Table 1.1.

Observations
Reagent/Procedure
Oxalic acid dihydrate in water
(+) potassium dichromate
heating solution to boiling
(+) potassium oxalate monohydrate
cooling
(+) ethanol
ice bath
filtration
filtrate
residue
washing and drying

table 1.3 Calculations

Parameter Al
Xg, calibration
X dia
xg,chromium
Xm
μ ef
μs
PARA/DIA
 Observations
white crystalline solids
purple coloration, darkening per each drop
dark viscous solution, warmed to thin
dark purple solution
formation ofdark bluish green precipitates
formation of dark bluish green precipitates
formation of dark bluish green precipitates

bluish green liquid mixture

wet dark bluish green precipitates
dark bluish green precipitates

Cr Fe Co
2.200242113
-0.0001587
1.22967623081057E-05
0.0061521174
3.8327999132
3.8729833462
PARAMAGNETIC
TABLE 1.2. Masses Al Cr Fe
Filter paper + watch glass,g 44.8746 52.245
Filter paper + watch glass + sample,g 45.454 52.8662
Parameter Al complex Cr complex Fe complex
mass sample,g 0.5794 0.6212 1.4062
Theo yield,g 0.722594515 0.82837 1.4537
% yield 80.18328238 74.990644277 96.7324757515
Co

Co complex
4.156
10.7003089598
38.84
Table 1. Observations
Reagent/Procedure Observations
KOH + H2O clear liquid sol'n
(+) Aluminum foil evolution of gas
Dissolution of Al foil evolution of gas
Decantation
residue black solid
decantate clear liquid sol'n
(+) Oxalic acid dihydrate clear liquid with white crystals
Heating until boiling clear liquid sol'n
Cooling formation of white crytals
(+) Ethanol formation of white crytals
Filtration
filtrate turbid mixture
residue white crystals
Washing white crystals
Drying white crystals
Metal Complex % yield l R m, grams
K3[Al(C2O4)3]•3H2O
K3[Cr(C2O4)3]•3H2O
K3[Fe(C2O4)3]•3H2O
K3[Co(C2O4)3]•3.5H2O
 Parameter K3[Al(C2O4)3]•3H2O K3[Cr(C2O4)3]•3H2O K3[Fe(C2O4)3]•3H2O
Xg, calibration 2.200242113
X dia -0.0001587 -0.0001587 -0.0001587
xg,chromium -3.4769712320599E-07 1.22967623081057E-05 2.59132992411384E-05
Xm -0.000002068 0.0061520657 0.0128884191
μ ef n/a 3.8327838252 5.5475811912
μs n/a 3.8729833462 5.9160797831
PARA/DIA diamagnetic paramagnetic paramagnetic
K3[Co(C2O4)3]•3.5H2O Metal Complex % yield l, cm
Hg[Co(SCN)4] (-) 2.35
-0.0001652 K3[Al(C2O4)3]•3H2O 80.1834 2.7
-3.04205107397358E-07 K3[Cr(C2O4)3]•3H2O 74.9904 3.5
1.20818271297644E-05 K3[Fe(C2O4)3]•3H2O 96.7355 3.1
0.169851799 K3[Co(C2O4)3]•3.5H2O 38.84 2.9
4.8989794856
paramagnetic
Ro R m, grams MM, g/mol
586 0.2189 (--)
-117 0.1196 462.3793
-110 210 0.2004 487.3938
730 0.2211 491.2427
-118 0.1678 503.3386
Complex Peak Intensity Asignment
Al 3500 weak, sharp O-H
1700-1800 medium, sharp C=O
1400 medium, sharp
1250-1300 medium, sharp C-O
950 medium, sharp C-C
800 medium, sharp C-C
600 medium, sharp M-O
450-500 strong, sharp M-O

Cr 3500 weak, sharp O-H

1700-1750 medium, sharp C=O
1400 medium, sharp
1250 medium, sharp C-O
900 weak, sharp C-C
800 medium, sharp C-C
600 medium, sharp M-O
500 medium, sharp M-O
450 medium, sharp M-O

Fe 3500 weak, sharp

1650-1700 medium, sharp C=O
1400 medium, sharp
1250 medium, sharp C-O
850 weak, sharp C-C
800 medium, sharp C-C
550 medium, sharp M-O
500 medium, sharp M-O

Co 3450 weak, sharp

1600 medium, sharp
1400 medium, sharp
1300 medium, sharp C-O
1250 weak, sharp C-O
900 weak, sharp C-C
800 medium, sharp C-C
550 medium, sharp M-O
450-500 medium, sharp M-O