NAMA: Putu Chandra Mandala

NRP: 03211740000097

TUGAS KUIS REMEDIASI

Dik :
Massa Konsentrasi Pb di
Waktu Volume Konsentrasi Pb awal
Absorban effluent
jam g mL mg/L mg/L
0 100 1000 150 0
2 100 1000 150 20,3
4 100 1000 150 37,78
6 100 1000 150 34,49
8 100 1000 150 30,4
10 100 1000 150 23,04
12 100 1000 150 13,02
14 100 1000 150 12,9
16 100 1000 150 12,3
18 100 1000 150 12,9
20 100 1000 150 12,4

Ditanya :
Buatlah model kinetic terhadap data adsorpsi logam berat timbal (Pb) berikut dengan
menggunakan model kinetic :
- First-order
- Pseudo first-order equation
- Pseudo second-order equation
- Pore diffusion model
- Elovich equation model
Jelaskan model yang paling sesuai untuk data tersebut
NAMA: Putu Chandra Mandala
NRP: 03211740000097

Penyelesaian :
First Order

Waktu Co Ct Ln (Ct/Co)
jam mg/L mg/L mg/L
0 150 0 0
2 150 20,3 -2,000014408
4 150 37,78 -1,378855432
6 150 34,49 -1,469965867
8 150 30,4 -1,596192686
10 150 23,04 -1,873403458
12 150 13,02 -2,444148657
14 150 12,9 -2,453407983
16 150 12,3 -2,501036032
18 150 12,9 -2,453407983
20 150 12,4 -2,492938821

First Order
0
0 5 10 15 20 25
-0.5

y = -0.093x - 0.9485
-1
R² = 0.6577
Ln (Ct/Co)

-1.5

-2

-2.5

-3
Waktu (jam)

Nilai R First Order: 0,7001

NAMA: Putu Chandra Mandala
NRP: 03211740000097

Pseudo first-order equation

Waktu Co Ct qt qe qe-qt log(qe-qt)

jam mg/L mg/L mg/g mg/g mg/g mg/g

0 150 0 1,5 1,5 0 0
2 150 20,3 1,297 1,5 0,203 -0,692503962
4 150 37,78 1,1222 1,5 0,3778 -0,422738046
6 150 34,49 1,1551 1,5 0,3449 -0,462306806
8 150 30,4 1,196 1,5 0,304 -0,517126416
10 150 23,04 1,2696 1,5 0,2304 -0,637517525
12 150 13,02 1,3698 1,5 0,1302 -0,885389016
14 150 12,9 1,371 1,5 0,129 -0,88941029
16 150 12,3 1,377 1,5 0,123 -0,910094889
18 150 12,9 1,371 1,5 0,129 -0,88941029
20 150 12,4 1,376 1,5 0,124 -0,906578315

Pseudo First Order

0
0 5 10 15 20 25
-0.2

-0.4
Log (Qe-Qt)

-0.6 y = -0.0364x - 0.2919

R² = 0.7001

-0.8

-1

-1.2
Waktu (jam)

Nilai R Pseudo First Order: 0,9947

NAMA: Putu Chandra Mandala
NRP: 03211740000097

Pseudo second-order equation

Waktu Co Ct qt t/qt

jam mg/L mg/L mg/g

0 150 0 1,5 0
2 150 20,3 1,297 1,54202
4 150 37,78 1,1222 3,564427
6 150 34,49 1,1551 5,194355
8 150 30,4 1,196 6,688963
10 150 23,04 1,2696 7,876497
12 150 13,02 1,3698 8,760403
14 150 12,9 1,371 10,21152
16 150 12,3 1,377 11,61946
18 150 12,9 1,371 13,1291
20 150 12,4 1,376 14,53488

Pseudo Second Order

16
14
y = 0.7059x + 0.4977
12 R² = 0.9947
10
t/qt

8
6
4
2
0
0 5 10 15 20 25
Waktu (jam)

Nilai R Pseudo Second Order: 0,9947

NAMA: Putu Chandra Mandala
NRP: 03211740000097

Pore diffusion model

Waktu Co Ct t^(0,5) qt

jam mg/L mg/L mg/g

0 150 0 0 1,5
2 150 20,3 1,414214 1,297
4 150 37,78 2 1,1222
6 150 34,49 2,44949 1,1551
8 150 30,4 2,828427 1,196
10 150 23,04 3,162278 1,2696
12 150 13,02 3,464102 1,3698
14 150 12,9 3,741657 1,371
16 150 12,3 4 1,377
18 150 12,9 4,242641 1,371
20 150 12,4 4,472136 1,376

Pore Diffusion Model

1.6
1.4
1.2
1
qt

0.8 y = 0.0027x + 1.3017

0.6 R² = 0.001

0.4
0.2
0
0 1 2 3 4 5
t^0,5

Nilai R Pseudo Pore Diffusion Order: 0,9947

NAMA: Putu Chandra Mandala
NRP: 03211740000097

Elovich model

Waktu Co Ct ln T qt

jam mg/L mg/L mg/g

0 150 0 0 1,5
2 150 20,3 0,693147 1,297
4 150 37,78 1,386294 1,1222
6 150 34,49 1,791759 1,1551
8 150 30,4 2,079442 1,196
10 150 23,04 2,302585 1,2696
12 150 13,02 2,484907 1,3698
14 150 12,9 2,639057 1,371
16 150 12,3 2,772589 1,377
18 150 12,9 2,890372 1,371
20 150 12,4 2,995732 1,376

Elovich Model
1.6
1.4
1.2
1
y = 0.0003x + 1.3089
qt

0.8 R² = 8E-06
0.6
0.4
0.2
0
0 0.5 1 1.5 2 2.5 3 3.5
Ln t

Nilai R Elovich model: 0,000008

NAMA: Putu Chandra Mandala
NRP: 03211740000097

Nilai R masing-masing model kinetic

No. Parameter Kinetik Nilai R

1. First-order 0,6577
2. Pseudo first-order 0,7001
3. Pseudo second-order 0,9947
4. Pore diffusion model 0,001
5. Elovich model 0,000008

Jadi model yang paling sesuai untuk data tersebut adalah Parameter Kinetik Pseudo
second-order dengan nilai R 0,9947, dikarenakan Nilai R Psedudo Second-order
mendekati 1.