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PHYSICS
1. 1.2 kg ice at 0°C is mixed with 1 kg water at 24°C in 3. Two coaxial cylinders of radius r and 3r are made of
a closed calorimeter. The fraction of ice that melts is material of thermal conductivity K1 and K2
(Lf = 80 cal/g) respectively. The equivalent thermal conductivity of
(1) Decreases Q
(1) (2) Q
(2) Increases 2
Q Q
(1) (2) V
° P P
Q Q
(1) (2)
T
(3) (4)
P P
° °
t
(3) 8 R R
(1) (2) R
2
(4) 12 R
Q P
V2
(0°C)
V1
Q2
Q1
T
t
(0, 0) 5 20 30 40 (1) V1 < V2
(Minute)
(2) V1 > V2
(1) 6 cal/g (2) 18 cal/g (3) V1 = V2
(3) 24 cal/g (4) 30 cal/g (4) There is no relation between V1 and V2
31. Walls of a room are made up of double layer, having 37. The mean free path for a gas is equal to (where n
thermal conductivities of inner and outer layer in is number of gas molecules per unit volume, d is
ratio of 1 : 3. The thickness of the layers is the same, diameter of gas molecules).
the temperature inside the room is 20°C and that of
outside the room is –10°C in the steady state. The 1 1
(1) (2)
temperature at the junction of the two layers is 2n 2nd 2
(1) – 0.5°C (2) – 1°C 1 1
(3) 3 (4)
(3) – 2.5°C (4) 2°C 2nd 2d 3/2
38. First law of thermodynamics is based on the 42. A gas (ideal) is allowed to expand according to
principle of conservation of dP dV
. Select correct relation
(1) Mass (2) Momentum P V
(3) Energy (4) Pressure (1) du < 0 (2) du > 0
O V
V
(0, 0)
(1) T1 = T2 (2) T1 > T2
(1) The system is cooled
(3) T1 < T2 (4) None of these (2) The system is heated
40. H2 gas kept in vessel at 27°C is heated so that root (3) The system heated first and then cooled
mean square velocity of its molecules increases by (4) The system cooled first and then heated
41.4%. The final temperature of the gas is
44. The temperature of a body is changed by 20°C, then
(1) 87°C (2) 127°C this temperature change is equal to
(3) 227°C (4) 327°C (1) 293 K (2) 24°F
(3) 20 K (4) 20°R
41. First 1cm thick layer of ice is formed in 10 minutes
on a lake. Time taken to form next 1 cm thick layer 45. 21 J of heat energy is supplied to a diatomic ideal
of ice is gas at constant pressure, then change in internal
energy of the gas is
(1) 40 minutes (2) 30 minutes
(1) 10 J (2) 12 J
(3) 25 minutes (4) 36 minutes (3) 15 J (4) 18 J
CHEMISTRY
46. Arrange the following carbanion in the order of 48. Which of the following is an aromatic carbocation?
stability
O O O
(1) (2)
|| || ||
(3) C > A > B (4) A > C > B 49. Which of the following is antiaromatic carbanion?
::
51. The carbocation which is stabilized by mesomeric
effect is completely delocalised
(1) 4-electrons (2) 8-electrons
(1) PhCH=CHCH (2) CH3–CH–CH3
(3) 6-electrons (4) 2-electrons
CH3 61. The group which is most activating in electrophilic
aromatic substitution is
(3) (4) All of these O
||
52. Which of the following has maximum number of 3°H (1) –NO2 (2) –C–OH
atom? (3) –NH2 (4) –CF3
(1) 2, 2-Dimethylpropane (2) 2, 3-Dimethylbutane 62. Identify the planar molecule.
(3) 2-Methylpentane (4) 3-Methylpentane
53. The number of metamers possible for the molecular H3C H
formula C4H10O is C=C=C
H CH3
(1) 3 (2) 2
(I) (II) (III)
(3) 4 (4) 1
54. The cyclic structural isomers possible for C3H6O is (1) (I) & (II) (2) (I) & (III)
(1) 2 (2) 3 (3) Only (I) (4) (I), (II) & (III)
(3) 4 (4) 1 63. Which of the following is the most reactive towards
55. The compound which will not show geometrical electrophilic reagent?
isomerism is
NO2 CH3
(1) Propene (2) But-1-ene
(1) (2)
(3) (4) All of these
O (3) (4)
||
OCH3 C–H 75. Identify the group which is m-directing?
| |
(1) –COOH (2) –CHO
(3) & (4) All of these
(3) –NO2 (4) All of these
76. The heterocyclic aromatic compound is
68. Identify the Z-form
H Br Cl H
(3) C=C (4) C=C (3) (4) Both (1) & (3)
Cl H F I
69. In the Lassaigne’s test for nitrogen in an organic H
compound, the prussian blue colour is obtained due 77. The compound which is non-planar is
to formation of
COOH
(1) Fe [Fe(CN) ] NO2
4 63
:
(3) 26 and 7 (4) 24 and 6
82. The correct order of stability of alkene is
(3) (4) Both (1) & (2)
CH3 CH3 CH3 H H H (+)
C=C C=C C=C
H3C CH3 H CH3 H H
(I) (II) (III)
88. + || , is an example of
(1) (I) > (II) > (III) (2) (II) > (III) > (I)
(3) (III) > (II) > (I) (4) (II) > (I) > (III) (1) Pericyclic reaction (2) Rearrangement
83. The compound which will not show tautomerism is (3) Electrophilic addition (4) Nucleophilic addition
89. W hich of the following sets contains only
O nucleophile?
|| O
||
:
(2) Leghaemoglobin – Synthesised by host only B. Cannot arrange themselves according to incident
light
(3) Azotobacter – Free living anaerobic microbe
C. Has membrane system for trapping sunlight
(4) Anabaena – Free living nitrifying bacteria
D. Has light independent, non-enzymatic reactions
108. How many electrons and protons are required for
for CO2 assimilation
reduction of one molecule of nitrogen?
(1) Four (2) Three
(1) 6e– & 6H+ (2) 8e– & 8H+
(3) Two (4) One
(3) 12e– & 12H+ (4) 16e– & 16H+
115. Following is the absorption spectrum of
109. Arrange the following events of nodule formation
photosynthesis. Identify X, Y and Z.
according to the correct sequence.
a. Root hair curl and bacteria invade them
b. Rhizobia multiply and colonise surrounding of
roots
c. Formation of nodule
d. Infection thread is produced carrying the bacteria
into the cortex of the root
(1) b d c a (2) a c b d
(3) b a d c (4) a b d c
110. Soyabean root nodules export fixed nitrogen as X Y Z
(1) Ureides (2) Amides (1) Chlorophyll-b Carotenoids Chlorophyll-a
111. First action spectrum of photosynthesis was (3) Chlorophyll-b Phycobillins Carotenes
described by (4) Chlorophyll-a Carotenes Xanthophyll
(1) T.W. Engelmann (2) J.V. Sachs
(3) J. Ingenhousz (4) J. Priestley 116. Select incorrect statement w.r.t. LHC.
112. The experiment performed by Jan Ingenhousz (1) Made up of hundreds of pigment molecules
concludes that (2) Pigment molecules are bound to lipids
(1) Plant restores to air whatever breathing animals (3) Harvest different wavelengths of light
and burning candles remove
(4) Help to make photosynthesis more efficient
(2) Sunlight is essential to the plant process that
somehow purifies the air fouled by burning 117. LHC
candles (1) Enables wider wavelength of incoming radiation
(3) Glucose is produced when plants grow and
(2) Consists of accessory pigments
glucose is usually stored as starch
(3) Has hundreds of pigment molecules
(4) Oxygen evolved by the green plants comes from
H2O, not from carbon dioxide (4) More than one option is correct
118. Statement-I – PS II absorbs 680 nm of light. 124. Which of the following (labelled as A, B, C, D)
shows conformational change for the synthesis of
Statement-II – PS I is located on non-appressed
energy packed molecule during chemiosmosis?
region of grana thylakoid.
Choose the correct statement.
(1) Statement-I is correct, statement-II is incorrect
NADPH
(2) Statement-I and statement-II are correct
(3) Statement-I and statement-II are incorrect
(4) Statement-I is incorrect; statement-II is correct
119.In non-cyclic photophosphorylation the last electron
acceptor is membrane
132. The major limiting factor for photosynthesis is 135. In majority of plants, the light saturation occurs at
(1) Light (2) CO2 (1) 70% of sunlight (2) 10% of sunlight
(3) Temperature (4) H2O (3) 50% of sunlight (4) 25% of sunlight
136. Which of the following animal has capillaries? 142. Pulmonary vein can be best defined as the blood
vessels which
(1) Arthropods (2) Leech
(3) Tunicates (4) Frog (1) Transport blood to lungs
137. Which structure do you think, would prevent the (2) Carry deoxygenated blood
pushing of muscular flaps into atrium during the
ventricular contraction? (3) Carries oxygenated blood to the heart
(1) Mitral valve (2) Columnae carinae (4) Carry blood away from the heart
(3) Musculi pectineti (4) Chordae tendinae 143. The product of stroke volume and heart rate is
138. At the end of joint diastole, right ventricle is (1) The volume of blood pumped by each ventricle
1 per beat
(1) rd filled by blood
3 (2) The volume of blood pumped by both ventricles
(2) Completely filled by blood per minute
2 (3) 70 ml/minute
(3) rd filled by blood
3
(4) The volume of blood pumped by each ventricle
(4) Fully empty per minute
139. All of the following valves are in contact with
144. A red blood cell is located in the artery supplying to
deoxygenated blood only, except
right leg, how many capillary beds must this cell
(1) Bicuspid valve (2) Tricuspid valve pass through before it is returned to the left atria?
(3) Eustachian valve (4) Thebasian valve (1) One
140. In cardiac cycle, the duration between the closure of
(2) Two
semilunar valve and AV valves is
(1) 0.3 seconds (2) 0.4 seconds (3) Three