14 ONLINE JEE Main 2019

Solutions
PHYSICS
1 (c) Given, radius of wire, r = 2 mm = 2 ´ 10-3 m m = 2g = 2 ´ 10-3 kg, g = 10 ms -2
-2
Weight of load, m = 4 kg, g = 31
. p ms 5 ´ 10-6 ´ 2000 1
Force (F ) mg \ tan q = -3
= = 0.5
\ Tensile stress = = 2 ´ 10 ´ 10 2
Area (A ) pr 2
So, the angle made by the string of the
. ´p
4 ´ 31 pendulum with the vertical is
=
p ´ (2 ´ 10-3 )2
q = tan -1 (0.5)
6 -2
= 31
. ´ 10 Nm 4 (a) When rubber cord is stretched, then it
2 (*) Momentum imparted to the surface in stores potential energy and when released, this
one collision, potential energy is given to the stone as kinetic
Dp = ( pi - pf ) = mv – (- mv) = 2mv …(i) energy.

Force on the surface due to n collision per

n m
second, F = (Dp ) = nDp (Q t = 1s)
t Rubber v
cord L
= 2 mnv [from Eq. (i)]
So, pressure on the surface,
F 2mnv
p= =
A A
So, potential energy of stretched cord
Here, m = 10-26 kg, n = 1022 s-1 , = kinetic energy of stone
2
v = 104 ms-1 , A = 1 m2 1 æ DL ö 1 2
Þ Yç ÷ A × L = mv
2 ´ 10-26 ´ 1022 ´ 104 2 è L ø 2
\Pressure, p = = 2 N / m2
1 Here, DL = 20 cm = 0.2 m, L = 42 cm = 0.42 m,
So, pressure exerted is of order of 100 . v = 20 ms -1 , m = 0.02 kg, d = 6 mm = 6 ´ 10-3 m
2
3 (d) Forces on the bob are as shown ædö
2
æ 6 ´ 10-3 ö
\ A = pr 2 = p ç ÷ = p çç ÷
÷
è 2ø è 2 ø
T cosq = p(3 ´ 10-3 )2 = 9p ´ 10-6 m 2
q T
q E On substituting values, we get
qE mv 2L 0.02 ´ (20) 2 ´ 0.42
Y = =
T sinq A ( DL ) 2
9p ´ 10-6 ´ (0.2) 2

mg » 3.0 ´ 106 Nm-2

So, the closest value of Young’s modulus
For equilibrium, is 106 Nm -2.
T cosq = mg …(i)
5 (a) Key Idea For an electromagnetic wave, ratio of
and T sin q = qE …(ii) magnitudes of electric and magnetic field is
Dividing Eq. (ii) by Eq. (i), we get E
=c
qE B
tan q = where, c is the speed of electromagnetic wave
mg in vacuum.
Here, q = 5mC = 5 ´ 10-6 C, E = 2000 V / m,
2 ONLINE JEE Main 2019

Given, E = 6 V/m, c = 3 ´ 108 ms -1 Þ 2(80 - 40t )(-40) + 2(150 - 50t ) (-50) = 0

E 6
So, B= = = 2 ´ 10-8 T Þ -3200 + 1600t - 7500 + 2500t = 0
c 3 ´ 108
Þ 4100t = 10700
Also, direction of propagation of
10700
electromagnetic wave is given by Þ t= = 2.6 h
$ = E´B 4100
n
Here, n$ = i$ and E = Unit vector of Alternate Solution
electric field ($j) Time after which the distance is minimum
B = unit vector of magnetic field. between A and B can be calculated as
$i = $j ´ B |r . v |
Þ t = BA BA
$ |vBA|2
\ B=k
where, r = r - r = 80$i + 150$j
BA B A
Hence, magnetic field components,
and vBA = - 10$i - (30i$ + 50$j)
B = 2 ´ 10-8 k
$T
= 2 ´ 10-8 T (along z-direction) = -40$i - 50$j

6 (b) Considering the initial position of ship A |(80i$ + 150$j) × (-40i$ - 50$j)|
Þ t=
as origin, so the velocity and position of ship | - 40$i - 50$j|2
will be
vA = (30 i$ + 50 $j) and rA = (0 $i + 0 $j) 3200 + 7500 10700
= = = 2.6 h
4100 4100
Now, as given in the question, velocity and
position of ship B will be, vB = -10 i$ 7 (c) There are two forces on slider.
× × ×
and r = (80 $i + 150 $j)
B

Hence, the given situation can be represented ×

kx × ×

graphically as ×
Bil × ×
B (80,150)
× × ×
vB=–10 î
y Spring force = kx
where, k = spring constant.
A i + 50^
vA=30^ j As the slider is kept in a uniform magnetic
field B = 01
. T, hence it will experience a force,
x i.e.
(0,0)
Magnetic force = Bil
where, l = length of the strip.
Now, using
Fnet = ma
After time t, coordinates of ships A and B are We have,
(80 - 10t , 150) and (30t , 50t ). (- kx) + (- Bil) = ma
So, distance between A and B after time t is Þ - kx - Bil - ma = 0
d= (x2 - x1 )2 + ( y2 - y1 )2 B 2 l2 é Blv ù
Þ - kx - × v - ma = 0 êëQ i = R úû
d= (80 - 10t - 30t )2 + (150 - 50t )2 R
Þ d = (80 - 40t )2 + (150 - 50t )2
2 d 2x
and acceleration, a =
d 2 dt 2
Distance is minimum when (d ) = 0
dt Hence, the modified equation becomes
After differentiating, we get md 2x B 2l2 æ dx ö
Þ + ç ÷ + kx = 0
d dt 2 R è dt ø
Þ [(80 - 40t )2 + (150 - 50t )2 ] = 0
dt This is the equation of damped simple
harmonic motion.
APRIL ATTEMPT ~ 08 April 2019, Shift I 3

So, amplitude of oscillation varies with time as 9 (d) Initially when uncharged shell encloses
-
B 2l 2
×t
charge Q, charge distribution due to induction
A = A0 e 2Rm will be as shown,
A0 +Q
Now, when amplitude is , then –Q
e
A0 A0 Q
= (as given)
e B 2l 2
×t VB VA b
e 2Rm a

æ B 2l2 ö 2Rm
Þ ç ÷
ç 2Rm ÷ t = 1 or t = B 2l2
è ø
According to the question, magnetic field The potential on surface of inner shell is
. T, mass of strip m = 50 ´ 10-3 kg,
B = 01 kQ k (-Q ) kQ
VA = + + …(i)
resistance R = 10W, l = 10 cm = 10 ´ 10-2 m a b b
2Rm 2 ´ 10 ´ 50 ´ 10-3 where, k = proportionality constant.
\ t= 22 =
B l . )2 ´ (10 ´ 10-2 )2
(01 Potential on surface of outer shell is
1 kQ k (-Q ) kQ
= -4 = 10000 s VB = + + …(ii)
10 b b b
Given, spring constant, k = 0.5 Nm -1 Then, potential difference is
æ 1 1ö
Also, time period of oscillation is DV AB = V A - VB = kQ ç - ÷
è a bø
m 50 ´ 10-3 2p
T = 2p = 2p = » 2s Given, DV AB = V
k 0.5 10
æ 1 1ö
So, number of oscillations is So, kQ ç - ÷ = V …(iii)
t 10000 è a bø
N = = = 5000 Finally after giving charge - 4Q to outer shell,
T 2
potential difference will be
8 (a) For a system of discrete masses,
DV AB = V A - VB
acceleration of centre of mass (CM) is given by
m a + mB aB + mC aC + mD aD æ kQ k (-4Q ) ö æ kQ k (-4Q ) ö
aCM = A A =ç + ÷-ç + ÷
mA + mB + mC + mD è a b ø è b b ø
æ 1 1ö
a^

= kQ ç - ÷ = V [from Eq. (iii)]

j

a^
i è a bø
mB=2m

B mC=3m
C Hence, we obtain that potential difference does
not depend on the charge of outer sphere,
hence potential difference remains same.
10 (c) Given circuit is a series L-R circuit
R=10W
mD=4m

A i
mA=m D
–ai L= 20H
E
– a^
j

where, mA = m, mB = 2m, mC = 3m and

mD = 4m,|a A| = |aB| = |aC| = |aD|= a (according
In an L-R circuit, current increases as
to the question)
Eæ
-R ö
- ma$i + 2ma$j + 3ma$i - 4ma$j i = ç1 - e L ÷
t
aCM = Rç ÷
m + 2m + 3m + 4m è ø
2a$i - 2a$j a $ $ Now, energy stored in inductor is
= = × (i - j) ms -2
10 5 1
UL = Li 2
2
4 ONLINE JEE Main 2019

where, L = self inductance of the coil 12 (d) Dimensions of e0 (permittivity of free space)
and energy dissipated by resistor is are
UR = i 2R [e0 ] = M-1 L-3 T 4 A2
Given, rate of energy stored in inductor is As, c = speed of light.
equal to the rate of energy dissipation in
\ Dimension of [c] = [LT -1 ]
resistor. So, after differentiating, we get
di e0
iL = i 2R So, dimensions of are
dt m0

Þ
di R
= i é e0 ù é e20 ù é 2 1 ù
dt L ê ú=ê ú = [e0 c] êQ c = ú
êë m 0 úû êë e0m 0 úû ë m 0 e0 û
E R - L t R E æç - tö
R R
Þ × e = × 1- e L ÷ = [M-1 L-3 T 4 A2 ][LT -1 ] = [M-1 L-2T3 A2 ]
R L L Rç ÷
è ø
R
13 (b) Let x grams of water is evaporated.
- t
Þ 2e L =1 According to the principle of calorimetry,
R Heat lost by freezing water (that turns into ice)
- t
1
Þ e L = = Heat gained by evaporated water
2 Given, mass of water = 150 g
Taking log on both sides, we have
Þ (150 - x) ´10-3 ´ 3.36 ´ 105
-R æ 1ö R
Þ t = ln ç ÷ Þ t = ln 2 = x ´10-3 ´ 2.10 ´106
L è 2ø L
Þ (150 - x) ´ 3.36 = 21x
L 20
Þ t = ln 2 = ln 2Þ t = 2 ln 2 150
R 10 Þ x= = 20.6
7.25
11 (*) Consider an elementary ring of thickness dx \ x » 20 g
and radius x.
14 (a) Given circuit is Zener diode circuit
200W i2
dx
iz

i1 Vz=5.6 V 800W
x
+ –
R
9V

Moment of inertia of this ring about a where,potential drop across 800 W resistance =
perpendicular axes through centre is potential drop across Zener diode = 5.6 V
dI c = dm × x2 = r0 x(2px)dx × x2 = 2pr0 x4 dx V 5.6
So, current, i2 = = = 7mA
Moment of inertia of this elementary ring R 800
about a perpendicular axes at a point through Now, potential drop across 200 W resistance
edge, (by parallel axes theorem) = 9 - 5.6 = 3.4 V
dI = dmx2 + dmR 2 V 3.4
Current, i1 = = = 17 mA
R 200
= 2pr0 x4 dx + 2pr0 R 2x2dx
So, current, iz = i1 - i2 = 17 - 7 = 10 mA
Moment of inertia of complete disc is
R R R 15 (c) In Young’s double slit experiment, ratio of
I = ò dI = ò 2pr0 x4 dx + ò02pr0 R x dx
2 2
maxima and minima intensity is given by
0 0
2 2
2pr0 R 2pr0 R
5
16pr 0 R 5 5 I max æç I1 + I2 ö æ I / I + 1ö
÷ =ç 1 2 ÷
= + = =
5 3 15 I min çè I1 - ÷
I2 ø ç I / I - 1÷
è 1 2 ø
16
\ a= As, intensity (I ) µ [amplitude (a )]2
15
APRIL ATTEMPT ~ 08 April 2019, Shift I 5

I1 æ a1 ö
2
æ 1ö
2
1 So, rA < rB , sA < sB and rA sA < rB sB
\ = çç ÷÷ = ç ÷ =
I 2 è a2 ø è 3ø 9 1 1 dQA dQB
Þ > Þ >
2 rA sA rB sB dt dt
æ1 ö
+ 1÷
I max ç 3 So, for container B, rate of cooling is smaller
So, = ç ÷ = 4:1
I min ç 1 - 1 ÷ than the container A. Hence, graph of B lies
ç ÷
è3 ø above the graph of A and it is not a straight
line (slope of A is greater than B).
16 (b) Reynolds’ number for flow of a liquid is
given by 18 (b) As we know, capacitance of a capacitor
rvD filled with dielectric medium,
Re =
h e KA
where, velocity of flow, C= 0 …(i)
d
volume flow rate V / t
v= = d
area of flow A
rVD rV 2r 2rV
So, Re = = =
hAt h ´ pr 2 ´ t hprt C
-3
Here, r = density of water = 1000 kgm
A=area
V 100 ´ 10-3 3 -1
= m s
t 60
where, h = viscosity of water = 1 ´ 10-3 Pa-s V

and r = radius of pipe = 5 ´ 10-2 m and potential difference between plates is

2 ´ 1000 ´ 100 ´ 10-3 E=
V
Þ d=
V
Re = …(ii)
1 ´ 10-3 ´ 60 ´ 314
. ´ 5 ´ 10-2 d E
So, by combining both Eqs. (i) and (ii),
= 212.3 ´ 102 » 2.0 ´ 104
we get
So, order of Reynolds’ number is of 104 .
CV
K = …(iii)
e0 AE
17 (b) Key Idea From Newton’s law of cooling, we
have rate of cooling, Given, C = 15pF = 15 ´ 10-12 F,
dQ
=
h
(T - T0 ) V = 500 V, E = 106 Vm -1 ,
dt ms
A = 10-4 m2
where, h = heat transfer coefficient,
and e0 = 8.85 ´ 10-12 C 2N -1 m -2
T = temperature of body,
T0 = temperature of surrounding, Substituting values in Eq. (iii), we get
m = mass and s = specific heat. 15 ´ 10-12 ´ 500
K =
8.85 ´ 10-12 ´ 10-4 ´ 106
We know, m = V × r
where, V = volume and r = density. = 8.47 » 8.5
So, we have 19 (a) Given, de-Broglie wavelengths for particles
dQ h h (T - T0 ) are l1 and l2.
= (T - T0 ) =
dt ms V × rs So, l1 =
h
and l2 =
h
Since, h, (T - T0 ) and V are constant for both p1 p2
beaker. and momentum of particles are
dQ 1 h h
\ µ p1 = and p2 =
dt rs l1 l2
We have given that rA = 8 ´ 102 kgm - 3 , Given that, particles are moving perpendicular
rB = 103 kgm -3 , sA = 2000 J kg -1 K -1 and to each other and collide inelastically.
sB = 4000 J kg -1 K -1 , So, they move as a single particle.
rA sA = 16 ´ 105 and rB sB = 4 ´ 106
6 ONLINE JEE Main 2019

FBO net = FBD + FBA sin 45° + FBC cos 45°

p1
GM 2 GM 2 æ 1 ö GM 2 æ 1 ö
= + ç ÷+ ç ÷
( 2a ) 2
a2 è 2 ø a2 è 2 ø
p2 [where, diagonal length BD is 2a]
GM 2 GM 2 æ 2 ö GM 2 æ 1 ö
= + ç ÷= ç + 2÷
2a 2 a2 è 2 ø a2 è 2 ø
pnet
This force will act as centripetal force.
a
So, by conservation of momentum and vector Distance of particle from centre of circle is .
addition law, net momentum after collision, 2
Mv2 Mv2 2Mv2
pnet = p12 + p22 + 2 p1 p2 cos 90° = p12 + p22 Here, Fcentripetal = = =
r a a
h h
Since, p1 = and p2 = 2 æ a ö
l1 l2 çQ r = ÷
è 2ø
h2 h2 So, for rotation about the centre,
So, pnet = + …(i)
l21 l22 Fcentripetal = FBO( net)
Let the de-Broglie wavelength after the Mv2 GM 2 æ 1 ö
Þ 2 = ç + 2÷
collision is lnet , then a a2 è 2 ø
h GM æ 1 ö GM
pnet = …(ii) Þ v =
2
ç1 + ÷= (135
. )
lnet a è 2 2ø a
From Eqs. (i) and (ii), we get GM
Þ v = 116
.
h h2 h2 1 1 1 a
= + Þ = +
lnet l21 l22 l2net l21 l22 22 (b) In optical fibre communication network, the
20 (d) Given, resistance is 200 W. signals are transmitted by laser light operating
in range of 1310 nm-1550 nm.
= 20 ´ 10 W 1
So, the closest value is 1500 nm.
R B Br 23 (*) In given system of lens and mirror, position
of object O in front of lens is at a distance 2f .
i.e. u = 2f = 40 cm
f=20 cm
So, colour scheme will be red, black and brown.
Significant figure of red band is 2 and for green
is 5. When red (2) is replaced with green (5), 40 cm 2f
new resistance will be 2f 40 cm
200 ohm ¾¾® 500 ohm.
I1

21 (b) Key Idea In given configuration of masses, net

gravitational force provides the necessary So, image (I1 ) formed is real, inverted and at a
centripetal force for rotation. distance, v = 2f = 2 ´ 20 = 40 cm, (behind lens)
v 40
magnification, m1 = = =1
M u 40
A B
M FBA Thus, size of image is same as that of object.
FBD 45°
This image (I1 ) acts like a real object for
O FBC mirror.
a
Ö2

M
DM C
a

Net force on mass M at position B towards

centre of circle is
APRIL ATTEMPT ~ 08 April 2019, Shift I 7

Final I2 Its direction is perpendicular to the area of coil

image and is along Y-axis.
O 20 cm
40 cm Then, torque on the current coil is
2f 40 cm 2f t = m ´ B = mB sin 90° = NIAB
= NIpr 2B (N-m)
I1 25 (d) In an AC resistive circuit, current and
60 cm f=10 cm voltage are in phase.
V 220
So, I= Þ I= sin(100pt ) …(i)
As object distance for mirror is R 50
u = C = 2f = - 20 cm \Time period of one complete cycle of current is
where, C = centre of curvature. 2p 2p 1
T = = = s
So, image (I 2 ) formed by mirror is at 2f . w 100p 50
\For mirror v = 2f = 2(-10) I
Imax Imax
= - 20 cm ——
v (-20) 2 3T/4
Magnification, m2 = - = - = -1 t
u (-20) T/4 T/2 1
T= — s
Thus, image size is same as that of object. 50
The image I 2 formed by the mirror will act like
an object for lens.
So, current reaches its maximum value at
f=20 cm T 1
I2 t1 = = s
4 200
O
2f 2f When current is half of its maximum value,
40 cm 20 cm then from Eq. (i), we have
40 cm
I
I3 I1 I = max = I max sin(100pt2 )
2
1 5p
f=10 cm Þ sin(100pt2 ) = Þ 100pt2 =
2 6
As the object is at 2f distance from lens, so
image (I3 ) will be formed at a distance 2f or So, instantaneous time at which current is half
1
40 cm. Thus, magnification, of maximum value is t2 = s
v 40 120
m3 = = =1 Hence, time duration in which current reaches
u 40
half of its maximum value after reaching
So, final magnification, m = m1 ´ m2 ´ m3 = - 1 maximum value is
Hence, final image (I3 ) is real, inverted of same 1 1 1
size as that of object and coinciding with object. Dt = t2 - t1 = - = s = 3.3 ms
120 200 300
24 (b) According to the question, the situation can 26 (d) De-excitation energy of hydrogen electron
be drawn as in transition n = 2 to n = 1is
Y
æ 1 1 ö æ1 1ö
m
E = 13.6 ´ ç 2 - 2 ÷ eV = 13.6 ç 2 - 2 ÷
çn ni ÷ø è1 2 ø
è f
B
I r X = 10.2 eV
Now, energy levels of helium ion’s (He+ )
electron are
Z (For helium, Z = 2)
Let the current I is flowing in anti-clockwise
direction, then the magnetic moment of the coil is
m = NIA
where, N = number of turns in coil
and A = area of each coil = pr 2.
8 ONLINE JEE Main 2019

– 3.4 eV
n=4
28 (d) Total internal reflection occurs through
– 6.04 eV given glass rod as shown in figure.
10.2 eV n=3 2m
– 13.6 eV
n=2 B
13.6(Z)2
En = ——— q
n2 – 54.4 eV 20 mm
n=1 r= q2
So, a photon of energy 10.2 eV can cause a 40°=i O A
x
transition n = 2 to n = 4 in a He+ ion.
Alternate Solution
From Snell’s law, n1 sin i = n2 sin r
For He+ ion, when in n = 1state,
æ1 1 ö where, n1 = 1, n2 = 131
. and i = 40°
10.2 = 13.6 ´ 22 ç 2 - 2 ÷ Þ n = 1
è1 n ø So, we get
0.64
Thus, no transition takes place. 1sin 40° = 131
. sin r Þ sin r = = 0.49 » 0.5
131
.
Similarly, when in n = 2 state, So, r = 30°
æ 1 1 ö
10.2 = 13.6 ´ 22 ç 2 - 2 ÷ Þ n = 4 From DOAB, q = 90 - r = 60°
è2 n ø x
Now, tan q =
27 (c) Wire A Wire B 20 mm
Þ x = 20 3 mm [Q tan 60° = 3 ]
One reflection occurs in 20 3 mm.
Node
L L \ Total number of reflections occurring in 2m
2m 2
Let mass per unit length of wires are m A and =n= =
20 3 mm 20 3 ´ 10-6
m B , respectively.
Q For same material, density is also same. = 57735 reflections » 57000 reflections
rpr 2L r 4pr 2L
So, m A = = m and m B = = 4m 29 (c) Key Idea Area under force-displacement graph
L L gives the value of work done.
Tension (T ) in both connected wires are same.
F(N)
So, speed of wave in wires are
C
T T 3
vA = = [Qm A = m and m B = 4 m]
mA m 1
A B
T T 2
and vB = = D
mB 4m 2
So, nth harmonic in such wires system is 0 F E
x(m)
pv O 2 3
fnth =
2L
pvA p T \ Work done on the particle
Þ fA = = (for p antinodes) = Area under the curve ABC
2L 2L m
W = Area of square ABFO + Area of DBCD
qvB q T 1æ q T ö
Similarly, fB = = = çç ÷ + Area of rectangle BDEF
2L 2L 4 m 2 è 2L m ÷ø 1
= 2 ´ 2 + ´1´1+ 2 ´1
(for q antinodes) 2
As frequencies fA and fB are given equal. = 6.5 J
p T qé 1 T ù Now, from work-energy theorem,
So, fA = fB Þ = ê ú
2L m 2 ë 2L m û DW = K f - Ki
p 1 Þ K f = DW = 6.5 J [Q Ki = 0]
= Þ p : q = 1: 2
q 2 30 (d) Given circuit is
APRIL ATTEMPT ~ 08 April 2019, Shift I 9

1W a 1W
This is a parallel combination of three cells or
in other words, a parallel grouping of three
2W cells with internal resistances.
2V 4V
E1 E E
+ 2+ 3
4V I eq r1 r2 r3
So, V ab = Eeq = =
req 1 1 1
1W b 1W + +
r1 r2 r3
Above circuit can be viewed as 2 4 4
+ +
2V 10
2W = 2 2 2= V » 3.3 V
1 1 1 3
+ +
2 2 2
a b

4V 2W

4V 2W

CHEMISTRY
1 (c) m-cresol is the organic compound that
shows the following solubility profile. 2 (a) Key Idea According to Freundlich,
Water
Insoluble x
CH3 = Kp1 / n [ n >1]
m
5% HCl
Insoluble where, m = mass of adsorbent, x = mass of
10% NaOH x
OH
Soluble the gas adsorbed, = amount of gas adsorbed
m-cresol m
10% NaHCO3
Insoluble per unit mass of solid adsorbent, p = pressure, K
and n = constants.
m-cresol on reaction with 10% NaOH forms
3-methyl sodiumphenoxide ion. The logarithm equation of Freundlich
OH O–Na+ adsorption isotherm is
x 1
log = log K + log p
10% NaOH m n
CH3 CH3 On comparing the above equation with straight
line equation, ( y = mx + c)
It does not react with H2O, 5% HCl and 10%
we get
NaHCO3 . 1
m = slope =
Oleic acid (C18 H34 O2 ) is soluble in 10% NaOH n
and 10% NaHCO3 due to the presence of COOH and c = log K
group.
O From the given plot,
½½ y -y
m= 2 1
Benzamide (C6 H5 C NH2) is insoluble in 5% x2 - x1
HCl, 10% NaOH and 10% NaHCO3 due to the 1 2
= =
presence ¾ CONH2 group. o-toluidine is n 3
soluble in 5%. HCl due to presence of basic x
\ = Kp 2/3
group ( ¾ NH2 ) attached to ring. m
10 ONLINE JEE Main 2019

3 (d)According to the given conditions, Change in oxidation number of Mn is 5.

compound (d) neither reacts with neutral ferric Change in oxidation number of Fe in (i), (ii) and
chloride solution nor with Fehling solution. It (iii) are +3, + 6, + 1, respectively.
however reacts with Grignard reagent and n eq KMnO 4 = n eq [ FeC 2O 4 + Fe 2 ( C 2O 4 ) 3 + FeSO 4 ]
gives positive iodoform test. n ´ 5 = 1´ 3 + 1´ 6 + 1´1
● As the compound does not contain any
\ n=2
phenolic ¾ OH group. Hence, it gives
negative neutral FeCl3 test. 6 (c) Basic strength can be compared by the
reaction of an alkanamine and ammonia with
OH proton.
|
CH3 Neutral H H
no reaction | |
FeCl3
C—Et
(FeCl3 test for phenolic R—N + H+ R—N+—H
group) | |
O
H H
H H
| |
●Compound gives reaction with H—N + H+ H—N+—H
RMgX as it contains ¾ C ¾ Et. | |
½½ H H
OH O OH
| | Basicity of an amine in aqueous solution
CH3 RMgX CH3 depends upon the solubility of ammonium
Grignard R cation formed by accepting proton from water.
reagent C2H5
C—Et The stability of ammonium cation depends
O OH upon the following factors.
(a) + I effect (b) Steric effect
Compound with CH3 CH ¾ group (c) Solvation effect
½ In first case, on increasing the size of alkyl
OH
group + I effect increases and the positive
undergoes iodoform test in presence of NaOH charge of ammonium cation gets dispersed
and I2. more easily, Therefore, order of basicity is 2º
O amine > 1º amine > ammonia. In second case,
OH
| substituted ammonium cation is also stabilised
CH3 NaOH+I2
O–Na+ by solvation with water molecules. Greater the
CH3I ¯ + size of ion, lesser will be the solvation and less
Iodoform
test Yellow Et stabilised is the ion.
C—Et ppts.
O OH2
O
H
| C2H5 H----OH2
4 (d) The radius of isoelectronic species is +
C2H2—N+—H----OH2 > N
inversely proportional to their nuclear charge | C2H5 H----OH2
or atomic number (Z). Thus, greater the value H
2° amine
of Z, lesser the radii of isoelectronic species.
OH2
5 (a) The oxidation of a mixture of one mole of 1° amine
each of FeC2O4 , Fe2 (C2O4 )3 FeSO4 and
Fe2 (SO4 )3 in acidic medium with KMnO4 is Considering both steric and solvation effect, it
as follows : can be concluded that greater the number of
FeC2O4 + KMnO4 ¾¾® Fe3 + + CO2 + Mn 2+ H-atoms on the N-atom, greater will be the
…(i) H-bonding and hence more stable is the
Fe2 (C2O4 )3 + KMnO4 ¾¾® Fe3 + + CO2 + Mn 2+ ammonium cation. But in case of ¾ C2H5
…(ii) group, + I effect predominates over H-bonding.
Therefore, order is 2º amine > 1° amine >
FeSO4 + KMnO4 ¾¾® Fe3 + + SO24- + Mn 2+
ammonia i.e. (C2H5 )2 NH > C2H5 NH2 > NH3 .
…(iii)
APRIL ATTEMPT ~ 08 April 2019, Shift I 11

All the given complexes possess strong field

7 (b) Key Idea Ethers are least reactive functional
ligands (CN, NH3 ). Hence, readily form low
groups. The cleavage of C ¾ O bond in ethers
take place under drastic conditions with excess spin complexes.
of HX . Complex Oxidation Configuration Orbital No. of
state splitting unpaired
The major product obtained in the reaction is electrons
as follows : eg
OCH3 OH [V(CN)6]4– V
2+ 3
t2g eg
0
3
Conc. HBr (excess)
Heat t2g

eg
CH=
=CH2 Br—CH— CH3 [Cr(NH3)6]2+ Cr2+ 4
t2g eg0 2
As conc. HBr is in excess. So, reaction will take t2g
place at both the substituents.
eg
Mechanism
[Ru(NH3)6]3+ Ru3+ t25g eg0 1
Step 1 Protonation of ether to form oxonium ion.
t2g
H
|r
O—CH3 O—CH3 + Br
s eg
H—Br [Fe(CN)6]4– Fe2+ t26g eg0 0
t2g

CH=
=CH2 CH=
=CH2
Oxonium ion 9 (d) The major product of the O
given reaction is (d).
Step 2 Attack of nucleophile at the protonated
This reaction proceed via
ether.
Friedel-Craft acylation.
H s
|r
H Here, ¾ Cl group present COOH (d) Cl
|+
O—CH3 O CH3 on chlorobenzene is ortho
|

SN2
Br-+ Slow
and para-directing. It can be easily understood
Br by resonating structures of chlorobenzene.
r r r
CH=
=CH2 CH=
=CH2 Cl Cl Cl Cl Cl
s s
OH
CH3—Br + s

The given reaction proceed as follows :

CH=
=CH2
O
Step 3 As HBr is in excess, so, reaction will O +
also take place at alkene. C
OH OH O + AlCl3 –
Markownikov’s rule, HBr O----Al + Cl3
Addition reaction
O
O
Cl
CH=
=CH2 Br CH3

8 (b) Key Idea In presence of strong field ligands,

D 0 > p, for fourth electron it is more
O
energetically favourable to occupy t 2g orbital O
with configuration t 24g e g0 and form low spin
complexes. C
H2O

The correct order of the spin only magnetic COOH Cl C—O – + Cl

moment of metal ions in the given low-spin —AlC
l3
complexes is V2+ > Cr2+ > Ru3 + > Fe2+ . O
12 ONLINE JEE Main 2019

10 (a) According to Kirchoff’s relation,

T2
13 (b) Key Idea The concentration of a substance in a
DH = n ò C p dT …(i) saturated solution is defined as its solubility(S).
T1 For A x By - xAy + + yB x - ; K sp = [Ay + ] x [B x - ] y
where, DH = Change in enthalpy. For, Zr3 (PO4 )4
C p = Heat capacity at constant pressure. Zr3 (PO4 )4 (s) - 3Zr4 + (aq) + 4PO34 - (aq)
Given, n = 3 moles, T1 = 300 K, T2 = 1000 K, 3 SM 4 SM
C p = 23 + 0.01 T Ksp = [Zr4 + ]3 [PO34 - ]4
1
On substituting the given values in Eq. (i), æ Ksp ö7
Ksp = (3S) (4S) = 6912 S or S = çç ÷÷
3 4 7
we get
1000 1000 è 6912 ø
DH = 3 ò (23 + 0.01 T )dT = 3 ò 23dT + 0.01T dT Thus, the relation between molar solubility(S)
300 300 and solubility product (Ksp ) will be
1/7
é 0.01 T 2 ù
1000
æ Ksp ö
= 3 ê 23T + ú S = çç ÷÷
êë 2 úû300 è 6912 ø
é 0.01 ù 14 (d) Major product obtained in the given
= 3 ê 23 (1000 - 300) + (10002 - 3002 )ú
ë 2 û reaction is
= 3 [16100 + 4550] = 61950 J » 62 kJ
11 (d) Using plastic bags is wrong with respect to O
responsibility as a human being to protect our
environment. Plastic bags are non-biodegradable
NaBH4 in the reaction is used for the
in nature. It remains in the environment as
reduction by addition of a hydride ion and a
such and does not degraded by bacteria. If it is
proton. Carbon-oxygen double bonds are easily
not disposed properly then it may lead serious
reduced by sodium borohydride. The actual
threat to the environment. The activities that
reducing agent in these reductions is hydride
can be used to protect our environment are as
ion (H- ). Hydride ion adds to the carbonyl
follows:
carbon and the alkoxide ion that is formed is
● Restricting the use of vehicles.
subsequently protonated by water. In other
● Avoiding the use of flood lighted facilities.
words, the carbonyl group is reduced by adding
● Setting up compost tin in gardens. an H- followed by an H+ . The mechanism of the
given reaction is as follows :
12 (b) Key Idea Denticity of ligand is defined as O O–
donor sites or number of ligating groups.
C – C—CH2Br
CH2Br H from NaBH4 H 2O
The given ligand is tetradentate. It contains H
four donor atoms. It can bind through two
nitrogen and two oxygen atom to the central OH
metal ion.
C—CH2 — Br
Ligand bound to the central atom or ion EtOH, 25°C

through coordinate bond in the coordination O Intramolecular H

cyclisation
entity. It act as a Lewis base. The attacking site
of the given ligand is given in bold.
15 (a) Diborane (B2H6 ) reacts independently with
NEt2
O2 and H2O to produce B2O3 and H3 BO3
N respectively. Diborane is a colourless, highly
toxic gas, having boiling point 180 K. Because
O- -O of its inflammable nature, it catches fire
spontaneously when exposed to air and burns
in oxygen releasing an enormous amount of
energy as:
APRIL ATTEMPT ~ 08 April 2019, Shift I 13

B2H6 + 3O2 ¾¾® B2O3 + 3H2O + 1976 kJ/mol Generally, the diagram consists of plots of DG°
It gets hydrolysed readily to give boric acid. versus T for the formation of oxides of elements
B2H6 + 6H2O ¾¾® 2H3 BO3 + 6H2 ­ 2xM (s) + O2 ( g ) ¾¾® 2Mx O(s)
Borane Orthoboric acid Dihydrogen Thermal reduction product
In this reaction, amount of gas decreases thus,
16 (b) From the 1st law of thermodynamics, randomness decreases. Hence, DS becomes
DU = q + W negative. Therefore, the value of free energy
where, DU = change in internal energy increases with increase in temperature. There
is a point in a curve below which DG is
q = heat
negative. So, Mx O is stable. Above this point,
W = work done Mx O will decompose on its own.
The above equation can be represented for the
given processes involving ideal gas as follows: 18 (d) Given, WCa( HCO = 0.81 g
3 )2
(a) Cyclic process For cyclic process, DU = 0 WMg = 0.73 g
( HCO3 ) 2
\ q = -W MCa(HCO ) = 162 g mol -1 ,
3 2
Thus, option (a) is correct. MMg(HCO3 ) 2 = 146 mol -1
(b) Adiabatic process For adiabatic process, V H 2O = 100 mL
q= 0
Now,
\ DU = W
neq (CaCO3 ) = neq [Ca(HCO3 )2 ] + neq [Mg(HCO3 )2 ]
Thus, option (b) is incorrect. W 0.81 0.73
´2= ´2+ ´2
(c) Isochoric process For isochoric process, 100 162 146
DV = 0. Thus, W = 0 (QW = pDV ). W
\ = 0.005 + 0.005
\ DV = q 100
Thus, option (c) is correct. W = 0.01 ´ 100 = 1
(d) Isothermal process For isothermal 1
Thus, hardness of water sample = ´ 106
process, DU = 0 100
\ q = -W = 10,000 ppm
Thus, option (d) is correct. 19 (c) Higher the standard reduction potential
17 (d) With respect to an ore, Ellingham diagram (E º ), better is oxidising agent. Among the
M n + /M
helps to predict the feasibility of its thermal °
given, E S 2O 28- / SO 24- is highest, hence S2O2-
8 is the
reduction. It is a graph representation of Gibbs
energy change versus absolute temperature. strongest oxidising agent.
0
The decreasing order of oxidising agent among
–100 2Cu 2O the given option is as follows:
–200 4Cu+O 2
2FeO S2O28- > Au3 + > O2 > Br2
–300 2Fe+O 2 C+O2 CO2
–400 20 (c) The IUPAC name of the given compound is
2C+O
DGº/kJ mol–1 of O2

2CO 2 2 3-hydroxy-4-methylpentanoic acid.

–500 +O 2 O 2CO
2CO 2Zn
–600 +O 2 CH3 OH
2Zn
–700 5 ½ 4 ½3 2 1
–800 H3 C ¾ CH ¾ CH ¾ CH2 ¾ COOH
l +O 3
–900 2 /3 A 2 Principal chain
A l+O 2 O
–1000 4/3 2 Mg While naming the compound, the longest chain
O2
–1100 2 Mg+ that have principal functional group ¾ COOH
–1200 is choosen and numbered in such a manner
that the principal functional group gets the
0°C 400°C 800°C 1200°C 1600°C 2000°C lowest possible number. ¾ OH act as
273 K 673 K 1073 K 1473 K 1873 K 2273 K
substituent and used as prefix in
Temperature
nomenclature.
Gibbs energy (DGº) versus T plots (schematic)
for the formation of some oxides (Ellingham diagram)
14 ONLINE JEE Main 2019

21 (b) The number of element ‘B ’ in the crystal Lu3 + have fully-filled 4f -orbitals.
structure = 4 N Only Sm3 + contain 4f 5 . The electrons can
Number of tetrahedral voids = 2N easily undergoes excitation. That result in a
formation of colour.
Number of octahedral voids = N
N 4 24 (d) Maltose on treatment with dil. HCl gives
\Number of ‘A’ in the crystal = = =2
2 2 D-glucose. Hydrolysis of maltose yields two
Number of oxygen (O) atoms = 2N = 2 ´ 4 = 8 moles of a- D-glucose. Thus, it is composed of
two a-D-glucose units in which C-1 of one
\The structure of bimetallic oxide = A2 B4 O8
glucose unit (I) is linked to C-4 of another
= AB2 O4 glucose unit (II). The free aldehyde group can
22 (a) Let the rate equation be k [A ]x [B ]y be produced at C-1 of second glucose in solution
and it shows reducing properties. So, it is a
From Ist values, reducing sugar.
0.045 = k[0.05]x [0.05]y …(i)
CH2OH CH2OH
From 2nd values, O O
H H H H H
0.090 = k[010
. ]x [0.05]y …(ii) H
From 3rd values, OH H O OH H
OH OH
0.72 = k[0.20]x [010
. ]y …(iii)
On dividing equations (i) by (ii), we get H OH H OH
0.045 é 0.05 ù
x CH2OH
=ê ú O
0.09 ë 010
. û H OH
1 x
Dil. HCl H
é 0.05 ù é 0.05 ù 2
êë 010 =ê OH H H
. úû . úû
ë 010 OH

\ x=1 H OH
a-D-glucose
Similarly on dividing Eq. (ii) by (iii) we get
0.09 é 01. ù x é 0.05 ù y 25 (d) According to Dalton’s law of partial
=ê ú ê
0.72 ë 0.2 û ë 010. úû pressure ptotal = pA + pB
. é 0.05 ù
0.01 01
y = pA° c A + pB° cB …(i)
=
0.08 0.2 êë 01
. ûú Given, pA = 400 mm Hg, pBº = 600 mm Hg
º

y cB = 0.5, c A + cB = 1
é 0.05 ù
0.025 = ê ú \ c A = 0.5
ë 010
. û
On substituting the given values in Eq. (i). We
0.025 = [0.5]y
get,
[0.5]2 = [0.5]y
ptotal = 400 ´ 0.5 + 600 ´ 0.5 = 500 mm Hg
\ y=2
Mole fraction of A in vapour phase,
Hence, the rate law for the reaction
pA pAº c A 0.5 ´ 400
Rate = k [A ] [B ]2 YA = = = = 0.4
ptotal ptotal 500
23 (b) The lanthanide ion that would show colour
is Sm3 + . Colour of a compound depends on the Mole of B in vapour phase,
number of electrons in 4f -orbitals. YA + YB = 1
Electronic configuration of given lanthanides YB = 1 - 0. 4 = 0.6
are as follows: 26 (a) n- butylamine (CH3 CH2CH2CH2NH2 ) can
Gd3 + = 4f 7 be prepared by Gabriel phthalimide reaction.
Sm3 + = 4f 5 This method produces only primary amines
La3 + = 4f 0 without the traces of secondary or tertiary
Lu3 + = 4f 14 amines. In this method, phthalimide is treated
3+ with ethanolic KOH, it forms potassium salt of
Gd have half-filled 4f -orbitals.
phthalimide which on heating with alkyl halide
La3 + have no electron in 4f -orbitals.
APRIL ATTEMPT ~ 08 April 2019, Shift I 15

NaOH
followed by alkaline hydrolysis forms s
[Ar ¾ N ºº N]+ OH - Ar ¾ N == N ¾ OH
corresponding primary amines. H+ Does not couple
CO CO NaOH - +
NH+ Alc. KOH –H O N–K+ - Ar ¾ N == N ¾ O Na
+
2 H Does not couple
CO CO
nBu—X
Following conditions are very useful for
coupling reaction to take place.
COO–Na+ CO (a) The solution must be so alkaline that the
NaOH(aq.) concentration of diazonium ion is too low.
+ n Bu—NH2 N—R
COO–Na+ CO (b) It must not be so acidic that the
1° amine concentration of free phenoxide ion is
N-alkyl
phthalimide too low.

Triethylamine, t-butylamine and 29 (c) Ozone is destroyed by CFCs in the upper

neo-pentylamine cannot be prepared by Gabriel
phthalimide reaction.
27 (c) Smaller the value of (n + l), smaller the
energy. If two or more sub-orbits have same
values of (n + l), sub-orbits with lower values of
n has lower energy. The (n + l) values of the
given options are as follows :
I. n = 4, l = 2 ; n + l = 6
II. n = 3, l = 2; n + l = 5
III. n = 4, l = 1, n + l = 5
IV. n = 3, l = 1, n + l = 4
Among II and III, n = 3 has lower value of
energy. Thus, the correct order of their
increasing energies will be
IV < II < III < I
28 (c) Coupling of benzene diazonium chloride
with 1-naphthol in alkaline medium will give
the following coupling reaction.
OH OH
PhN2+
OH –
N==N
- +
In the presence of O H ion, ArN 2 exists in
equilibrium with an unionised compound
(Ar ¾ N == N ¾ OH) and salts [ArN == N+ ]–
s
¾OH derived from it, which do not couple.
stratosphere.
These compounds ultimately reach the
stratosphere where they get broken down by
powerful UV radiations and release chlorine
free radical. The chlorine free radicals react
with ozone and cause its depletion by
converting it into chlorine monoxide radical
and molecular oxygen.
hn ·
CF2Cl 2 ( g ) ¾¾® Cl( g ) + CF2Cl( g )
hn ·
CFCl3 ( g ) ¾¾® CFCl 2 ( g ) + Cl( g )
· ·
Cl( g ) + O3 ( g ) ¾¾® Cl O( g ) + O2 ( g )
Ozone holes increase the amount of UV
radiation reaching the earth. These radiations
can cause skin cancer, sunburns, ageing of
skin.
30 (d) Key Idea The amount of energy released when
one mole of gaseous ions combine with water
to form hydrated ions is called hydration
enthalpy.
The correct order of hydration enthalpies of
alkali metal ions is
Li + > Na + > K+ > Rb+ > Cs+
+
Li possesses the maximum degree of
hydration due to its small size. As a
consequence of hydration enthalpy, their
mobility also get affected. Cs+ has highest and
Li + has lowest mobility in aqueous solution.
16 ONLINE JEE Main 2019

Mathematics
1 (c) Given equation of curve is sin 2 x sin 2 x
= lim = lim
y =x-2 2
…(i) x ®0 æ xö x ®0 æxö
2 ç 1 - cos ÷ 2 ´ 2 sin 2 ç ÷
and the equation of line is è 2ø è 4ø
y=x …(ii) é x 2 xù
êëQ 1 - cos 2 = 2 sin 4 úû
Y y=x
y2=x–2
x2
M = lim 2
[lim sin x = lim x]
x ®0 æxö x ®0 x ®0
P(t2+2, t) 2 2ç ÷
è 4ø
16
X = =4 2
O (2, 0) 2 2

3 (b) Key Idea A homogeneous system of linear

equations have non-trivial solutions iff D = 0

Given system of linear equations is

Consider a point P (t 2 + 2, t ) on parabola (i). x - cy - cz = 0,
For the shortest distance between curve (i) and cx - y + cz = 0
line (ii), the line PM should be perpendicular to and cx + cy - z = 0
line (ii) and parabola (i), i.e. tangent at P
We know that a homogeneous system of linear
should be parallel to y = x.
equations have non-trivial solutions iff
dy
\ = Slope of tangent at point P to D=0
dx at point P curve (i) ½1 - c - c½
=1 [Q tangent is parallel Þ ½c - 1 c ½ = 0
to line y = x] ½ ½
1 ½c c - 1½
Þ =1
2y P Þ 1(1 - c2 ) + c(- c - c2 ) - c(c2 + c) = 0
dy Þ 1 - c2 - c2 - c3 - c3 - c2 = 0
[differentiating the curve (i), we get 2 y = 1] Þ -2c3 - 3c2 + 1 = 0
dx
1 1 Þ 2c3 + 3c2 - 1 = 0
Þ = 1Þ t = [Q P (x, y) = P (t 2 + 2, t )]
2t 2 Þ (c + 1)[2c2 + c - 1] = 0
æ 9 1ö Þ (c + 1)[2c2 + 2c - c - 1] = 0
So, the point P is ç , ÷.
è 4 2ø Þ (c + 1)(2c - 1)(c + 1) = 0
½
½9 - 1½
½ Þ c = - 1or
1
Now, minimum distance = PM = ½
4 2½ 2
2 1
Clearly, the greatest value of c is .
[Q distance of a point P (x1 , y1 ) from a line 2
|ax1 + by1 + c |ù 4 (a) Given statement is ‘‘If you are born in
ax + by + c = 0 is ú India, then you are a citizen of India’’.
a 2 + b2 úû
Now, let statement p : you are born in India
7
= units and q : you are citizen of India.
4 2
Then, given statement, ‘‘If you are born in
sin 2 x é0 ù India then you are a citizen of India’’ is
2 (a) Given limit is lim formú
x ®0 2 - 1 + cos x êë 0 û equivalent to p Þ q.
2
é Q The contrapositive of statement p Þ q is
sin x 2 xù
= lim êëQ 1 + cos x = 2 cos 2 úû ~ q Þ ~ p.
x ®0 x
2- 2 cos
2
APRIL ATTEMPT ~ 08 April 2019, Shift I 17

\ The contrapositive of the given statement is p p p

\ 0< a + b < + =
‘‘If you are not a citizen of India, then you are 4 4 2
not born in India. p
Þ 0< a + b <
5 (a) Given digits are 1, 1, 2, 2, 2, 2, 3, 4, 4. 2
According to the question, odd numbers 1, 1, 3 p
should occur at even places only. Also, - < -b < 0
4
p p
\ 0- < a -b < + 0
4 4
p p
Þ - < a -b <
4 4
æ pö æ p pö
Even places \ a + b Î ç 0, ÷ and a - b Î ç - , ÷
è 2ø è 4 4ø
\The number of ways to arrange odd numbers æ pö
3! But sin(a - b ) > 0, therefore a - b Î ç 0, ÷.
at even places are 4 C3 ´ è 4ø
2!
5
and the number of ways to arrange remaining Now, sin(a - b ) =
6! 13
even numbers are . 5
4! 2! Þ tan(a - b ) = …(i)
12
So, total number of 9-digit numbers, that can
3
be formed using the given digits are and cos(a + b ) =
3! 6! 5
4
C3 ´ ´ = 4 ´ 3 ´ 15 = 180 4
2! 4! 2! Þ tan (a + b ) = …(ii)
3
é cos a - sin a ù
6 (c) Given, matrix A = ê ú Now, tan(2a ) = tan[(a + b ) + (a - b )]
ë sin a cos a û 4 5
+
é cos a - sin a ù é cos a - sin a ù tan(a + b ) + tan(a - b ) 3 12
\ A2 = ê úê ú = =
ë sin a cos a û ë sin a cos a û 1 - tan(a + b ) tan(a - b ) 1 - 4 ´ 5
3 12
é cos2 a - sin 2 a - cos a sin a - sin a cos a ù
=ê ú [from Eqs. (i) and (ii)]
ë sin a cos a + cos a sin a - sin 2 a + cos2 a û
48 + 15 63
é cos 2 a - sin 2 a ù = =
=ê ú 36 - 20 16
ë sin 2 a cos 2 a û
Similarly,
é cos(na ) - sin(na )ù 8 (d) Key Idea Use formula :
An = ê ú, n Î N ( a + b) n + ( a - b) n =
ë sin(na ) cos(na ) û
é cos(32 a ) - sin(32 a )ù é 0 -1ù 2 [ n C 0 a n + nC 2a n - 2b 2 + nC 4 a n - 4 b 4 + ...... ]
Þ A32 = ê ú= ê ú (given)
ë sin(32 a ) cos(32 a ) û ë 1 0 û
So, cos(32 a ) = 0 and sin(32 a ) = 1 Given expression is
p p (x + x3 - 1)6 + (x - x3 - 1)6
Þ 32 a = Þ a =
2 64
= 2 [6 C0 x6 + 6C2x4 ( x3 - 1)2
5
7 (b) Given, sin(a - b ) =
13 + 6C4 x2 ( x3 - 1)4 + 6C6 ( x3 - 1)6 ]
3 æ pö {Q (a + b) + (a - b)n
n
and cos(a + b ) = , where a , b Î ç 0, ÷
5 è 4ø
= 2 [nC0 a n + nC2a n - 2b2 + nC4 a n - 4 b4 + …]}
p p
Since, 0 < a < and 0 < b <
4 4 = 2 [6 C0 x6 + 6C2x4 (x3 - 1) + 6C4 x2 (x3 - 1)2
+ 6C6 (x3 - 1)3 ]
18 ONLINE JEE Main 2019

The sum of the terms with even power of x

= 2 [6 C0 x6 + 6C2 (- x4 ) + 6C4 x8 + 6C4 x2 We know that,
+ 6C6 (-1 - 3x6 )] (a + b)2 = (a 2 + b2 ) + 2ab
= 2 [ C0 x - C2x + C4 x + C4 x2 - 1 - 3x6 ]
6 6 6 4 6 8 6 Þ (14)2 = 100 + 2ab
[from Eqs. (i) and (ii)]
Now, the required sum of the coefficients of
Þ 196 = 100 + 2ab
even powers of x in
Þ 2ab = 96
(x + x3 - 1)6 + (x - x3 - 1)6
Þ ab = 48
= 2 [6 C0 - 6C2 + 6 C4 + 6C4 - 1 - 3] So, product of remaining two observations is 48.
= 2 [1 - 15 + 15 + 15 - 1 - 3] 11 (c) Equations of given planes are
= 2(15 - 3) = 24 2x - y - 4 = 0 …(i)
5x 5x x and y + 2z - 4 = 0 …(ii)
sin 2 sin cos
9 (c) Let I = ò 2 dx = ò 2 2 dx Now, equation of family of planes passes
x x x through the line of intersection of given planes
sin 2 sin cos
2 2 2 (i) and (ii) is
x (2x - y - 4) + l( y + 2z - 4) = 0 …(iii)
[multiplying by 2 cos in numerator and
2 According to the question,
denominator]
sin 3x + sin 2x Plane (iii) passes through the point (1, 1, 0), so
=ò dx (2 - 1 - 4) + l(1 + 0 - 4) = 0
sin x
[Q 2sin A cos B = sin(A + B ) + sin(A - B ) and Þ -3 - 3l = 0
sin 2A = 2 sin A cos A] Þ l = -1
(3 sin x - 4 sin3 x) + 2 sin x cos x Now, equation of required plane can be
=ò dx obtained by putting l = - 1in the equation of
sin x
plane (iii).
[Q sin 3x = 3 sin x - 4 sin3 x]
Þ (2x - y - 4) - 1( y + 2z - 4) = 0
= ò (3 - 4 sin x + 2 cos x)dx
2
Þ 2x - y - 4 - y - 2z + 4 = 0
= ò [3 - 2(1 - cos 2x) + 2 cos x]dx Þ 2x - 2 y - 2z = 0
Þ x- y-z=0
[Q 2 sin 2 x = 1 - cos 2x]
= ò [3 - 2 + 2 cos 2x + 2 cos x]dx 12 (d) The normal vector to the plane containing
the vectors ($i + $j + k$ ) and ($i + 2$j + 3k$ ) is
= ò [1 + 2 cos 2x + 2 cos x]dx
n = ($i + $j + k$ ) ´ ($i + 2$j + 3k$ )
= x + 2 sin x + sin 2x + C ½$i $j k$ ½
10 (c) Let the remaining two observations are a = ½1 1 1½
½
½ ½
½
and b. According to the question,
½1 2 3½
2 + 4 + 10 + 12 + 14 + a + b
Mean = =8 = $i (3 - 2) - $j (3 - 1) + k$ (2 - 1) = $i - 2$j + k$
7
Þ 42 + a + b = 56 Now, magnitude of the projection of vector
Þ a + b = 14 …(i) 2$i + 3$j + k$ on normal vector n is
and variance |(2$i + 3$j + k$ ) × n| |(2$i + 3$j + k$ ) × ($i - 2 $j + k$ )|
=
a 2 + b2 + 4 + 16 + 100 + 144 + 196 |n| 1+ 4 + 1
= - 82 = 16
7 |2 - 6 + 1| 3 3
= = = units
a 2 + b2 + 460 6 6 2
Þ - 64 = 16
7 13 (d) Given equation of line is x + y = n,n ÎN …(i)
a 2 + b2 + 460
Þ = 80 and equation of circle is x2 + y2 = 16 …(ii)
7
Now, for intercept, made by circle (ii) with
Þ a 2 + b2 + 460 = 560 line (i)
Þ a 2 + b2 = 100 …(ii)
APRIL ATTEMPT ~ 08 April 2019, Shift I 19

Þ x - 1 = ± i [where i = -1]
x2+y2=16 Þ x = (1 + i ) or (1 - i )
(0, 0)
Clearly, if a = 1 + i, then b = 1 - i
4 n
d æaö
According to the question çç ÷÷ = 1
èb ø
A B x+y=n, n 0 N n
æ1+ iö
Þ ç ÷ =1
d<4 ç1- i ÷ø
n è
Þ <4 n
2 æ (1 + i )(1 + i ) ö
Þ ç ÷
ç (1 - i )(1 + i ) ÷ = 1 [by rationalization]
[Q d = perpendicular distance from (0, 0) to the è ø
|0 + 0 - n| n ù
n
æ 1 + i 2 + 2i ö n
line x + y = n and it equal to = ú Þ çç ÷ = 1Þ æç 2i ö÷ = 1Þ i n = 1
12 + 12 2 úû ÷ è 2ø
è 1- i
2
ø
Þ n<4 2 …(iii) So, minimum value of n is 4. [Q i 4 = 1]
Q n Î N , so n = 1, 2, 3, 4, 5 16 (c) Given, y £ x + 3x 2

Clearly, length of chord AB = 2 42 - d 2

æ 3 ö2 9
Þ y £ çx + ÷ -
n2 é n ù è 2ø 4
= 2 16 - êëQ d = 2 úû
2 æ 3 ö2 æ 9ö
Þ çx + ÷ ³ ç y + ÷
\Sum of square of all possible lengths of è 2 ø è 4ø
chords (for n = 1, 2, 3, 4, 5) Since, 0 £ y £ 4 and 0 £ x £ 3
é 1 ù \The diagram for the given inequalities is
= 4 ê (16 ´ 5) - (12 + 22 + 32 + 42 + 52 )ú
ë 2 û Y
5(6)(11) y=x2+3x
= 320 - 2 = 320 - 110 = 210
6
P (A Ç B )
14 (b) We know that, P( A / B ) = y=4
P (B )
–3/2
[by the definition of conditional probability] O X
(–3, 0) 1 3
Q AÌB –
9
4 x=3
Þ AÇB=A
P (A )
\ P( A / B ) = …(i) and points of intersection of curves y = x2 + 3x
P (B ) and y = 4 are (1, 4) and (-4, 4)
As we know that, 0 £ P (B ) £ 1 Now required area
1 1
\ 1£ <¥ 1 3
é x3 3x2 ù
P (B ) = ò (x2 + 3x)dx + ò 4 dx = ê 3 + ú + [4x]1
3

ë 2 û0
P (A ) 0 1
Þ P (A ) £ <¥ 1 3 2+ 9 11
P (B ) = + + 4(3 - 1) = + 8= + 8
P (A ) 3 2 6 6
Þ ³ P (A ) …(ii) 59
P (B ) = sq units
6
Now, from Eqs (i) and (ii), we get
P( A/B ) ³ P(A) 17 (c) Given function is
f (x) = 9x4 + 12x3 - 36x2 + 25 = y (let)
15 (c) Given, a and b are the roots of the quadratic dy
For maxima or minima put =0
equation, dx
x2 - 2x + 2 = 0 dy
Þ = 36x3 + 36x2 - 72x = 0
Þ (x - 1)2 + 1 = 0 dx
Þ (x - 1)2 = - 1 Þ x3 + x2 - 2x = 0
Þ x[x2 + x - 2] = 0
20 ONLINE JEE Main 2019

Þ x[x2 + 2x - x - 2] = 0 19 (b) Given series is

Þ x[x(x + 2) - 1(x + 2)] = 0 2 × 20C0 + 5 × 20C1 + 8 × 20C2 + ¼ + 62 × 20C20
Þ x(x - 1)(x + 2) = 0 20

Þ x = - 2, 0, 1
= å (3r + 2) ×20 Cr
r=0
By sign method, we have following [Q General term of the sequence 2, 5, 8, …,
– + – + which forms an AP, is 2 + (n - 1)3 = 3n - 1,
–2 0 1 where n = 1, 2, 3 ... and it can be written as
3n + 2, where n = 0, 1, 2, 3]
dy
Since, changes it’s sign from negative to 20 20
dx
positive at x = ‘-2 ’ and ‘1’, so x = - 2, 1 are
= 3× å r 20Cr + 2 å 20Cr
r=0 r=0
dy
points of local minima. Also, changes it’s 20
æ 20 ö 20
dx = 3 å r ç ÷ 19Cr - 1 + 2 å 20 Cr
sign from positive to negative at x = 0, so x = 0 r =1 è r ø r=0
is point of local maxima. é n n ù
n -1
\S1 = {-2, 1} and S2 = {0}. êëQ Cr = r Cr - 1 ú
û
æ 3ö æ 1ö 20 20
18 (d) Given, a = cos-1 ç ÷ and b = tan -1 ç ÷ = 3 ´ 20 å 19 Cr - 1 + 2 å 20 Cr
è 5ø è 3ø
r =1 r=0
p
where 0 < a , b < 19 20 é 20 19 ù
2 = 60 å Cr + 2 å Cr
19 20
êQ å 19Cr - 1 = å 19 Cr ú
r=0 r=0 êë r = 1 r=0 úû
é n ù
êQ å nCr = 2n ú
5
= (60 ´ 219 ) + (2 ´ 220 )
52 – 32 = 4 êë r = 0 úû
a = (15 ´ 221 ) + 221 = 16 ´ 221 = 225
3
4 Key Idea Reduce the given equation into
Clearly, a = tan -1 20 (d)
quadratic equation.
3
4 1
So, a - b = tan -1 - tan -1 Given equation is
3 3
| x - 2| + x ( x - 4) + 2 = 0
æ 4 1 ö
ç - ÷ Þ | x - 2| + x - 4 x + 4 = 2
= tan -1 ç 3 3 ÷
ç æ 4 1ö ÷ Þ | x - 2| + ( x - 2)2 = 2
ç1+ ç ´ ÷ ÷
è è 3 3ø ø Þ (| x - 2|)2 + | x - 2| - 2 = 0
é -1 -1 -1 x - y Let| x - 2| = y, then above equation reduced to
êQ tan x - tan y = tan , if xy > - 1]
ë 1 + xy y2 + y - 2 = 0 Þ y2 + 2 y - y - 2 = 0
1 9 Þ y( y + 2) - 1( y + 2) = 0Þ ( y + 2)( y - 1) = 0
= tan -1 = tan -1
1+
4 13 Þ y = 1, - 2
9 \ y=1 [Q y = | x - 2| ³ 0]
250 Þ | x - 2| = 1
2 =
3 Þ x - 2= ±1
2 1
9+ 9 Þ x = 3 or 1
a –b Þ x = 9 or 1
13 \ Sum of roots = 9 + 1 = 10
9 9
= sin -1 = sin -1 21 (d) Equation of given ellipse is
9 + 13
2 2 250
4x2 + y2 = 8 …(i)
æ 9 ö
= sin -1 ç ÷ x2 y2 x2 y2
è 5 10 ø Þ + = 1Þ + =1
2 8 ( 2 ) 2 (2 2 ) 2
APRIL ATTEMPT ~ 08 April 2019, Shift I 21

Now, equation of tangent at point (1, 2) is Q y(0) = 0

2x + y = 4 ...(ii) \ C=0
x2 y2 \ y(1 + x2 ) = tan -1 x [Q C = 0]
[Q equation of tangent to the ellipse 2 + 2 = 1
a b tan -1 x
xx yy Þ y=
at (x1 , y1 ) is 21 + 21 = 1] 1 + x2
a b æ tan -1 x ö
and equation of another tangent at point (a , b) Þ a y = a çç 2 ÷
÷
is 4ax + by = 8 …(iii) è 1+ x ø
Since, lines (ii) and (iii) are perpendicular to [multiplying both sides by a]
each other. Now, at x = 1
æ 2 ö æ 4a ö æ tan -1 (1) ö
\ ç- ÷ ´ ç- ÷ = -1 a y (1) = a çç ÷
÷
è 1ø è b ø è 1+ 1 ø
[if lines a1 x + b1 y + c1 = 0 and a2x + b2 y + c2 = 0 p
æ a öæ a ö ap p
are perpendicular, then çç - 1 ÷÷ çç - 2 ÷÷ = - 1] = a 4= = (given)
è b1 ø è b2 ø 2 8 32
1 1
Þ b = - 8a …(iv) \ a = Þa=
4 16
Also, the point (a , b) lies on the ellipse (i), so
23 (d) The natural numbers between 100 and 200
4a 2 + b2 = 8
are 101, 102, 103, …, 199.
Þ 4a 2 + 64a 2 = 8 [from Eq.(iv)] Since, 91 = 13 ´ 7, so the natural numbers
8
Þ 68a = 8 Þ a =
2 2 between 100 and 200 whose HCF with 91 is
68 more than 1 are the numbers which are either
2 divisible by 7 or 13.
Þ a =
2
17 So, the required sum of numbers between 100
22 (d) Given differential equation is and 200 = (sum of numbers divisible by 7) +
dy (sum of numbers divisible by 13) - (sum of
(x2 + 1)2 + 2x(x2 + 1) y = 1 numbers divisible by 91)
dx 14 8

Þ
dy æç 2x ö÷
+ y=
1 = å (98 + 7r ) + å (91 + 13r ) - (182)
dx çè 1 + x2 ÷ø
r =1 r =1
(1 + x2 )2
æ 14 ´ 15 ö
[dividing each term by (1 + x2 )2] …(i) = (98 ´ 14) + 7ç ÷ + (91 ´ 8)
è 2 ø
This is a linear differential equation of the
dy æ 8 ´ 9ö
form + P×y =Q + 13 ç ÷ - (182)
dx è 2 ø
2x 1 = 1372 + 735 + 728 + 468 - 182
Here, P = and Q =
(1 + x2 ) (1 + x2 )2 = 3303 - 182 = 3121
2x
ò x2
dx 24 (a) Equation of given line is
\Integrating Factor (IF) = e 1 + x+ 3 y-2 z
= = = r (let) …(i)
=e ln( 1 + x 2 )
= (1 + x )
2 10 -7 1
Coordinates of a point on line (i) is
and required solution of differential Eq. (i) is
given by A (10r - 3, - 7r + 2, r )
Now, let the line joining the points P (2, - 1, 4)
y × (IF) = ò Q (IF)dx + C and A (10r - 3, - 7r + 2, r ) is perpendicular to
1 line (i). Then,
Þ y(1 + x2 ) = ò
(1 + x2 )2
(1 + x2 )dx + C
PA × (10$i - 7$j + k$ ) = 0
dx [Q vector along line (i) is (10$i - 7$j + k$ )]
Þ y(1 + x2 ) = ò +C
1 + x2 Þ [(10r - 5)$i + (-7r + 3)$j + (r - 4)k$ ]
Þ y(1 + x2 ) = tan -1 (x) + C ×[10$i - 7$j + k$ ] = 0
Þ 10(10r - 5) - 7(3 - 7r ) + (r - 4) = 0
22 ONLINE JEE Main 2019

Þ 100r - 50 - 21 + 49r + r - 4 = 0 Þ x2 + y2 - 2 y + 1 = 3 - x2 + y2
1
Þ 150r = 75 Þ r = Þ x2 + y2 - 2 y + 1 = 9 + x2 + y2 - 6 x2 + y2
2
æ 3 1ö [squaring both sides]
So, the foot of perpendicular is A ç 2, - , ÷
è 2 2ø
Þ 1 - 2 y = 9 - 6 x + y2
2
1
[put r = in the coordinates of point A]
2 Þ 6 x2 + y2 = 2 y + 8
Now, perpendicular distance of point P (2, - 1, 4)
Þ 3 x2 + y2 = y + 4
from the line (i) is
æ 3 ö
2
æ1 ö
2 Þ 9(x2 + y2 ) = ( y + 4)2 [squaring both sides]
PA = (2 - 2)2 + ç - + 1÷ + ç - 4 ÷
è 2 ø è2 ø Þ 9x2 + 9 y2 = y2 + 8 y + 16
1 49 50 5 Þ 9x2 + 8 y2 - 8 y = 16
= + = =
4 4 4 2 Thus, the locus of point P (x, y) is
which lies in (3, 4). 9x2 + 8 y2 - 8 y = 16

25 (c) Given equation of line is 3x + 5 y = 15 …(i) 27 (b) Given expression is

2
æ æ 3 cos x + sin x ö ö
Clearly, a point on the line (i), which is 2 y = çç cot -1 çç ÷÷
÷÷
equidistance from X and Y -axes will lie on the è è cos x - 3 sin x ø ø
line either y = x or y = - x. 2
æ æ 3 cot x + 1 ö ö
Y = çç cot -1 çç ÷÷
÷÷
è è cot x - 3 ø ø
B y=x [dividing each term of numerator and
denominator by sin x]
(0, 3) 2
æ æ p öö
y=–x ç ç cot cot x + 1 ÷ ÷
A
ç é p ù
= cot -1 ç 6 ÷÷
ç ç cot x - cot p ÷ ÷ êëQ cot 6 = 3ú
û
(5, 0) ç ç ÷÷
X è è 6 øø
0
3x+5y=15 2
æ æ æp ööö
= çç cot -1 ç cot ç - x ÷ ÷ ÷÷
In the above figure, points A and B are è è è6 øøø
on the line (i) and are equidistance from the é cot A cot B + 1ù
coordinate axes. êQ cot(A - B ) = ú
ë cot B - cot A û
æ 15 15 ö
On solving line (i) and y = x, we get A ç , ÷. ì æp 2
è 8 8ø ö p
ï ç - x÷ , 0< x <
Similarly, on solving line (i) and y = - x, we get ï è6 ø 6
=í 2
æ 15 15 ö ïæç p + æç p - x ö÷ ö÷ , p < x < p
B ç - , ÷. ïîè
è 2 2ø è6 øø 6 2
So, the required points lie only in I and II é ìp + q, - p < q < 0ù
ê -1 ï ú
quadrants.
ê Q cot (cot q) = í q, 0< q< p ú
26 (c) Given vertices of DAOP are O(0, 0) and A(0, 1) êë ï q - p , p < q < 2p ú
î û
Let the coordinates of point P are (x, y). ì æp ö
2
p
Clearly, perimeter = OA + AP + OP = 4 (given) ï ç - x÷ , 0 < x <
ïè6 ø 6
Þ 2y = í 2
Þ (0 - 0)2 + (0 - 1)2 + (0 - x)2 + (1 - y)2 ïæç 7p - x ö÷ , p < x < p
ïîè 6 ø 6 2
+ x2 + y2 = 4
ì æp ö p
2ç - x ÷ (-1), 0 < x <
Þ1+ x2 + ( y - 1)2 + x2 + y2 = 4 dy ïï è 6 ø 6
Þ2 =í
dx ï2æ 7p - x ö (-1), p < x < p
ç ÷
ïî è 6 ø 6 2
Þ x2 + y2 - 2 y + 1 + x2 + y2 = 3
APRIL ATTEMPT ~ 08 April 2019, Shift I 23

ì p p Thus, f(x) is increasing on (1, 2).

dy ï x - 6 , 0 < x < 6
Þ =í Similarly, for f(x) to be decreasing,
dx ïx - 7p , p < x < p
f¢(x) £ 0
î 6 6 2
Þ f ¢ (x ) - f ¢ (2 - x ) £ 0 [using Eq. (i)]
æ1- x ö
28 (a) Given, f (x) = log e çç ÷,|x|< 1, then Þ f ¢ (x ) £ f ¢ (2 - x )
÷
è1+ x ø Þ x<2- x
æ 2x ö [Q f ¢ is a strictly increasing function]
ç1- ÷
æ 2x ö + x2 ÷ é ½ 2x ½ ù
f çç ÷ = log e ç 1
êQ½ ½< 1ú Þ 2x < 2
2÷ ç 2x ÷
è 1 + x ø êë ½1 + x ½ úû
2
Þ x <1
ç1+ 2 ÷
è 1+ x ø Thus, f(x) is decreasing on (0, 1).
æ 1 + x - 2x ö
2
ç ÷ 30 (d) The given functions are
ç 1 + x2 ÷ æ (1 - x)2 ö 2 - x cos x
= log e ç ÷ = log e çç 2÷
÷ g (x) = log e x, x > 0 and f (x) =
2 + x cos x
ç 1 + x + 2x ÷ è (1 + x) ø
2

ç 1 + x2 ÷ p/4
è
2
ø Let I= ò- p / 4 g (f (x))dx
æ1- x ö æ1- x ö æ 2 - x cos x ö
= log e çç ÷ = 2 log e ç ÷ p/4
è 1 + x ÷
ø
ç1+ x ÷
è ø
Then, I= ò- p / 4 log e ç
è
÷
ç 2 + x cos x ÷ dx
ø
…(i)

[Q log e|A| = m log e|A|]

m
Now, by using the property
é æ 1 - x öù b b
= 2f (x) êQ f (x) = log e çç ÷ú
êë
÷
è 1 + x ø úû ò f (x)dx = ò f (a + b - x)dx, we get
a a
29 (c) Given, f(x) = f (x) + f (2 - x), " x Î (0, 2) p/4 æ 2 + x cos x ö
Þ f¢(x) = f ¢(x) - f ¢(2 - x) …(i)
I= ò- p / 4 log e ç ÷
ç 2 - x cos x ÷ dx
è ø
…(ii)

Also, we have f ¢¢(x) > 0 " x Î (0, 2) On adding Eqs. (i) and (ii), we get
Þ f ¢(x) is a strictly increasing function p/4 é æ 2 - x cos x ö æ 2 + cos x ö ù
" x Î (0, 2). 2I = ò ê log e çç ÷ + log e ç
÷
÷
ç 2 x cos x ÷ údx
Now, for f(x) to be increasing,
-p / 4
êë è 2 + x cos x ø è ø úû
f¢(x) ³ 0 p/4 æ 2 - x cos x 2 + x cos x ö
=ò log e çç ´ ÷ dx
÷
Þ f ¢ (x ) - f ¢ (2 - x ) ³ 0 [using Eq. (i)] -p / 4
è 2 + x cos x 2 - x cos x ø
Þ f ¢ (x ) ³ f ¢ (2 - x ) Þ x > 2 - x [Q log e A + log e B = log e AB]
p/4
[Q f ¢ is a strictly increasing function] Þ 2I = ò- p / 4 log e (1)dx = 0
Þ 2x > 2
Þ I = 0 = log e (1)
Þ x >1