Technological University of the Philippines Name:

Basic Arts and Sciences Department Student No.:

Taguig Campus Program/Year/Section:
Bicutan, Taguig City Instructor:

WRITING AND BALANCING CHEMICAL EQUATION:

Write and balance the following reaction. Indicate the state and reaction condition if possible (25 points).

1. 𝑆𝑜𝑙𝑖𝑑 𝑀𝑎𝑔𝑛𝑒𝑠𝑖𝑢𝑚 + 𝑂𝑥𝑦𝑔𝑒𝑛 𝑔𝑎𝑠 → 𝑆𝑜𝑙𝑖𝑑 𝑀𝑎𝑔𝑛𝑒𝑠𝑖𝑢𝑚 𝑂𝑥𝑖𝑑𝑒

2. 𝐶𝑜𝑚𝑝𝑙𝑒𝑡𝑒 𝑐𝑜𝑚𝑏𝑢𝑠𝑡𝑖𝑜𝑛 𝑜𝑓 𝐵𝑢𝑡𝑎𝑛𝑒, 𝐶4 𝐻10

3. 𝑅𝑒𝑎𝑐𝑡𝑖𝑜𝑛 𝑜𝑓 𝑆𝑜𝑑𝑖𝑢𝑚 𝑀𝑒𝑡𝑎𝑙 𝑡𝑜 𝑙𝑖𝑞𝑢𝑖𝑑 𝑤𝑎𝑡𝑒𝑟

4. 𝐷𝑒𝑐𝑜𝑚𝑝𝑜𝑠𝑖𝑡𝑖𝑜𝑛, 𝑏𝑦 ℎ𝑒𝑎𝑡𝑖𝑛𝑔, 𝑜𝑓 𝑠𝑜𝑙𝑖𝑑 𝑎𝑚𝑚𝑜𝑛𝑖𝑢𝑚 𝑛𝑖𝑡𝑟𝑎𝑡𝑒 𝑡𝑜 𝑝𝑟𝑜𝑑𝑢𝑐𝑒 𝑑𝑖𝑛𝑖𝑡𝑟𝑜𝑔𝑒𝑛

𝑚𝑜𝑛𝑜𝑥𝑖𝑑𝑒 𝑔𝑎𝑠 (𝑙𝑎𝑢𝑔ℎ𝑖𝑛𝑔 𝑔𝑎𝑠) 𝑎𝑛𝑑 𝑤𝑎𝑡𝑒𝑟 𝑣𝑎𝑝𝑜𝑟

5. 𝑅𝑒𝑎𝑐𝑡𝑖𝑜𝑛 𝑜𝑓 𝑚𝑒𝑡ℎ𝑎𝑛𝑒 (𝐶𝐻4 ), 𝑎𝑚𝑚𝑜𝑛𝑖𝑎, 𝑎𝑛𝑑 𝑜𝑥𝑦𝑔𝑒𝑛 𝑔𝑎𝑠𝑒𝑠 𝑡𝑜 𝑓𝑜𝑟𝑚 𝑔𝑎𝑠𝑒𝑜𝑢𝑠 ℎ𝑦𝑑𝑟𝑜𝑔𝑒𝑛
𝑐𝑦𝑎𝑛𝑖𝑑𝑒 (𝐻𝐶𝑁) 𝑎𝑛𝑑 𝑤𝑎𝑡𝑒𝑟 𝑣𝑎𝑝𝑜𝑟

6. 𝐶𝑜𝑚𝑝𝑙𝑒𝑡𝑒 𝑐𝑜𝑚𝑏𝑢𝑠𝑡𝑖𝑜𝑛 𝑜𝑓 𝐿𝑎𝑐𝑡𝑖𝑐 𝐴𝑐𝑖𝑑, 𝐶𝐻3 𝐶𝐻(𝑂𝐻)𝐶𝑂𝑂𝐻

7. 𝐺𝑎𝑠𝑒𝑜𝑢𝑠 𝐸𝑡ℎ𝑎𝑛𝑒 (𝐶2 𝐻6 ) + 𝑂𝑥𝑦𝑔𝑒𝑛 𝐺𝑎𝑠 → 𝐶𝑎𝑟𝑏𝑜𝑛 𝐷𝑖𝑜𝑥𝑖𝑑𝑒 𝑔𝑎𝑠 + 𝐿𝑖𝑞𝑢𝑖𝑑 𝑤𝑎𝑡𝑒𝑟

8. 𝐷𝑖𝑠𝑠𝑜𝑙𝑣𝑖𝑛𝑔 𝑜𝑓 𝑙𝑖𝑚𝑒𝑠𝑡𝑜𝑛𝑒 (𝑐𝑎𝑙𝑐𝑖𝑢𝑚 𝑐𝑎𝑟𝑏𝑜𝑛𝑎𝑡𝑒)𝑖𝑛 𝑤𝑎𝑡𝑒𝑟 𝑐𝑜𝑛𝑡𝑎𝑖𝑛𝑖𝑛𝑔 𝑑𝑖𝑠𝑠𝑜𝑙𝑣𝑒𝑑 𝑐𝑎𝑟𝑏𝑜𝑛

𝑑𝑖𝑜𝑥𝑖𝑑𝑒 𝑡𝑜 𝑝𝑟𝑜𝑑𝑢𝑐𝑒, 𝑐𝑎𝑙𝑐𝑖𝑢𝑚 ℎ𝑦𝑑𝑟𝑜𝑔𝑒𝑛 𝑐𝑎𝑟𝑏𝑜𝑛𝑎𝑡𝑒.

9. 𝐶𝑜𝑚𝑝𝑙𝑒𝑡𝑒 𝑐𝑜𝑚𝑏𝑢𝑠𝑡𝑖𝑜𝑛 𝑜𝑓 𝑝𝑟𝑜𝑝𝑦𝑙𝑒𝑛𝑒, (𝐶3 𝐻6 )

10. 𝐶𝑜𝑚𝑝𝑙𝑒𝑡𝑒 𝑐𝑜𝑚𝑏𝑢𝑠𝑡𝑖𝑜𝑛 𝑜𝑓 𝑖𝑠𝑜𝑝𝑟𝑜𝑝𝑦𝑙, (𝐶𝐻3 𝐶𝐻(𝑂𝐻)𝐶𝐻3 )

Problem Set – Stoichiometry /JOA/ Page 1 of 6

WRITING AND BALANCING CHEMICAL EQUATION:

Balance the following chemical equation (25 points).

1. 𝐶 + 𝑂2 → 𝐶𝑂

14. 𝐶𝐻4 + 𝐵𝑟2 → 𝐶𝐵𝑟4 + 𝐻𝐵𝑟

2. 𝐶𝑂 + 𝑂2 → 𝐶𝑂2

15. 𝑁2 𝑂5 → 𝑁2 𝑂4 + 𝑂2
3. 𝐻2 + 𝐵𝑟2 → 𝐻𝐵𝑟

16. 𝐾𝑁𝑂3 → 𝐾𝑁𝑂2 + 𝑂2

4. 𝐾 + 𝐻2 𝑂 → 𝐾𝑂𝐻 + 𝐻2

17. 𝑁𝐻4 𝑁𝑂3 → 𝑁2 𝑂 + 𝐻2 𝑂

5. 𝑀𝑔 + 𝑂2 → 𝑀𝑔𝑂

18. 𝑁𝐻4 𝑁𝑂2 → 𝑁2 + 𝐻2 𝑂

6. 𝑂3 → 𝑂2

19. 𝑁𝑎𝐻𝐶𝑂3 → 𝑁𝑎2 𝐶𝑂3 + 𝐻2 𝑂 + 𝐶𝑂2

7. 𝐻2 𝑂2 → 𝐻2 𝑂 + 𝑂2

20. 𝑃4 𝑂10 + 𝐻2 𝑂 → 𝐻3 𝑃𝑂4

8. 𝑁2 + 𝐻2 → 𝑁𝐻3

21. 𝐻𝐶𝑙 + 𝐶𝑎𝐶𝑂3 → 𝐶𝑎𝐶𝑙2 + 𝐻2 𝑂 + 𝐶𝑂2

9. 𝑍𝑛 + 𝐴𝑔𝐶𝑙 → 𝑍𝑛𝐶𝑙2 + 𝐴𝑔

22. 𝐴𝑙 + 𝐻2 𝑆𝑂4 → 𝐴𝑙2 (𝑆𝑂4 )3 + 𝐻2

10. 𝑆8 + 𝑂2 → 𝑆𝑂2

23. 𝐶𝑂2 + 𝐾𝑂𝐻 → 𝐾2 𝐶𝑂3 + 𝐻2 𝑂

11. 𝑁𝑎𝑂𝐻 + 𝐻2 𝑆𝑂4 → 𝑁𝑎2 𝑆𝑂4 + 𝐻2 𝑂

24. 𝐶𝐻4 + 𝑂2 → 𝐶𝑂2 + 𝐻2 𝑂

12. 𝐶𝑙2 + 𝑁𝑎𝐼 → 𝑁𝑎𝐶𝑙 + 𝐼2

25. 𝐵𝑒2 𝐶 + 𝐻2 𝑂 → 𝐵𝑒(𝑂𝐻)2 + 𝐶𝐻4

13. 𝐾𝑂𝐻 + 𝐻3 𝑃𝑂4 → 𝐾3 𝑃𝑂4 + 𝐻2 𝑂

Problem Set – Chemical Equation /JOA/ Page 2 of 6

STOICHIOMETRY:

Solve the following problem:

1. Elemental sulfur occurs as octatomic molecules, S8. What mass of fluorine gas is needed to react completely
with 17.8 g of sulfur to form sulfur hexafluoride?

2. Elemental phosphorus occurs as tetratomic molecules, P4. What mass of chlorine gas is needed to react
completely with 455 g of phosphorus to form phosphorus pentachloride?

3. When 0.100 mol of carbon is burned in a closed vessel with 8.00 g of oxygen, how many grams of carbon dioxide
can form? Which reactant is in excess, and how many grams of it remain after the reaction?

4. A mixture of 0.0375 g of hydrogen and 0.0185 mol of oxygen in a closed container is sparked to initiate a
reaction. How many grams of water can form? Which reactant is in excess, and how many grams of it remain
after the reaction?

5. Calcium nitrate and ammonium fluoride react to form calcium fluoride, dinitrogen monoxide, and water vapor.
What mass of each substance is present after 16.8 g of calcium nitrate and 17.50 g of ammonium fluoride react
completely?

Problem Set – Chemical Equation /JOA/ Page 3 of 6

CHEMICAL REACTION IN A SOLUTION:

Solve the following problem.

1. What volume of 0.0797 M of KMnO4 is necessary to convert 9.13 g Potassium Iodide to in the reaction below?
Assume that Sulfuric Acid is present in excess.

2 𝐾𝑀𝑛𝑂4 + 10 𝐾𝐼 + 8 𝐻2 𝑆𝑂4 → 6 𝐾2 𝑆𝑂4 + 2 𝑀𝑛𝑆𝑂4 + 5 𝐼2 + 8 𝐻2 𝑂

2. How many milliliters of 0.650 M of K2CrO4 are needed to precipitate all the silver in 415 mL of 0.186 M Silver
Nitrate?

2 𝐴𝑔𝑁𝑂3 (𝑎𝑞) + 𝐾2 𝐶𝑟𝑂4 (𝑎𝑞) → 𝐴𝑔2 𝐶𝑟𝑂4 (𝑠) + 2 𝐾𝑁𝑂3 (𝑎𝑞)

3. Concentrated sulfuric acid (18.3 M) has a density of 1.84 g/mL. (a) How many moles of sulfuric acid are present
per milliliter of solution? (b) What is the mass % of H2SO4 in the solution?

4. A sample of concentrated nitric acid has a density of 1.41 g/mL and contains 70.0% HNO3 by mass. (a) What
mass of HNO3 is present per liter of solution? (b) What is the molarity of the solution?

5. Which reactant is in excess and by how many moles when 350.0 mLof 0.210 M sulfuric acid reacts with 0.500 Lof
0.196 M sodium hydroxide to form water and aqueous sodium sulfate?

Problem Set – Chemical Equation /JOA/ Page 4 of 6

LIMITING REAGENT:

Solve the following:

1. The reaction of calcium hydride and water produces calcium hydroxide and hydrogen as products. How many
moles of Calcium Hydroxide will be formed in the reaction between 0.82 mol CaH2 (s) and 1.54 mol H2O (l)?

2. Ammonia can be generated by heating together the solids NH4Cl and Ca(OH)2, CaCl2 and H2O are also formed. (a)
If a mixture containing 33.0 g each of NH4Cl and Ca(OH)2 is heated, how many grams of NH3 will form? (b) Which
reactant remains in excess, and in what mass?

3. Chlorine can be generated by heating together calcium hypochlorite and hydrochloric acid. Calcium chloride and
water are also formed. (a) If 50.0 g Ca(OCl)2 and 275 mL of 6.00 M HCl are allowed to react, how many grams of
chlorine gas will form? (b) Which reactant, Ca(OCl)2 or HCl, remains in excess, and in what mass?

Problem Set – Chemical Equation /JOA/ Page 5 of 6

THEORETICAL, ACTUAL AND PERCENTAGE YIELD:

Solve the following:

1. In the reaction of 277 g CCl4 with an excess of HF, 187 g CCl2F2 is obtained. What are the (a) theoretical, (b)
actual, and (c) percent yields of this reaction?
𝐶𝐶𝑙4 + 2 𝐻𝐹 → 𝐶𝐶𝑙2 𝐹2 + 2𝐻𝐶𝑙

2. Nitrogen gas, N2, can be prepared by passing gaseous ammonia over solid copper(II) oxide, CuO, at high
temperatures. The other products of the reaction are solid copper, Cu, and water vapor. In a certain experiment,
a reaction mixture containing 18.1 g NH3 and 90.4 g CuO yields 6.63 g N2. Calculate the percent yield for this
experiment.

3. The reaction of 15.0 g C4H9OH, 22.4 g NaBr, and 32.7 g H2SO4 yields 17.1 g C4H9Br in the reaction shown. What
are the (a) theoretical yield, (b) actual yield, and (c) percent yield of this reaction?

𝐶4 𝐻9 𝑂𝐻 + 𝑁𝑎𝐵𝑟 + 𝐻2 𝑆𝑂4 → 𝐶4 𝐻9 𝐵𝑟 + 𝑁𝑎𝐻𝑆𝑂4 + 𝐻2 𝑂

Problem Set – Chemical Equation /JOA/ Page 6 of 6