Chapter 3 Material and Energy Balance

3.1 MATERIAL BALANCE

Basis:
Annual Plant Capacity = 1.314 × 107 Metric Tons
Plant Capacity per day = 120 Metric Tons
Flow rate of TDI produced per Hr. = 4850 Kg
Yield of TDI = 85.3 %

Component From TDA From O- T0 E-111 From To E-213 or

Storage (1) DCB (3) COC12 R-110 (7)
Storage (2) Storage (5)
TDA 4086 4086
O-DCB 16344 16344 15063.5
CoCl2 25140 9.05
TDI 24.14
HCL
Res

Component To D-210 To Section To D-211 From D- T0 D-310

(9) 500 (10) (11) 211 (12) (13)
TDA
O-DCB 31711 609.4 31101.6 295 30806.6
CoCl2 18644 12820 5824 5805.8 18.2
TDI 5000 45.012 4987.7 26 4961.7
HCL 4675 4349.1 325.9 325.9
Res 643.3 643.3 643.3

Component To E-312 To Section To Res. To TDI To V-410

(14) 500 (19) Storage (23) Storage (24) (20)
TDA 12712.5
O-DCB 30776 9.45 30.6 30.6
CoCl2 18.2 25.2

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Chapter 3 Material and Energy Balance

TDI 49.6 62.08 4850 4912.08

HCL
Res 643.3 643.3

3.2 ENERGY BALANCE

Unit Unit Name Heat Load T or ΔT (ْC) Utility

E-111 TDA Soln. Pre-Heater 9.8x105 105-145 Saturated Steam
E-112 COCl2 Pre-Heater 1.51x106 25-75 Saturated Steam
R-110 Reactor 0 135 No Utility required
E-311 Crude TDI Pre-heater 2.71x105 115-190 Saturated Steam
E-312 Reflex Condenser 1.12x107 165 Cooling Water
E-313 Re-boiler 1.12x107 252.22 Thermal Fluid
V-410 Evaporator 2.05x106 252.22-270 Thermal Fluid
E-411 TDI Sub-Cooler 2.4x105 252.22-25 Cooling Water
E-412 Res. Sub-Cooler 2 x106 270-25 Cooling water

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