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WHAT IS STEAM? A
Like other substances, water can exist in the
form of a solid, when we call it ice; as a liquid
when we call it water or as a gas when we
call it steam. In this section our attention will
largely be concentrated on the liquid and gas
phases and on the change from one phase
to the other.
If heat energy is added to water, its temperature
rises until a value is reached at which the water
can no longer exist as a liquid. We call this the
“saturation” point and with any further addition
of energy, some of the water will boil off as
steam. This evaporation requires relatively
large amounts of energy, and while it is being
added, the water and the steam released are
both at the same temperature.
Equally, if we can encourage the steam to
release the energy that was added to evaporate
it, the steam will condense and water of the
same temperature will be formed.
WHY STEAM?
Steam has been used as a conveyor of energy When the total specific enthalpy of evaporation
since the Industrial Revolution. After its first has been added to the kilogram of water in our
use for cooking food, it has continued to be cylinder, then all the water will exist as steam
a flexible and versatile tool for the industry at atmospheric pressure.
wherever heating is needed. Its volume will be much more than the volume of
It is produced by the evaporation of water which the liquid water (over 1.600 times). Clearly the
is a relatively cheap and plentiful commodity molecules of water in the liquid condition are Weight
in most parts of the world. Its temperature can held together more closely than the molecules
be adjusted very accurately by the control of of steam. The process of evaporation can be
its pressure, using valves; it carries relatively considered as one of adding sufficient energy
large amounts of energy in a small mass to each molecule that it can break the bonds
Piston Thermo-
and when it is encouraged to condense back holding them together, so that it can leave 1 kg of water meter
to water, high rates of energy flow (into the the liquid in the cylinder and move freely in Energy
material being heated) are obtained, so that the gas phase. supply
the heat using system does not have to be Now it is to be expected that if the pressure
unduly large. above the liquid were increased, the molecules
would find it more difficult to leave. We would
THE FORMATION OF STEAM have to give them more energy before they
The best way of explaining the formation could break the bonds and move into the gas
of steam is by considering an imaginary, phase, which means that the temperature of
idealised, experiment (see Fig. 1). the water would increase to over 100°C before Fig. 1
boiling occurred.
Suppose we took a cylinder with its bottom end DEFINITIONS
closed and surrounded it with insulation which This is, indeed, exactly what is found in
was 100% efficient so that there was no heat practice. If our imaginary cylinder were fitted Enthalpy
Availability, design and specifications are subject to change without notice. All rights reserved.
loss from it. If we poured into the cylinder 1 with a frictionless piston, and a weight placed
This is the term given for the total energy,
kg of water at the temperature of melting ice, on top of the piston so as to apply pressure to
due to both the pressure and temperature, of
0°C, we could use this as a datum point and the water, then the temperature of the water
a fluid or vapour (such as water or steam) at
say that for our purposes its heat content, or could be increased above the normal 100°C
any given time and condition.
enthalpy, was zero. Any addition of heat to before any evaporation commenced.
the water would raise its temperature, until The basic unit of measurement for all types
However, at any given pressure there is a
it reaches 100°C (the cylinder being open at of energy is the joule (symbol J). Since one
corresponding temperature above which water
the top so that only atmospheric pressure is joule represents a very small amount of
cannot exist as a liquid, and any enthalpy above
applied to the water). energy, it is usual to multiply it by 1.000 and
the “specific enthalpy of saturated water” will
use kilojoules (kJ).
With any further addition of enthalpy, the water evaporate some of the liquid.
cannot exist as a liquid and some of it will boil Equally, if the pressure of the water is lowered Specific Enthalpy
off as steam. below the normal atmospheric pressure, than
it is easier for the molecules to break free. Is the enthalpy (total energy) of a unit mass
The total enthalpy held by each kilogram of (1 kg). The units generally used are kJ/kg.
liquid water at the boiling temperature is called They require a lower energy level, so the
the “specific enthalpy of saturated water” and temperature at which boiling occurs, and the
is shown by the symbol “hf”. corresponding “enthalpy of saturated water”, Specific Heat Capacity
are reduced. A measure of the ability of a substance to
The extra enthalpy which has to be added to
absorb heat. It is the amount of energy (joules)
each kilogram of water to turn it into steam is
required to raise 1 kg by 1 K. Thus specific heat
called the “specific enthalpy of evaporation”
capacity is expressed in kJ/kgK.
and is show by the symbol “hfg”.
The specific heat capacity of water is 4,186 kJ/
00099GB-2005/R01
Availability, design and specifications are subject to change without notice. All rights reserved.
will be exactly 1 kg (mass) of steam. However,
further increase in temperature.The additional the volume occupied by a given mass depends the saturation temperature has been reached,
heat is used in evaporating the water and on its pressure. At atmospheric pressure 1 kg and it is found that the rate at which we can
converting it into steam. of steam occupies nearly 1.673 cubic metres get energy to flow from superheated steam is
(m3) At a pressure of 10 bar abs, that same often less than we can achieve with saturated
The enthalpy which produces a change
1 kg of steam will only occupy 0,1943 m3. The steam, even though the superheated steam
of state from liquid to gas without change
is at a higher temperature.
of temperature is called the “enthalpy of
evaporation”.The enthalpy of evaporation is the 20
difference between the enthalpy of saturated
water and that of dry saturated steam.
Absolute pressure (bar)
Dryness fraction
whereas the enthalpy of evaporation has
decreased (by 247,7 kJ). T2 Constant pressures D
The basic rules that arise from this are:
l) When steam pressure increases:
- Enthalpy of saturated steam increases E
slightly F
- Enthalpy of saturated water increases
- Enthalpy of evaporation decreases 200
ll) When steam pressure decreases: T1 B 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 Superheated
- Enthalpy of saturated steam decreases C region
slightly
- Enthalpy of saturated waterdecreases
- Enthalpy of evaporation increases
Thus, the lower the steam pressure the higher
Availability, design and specifications are subject to change without notice. All rights reserved.
Vapour Availability, design and specifications are subject to change without notice. All rights reserved.
Space heating
system
Process
Pan Pan vessel
Vapour
Make-up
water Vat
Vapour Condensate
Feed tank
00099GB-2005/R01
Feed pump
Fig. 8
Availability, design and specifications are subject to change without notice. All rights reserved.
187,96 10,987 12 0,163 6,127 798,42 190,7 1984,31 473,94 2782,73 664,64 2,6878 0,000015
191,6 11,987 13 0,151 6,617 814,68 194,58 1970,73 470,7 2785,42 665,29 2,7327 0,000015
194,04 12,987 14 0,141 7,106 830,05 198,26 1957,73 467,6 2787,79 665,85 2,7767 0,000016
198,28 13,987 15 0,132 7,596 844,64 201,74 1945,24 464,61 2789,88 666,35 2,8197 0,000016
212,37 18,987 20 0,1 10,047 908,56 217,01 1888,65 451,1 2797,21 668,1 3,0248 0,000016
217,24 21 22,013 0,091 11,032 930,92 222,35 1868,11 446,19 2799,03 668,54 3,1034 0,000016
219,55 21,987 23 0,087 11,525 941,57 224,89 1858,2 443,82 2799,77 668,71 3,1421 0,000016
221,78 22,987 24 0,083 12,02 951,9 227,36 1848,49 441,5 2800,39 668,86 3,1805 0,000017
223,94 23,987 25 0,080 12,515 961,93 229,75 1838,98 439,23 2800,91 668,99 3,2187 0,000017
224,02 24 25,013 0,0797 12,547 952,2 229,86 1840,9 439,77 2803,1 669,63 - -
233,84 28,987 30 0,067 15,009 1008,33 240,84 1793,94 428,48 2802,27 669,31 3,4069 0,000017
242,54 33,987 35 0,057 17,536 1049,74 250,73 1752,2 418,51 2801,95 669,23 3,5932 0,000017
250,33 38,987 40 0,050 20,101 1087,4 259,72 1712,94 409,13 2800,34 668,85 3,7806 0,000018
251,8 40 41,013 0,048 20,619 1094,56 261,43 1705,33 407,31 2799,89 668,74 3,8185 0,000018
Boiling point: Temperature of saturated vapour or also of boiling water under the same pressure. Specific enthalpy of steam: Total heat contained in 1 kg of steam. It is the sum of the enthalpy of the
Relative pressure: Pressure above atmospheric pressure measured by commonly used pressure gauges. various states, liquid (water) and gas (vapour).
Absolute pressure: Relative pressure + 1,013 bar (normal atmospheric pressure at sea level at 0°C). Specific enthalpy (or latent heat) of evaporation: Heat required to transform 1 kg of boiling water into
Specific volume of steam: Number of cubic meters occupied by 1 kg of steam. vapour without change of temperature (thermal energy required during the change of state from liquid to
Density (or mass density) of steam: Specific mass of steam contained in a volume of 1 m3. vapour).
Specific enthalpy of liquid water: Sensible heat; the quantity of heat contained in 1 kg of boiling water. Specific heat of steam: Amount of heat required to raise the temperature of 1 kg of steam by 1°C.
Dynamic viscosity: The viscosity of a fluid characterises the resistance to the movement of the fluid.
00099GB-2005/R01