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[section 1]
1. Water vapor
Water vapor is the invisible, gaseous form
of water. The amount of water vapor in the
A. Atmospheric Composition atmosphere can vary greatly over time and from
The ancient Greeks thought that air was one of the one place to another. At a given place and time, the
four fundamental elements from which all other substances concentration of water vapor can be as much as 4
were made. In fact, air is a combination of gases, such as percent or as little as nearly zero. the concentration
nitrogen and oxygen, and particles, such as dust, water varies with the seasons, with the altitude of a
droplets, and ice crystals. These gases and particles form particular mass of air, and with the properties of
Earth’s atmosphere, which surrounds Earth and extends Earth’s surface beneath the air. Air over deserts, for
from Earth’s surface to outer space. instance, contains much less water vapor than the
air over oceans.
Permanent Atmospheric Gases
2. Carbon dioxide
About 99 percent of the atmosphere is composed Carbon dioxide, another variable gas,
of nitrogen (N2) and oxygen (O2). The remaining 1 percent currently makes up about 0.038 percent of the
consists of argon (Ar), carbon dioxide (CO2), water vapor atmosphere. During the past 150 years,
(H2O), and other trace gases, as shown in Figure 1. The measurements have shown that the concentration
amounts of nitrogen and oxygen in the atmosphere are fairly of atmospheric carbon dioxide has increased from
constant over recent time. However, over Earth’s history, about 0.028 percent to its value. Carbon dioxide is
the composition of the atmosphere has changed greatly. For also cycled between the atmosphere, the oceans,
example, Earth’s early atmosphere probably contained living organisms, and Earth’s rocks.
mostly helium (He), hydrogen (H 2), methane (CH4), and The recent increase in the atmospheric
ammonia (NH 3). Today, oxygen and nitrogen are continually carbon dioxide is due primarily to the burning of
being recycled between the atmosphere, living organisms, fossil fuels, such as oil, coal, and natural gas. These
the oceans, and Earth’s crust. fuels are burned to heat buildings, produce
electricity, and power vehicles. Burning fossil fuels
can also produce other gases, such as sulfur dioxide
Composition of Earth’s Atmosphere and nitrogen oxides, that can cause respiratory
illnesses, as well as other environmental problems.
3. Ozone
Molecules of ozone are formed by the
addition of an oxygen molecule, as shown in Figure
2. Most atmospheric ozone is found in the ozone
layer, 20 km to 50 km above Earth’s surface, as
shown in Figure 3. The maximum concentration
ozone in this layer is 9.8 x 10 12 molecules per cm3 –
is only about 0.0012 percent of the atmosphere.
B. Atmospheric Layers
The atmosphere is classified into five different layers, as
shown in Table 1 and Figure 4. These layers are the
troposphere, stratosphere, mesosphere, thermosphere, and
exosphere. Each layer differs in composition and
Figure 3. The ozone layer blocks harmful
temperature profile.
ultraviolet rays from reaching Earth’s surface.
Ozone concentration is highest at about 20 km 1. Troposphere
above Earth’s surface, in the ozone layer. The layer closest to Earth’s surface, the
troposphere, contains most of the mass of the
The ozone concentration in the ozone layer varies atmosphere. Weather occurs in the troposphere. In
seasonally at higher latitudes, reaching a minimum in the the troposphere, air temperature decreases as
spring. The greatest seasonal changes occur over Antarctica. altitude increases. The altitude at which the
During the past several decades, measured ozone levels over temperature stops decreasing is called the
Antarctica in the spring has dropped significantly. These tropopause. The height of the tropopause varies
decrease is due to the presence of chemicals called from about 16 km above Earth’s surface in the
chlorofluorocarbons (CFCs) that react with ozone and break tropics to about 9 km above it at the poles.
it down in the atmosphere. Temperatures at the tropopause can be as low as
minus 60 oC.
Figure 4. Earth’s atmosphere is made up of five layers. Each layer is unique in composition and temperature.
Conduction
Temperature Inversion
Density of Air In the troposphere, air temperature decreases as
height increases. However, sometimes over a localized
The density of a material is the mass of material in
region in the troposphere, a temperature inversion can
a unit volume, such as 1 kg/m 3. Atoms and molecules
occur. A temperature inversion is an increase in temperature
become farther apart in the atmosphere as altitude
with height in an atmospheric layer. In other words, when a
increases. This means that the density of air decreases with
temperature inversion occurs, warmer air is on top of cooler
increasing altitude. Near sea level, the density of air is about
air. This is called a temperature inversion because the
1.2 kg/m 3. At the average altitude of the tropopause, or
temperature-altitude relationship is inverted, or turned
about 12 km above Earth’s surface, the density of air is about
25 percent of its sea level value. At the stratopause, or about upside down.
48 km above Earth’s surface, air density has decreased to 1. Causes of temperature inversion
only about 0.2 percent of the air density at sea level. One example of a temperature inversion in
the troposphere is the rapid cooling of land on a
cold, clear, winter night when the air is calm. Under
Pressure-Temperature-Density Relationship these conditions, the land does not radiate thermal
energy to the lower layers of the atmosphere. As a
In the atmosphere, the temperature, pressure, and result, the lower layers of air become cooler than
density of air are related to each other. Imagine a sealed the air above them, so that temperature increases
container containing only the air. The pressure exerted by
with height and forms a temperature inversion.
the air inside the container is related to the temperature
inside the container and the air density. How does the
pressure change if the air temperature or the density
2. Effects of temperature inversion
changes?
If the sky is very hazy, there is probably an
1. Air pressure and temperature inversion somewhere in the lower atmosphere. A
The pressure exerted by the air in the temperature inversion can lead to a fog or low-level
container is due to the collision of the gas particles clouds. Fog is a significant factor in lowering
in the air with the sides of the container. When visibility in may coastal cities. In some cities, a
these particles move faster due to an increase in temperature inversion can worsen air pollution
temperature, they exert a greater force when they problems. Because air rises as long as it is warmer
collide with the sides of the container. The air than the air above it, the cool pollution-filled air
pressure inside the container increases. This means becomes trapped under the warm layer. Pollutants
that for air with the same density, warmer air is at are consequently unable to be lifted from Earth’s
a higher pressure than cooler air. surface. Temperature inversions that remain over
an industrial area for a long time usually result in
2. Air pressure and density episodes of smog – a type of air pollution – that can
Imagine that the temperature of the air cause respiratory problems.
does not change, but that more air is pumped into
the container. Now there are more gas particles in
the container, and therefore, the mass of the air in
Unstable air
Clouds can form when moist air rises, expands, and temperature, then water vapor can condense on
cools. Air rises when it is heated and becomes warmer than condensation nuclei and form a cloud. This cloud formation
the surrounding air. This process is known as convective mechanism is common at middle latitudes where severe
lifting. Clouds can also form when air is forced upward or storm systems form along the cold polar front. Convergence
lifted by mechanical processes. Two of these processes are also occurs near the equator where the trade winds meet at
Orographic lifting
High clouds
All forms of water that fall from clouds to the ground are More than 97 percent of Earth's water is in the
precipitation. Rain, snow, sleet, and hail are the four main oceans. At any one time, only a small percentage of water is
types of precipitation. Clouds contain water droplets that are present in the atmosphere. Still, this water is vitally
so small that the upward movement of air in the cloud can important because, as it continually moves between the
keep the droplets from falling. In order for these droplets to atmosphere and Earth's surface, it nourishes living things.
become heavy enough to fall, their size must increase by 50 The constant movement of water between the atmosphere
to 100 times. and Earth's surface is known as the water cycle.