Polyester polyols division

hoocker

Markets supplied by Synthesia
Products for Reactive Hot-Melt
Products for CASE
Products for Rigid foam
Products for Flexible foam
Products for Shoe-soles
3
Reactive Hot Melt Market
• Reactive Hot Melts (RHM) adhesives are isocyanate terminated prepolymers made from highly crystalline or glassy
amorphous polyester polyols and pure MDI
• The advantage of RHM adhesives is that they combine the speed of a conventional hot-melt with the strength of a
reactive system. Moreover, Reactive Hot Melt adhesives are solvent free
• There are three families of this type of products:
- Crystalline
- Amorphous
- Liquid
3
Reference OHV AV Glass Melting Mol. Weight Viscosity
(mg KOH/g) (mg KOH/g) Trans (ºC) Point (ºC) (g/mol) (mPa s)
Hoopol F-580 37-40 < 0,5 - 50 3.000 3.000–4.000 (60ºC)
4 Hoopol F-531 26,4-28,4 < 0,2 - 53 4.000 6.000-10.000 (60º)
Hoopol F-900 53-58 < 0,5 - 53 2.000 700-1.300 (60ºC)
Hoopol F-970 38-42 < 0.5 - 54 2.800 1800 – 3000 (60ºC)
Hoopol F-972 44-48 < 0.5 - 54 2.400 1000 – 2300 (60ºC)
Hoopol F-931 28-32 < 0,5 - 57 3.750 4.000-7.000 (60ºC)
5 Crystalline Hoopol F-902
Hoopol F-911
18-24
10-16
< 2,0
< 2,0
-
-
58
59
5.500
8.500
2.000-8.000 (80ºC)
35.000 (80ºC)
Hoopol FS-930 27-34 < 2,0 - 67 3.750 2.000 (80º)
Hoopol F-3000 27-33 < 0,5 - 71 3.750 2.000-4.000 (80ºC)
Hoopol F-7931 27-34 < 2,0 - 96 3.750 1.500 (130ºC)
Hoopol F-88933 27 - 34 < 2,0 - 106 3750 2000 (130ºC)
6 Hoopol F-88931 27-34 1,0 – 2,0 - 120 3.750 3.000-5.000 (130ºC)
Hoopol F-5630 30-34 < 2,0 16 - 3.500 3.000 (130ºC)
Amorphous Hoopol F-39030 33-37 < 2,0 29 - 3.200 9.000-16.000 (130ºC)
Hoopol F-37070 38 - 46 < 2,0 51 - 2650 60.000 (130ºC)
Hoopol F-37040 27-34 < 2,0 -20 - 3.750 10.000 (80ºC)
Hoopol F-37030 27-32 < 1,0 -27 - 3.750 5.000-10.000 (80ºC)
7 Hoopol F-7930 27-34 < 2,0 -28 - 3.750 2.000 (130ºC)
Liquid Hoopol F-37031 30-34 < 2,0 -30 - 3.500 4.000-10.000 (80ºC)
Hoopol F-37032 27-34 < 2,0 -37 - 3.750 8.000 (80ºC)
Hoopol F-37050 27-34 < 2,0 -41 - 3.750 12.000 (80ºC)
Hoopol FJ-20030 18-24 < 2,0 -55 - 5.500 5.000 (80ºC)
4 Hoocker Polyester polyols división 5

CASE Market Rigid Foam Market

• Synthesia produces polyester polyols s based on three different acid sources:
Synthesia produces all types of combinations diacids / diols / molecular weights / functionalities for the CASE market:
- PET scrap
- Phtalic anhydride
• One and two component adhesives
- AGS acids mixture

• TPU’s: These polyester polyols s are linear and based on a mixture of standard glycols and adipic acid
• Synthesia has polyester polyols s specially developed for improved compatibility with different blowing agents:
pentanes, HCFC, HFC, water
• Cast elastomers. These polyester polyols s are linear and based on a mixture of standard glycols, aliphatic and
aromatic diacids
• Synthesia supplies the following markets:
- Continuous and discontinuous block
• Leather coatings
- Continuous and discontinuous panel
- Spray insulation
• Artificial leather
- OCF

Reference OHV AV Mol. Weight Viscosity Reference OHV AV Viscosity

(mg KOH/g) (mg KOH/g) (g/mol) (mPa s 60ºC) (mg KOH/g) (mg KOH/g) (mPa s 60ºC)

Hoopol F-116 54-58 < 0,5 2.000 960 - 1440 Hoopol F-1360 325-375 1,7-2,3 1.000 – 2.000
Hoopol F-123 108-116 < 0,5 1.000 300-350 Hoopol F-1394 230-250 0,8-1,2 1.500 – 2.500
Polyester
Hoopol F-330 38-44 < 0,5 2.750 1.600-2.400 Hoopol F-1395-P 160-180 < 2,0 1.500 – 2.100
Polyol
Hoopol F-412 54-60 0,5 – 0,8 2.000 7.000-9.000 (25ºC) (PET based) Hoopol F-1396 230-250 0,8-1,2 1.500 – 2.500
Hoopol F-531 26,4-28,4 < 0,2 4.000 6.000-10.000 Hoopol F-7020 120-130 < 5,0 1.000
Hoopol F-580 37-40 < 0,5 3.000 3.000-4.000 Hoopol F-7021 155 - 165 < 5,0 750
Hoopol F-501 54-58 < 0,5 2.000 1.300-1.500 Hoopol F-3362 300-320 1,7-2,3 1.500-2.900
Hoopol F-523 114-122 0,1-0,3 950 200-600 Polyester Hoopol F-4091-M 180-200 0,8-1,3 8.000-12.000
Hoopol F-690 218-230 < 0,7 500 2.300-3.300 (25ºC) Polyol Hoopol F-4390 230-260 < 2,0 8.000-12.000
(AnF based)
Hoopol F-900 53-58 < 0,5 2.000 700 – 1.300 Hoopol F-4391-D 230-250 < 1,0 2.100 – 3.500
Hoopol F-9480 82-95 < 1,0 1.250 2.100-2.800 Hoopol F-4361 300-320 < 2,0 2.500 – 3.200
Hoopol F-9900 54-58 < 0,6 2.000 2.300 – 2.900 Hoopol MT-480 460-500 - 8.000-15.000
Bases
Hoopol F-9920 115-125 < 0,5 950 400-600 Mannich Hoopol MP-115-P 465-515 - 9.000-15.000
Hoopol F-9690 218-230 < 0,7 500 15.000 – 19.000 (25ºC) Hoopol MP-126-A 420-475 - 10.000-18.000
Hoopol F-881 84-93 < 2,0 1250 2.800 – 3.600 (25ºC)
Hoopol F-5321 109-115 < 0,5 1.000 3.500 – 5.500 (25ºC)
Hoopol F-10670 41-44 0,5–1,0 2.650 2.300-2.700
Hoopol F-10201 54-58 < 0,4 2.000 1.500-2.000
Hoopol F-20013 54 - 58 < 0,5 2.000 1.300 – 1.600
Hoopol S-101-55 * 53-58 < 0,8 2.000 1.050-1.350
Hoopol S-101-135 130-140 < 0,6 830 200-300
Hoopol S-1015-35 35,5-38,5 < 0,6 3.000 3.000-3.600
Hoopol S-1015-120 117-123 < 0,6 950 300-400
Hoopol S-1015-210 205-215 < 0,6 530 140-150
Hoopol S-1017-70 65-75 < 0,5 1.600 600 - 950
Hoopol S-1042-55 54 - 58 < 0,5 2.000 800 – 1.300
Hoopol S-1063-35 34-38 < 0,6 3.000 3.200 – 4.200
Hoopol S-1100-100 97 - 107 < 0,5 1.100 300 - 500
Hoopol S-1155-55 53-58 < 0,5 2.000 1.300 – 1.500

*1) Hoopol S-101-55 = Hoopol F-200

6 Hoocker Polyester polyols división 7

Flexible Foam Market Shoe-soles Market

• All types of diacid/diol combinations with different molecular weights & functionalities for the flexible foam market:
Standard polyester polyols based on adipic acid and glycols, with functionalities between 2.0 and 3.7 • Synthesia produces all types of combinations diacids / diols / molecular weights / functionalities for the shoe-sole
market: Standard polyester polyols based on adipic acid and monoethyleneglycol and/or diethyleneglycol and/or
• Low fogging version of standard and polymeric polyesters 1,4 butanediol, with functionalities between 2.0 and 2.7

• Unique type of polymeric polyesters as the result of a vinylic polymerisation of monomers into the standard polyester • Synthesia produces a unique type of polymeric polyesters as the result of a vinylic polymerisation of monomers into
matrix. Advantages: the standard polyester matrix. Advantages:
- mechanical properties and densities - mechanical properties and densities
- savings of TDI 65 - savings of MDI formulation economy
- cell size regulation less scrap better economy - skin improver in only water based formulations
- cell size regulation
• New developments: hydrolysis resistant polyester polyols, taylor made prepolymers for increased abrasion resistance

Reference OHV AV Viscosity Functionality Reference OHV AV Viscosity Functionality

(mg KOH/g) (mg KOH/g) (mPa s 60ºC)
Hoopol F-740-SF 58-62 0,8-1,4 17.000 – 21.000 (25ºC) 2,5 – 3,0
Hoopol F-745-SF 57-62 0,6-0,9 20.500 – 23.500 (25ºC) 2,5 – 3,0
Polyester Hoopol F-759-SF 51-55 0,9-1,2 20.500 – 23.500 (25ºC) 2,5 – 3,0
Polyol Hoopol F-772-P 58-62 1,0-1,4 17.000 – 21.000 (25ºC) 2,5 – 3,0
Hoopol Q-5014 207-219 1,0-2,0 18.000-22.000 (25ºC) 3,0 – 3,5
Hoopol Q-5017 215-225 1,0-2,0 25.000-35.000 (25ºC) 3,0 – 3,5
Polymeric Hoopol PM-7872-SF 55-59 0,8-1,2 20.000-30.000 (25ºC) -
Polyester Hoopol PM-7812-SFC 53-57 0,8-1,2 27.000-37.000 (25ºC) -
(mg KOH/g) (mg KOH/g) (mPa s 60ºC)
Hoopol F-110-1000 54-58 0,2-0,7 900-1.200 2,0
Hoopol F-113 54-58 < 0,4 1.000-1.400 2,0
Polyester
Hoopol F-171 44-48 < 0,5 1.500-1.800 2,0-2,5
Polyol
Hoopol F-173 54-60 0,5-0,8 1.300-1.800 2,0-2,5
Hoopol F-772-D 58-62 1,0 –1,4 17.000-21.000 (25ºC) 2,5-3,0
Hoopol PM-245 57-63 < 0,8 1.500-3.000 -
Plymeric
Polyester Hoopol PM-2245 60-64 < 0,1 2.500-5.000 -
Hoopol PM-445 57-63 0,2 – 0,8 1.000 – 3.000 -
 ESPAÑA
Central Office Synthesia
Comte Borrell, 62 · 08015 Barcelona
Tel. +34 93 325 31 58 · +34 93 682 13 00 · Fax +34 93 423 67 53
Juan Sánchez · jsanchez@synte.es
Elisabet Pons · epons@synte.es
info@synte.es · www.synte.es Update: Abril 2010

DISTRIBUTORS:

BENELUX GREECE
EVS Polyservice BVBA Delta Chemical SA
Mechelsevest 16/02.02. 3000 Leuven - BELGIUM 180 Pireos and Lamias Str. 17778 Tavros, Athens
Tel. +32486311745 · Fax +32(0) 13-676061 Tel. +302103470780
Eddy Vanstraelen · eddy@evspolyservice.be · evanstraelen@synte.es
Polivios Sakellarios · sakellarios@delta.chemicals.gr
BRAZIL
Proquimil INDIA
Rua Rio de Janeiro 641, Jardim Ruyce, Diadema Sao Paulo Bharat Enterprises
Tel. +55 11 4061-4061 · Fax +55 11 4066-5225 217-218-219,Gupta Complex,Inderlok,1,Old Rohtak Road, Delhi-110035
Karina Afonso · karina@proquimil.com.br Tel. +91 11 23658973 · Fax +91 11 23658955
Shailendra Agarwal · sa@bharat-enterprises.com
COLOMBIA
Barnisol ITALY
Carrera 55, 152-35. Int. 4. Apto 704. Barrio Colina Campestre. Bogota
Berk di Raffaele Bernardini
Tel. +5714773666
Jose Camero · josecamero2002@cable.net.co Viale Einaudi, 41/A - 20020 Arese (Mi)
Tel. +39029382008 · Fax +39029382008
CHINA Raffaele Bernardini · r.bernardini@berk.191.it
Shangai Achemical Trading Co., Ltd.
Room A.B.C 10F Careri BLDG Nº432 West Huai Hai Rd., Shangai TAIWAN
Tel. +86-21-52585511-40 · Fax +86-21-62802224 Funle Trading Co., Ltd.
Chunhai Qiu · qiuchunhai@achemc.com.cn 12F-4, Nº 295, Sec. 2, Kuang Fu Road, ZIP 300-17. Hsin-chu city
Tel. 886-3-572-4813 · Fax 886-3-572 4342
EEUU
Ming Chiun Lee · funle@mail.apol.com.tw · mingchiunlee@yahoo.com.tw
ChemFoam
Suite 305-135, 3455 Peachtree, Industrial Blvd. Duluth, GA 30096
Tel. +1 770-418-0365 THAILAND
Steven Gabelman · sgabelman@aol.com ZI-Techasia Solutions
11/F Ploenchit Center, 2 Sukhumvit Road, Khet Klongtoey, Bangkok
FRANCE Tel. (662)6568710-54#4700 · Fax (662)6568767-69
Guy Berenguer Thanakorn Pongpaiboobsiri · Thanakorn@zi-th.com
9 rue du Guirbaden, Mundolsheim, 67450 Yupinya Paneetapalin · Yupinya@zi-th.com
Tel. +33 611277490 · Fax +33351081598 Woranut Sutthiloetrat · Woranut.s@zi.th.com
Guy Berenguer · berenguerguy@aol.com

GERMANY, AUSTRIA, POLAND, SWITZERLAND TURKEY

Danquinsa GmbH Uni-Grup
P.O. Box 147 Störrenstr. 30, 72133 Dettenhausen Emek Mahallesi,Mevlana Caddesi No 40 34785 Sancaktepe / Istanbul
Tel. +4971575225-0 · Fax +4971575225-22 Tel. +9002166227630
Peter Daniel · peter.daniel@danquinsa.de Muge Pinar · muge.pinar@unigrup.com