29/12/2019 OYMR

Code-A

Regd. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Ph.011-47623456

MM : 70 FORTNIGHTLY TEST SERIES Time : 3 Hrs.

(for NEET-2020)
Subjective Test - 5

CHEMISTRY
(Complete Syllabus of Class XII)

GENERAL INSTRUCTIONS :
(i) All questions are compulsory.
(ii) Section A: Question number 1 to 20 are very short answer questions (objective type) and carry
1 mark each.
(iii) Section B: Question number 21 to 27 are short answer questions and carry 2 marks each.
(iv) Section C: Question number 28 to 34 are long answer questions and carry 3 marks each.
(v) Section D: Question number 35 to 37 are also long answer questions and carry 5 marks each.
(vi) There is no overall choice. However an internal choice has been provided in two questions of two
marks, two questions of three marks and all the three questions of five marks weightage. You have
to attempt only one of the choices in such questions.
(vii) Use log tables if necessary, use of calculator is not allowed.

SECTION-A

Read the given passage and answer the questions 1 to 5 that follow:

The d-block elements involve filling of (n – 1)d sub shells for their valence electrons while f-block is constituted by
lanthanoids and actinoids. These elements impart certain distinct characteristics like variable oxidation states,
paramagnetic behaviours, catalytic properties and tendency for the formation of coloured ions and interstitial
compounds and complexes. Lanthanoids exhibit +3 as the principal oxidation state, although +4 and +2 oxidation
states are also exhibited occasionally.

1. What is the reason for the extraordinary stability of Mn2+ and Zn2+ ions?

2. What is the general electronic configuration of d-block elements?

3. Out of Sc3+, Zn2+, Cr3+ and Ti4+ which one is coloured?

4. What is the most common oxidation state of Lanthanoids?

5. Why does MnO4– not disproportionate?

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One Year Medical-2020 Subjective Test (OYMR_ST05) Code-A

Questions 6 to 10 are one word answers:

6. Out of Li+, H+, Cs+ and Ca2+ which one has the highest molar conductivity?
7. What is the unit of Cryoscopic constant?
8. What is the total number of ions given by the complex [Co(NH3)5Cl]Cl2 in the aqueous solution?
9. What is the IUPAC name of the compound CH 2 = CH – CH – CH – CH 2 – CH 3 ?
OH OH
10. What is the polymer of Caprolactam called?
Questions 11 to 15 are multiple choice questions:
11. To which colloidal system does milk belong?
(a) Liquid in solid (b) Liquid in liquid (c) Gas in liquid (d) Solid in liquid
12. The ∆G° for the reaction,
Zn(s) + Cu2+(aq) → Zn2+(aq) + Cu(s) is
(Given, E0 cell =+1.1 V, 1F = 96500 C mol–1)
(a) –190 kJ/mol (b) –300.8 kJ/mol (c) 212.3 kJ/mol (d) –212.3 kJ/mol
13. On increasing temperature, the rate constant of a reaction
(a) Increases (b) Decreases
(c) Remains same (d) Initially decreases then increases
14. The method which is used for the refining of nickel is
(a) Zone refining (b) Mond process (c) Liquation (d) van Arkel method
15. Which of the following has the highest negative electron gain enthalpy?
(a) O (b) S (c) Se (d) Te
In the following questions (16 to 20), a statement of assertion (A) is followed by a statement of reason (R):
(A) Both assertion and reason are correct statements, and reason is the correct explanation of the assertion.
(B) Both assertion and reason are correct statements, but reason is not the correct explanation of the assertion.
(C) Assertion is correct, but reason is wrong statement.
(D) Assertion is wrong, but reason is correct statement.
16. Assertion : 4-Nitrobenzoic acid is more acidic than 4-methylbenzoic acid.
Reason : Electron withdrawing group increases the acidic character.
17. Assertion : Sucrose is a non-reducing sugar.
Reason : In sucrose the reducing groups of glucose and fructose are involved in glycosidic bond
formation.
18. Assertion : CH3 – CH2Br is more reactive towards SN2 than SN1.
Reason : Primary alkyl halides are most hindered.
19. Assertion : [Fe(CN)6]4– is an octahedral complex.
Reason : The oxidation state of Fe in [Fe(CN)6]4– is +2.
20. Assertion : Hydrolysis of cane sugar is a pseudo first order reaction.
Reason : Water is present in large excess during hydrolysis.

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Subjective Test (OYMR_ST05) Code-A One Year Medical-2020

SECTION-B

21. What type of deviation (positive or negative) from ideal behaviour will be shown by the solution of ethanol
and Cyclohexane? Give suitable reason.
22. What do you understand by nucleophilic substitution in alkyl halides? Why haloarenes are less reactive than
alkyl halides towards such reaction?
23. If a non-electrolytic solute is added to water, then the difference between boiling point and melting point
becomes 105°C. What will be the sum of Kf and Kb if the molality of the solution is 0.1 m?

24. Draw crystal field splitting energy diagram for octahedral complex.
25. How will you convert aniline to benzyl alcohol?
26. Name the reagent used in the following reactions:
(a) Bromination of phenol to 2, 4, 6-tribromophenol.
(b) Oxidation of primary alcohol to aldehyde.
OR
Complete the following reaction.

(a) OH + SOCl2

H2SO4
(b) CH3 − =
CH CH2 + H2O  →

27. Given that, the standard electrode potential (E0) of metals are
Li+/Li = –3.05 V
Al3+/Al = –1.66 V
Fe2+/Fe = –0.44 V
Sn2+/Sn = –0.14 V
Arrange these metals in an increasing order of their reducing power.
OR
A galvanic cell is represented as
Ni(s) |Ni2+(aq)||Ag+(aq)|Ag(s)
(a) Which one of its electrode is positively charged?
(b) Write the reaction taking place at each of its electrode.

SECTION-C
28. Explain the following terms with one suitable example in each case:
(a) Antacids
(b) Antibiotics
(c) Antiseptics
29. Give an example of coordination compound having trans form optically inactive but cis form optically active.
Draw the structures as well.
30. (i) Why does reaction of RX give different products on reaction with KCN and AgCN?
(ii) What does happen when phenol reacts with zinc?

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One Year Medical-2020 Subjective Test (OYMR_ST05) Code-A

OR
CH3
373 K
(i) CH3 C O CH3 + HI A + B
(conc.) (Alkyl iodide) (Alcohol)
CH3
What are A and B and through which mechanism does this reaction proceed?
(ii) Write a short note on Wolff-Kishner reduction of aldehydes.
31. (i) If t1/2 of a 1st order reaction is 10 seconds, then what will be the value of t1/16 (1/16th remains)?
(ii) What is the relation between t1/2 and [A0] for zero order reaction?
32. (i) How will you convert chlorobenzene to phenol?
(ii) Why is phenoxide ion more stable than phenol?
33. There are two volatile components A and B having vapour pressures 200 mm Hg and 300 mm Hg
respectively. If an ideal mixture is formed by mixing of both components, calculate the vapour pressure of
solution if mole fraction of component B is 0.6 in vapour phase.
34. Write down the method to distinguish between primary, secondary and tertiary alcohols.
OR
How will you convert
(a) Benzene to benzophenone
(b) Benzyl chloride to benzyl alcohol
(c) Bromobenzene to benzoic acid

SECTION-D

35. (a) Describe the mechanism of esterification reaction of carboxylic acid with alcohol in acidic medium.
(b) Complete the reaction
O CHO
C
CH3 NaOH
X
∆
Y.
+

OR
COOH
∆ strong
+ NH3 A B C
heating
COOH
KOH
COOH H2O E R – X D
F +
COOH
Identify A, B, C, D, E and F.
36. Arrange the following in correct order of property enclosed in bracket.
(i) F2, Br2, Cl2, I2 (Bond dissociation enthalpy)
(ii) HF, HCl, HBr (Acidic character)
(iii) HOCl, HOBr, HOI (Acidic character)
(iv) H2O, H2S, H2Se (Boiling point)

(v) ClO 2− , ClO 3− , ClO 4− (Basic character)

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Subjective Test (OYMR_ST05) Code-A One Year Medical-2020

OR
(i) Explain how chlorine is manufactured by Deacon process.
(ii) Write the reactions of Cl2 with NaOH (cold-dilute) and (hot-conc).
(iii) Which type of reaction takes place between Cl2 and NaOH?
37. Carry out the following conversion in not more than two steps.
(a) Toluene to benzaldehyde
(b) Aniline to chlorobenzene
(c) Propan-1-ol to propan-2-ol
OR
Give the following reactions
(a) Cannizzaro reaction
(b) Reimer-Tiemann reaction
(c) Carbylamine reaction

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