax (w=3mm)
40
9
30
iLmax (w=5mm)
8
20
7 L/d (w=3mm)
6 10
L/d (w=5mm)
5 0
0 0.05 0.1 0.15 0.2 0.25 0.3
59
60
30
Rectangular cross section: iL v. L
61
o channel length iL
o channel width iL for lower depths (d< ~ 1-2.5mm depending upon L),
There exist optimum channel depths for channels wider than ~ 1.5mm
62
31
Closing Remarks
63
• Analytical and numerical studies did not coincide, mainly due to the
assumptions with which the analytical study is carried out
• Numerical trend for change in values for current density v. channel depth
was similar to the analytical one – a big positive!
64
32
Acknowledgements
• Erik Birgersson, Department of Chemical
and Bio-molecular Engineering, NUS
• Rina Lum, IHPC
• Agus Pulung Sasmito, NUS
• Narissara Bussayajarn, SIMTech
• Xing Xiuqing & Wu Yanling, IHPC
• Gaurav Pundir, NUS
65
33
APPNDIX B: MATLAB CODE [SQ CS – LCD v CD]
% Square cross section, limiting current density v channel depth for diff lengths
for i=100:500
d(i) = i/100000;
C_O2_out2(i) = C_O2_in*exp(-h_m(i)*channel_length2/(d(i)*air_velocity));
limitng_current_density2(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out2(i))/log(C_O2_in/C_O2_out2(i))/10000;
C_O2_out3(i) = C_O2_in*exp(-h_m(i)*channel_length3/(d(i)*air_velocity));
limitng_current_density3(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out3(i))/log(C_O2_in/C_O2_out3(i))/10000;
C_O2_out4(i) = C_O2_in*exp(-h_m(i)*channel_length4/(d(i)*air_velocity));
limitng_current_density4(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out4(i))/log(C_O2_in/C_O2_out4(i))/10000;
C_O2_out5(i) = C_O2_in*exp(-h_m(i)*channel_length5/(d(i)*air_velocity));
limitng_current_density5(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out5(i))/log(C_O2_in/C_O2_out5(i))/10000;
C_O2_out6(i) = C_O2_in*exp(-h_m(i)*channel_length6/(d(i)*air_velocity));
limitng_current_density6(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out6(i))/log(C_O2_in/C_O2_out6(i))/10000;
C_O2_out7(i) = C_O2_in*exp(-h_m(i)*channel_length7/(d(i)*air_velocity));
limitng_current_density7(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out7(i))/log(C_O2_in/C_O2_out7(i))/10000;
C_O2_out8(i) = C_O2_in*exp(-h_m(i)*channel_length8/(d(i)*air_velocity));
limitng_current_density8(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out8(i))/log(C_O2_in/C_O2_out8(i))/10000;
C_O2_out9(i) = C_O2_in*exp(-h_m(i)*channel_length9/(d(i)*air_velocity));
limitng_current_density9(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out9(i))/log(C_O2_in/C_O2_out9(i))/10000;
C_O2_out10(i) = C_O2_in*exp(-h_m(i)*channel_length10/(d(i)*air_velocity));
limitng_current_density10(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out10(i))/log(C_O2_in/C_O2_out10(i))/10000;
C_O2_out11(i) = C_O2_in*exp(-h_m(i)*channel_length11/(d(i)*air_velocity));
limitng_current_density11(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out11(i))/log(C_O2_in/C_O2_out11(i))/10000;
C_O2_out12(i) = C_O2_in*exp(-h_m(i)*channel_length12/(d(i)*air_velocity));
limitng_current_density12(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out12(i))/log(C_O2_in/C_O2_out12(i))/10000;
C_O2_out13(i) = C_O2_in*exp(-h_m(i)*channel_length13/(d(i)*air_velocity));
limitng_current_density13(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out13(i))/log(C_O2_in/C_O2_out13(i))/10000;
C_O2_out14(i) = C_O2_in*exp(-h_m(i)*channel_length14/(d(i)*air_velocity));
limitng_current_density14(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out14(i))/log(C_O2_in/C_O2_out14(i))/10000;
C_O2_out15(i) = C_O2_in*exp(-h_m(i)*channel_length15/(d(i)*air_velocity));
limitng_current_density15(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out15(i))/log(C_O2_in/C_O2_out15(i))/10000;
C_O2_out16(i) = C_O2_in*exp(-h_m(i)*channel_length16/(d(i)*air_velocity));
limitng_current_density16(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out16(i))/log(C_O2_in/C_O2_out16(i))/10000;
C_O2_out17(i) = C_O2_in*exp(-h_m(i)*channel_length17/(d(i)*air_velocity));
limitng_current_density17(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out17(i))/log(C_O2_in/C_O2_out17(i))/10000;
C_O2_out18(i) = C_O2_in*exp(-h_m(i)*channel_length18/(d(i)*air_velocity));
limitng_current_density18(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out18(i))/log(C_O2_in/C_O2_out18(i))/10000;
C_O2_out19(i) = C_O2_in*exp(-h_m(i)*channel_length19/(d(i)*air_velocity));
limitng_current_density19(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out19(i))/log(C_O2_in/C_O2_out19(i))/10000;
C_O2_out20(i) = C_O2_in*exp(-h_m(i)*channel_length20/(d(i)*air_velocity));
limitng_current_density20(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out20(i))/log(C_O2_in/C_O2_out20(i))/10000;
C_O2_out21(i) = C_O2_in*exp(-h_m(i)*channel_length21/(d(i)*air_velocity));
limitng_current_density21(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out21(i))/log(C_O2_in/C_O2_out21(i))/10000;
end
for i=100:500
d(i) = i/100000;
C_O2_out2(i) = C_O2_in*exp(-h_m(i)*channel_length2/(d(i)*air_velocity));
limitng_current_density2(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out2(i))/log(C_O2_in/C_O2_out2(i))/10000;
C_O2_out3(i) = C_O2_in*exp(-h_m(i)*channel_length3/(d(i)*air_velocity));
limitng_current_density3(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out3(i))/log(C_O2_in/C_O2_out3(i))/10000;
C_O2_out4(i) = C_O2_in*exp(-h_m(i)*channel_length4/(d(i)*air_velocity));
limitng_current_density4(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out4(i))/log(C_O2_in/C_O2_out4(i))/10000;
C_O2_out5(i) = C_O2_in*exp(-h_m(i)*channel_length5/(d(i)*air_velocity));
limitng_current_density5(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out5(i))/log(C_O2_in/C_O2_out5(i))/10000;
C_O2_out6(i) = C_O2_in*exp(-h_m(i)*channel_length6/(d(i)*air_velocity));
limitng_current_density6(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out6(i))/log(C_O2_in/C_O2_out6(i))/10000;
C_O2_out7(i) = C_O2_in*exp(-h_m(i)*channel_length7/(d(i)*air_velocity));
limitng_current_density7(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out7(i))/log(C_O2_in/C_O2_out7(i))/10000;
C_O2_out8(i) = C_O2_in*exp(-h_m(i)*channel_length8/(d(i)*air_velocity));
limitng_current_density8(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out8(i))/log(C_O2_in/C_O2_out8(i))/10000;
C_O2_out9(i) = C_O2_in*exp(-h_m(i)*channel_length9/(d(i)*air_velocity));
limitng_current_density9(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out9(i))/log(C_O2_in/C_O2_out9(i))/10000;
C_O2_out10(i) = C_O2_in*exp(-h_m(i)*channel_length10/(d(i)*air_velocity));
limitng_current_density10(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out10(i))/log(C_O2_in/C_O2_out10(i))/10000;
C_O2_out11(i) = C_O2_in*exp(-h_m(i)*channel_length11/(d(i)*air_velocity));
limitng_current_density11(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out11(i))/log(C_O2_in/C_O2_out11(i))/10000;
C_O2_out12(i) = C_O2_in*exp(-h_m(i)*channel_length12/(d(i)*air_velocity));
limitng_current_density12(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out12(i))/log(C_O2_in/C_O2_out12(i))/10000;
C_O2_out13(i) = C_O2_in*exp(-h_m(i)*channel_length13/(d(i)*air_velocity));
limitng_current_density13(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out13(i))/log(C_O2_in/C_O2_out13(i))/10000;
C_O2_out14(i) = C_O2_in*exp(-h_m(i)*channel_length14/(d(i)*air_velocity));
limitng_current_density14(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out14(i))/log(C_O2_in/C_O2_out14(i))/10000;
C_O2_out15(i) = C_O2_in*exp(-h_m(i)*channel_length15/(d(i)*air_velocity));
limitng_current_density15(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out15(i))/log(C_O2_in/C_O2_out15(i))/10000;
C_O2_out16(i) = C_O2_in*exp(-h_m(i)*channel_length16/(d(i)*air_velocity));
limitng_current_density16(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out16(i))/log(C_O2_in/C_O2_out16(i))/10000;
C_O2_out17(i) = C_O2_in*exp(-h_m(i)*channel_length17/(d(i)*air_velocity));
limitng_current_density17(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out17(i))/log(C_O2_in/C_O2_out17(i))/10000;
C_O2_out18(i) = C_O2_in*exp(-h_m(i)*channel_length18/(d(i)*air_velocity));
limitng_current_density18(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out18(i))/log(C_O2_in/C_O2_out18(i))/10000;
C_O2_out19(i) = C_O2_in*exp(-h_m(i)*channel_length19/(d(i)*air_velocity));
limitng_current_density19(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out19(i))/log(C_O2_in/C_O2_out19(i))/10000;
C_O2_out20(i) = C_O2_in*exp(-h_m(i)*channel_length20/(d(i)*air_velocity));
limitng_current_density20(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out20(i))/log(C_O2_in/C_O2_out20(i))/10000;
C_O2_out21(i) = C_O2_in*exp(-h_m(i)*channel_length21/(d(i)*air_velocity));
limitng_current_density21(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out21(i))/log(C_O2_in/C_O2_out21(i))/10000;
end
%Rectangular x-section, limiting current density v channel depth for diff widths
% Replace highlighted ? with relevant channel length (in m) before running the
code
for i=100:500
d(i) = i/100000;
D_k2(i) = 2*w2*d(i)/(w2+d(i));
RE2(i) = air_velocity*D_k2(i)/meu;
h_m2(i) = Sh*D_o2_n2/D_k2(i);
C_O2_out2(i) = C_O2_in*exp(-h_m2(i)*channel_length/(d(i)*air_velocity));
limitng_current_density2(i) = n*F*h_m2(i)*(C_O2_in -
C_O2_out2(i))/log(C_O2_in/C_O2_out2(i))/10000;
D_k3(i) = 2*w3*d(i)/(w3+d(i));
RE3(i) = air_velocity*D_k3(i)/meu;
h_m3(i) = Sh*D_o2_n2/D_k3(i);
C_O2_out3(i) = C_O2_in*exp(-h_m3(i)*channel_length/(d(i)*air_velocity));
limitng_current_density3(i) = n*F*h_m3(i)*(C_O2_in -
C_O2_out3(i))/log(C_O2_in/C_O2_out3(i))/10000;
D_k4(i) = 2*w4*d(i)/(w4+d(i));
RE4(i) = air_velocity*D_k4(i)/meu;
h_m4(i) = Sh*D_o2_n2/D_k4(i);
C_O2_out4(i) = C_O2_in*exp(-h_m4(i)*channel_length/(d(i)*air_velocity));
limitng_current_density4(i) = n*F*h_m4(i)*(C_O2_in -
C_O2_out4(i))/log(C_O2_in/C_O2_out4(i))/10000;
D_k5(i) = 2*w5*d(i)/(w5+d(i));
RE5(i) = air_velocity*D_k5(i)/meu;
h_m5(i) = Sh*D_o2_n2/D_k5(i);
C_O2_out5(i) = C_O2_in*exp(-h_m5(i)*channel_length/(d(i)*air_velocity));
limitng_current_density5(i) = n*F*h_m5(i)*(C_O2_in -
C_O2_out5(i))/log(C_O2_in/C_O2_out5(i))/10000;
D_k6(i) = 2*w6*d(i)/(w6+d(i));
RE6(i) = air_velocity*D_k6(i)/meu;
h_m6(i) = Sh*D_o2_n2/D_k6(i);
C_O2_out6(i) = C_O2_in*exp(-h_m6(i)*channel_length/(d(i)*air_velocity));
limitng_current_density6(i) = n*F*h_m6(i)*(C_O2_in -
C_O2_out6(i))/log(C_O2_in/C_O2_out6(i))/10000;
D_k7(i) = 2*w7*d(i)/(w7+d(i));
RE7(i) = air_velocity*D_k7(i)/meu;
h_m7(i) = Sh*D_o2_n2/D_k7(i);
C_O2_out7(i) = C_O2_in*exp(-h_m7(i)*channel_length/(d(i)*air_velocity));
limitng_current_density7(i) = n*F*h_m7(i)*(C_O2_in -
C_O2_out7(i))/log(C_O2_in/C_O2_out7(i))/10000;
D_k8(i) = 2*w8*d(i)/(w8+d(i));
RE8(i) = air_velocity*D_k8(i)/meu;
h_m8(i) = Sh*D_o2_n2/D_k8(i);
C_O2_out8(i) = C_O2_in*exp(-h_m8(i)*channel_length/(d(i)*air_velocity));
limitng_current_density8(i) = n*F*h_m8(i)*(C_O2_in -
C_O2_out8(i))/log(C_O2_in/C_O2_out8(i))/10000;
D_k9(i) = 2*w9*d(i)/(w9+d(i));
RE9(i) = air_velocity*D_k9(i)/meu;
h_m9(i) = Sh*D_o2_n2/D_k9(i);
C_O2_out9(i) = C_O2_in*exp(-h_m9(i)*channel_length/(d(i)*air_velocity));
limitng_current_density9(i) = n*F*h_m9(i)*(C_O2_in -
C_O2_out9(i))/log(C_O2_in/C_O2_out9(i))/10000;
end
% Replace highlighted ? with relevant channel depth (in mm) before running the
code
for i=100:500
w(i) = i/100000;
C_O2_out2(i) = C_O2_in*exp(-h_m(i)*channel_length2/(d*air_velocity));
limitng_current_density2(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out2(i))/log(C_O2_in/C_O2_out2(i))/10000;
C_O2_out3(i) = C_O2_in*exp(-h_m(i)*channel_length3/(d*air_velocity));
limitng_current_density3(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out3(i))/log(C_O2_in/C_O2_out3(i))/10000;
C_O2_out4(i) = C_O2_in*exp(-h_m(i)*channel_length4/(d*air_velocity));
limitng_current_density4(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out4(i))/log(C_O2_in/C_O2_out4(i))/10000;
C_O2_out5(i) = C_O2_in*exp(-h_m(i)*channel_length5/(d*air_velocity));
limitng_current_density5(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out5(i))/log(C_O2_in/C_O2_out5(i))/10000;
C_O2_out6(i) = C_O2_in*exp(-h_m(i)*channel_length6/(d*air_velocity));
limitng_current_density6(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out6(i))/log(C_O2_in/C_O2_out6(i))/10000;
C_O2_out7(i) = C_O2_in*exp(-h_m(i)*channel_length7/(d*air_velocity));
limitng_current_density7(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out7(i))/log(C_O2_in/C_O2_out7(i))/10000;
C_O2_out8(i) = C_O2_in*exp(-h_m(i)*channel_length8/(d*air_velocity));
limitng_current_density8(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out8(i))/log(C_O2_in/C_O2_out8(i))/10000;
C_O2_out9(i) = C_O2_in*exp(-h_m(i)*channel_length9/(d*air_velocity));
limitng_current_density9(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out9(i))/log(C_O2_in/C_O2_out9(i))/10000;
C_O2_out10(i) = C_O2_in*exp(-h_m(i)*channel_length10/(d*air_velocity));
limitng_current_density10(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out10(i))/log(C_O2_in/C_O2_out10(i))/10000;
C_O2_out11(i) = C_O2_in*exp(-h_m(i)*channel_length11/(d*air_velocity));
limitng_current_density11(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out11(i))/log(C_O2_in/C_O2_out11(i))/10000;
C_O2_out12(i) = C_O2_in*exp(-h_m(i)*channel_length12/(d*air_velocity));
limitng_current_density12(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out12(i))/log(C_O2_in/C_O2_out12(i))/10000;
C_O2_out13(i) = C_O2_in*exp(-h_m(i)*channel_length13/(d*air_velocity));
limitng_current_density13(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out13(i))/log(C_O2_in/C_O2_out13(i))/10000;
C_O2_out14(i) = C_O2_in*exp(-h_m(i)*channel_length14/(d*air_velocity));
limitng_current_density14(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out14(i))/log(C_O2_in/C_O2_out14(i))/10000;
C_O2_out15(i) = C_O2_in*exp(-h_m(i)*channel_length15/(d*air_velocity));
limitng_current_density15(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out15(i))/log(C_O2_in/C_O2_out15(i))/10000;
C_O2_out16(i) = C_O2_in*exp(-h_m(i)*channel_length16/(d*air_velocity));
limitng_current_density16(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out16(i))/log(C_O2_in/C_O2_out16(i))/10000;
C_O2_out17(i) = C_O2_in*exp(-h_m(i)*channel_length17/(d*air_velocity));
limitng_current_density17(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out17(i))/log(C_O2_in/C_O2_out17(i))/10000;
C_O2_out18(i) = C_O2_in*exp(-h_m(i)*channel_length18/(d*air_velocity));
limitng_current_density18(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out18(i))/log(C_O2_in/C_O2_out18(i))/10000;
C_O2_out19(i) = C_O2_in*exp(-h_m(i)*channel_length19/(d*air_velocity));
limitng_current_density19(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out19(i))/log(C_O2_in/C_O2_out19(i))/10000;
C_O2_out20(i) = C_O2_in*exp(-h_m(i)*channel_length20/(d*air_velocity));
limitng_current_density20(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out20(i))/log(C_O2_in/C_O2_out20(i))/10000;
C_O2_out21(i) = C_O2_in*exp(-h_m(i)*channel_length21/(d*air_velocity));
limitng_current_density21(i) = n*F*h_m(i)*(C_O2_in -
C_O2_out21(i))/log(C_O2_in/C_O2_out21(i))/10000;
end
% Replace highlighted ? with relevant channel length (in m) before running the
code
for i=100:500
w(i) = i/100000;
D_k2(i) = 2*w(i)*d2/(w(i)+d2);
RE2(i) = air_velocity*D_k2(i)/meu;
h_m2(i) = Sh*D_o2_n2/D_k2(i);
C_O2_out2(i) = C_O2_in*exp(-h_m2(i)*channel_length/(d2*air_velocity));
limitng_current_density2(i) = n*F*h_m2(i)*(C_O2_in -
C_O2_out2(i))/log(C_O2_in/C_O2_out2(i))/10000;
D_k3(i) = 2*w(i)*d3/(w(i)+d3);
RE1(i) = air_velocity*D_k3(i)/meu;
h_m3(i) = Sh*D_o2_n2/D_k3(i);
C_O2_out3(i) = C_O2_in*exp(-h_m3(i)*channel_length/(d3*air_velocity));
limitng_current_density3(i) = n*F*h_m3(i)*(C_O2_in -
C_O2_out3(i))/log(C_O2_in/C_O2_out3(i))/10000;
D_k4(i) = 2*w(i)*d4/(w(i)+d4);
RE4(i) = air_velocity*D_k4(i)/meu;
h_m4(i) = Sh*D_o2_n2/D_k4(i);
C_O2_out4(i) = C_O2_in*exp(-h_m4(i)*channel_length/(d4*air_velocity));
limitng_current_density4(i) = n*F*h_m4(i)*(C_O2_in -
C_O2_out4(i))/log(C_O2_in/C_O2_out4(i))/10000;
D_k5(i) = 2*w(i)*d5/(w(i)+d5);
RE5(i) = air_velocity*D_k5(i)/meu;
h_m5(i) = Sh*D_o2_n2/D_k5(i);
C_O2_out5(i) = C_O2_in*exp(-h_m5(i)*channel_length/(d5*air_velocity));
limitng_current_density5(i) = n*F*h_m5(i)*(C_O2_in -
C_O2_out5(i))/log(C_O2_in/C_O2_out5(i))/10000;
D_k6(i) = 2*w(i)*d6/(w(i)+d6);
RE6(i) = air_velocity*D_k6(i)/meu;
h_m6(i) = Sh*D_o2_n2/D_k6(i);
C_O2_out6(i) = C_O2_in*exp(-h_m6(i)*channel_length/(d6*air_velocity));
limitng_current_density6(i) = n*F*h_m6(i)*(C_O2_in -
C_O2_out6(i))/log(C_O2_in/C_O2_out6(i))/10000;
D_k7(i) = 2*w(i)*d7/(w(i)+d7);
RE7(i) = air_velocity*D_k7(i)/meu;
h_m7(i) = Sh*D_o2_n2/D_k7(i);
C_O2_out7(i) = C_O2_in*exp(-h_m7(i)*channel_length/(d7*air_velocity));
limitng_current_density7(i) = n*F*h_m7(i)*(C_O2_in -
C_O2_out7(i))/log(C_O2_in/C_O2_out7(i))/10000;
D_k8(i) = 2*w(i)*d8/(w(i)+d8);
RE8(i) = air_velocity*D_k8(i)/meu;
h_m8(i) = Sh*D_o2_n2/D_k8(i);
C_O2_out8(i) = C_O2_in*exp(-h_m8(i)*channel_length/(d8*air_velocity));
limitng_current_density8(i) = n*F*h_m8(i)*(C_O2_in -
C_O2_out8(i))/log(C_O2_in/C_O2_out8(i))/10000;
D_k9(i) = 2*w(i)*d9/(w(i)+d9);
RE9(i) = air_velocity*D_k9(i)/meu;
h_m9(i) = Sh*D_o2_n2/D_k9(i);
C_O2_out9(i) = C_O2_in*exp(-h_m9(i)*channel_length/(d9*air_velocity));
limitng_current_density9(i) = n*F*h_m9(i)*(C_O2_in -
C_O2_out9(i))/log(C_O2_in/C_O2_out9(i))/10000;
end
% Replace highlighted ? with relevant channel depth (in mm) before running the
code
for i=1000:3000
channel_length(i) = i/10000;
D_k2 = 2*w2*d/(w2+d);
RE2 = air_velocity*D_k2/meu;
h_m2 = Sh*D_o2_n2/D_k2;
C_O2_out2(i) = C_O2_in*exp(-h_m2*channel_length(i)/(d*air_velocity));
limitng_current_density2(i) = n*F*h_m2*(C_O2_in -
C_O2_out2(i))/log(C_O2_in/C_O2_out2(i))/10000;
D_k3 = 2*w3*d/(w3+d);
RE3 = air_velocity*D_k3/meu;
h_m3 = Sh*D_o2_n2/D_k3;
C_O2_out3(i) = C_O2_in*exp(-h_m3*channel_length(i)/(d*air_velocity));
limitng_current_density3(i) = n*F*h_m3*(C_O2_in -
C_O2_out3(i))/log(C_O2_in/C_O2_out3(i))/10000;
D_k4 = 2*w4*d/(w4+d);
RE4 = air_velocity*D_k4/meu;
h_m4 = Sh*D_o2_n2/D_k4;
C_O2_out4(i) = C_O2_in*exp(-h_m4*channel_length(i)/(d*air_velocity));
limitng_current_density4(i) = n*F*h_m4*(C_O2_in -
C_O2_out4(i))/log(C_O2_in/C_O2_out4(i))/10000;
D_k5 = 2*w5*d/(w5+d);
RE5 = air_velocity*D_k5/meu;
h_m5 = Sh*D_o2_n2/D_k5;
C_O2_out5(i) = C_O2_in*exp(-h_m5*channel_length(i)/(d*air_velocity));
limitng_current_density5(i) = n*F*h_m5*(C_O2_in -
C_O2_out5(i))/log(C_O2_in/C_O2_out5(i))/10000;
D_k6 = 2*w6*d/(w6+d);
RE6 = air_velocity*D_k6/meu;
h_m6 = Sh*D_o2_n2/D_k6;
C_O2_out6(i) = C_O2_in*exp(-h_m6*channel_length(i)/(d*air_velocity));
limitng_current_density6(i) = n*F*h_m6*(C_O2_in -
C_O2_out6(i))/log(C_O2_in/C_O2_out6(i))/10000;
D_k7 = 2*w7*d/(w7+d);
RE7 = air_velocity*D_k7/meu;
h_m7 = Sh*D_o2_n2/D_k7;
C_O2_out7(i) = C_O2_in*exp(-h_m7*channel_length(i)/(d*air_velocity));
limitng_current_density7(i) = n*F*h_m7*(C_O2_in -
C_O2_out7(i))/log(C_O2_in/C_O2_out7(i))/10000;
D_k8 = 2*w8*d/(w8+d);
RE8 = air_velocity*D_k8/meu;
h_m8 = Sh*D_o2_n2/D_k8;
C_O2_out8(i) = C_O2_in*exp(-h_m8*channel_length(i)/(d*air_velocity));
limitng_current_density8(i) = n*F*h_m8*(C_O2_in -
C_O2_out8(i))/log(C_O2_in/C_O2_out8(i))/10000;
D_k9 = 2*w9*d/(w9+d);
RE9 = air_velocity*D_k9/meu;
h_m9 = Sh*D_o2_n2/D_k9;
C_O2_out9(i) = C_O2_in*exp(-h_m9*channel_length(i)/(d*air_velocity));
limitng_current_density9(i) = n*F*h_m9*(C_O2_in -
C_O2_out9(i))/log(C_O2_in/C_O2_out9(i))/10000;
end
% Replace highlighted ? with relevant channel width (in mm) before running the
code
for i=1000:3000
channel_length(i) = i/10000;
D_k2 = 2*w*d2/(w+d2);
RE2 = air_velocity*D_k2/meu;
h_m2 = Sh*D_o2_n2/D_k2;
C_O2_out2(i) = C_O2_in*exp(-h_m2*channel_length(i)/(d2*air_velocity));
limitng_current_density2(i) = n*F*h_m2*(C_O2_in -
C_O2_out2(i))/log(C_O2_in/C_O2_out2(i))/10000;
D_k3 = 2*w*d3/(w+d3);
RE3 = air_velocity*D_k3/meu;
h_m3 = Sh*D_o2_n2/D_k3;
C_O2_out3(i) = C_O2_in*exp(-h_m3*channel_length(i)/(d3*air_velocity));
limitng_current_density3(i) = n*F*h_m3*(C_O2_in -
C_O2_out3(i))/log(C_O2_in/C_O2_out3(i))/10000;
D_k4 = 2*w*d4/(w+d4);
RE4 = air_velocity*D_k4/meu;
h_m4 = Sh*D_o2_n2/D_k4;
C_O2_out4(i) = C_O2_in*exp(-h_m4*channel_length(i)/(d4*air_velocity));
limitng_current_density4(i) = n*F*h_m4*(C_O2_in -
C_O2_out4(i))/log(C_O2_in/C_O2_out4(i))/10000;
D_k5 = 2*w*d5/(w+d5);
RE5 = air_velocity*D_k5/meu;
h_m5 = Sh*D_o2_n2/D_k5;
C_O2_out5(i) = C_O2_in*exp(-h_m5*channel_length(i)/(d5*air_velocity));
limitng_current_density5(i) = n*F*h_m5*(C_O2_in -
C_O2_out5(i))/log(C_O2_in/C_O2_out5(i))/10000;
D_k6 = 2*w*d6/(w+d6);
RE6 = air_velocity*D_k6/meu;
h_m6 = Sh*D_o2_n2/D_k6;
C_O2_out6(i) = C_O2_in*exp(-h_m6*channel_length(i)/(d6*air_velocity));
limitng_current_density6(i) = n*F*h_m6*(C_O2_in -
C_O2_out6(i))/log(C_O2_in/C_O2_out6(i))/10000;
D_k7 = 2*w*d7/(w+d7);
RE7 = air_velocity*D_k7/meu;
h_m7 = Sh*D_o2_n2/D_k7;
C_O2_out7(i) = C_O2_in*exp(-h_m7*channel_length(i)/(d7*air_velocity));
limitng_current_density7(i) = n*F*h_m7*(C_O2_in -
C_O2_out7(i))/log(C_O2_in/C_O2_out7(i))/10000;
D_k8 = 2*w*d8/(w+d8);
RE8 = air_velocity*D_k8/meu;
h_m8 = Sh*D_o2_n2/D_k8;
C_O2_out8(i) = C_O2_in*exp(-h_m8*channel_length(i)/(d8*air_velocity));
limitng_current_density8(i) = n*F*h_m8*(C_O2_in -
C_O2_out8(i))/log(C_O2_in/C_O2_out8(i))/10000;
D_k9 = 2*w*d9/(w+d9);
RE9 = air_velocity*D_k9/meu;
h_m9 = Sh*D_o2_n2/D_k9;
C_O2_out9(i) = C_O2_in*exp(-h_m9*channel_length(i)/(d9*air_velocity));
limitng_current_density9(i) = n*F*h_m9*(C_O2_in -
C_O2_out9(i))/log(C_O2_in/C_O2_out9(i))/10000;
end
Professor A. S. Mujumdar
ME Department, NUS, 2011
Contents
Introduction
Particle Characterization
Flow past spheres, non-spheres
Heat transfer from spheres under large Re range
Fluid Beds – Concept and modifications
Geldart’s Classification
Heat Transfer
Bed to Immersed Surface Heat Transfer – Correlations
Sample Calculations
FB Drying – Plug flow vs Well-mixed
Fluid be combustion (Simple Model)
Example of Fluid Bed Calculation
Closing Remarks
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Introduction
• fluidized bed describes a finely granulated layer of solid material (referred to as “the
mass”) that is loosened by fluid flowing through to such an extent that the particles
of solid material are free to move to a certain degree
• It is called “fluidized” because the solid material takes on properties similar to those
of a fluid (liquid)
• Fluidized beds are used widely in engineering for applications such as combustion,
reactors, drying, gasification of coal/biomass, thermal treatments of metal and
powder coating, granulation, heat transfer etc ……
• Liquid- solid fluidized beds have also been used for wide applications
• Heat transfer in fluid beds can be from Fluid – Particle, Particle – Fluid, Wall – Fluid
and to immersed surfaces, if any- care needed in calculation method used!
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Particle Characterization
Particle Size
6Vp 1⁄3
Volume Diameter (dV) dv = �
π
�
S p 1 ⁄2
Surface Diameter (dS) d S =� �
π
6V p d 3v
Surface-Volume Diameter (dSV) dSv = =
S p d 2s
Sieve Diameter
18μU t
Stokes Diameter (dst) d st =�
�ρ p −ρ s �g
Table: Suggested equivalent particle diameters for catalysts in catalytic reactor application
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Particle Shape
Sphericity (ф)
Surface area of volume equivalent sphere
ф=
Surface area of particle
Circularity (⊄)
Circumference of a circle having same
cross − sectional area as the particle
⊄=
Actual Perim eter of the cross −section
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5
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Dimensionless numbers
ReP = Ur dP ρf / μ
6
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7
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Now
So equation becomes
Hence
In stokes law regime the terminal settling velocity is proportional to the squere of the
particle diameter
In the Newton’s law regime the terminal settling velocity is proportional to the square
root of particle diameter and independent of viscocity
8
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Simple analysis for the fluid particle interaction is not valid but can be adopted to
model the multiple particle system
For suspension of particles the stokes law is assumed to apply but an effective
suspension viscosity and effective average suspension density is assumed
For suspension of particles the drag coefficient in stokes law regime becomes
where
Urel,t is known as the particle settling velocity in presence of other particles or Hindered
Settling Velocity
9
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For uniform sphere forming a suspension of solid column fraction less than 0.1
Or (1-ε) < 0.1,
2
∑� �� ���
Surface Mean ��� = �
∑� ��
Volume Mean 3 ∑ � �3
� � ��
��� = �
∑� ��
Length Mean 2
∑� �� ���
��� =
∑� �� ���
10
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11
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It has two factors, viscous force and the kinetic energy force
At the onset of fluidization, the gravity force on the particles in the bed must be
balanced by the drag, buoyancy, and pressure forces.
12
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The umf, the superficial velocity at minimum fluidizing condition is found by using
expression for ∆p/L
In a simplified form
Or
or
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Geldart’s Classification
A: Aeratable (Umb > Umf) Material has significant deaeration time (FCC Catalyst)
B: Bubbles Above (Umb = Umf) 500 micron sand
C: Cohesive (Flour, Fly Ash)
D: Spoutable (wheat, 2000 micron polyethylene pellets)
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Fluidization Regimes
Velocity Increasing
0 ≤ U ≤ Umf Fixed Bed Particles are quiescent; gas flows through interstices
Umf ≤ U ≤ Umb Particulate Bed expands smoothly and homogeneously with small-scale particle
Regime motion; bed surface is well defined
Umb ≤ U ≤ Ums Bubbling Regime Gas bubbles form above distributor, coalesce and grow; gas bubbles
promote solids mixing during rise to surface and breakthrough
Ums ≤ U ≤ UC Slug flow Regime Bubble size approaches bed cross section; bed surface rises and falls
with regular frequency with corresponding pressure fluctuation
UC ≤ U ≤ Uk Transition to Pressure fluctuation decrease gradually until turbulent fluidization
turbulent regime is reached
Fluidization
Uk ≤ U ≤ Utr Turbulent Regime Small gas voids and particle clusters and streamers dart to and fro;
bed surface is diffused and difficult to distinguish
U ≥ Utr Fast Fluidization Particles are transported out of the bed and need to be replaced and
recycled; normally has a dense phase region at bottom coexisting
with a dilute phase region on top; no bed surface
U » Utr Pneumatic Usually a once-through operation; all particles fed are transported
Conveying out in dilute phase with concentration varying along the column
height; no bed surface
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Slugging criteria
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The pressure drop across the distributor ΔPd is used as the criterion for
design, and ΔPd, values varying from 0.01 to 1.0 times the pressure drop
across the bed ΔPb have been suggested.
Siegel (1986):
ΔPd/ΔPb = 0.14 - 0.22 [Galileo number (1 - 10,000)]
Siegel, M. H., Merchuk, J.C., Schugerl, K., 1986. Air-Lift Reactor Analysis: Interrelationships between Riser,
Downcomer and Gas-Liquid Separator Behavior, including Gas Recirculation Effects. AIChE Journal 32(10),
1585-1595
Kunni, D., Levenspiel, O., 1991. Fluidization Engineering, 2nd Ed., Butterworth-Heinemann, Boston.
Litz, W. J., 1972. Design of gas distributors. Chemical Engineering 13, 162-166.
18
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Example
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Example contd…..
ρbedVbed
Vbed −
ρ solids
∴ ρbedVbed ≅ ρ solidsVsolids and ε =
Vbed
kg
980 3
ρbed m
ε = 1− = 1− = 0.35
ρ solids kg
1500 3
m
Effective diameter Sphericity
π 6
3
a = D 3
p
Φs =
(6 π )1 3 a = π 1 3 = 0.81
6
6 6
(0.02)3 = π D 3p
a
∴ D p = 0.025m
6
ρ f umf2
150(1 − ε mf )µ
(ρ p − ρ f )g = 3
+ 1.75
Φ s D p ε mf Φ s D p umf ρ f
kg kg m kg
1500 − 994 ∗ 9.80 2 = 4959 2 2
m3 m3 s m s
Example contd…..
1
Φ sε mf
3
= ∴ ε mf = 0.445
14
kg 2
1.75 ∗ ρ f umf
2 1.75 ∗ 994 ∗ umf
m3 kg
= = 9.748 ×105 2 2 ∗ umf
2
Φ s D p ε mf
3
0.81∗ 0.025 ∗ (0.445)3 m s
kg
150 ∗ (1 − 0.445) ∗ (0.693 cp ) ∗ 0.001 ∗ u mf
150 ∗ (1 − ε mf )µ ∗ umf m s
=
2 2
Φ s D p ε mf
3
(0.81) ∗ (0.025 m ) ∗ (0.445)
2 2 3
kg
= 1597 ∗ umf
m2s 2
kg kg kg
0 = 9.748 ×105 2
∗ u mf + 1597 2 2 ∗ u mf − 4959 2 2
m2 s 2 m s m s
m
umf = 0.071
s
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• Main advantage of fluidized beds is the extremely large area of solid surface
exposed to the fluidizing media
• Because of the solids mixing generated within the bulk of a bubbling gas
fluidized bed, temperature gradients are reduced to negligible proportions
• High rates of heat transfer are obtainable between the fluidizing solids and
the immersed transfer surface
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For homogeneous model, temperature of fluid and of bed are assumed identical
for and
for and
for and
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• However, because of the very large heat transfer surface area provided by a mass of small
particles, the heat transfer between gas and particles is rarely limiting in fluid bed heat
transfer
• One of the most commonly used correlations for gas-particle heat transfer coefficient is that
of Kunii and Levenspiel (only for low particle Reynolds numbers)
for
• Gas to particle heat transfer is relevant where a hot fluidized bed is fluidized by cold gas
• While following are the correlation suggested based on experimental data*
for
for
*Chen, J.C., Heat Transfer in handbook of fluidization and fluid systems, 2003
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Is given by,
The distance over which the temperature distance is reduced to half its initial value,
L0.5 is then
A bed of 450µm particles is operating at 150˚C. The temperature and superficial velocity
of the incoming gas are 550˚C and 0.4 m/s, respectively. Approximately how far will
the incoming gas have penetrated into the bed before it is cooled to 350˚C
Gas physical properties can be estimated at average temperature over the specified
range. In this particular case the average temperature is 450˚C. Hence the physical
properties of air
Gas velocity at 450˚C for an inlet velocity of 0.4m/s at 550˚C will be 0.35m/s
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The interphase gas convective component hgc, by which heat transfer between
particle and surface is augmented by interphase gas convective heat transfer
Thus,
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Decreasing particle size, for example, decreases the mean gas film thickness and so
improves hpc. However, reducing particle size into the Group C range will reduce
particle mobility and so reduce particle convective heat transfer. Increasing gas
temperature increases gas conductivity and so improves hpc.
The heat transfer coefficient increases with fluidizing velocity up to a broad maximum
hmax and then declines as the heat transfer surface becomes blanketed by bubbles.
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The maximum in hpc occurs relatively closer to Umf for Group B and D powders
since these powders give rise to bubbles at Umf and the size of these bubbles
increase with increasing gas velocity
Group A powders exhibit a non-bubbling fluidization between Umf and Umb and
achieve a maximum stable bubble size.
Zabrodsky (1966) has given correlation for hmax for group B particles
Khan (1978) has given correlation for hmax for group A particles
27
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In gas convective heat transfer the gas specific heat capacity is important as the gas
transports the heat around.
Gas specific heat capacity increases with increasing pressure and in conditions where gas
convective heat transfer is dominant, increasing operating pressure gives rise to an improved
heat transfer coefficient hgc.
Baskakov and Suprun (1972) has given correlation for hgc
where Um is the superficial velocity corresponding to the maximum overall bed heat transfer
coefficient
The most common approach assigns thermal resistance to a gaseous boundary layer at the
heat transfer surface, the enhancement of heat transfer is then attributed to the scouring
action of the solid particles on the gas film, decreasing the effective film thickness
for
Where
Where r is the radial position of the heat transfer tube and Rb is the radius of the bed
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Changed
Equation
for
and
for
Where
For rule of thumb estimate, the radiative heat transfer component can be
estimated using absolute temperatures and an adaptation of the stefen -
Boltzman equation in the form
where εr is the reduced emissivity to take into account the different emissivity properties of
surface εs and bed εb and is given by
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Industrial Processes
Physical Chemical
Heat and/or Heat and/or mass Heat transfer Gas/gas reactions Gas/solid reactions
Dominating mass transfer transfer between between in which solid acts in which solids are
Mechanism between particle/particle bed/surface as catalyst or a transformed
gas/particles or particle/surface heat sink
Applications • Solids Drying • Plastic coating of • Heat treatment of • Oil cracking, • Coal combustion
• Absorption of surfaces textile fibres, reforming • Coal gasification
solvents • Coating of wires, rubber, manufacturing of • Roasting of nickel and
• Cooling of pharmaceutical tablets glass, metal • Acrylonitrile zinc sulphides
fertilizer prills • Granulation components • Phthalic Anhydride • Incineration of liquid
• Food Freezing • Mixing of solids • Constant • Polyethylene and solid waste
• Dust Filtration temperature baths • Chlorinated • Catalyst Regeneration
hydrocarbons • Decomposition of
limestone
30
Mass Transfer in Fluidized
Beds - An Overview
1/13/2011
Special topics in ME6203 MASS TRANSPORT
Mass Transfer in Fluidized Beds‐An Overview
Professor A. S. Mujumdar
ME Department, NUS
E‐mail ‐ mpeasm@nus.edu.sg
Guest Lecturer
Sachin V. Jangam
Minerals, Metals and Material Technology Centre
NUS, Singapore (2011)
Contents
1
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Introduction
• Main applications of fluidized beds – Fluidized catalytic cracking; Combustion and
Gasification; Drying; Granulation;
• The performance of fluidized beds in all the above processes is affected by the
interface mass transfer
• Many times the mass transfer in fluidized beds is a potential rate controlling step in
fluidized bed reactors
• Depending on the type gas‐solid interactions, the rate controlling mechanism can be
1. Particle – gas mass transfer (Gas film diffusion) control
2. Pore diffusion control
3. Surface phenomenon control
Various Industrial Applications
Fluidized bed reactor Fluid bed dryer
Fluid bed catalytic cracker
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Mass transfer in fluidized beds
There are two approaches that can be used for prediction of mass
transfer rates in fluidized beds
• Homogeneous bed approach – considers fluidized bed behaving
as a fixed bed reactor and correlate the mass transfer coefficient
in fluidized bed in similar manner to that in a fixed bed based on
plug‐flow model
• Bubbling bed approach – Considers fluidized bed to consist of
two phases, a bubble and an emulsion phase, the gas interchange
between the two phases constitutes the rate of mass transfer
Useful Dimensionless Numbers
Sherwood Number – ratio of convective to diffusive mass transport
Convective mass transfer coefficient k L
Sh
Diffusive mass transfer coefficient
Sh
Schmidt Number – ratio of momentum to mass diffusivity
Momentum diffusivity μ
Sc Sc
Mass Diffusivity ρ
Reynolds Number – Comparison of Inertial force to viscous force
Reynolds Number – Comparison of gravitational and viscous force
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Homogeneous Bed Approach
Transfer between single sphere and surrounding gas
• Rate of mass transfer between well‐dispersed sphere and surrounding air can be
written as
Concentration of
A in the bulk gas
stream
Transfer rate of Mass transfer Concentration of
A from particle coefficient of A at particle‐gas
to gas single particle interphase
• The single particle mass transfer coefficient can be obtained from well established
correlation (Froessling, 1938)
• Eq (2)
where particle Reynolds number and Schmidt number can be defined as
The mass transfer coefficient is proportional to diffusion coefficient of gas and inversly
proportional to diameter of particle
Homogeneous Bed Approach
Transfer between single sphere and surrounding gas
For non‐spherical particle the sieve diameter (dp) will replace the diameter of
the particle and the equation becomes
where particle Reynolds number is
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Homogeneous Bed Approach
Transfer between fixed bed particles and flowing gas
Rate of mass transfer between fixed bed of particles and surrounding gas can be written
in the same fashion as the one for single particle
Concentration of
Combined mass A in the bulk gas
transfer rate stream
Average mass Concentration of
from all the
transfer Total exterior A at particle‐gas
particles
coefficient of surface of all interphase
particles individual
particles
Homogeneous Bed Approach
Transfer between fixed bed particles and flowing gas
The correlation for the average mass transfer coefficient kg,bed was given by Ranz (1952)
Total particle exterior surfaces Sex,particles Volume of bes
segment Bed voidage
Method of Kunni Levenspiel
Particle surface to
particle volume ratio
Hence the equation for total exterior particle
surfaces becomes
Sphericity of bed
particles
5
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Homogeneous Bed Approach
Transfer between fluidized bed particles and fluidizing gas
The rate of particle to gas mass transfer in the differential segment of fluidized bed can
be written as
Average mass Total exterior
transfer coefficient surfaces of the
associated with fluidized particles in
fluidizing particles the segment of bed
Kg,bed for fluidized beds is always higher than that for fixed beds
Homogeneous Bed Approach
Average mass transfer coefficient for fluidizing particles
The mass transfer coefficient for fluidized bed particles can be lower or higher than that
of single particles
Generally for low Reynolds numbers the mass transfer coefficient for single particles is
higher than for fluidizing particles however, reverse is true for higher particle
Reynolds numbers (>80)
Resnick and White (1949) reported the average mass transfer coefficient for the
fluidizing particles (for air system with Sc = 2.35)
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Homogeneous Bed Approach
Average mass transfer coefficient for fluidizing particles
Homogeneous Bed Approach
Particle – gas mass transfer coefficient for fluidized bed particles
Using Sh equation for
single particle Eq (2) Using Sh equation for
single particle Eq (2)
particle‐gas mass transfer coefficient for Comparison of mass transfer coefficient for
fluidized bed particles fluidized bed and fixed bed
• It should be noted that the same correlations can be used for fluidized beds and fixed beds…
• “Sh” for same group of particles continues to increase with the particle Reynolds number even
during the transition from fixed bed to fluidized bed operations
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Homogeneous Bed Approach
Limitations of Homogeneous bed approach
The experimentally measured coefficient values for the bed particles under fixed bed or
fluidized bed conditions can be lower or higher than the theoretically estimated
values
For fine particles the mass transfer coefficients were found to be well below the
estimated values from correlations
The measured mass transfer coefficient by this approach should be treated as empirical
in nature
Using Sh equation
for single particle
Eq (2)
Summary of particle‐gas mass
transfer coefficient
Bubbling Bed Approach
Takes in to account existence of a two phases: bubble phase and
emulsion phase
Bubble phase – considered as spherical bubbles surrounded by spherical clouds
Bubble
Cloud
There are three different models available based on this approach
Kunni and Levenspiel (bubble – emulsion transfer)
Partridge and Rowe (cloud – emulsion transfer)
Chavarie and Grace (Empirical correlation for bubble‐ emulsion transfer)
8
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Model of Kunni and Levenspiel
Model for vaporization or sublimation of A from all particles in bed
Assumptions:
Fresh gas enters the bed only as bubbles
Equilibrium is established rapidly between CA at gas‐particle interphase and
its surroundings
These assumptions lead to the following equation in terms of bubble‐emulsion mass
transfer coefficient (KGB)as follows
In this approach both cloud and the emulsion phases are assumed perfectly mixed
Model of Kunni and Levenspiel
Relation between KGB and Kg,bed
The equation reported in last slide for mass transfer by Kunni and Levenspiel can be
derived using the mass transfer rate equation for homogeneous bed approach
With the assumption that fresh gas enters the
bed only as bubbles the above equation
becomes
Where CA,b is the concentration of A in
bubble phase
9
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Model of Kunni and Levenspiel
Relation between KGB and Kg,bed
The solutions of the previous equations finaly results in the following relation between
KGB and kg,bed
The definition of Sherwoods Number becomes
KGB for Nonporous and Nonadsorbing Particles
The particles dispersed in bubble phase will not contribute to any additional mass
transfer and hence; hence transfer across the bubble‐cloud boundary therefore is the
only source of mass transfer
Hence
Where Kbc is the bubble‐cloud interchange coefficient derived by Davidson and Harrison
as
KGB for highly adsorbing particles
For single particle
So the KGB equation becomes
10
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KGB for highly adsorbing particles
For highly adsorbing particles, both particles dispersed in bubble and the bubble‐cloud
gas interchange can contribute to the particle‐gas mass transfer and the expression
for KGB becomes
For single particle
So the KGB equation becomes
Hence the Sherwood number for bed becomes
KGB for Porous or Partially Adsorbing Particles
For porous or partially adsorbing particles, Kunni and Levenspiel derived the following
equation
Where,
And
m is the adsorption equilibrium constant defined as
CAs is the concentration of tracer A within the particle in equilibrium with the
concentration CiA of tracer gas at the gas‐particle interphase.
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Model of Partidge and Rowe
The cloud surrounding the bubble is considered as the primary mass transfer boundary
and the bubble and the clod phases are considered as perfectly mixed single phase
as shown in the following figure
The mass transfer equation is
Volume of gas Cloud
in the bubble‐ emulsion mass Cloud exterior
transfer surface
cloud phase
coefficient
Model of Partidge and Rowe
Partidge and Rowe have given a correlation for mass transfer coefficient in terms of
Sherwood number as follows
where Sc is the Schmidt number as defined earlier while Rec is defined as
Relative velocity Diameter of
sphere with
between rising
the same
cloud and
emulsion volume as the
cloud
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Model of Chavarie and Grace
Measurement of mass transfer rates for bubble containing ozone injected into an air‐
fluidized two dimensional bed and proposed following empirical equation,
Table shows the models for kgc given by various researchers
Model of Chavarie and Grace
Table showing some more models for kgc given by various researchers
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Relation between mass and heat transfer coefficient
The correlations for particle to gas mass and heat transfer coefficient are closely related
when the Sherwood number (Sh) is equivalent to Nusselt number (Nu) and the
Schmidt number (Sc) is equivalent to Prandtl number (Pr)
For example, the correlation for Nusselt number for particles in a fixed bed is expressed
as
The corresponding correlation equation for the Sherwood number has the form
Hence the correlations obtained for Nu (heat transfer) can be converted to Sherwood
number to obtain mass transfer coefficient, provided ‐‐‐ Sh Nu and Sc Pr
Some Concluding Remarks on Mass Transfer in FB
Fluidized beds are very important for solid‐fluid contact for various important
industrial applications
Heat as well as mass transfer is important for design considerations
When kinetic processes such as mass transfer are carried out with fluidized
beds the particles dispersed in bubble phase should be taken in to account
Mass transfer coefficient measured for the bed as a whole (kgbed) is model
dependent
For large particles (cloudless bubble bed) the plug flow model closely matches
the bed conditions in the bed and the mass transfer coefficient for bed should
be equal to single particle mass transfer coefficient
For fine particles kgbed << kgsingle
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Application of Fluidized Beds
Industrial Processes
Physical Chemical
15
1/13/2011
Applications
Fluidized bed drying
Fluidizing with hot air is an attractive means for drying many moist powders and
granular products
The technique has been used industrially for drying crushed minerals, sand,
polymers, fertilizers, pharmaceuticals, crystalline materials and many other
products.
The main reason for its popularity is
Efficient gas‐solids contacting leads to compact units and relatively low capital cost
combined with high thermal efficiency
Very high heat and mass transfer and hence reduced drying times
The absense of moving parts, low maintenance cost and possibility of using
continuous mode
The main limitation is the material to be dried should be fluidizable and should
have narrow particle size distribution
Fluid Bed Dryer
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Fluidized Bed Drying
Different designs of fluid bed dryers
Fluidized Bed Drying
Well mixed fluid bed dryer • common FBD used in industry.
• bed temperature uniform, equal to the
product and exhaust gas temperatures.
• particle residence time distribution is
wide
• wide range of product moisture content.
• feed is continuously charged into FB of
relatively dry particles, this enhances
fluidization quality.
• a series of well‐mixed continuous dryers
may be used with variable operating
parameters.
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Fluidized Bed Drying
Modeling ‐ Fluid Bed Dryer
Diffusion model
This model assumes that the drying of single particle in the fluidized bed is controlled
by the diffusion of moisture inside the particle
Empirical model
• In this approach the drying process is divided into different periods where drying
mechanisms in each drying period are different;
• The solution of Fick’s law of diffusion expresses the moisture content in terms of
drying time by exponential function;
• Experimental data obtained from fluid bed drying experiments can be correlated
using exponential function
Kinetic model
Single phase model ‐ Explained later
Two‐phase model ‐ Explained later
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1/13/2011
Modeling ‐ Fluid Bed Dryer
Single phase model
The fluidized bed is regarded essentially as a continuum
Heat and mass balances are applied over the fluidized bed
Assumption ‐ particles in the bed are perfectly mixed
Mass balance
Energy balance
Modeling ‐ Fluid Bed Dryer
Two phase model
Two‐phase model of fluidized bed drying treats the fluidized bed to be composed of a
bubble phase (dilute phase) and an emulsion phase (dense phase)
gas in excess of minimum fluidization velocity, umf, flows through the bed as bubbles
whereas the emulsion phase stays stagnant at the minimum fluidization conditions
Mass balance
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Modeling ‐ Fluid Bed Dryer
Two phase model
Mass balance of liquid in the bubble phase
M ass balance of liquid in the interstitial gas in the dense phase gives the following ng
equation
Mass balance of liquid in the dense‐phase particles
The coupled mass and energy balance in dense phase that consists of particles and
interstitial gas phases
Fluidized bed combustion boilers
• Fluidized bed combustion systems use a heated bed of sand‐like material suspended (fluidized)
within a rising column of air to burn many types and classes of fuel.
• This technique results in a vast improvement in combustion efficiency of high moisture content
fuels, and is adaptable to a variety of "waste type fuels.
• The scrubbing action of the bed material on the fuel particle enhances the combustion process
by stripping away the carbon dioxide and char layers that normally form around the fuel
particle.
• This allows oxygen to reach the combustible material much more readily and increases the rate
and efficiency of the combustion process
• Particles (e.g. sand) are suspended in high velocity air stream: bubbling fluidized bed
• Combustion at 840° – 950°C
• Capacity range 0,5 T/hr to 100 T/hr
• Fuels: coal, washery rejects, rice husk, bagasse and agricultural wastes
• Benefits: compactness, fuel flexibility, higher combustion efficiency, reduced SOx & NOx
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Fluidized bed combustion boilers
Atmospheric Fluidized Bed Combustion (AFBC) Boiler
• Most common FBC boiler that uses preheated atmospheric air as fluidization and
combustion air
Fluidized bed combustion boilers
Pressurized Fluidized Bed Combustion (PFBC) Boiler
• Compressor supplies the forced draft and combustor is a pressure vessel
• Used for cogeneration or combined cycle power generation
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Fluidized bed combustion boilers
Circulating Fluidized Bed Combustion units
• A “Circulating Fluidized Bed Boiler” commonly
abbreviated as CFB is a device for generating
steam by burning fossil fuels (coal) in a furnace
operated under a special hydrodynamics
conditions.
• Bed material is heated upto the ignition
temperature of the coal with the help of natural
gas burner. Coal and limestone are injected at the
bottom of the combustor.
• Total air required for combustion is split in to
primary air and secondary air.
• Circulating solids are transported in the combustor
at a velocity exceeding the terminal velocity of
average particles.
• Recirculation of solids creating uniformity in the
temperature makes the combustor as an efficient
combustion system
Visit us at
http://serve.me.nus.edu.sg/arun/
http://www.mujumdar.net78.net/
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Key References
• Yang, W.C.; Handbook of Fluidization and Fluid –Particle Systems, Marcel Dekker, USA,
2003
• Kunni, D.; Levenspiel, O. Fluidization Engineering, 1969
• Mujumdar, A.S. Handbook of Industrial Drying, 3rd Ed; CRC Press: Boca Raton, FL,
2006
Some questions for self study
For drying of certain product, the ambient air of 80% relative humidity is heated
to 70°C before entering the fluid bed dryer of uniform particle size.
• Discuss qualitatively, what will be the effect if the air is cooled down to 5°C
and reheated back to same temperature of 70°C before entering the dryer.
During which drying rate period will this be more useful
• Discuss what will be the effect on performance if the bed particles have wide
size distribution, Suggest improvements to tackle this situation.
• What will be the effect on drying if heated inert spherical particles of same
size are added in a bed of particles to be dried?
• How can one enhance the drying of a non‐spherical particles in a fluidized
bed?
For combustion of a single particle
• Discuss what would be the combustion behavior of a single coal particle of
same mass with different shapes such as Sphere, Cylinder (D=L), cube
• Discuss qualitatively the difference in combustion of a coal particle one with
20% porosity and another with 60% porosity
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