26-12-19 - SR - Icon All - GTM-3 - Key & Sol's NOPASS

Sri Chaitanya IIT Academy 26-12-19_Sr.
Icon All_GTM-3 _Key & Sol's
Sri Chaitanya IIT Academy., India.

AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON Central Office , Madhapur – Hyderabad
Sec: Sr.Icon All GTM-03 Date: 26-12-19
Time: 09.00am to 12.00 Max.Marks:300
Key & Solutions

MATHEMATICS
1 4 2 3 3 2 4 2 5 3
6 1 7 2 8 1 9 3 10 4
11 4 12 3 13 1 14 2 15 2
16 2 17 1 18 3 19 3 20 2
21 0000.33 22 0004.00 23 0012.56 24 0003.00 25 1583.00
PHYSICS
26 2 27 2 28 1 29 3 30 4
31 1 32 3 33 2 34 1 35 1
36 2 37 2 38 1 39 1 40 3
41 3 42 4 43 1 44 2 45 4
46 0008.00 47 0120.00 48 0064.00 49 0000.00 50 0002.05
CHEMISTRY
51 4 52 3 53 1 54 1 55 1
56 1 57 4 58 3 59 2 60 3
61 4 62 1 63 1 64 2 65 2
66 3 67 4 68 1 69 3 70 2
71 0003.00 72 0001.00 73 0007.00 74 0003.00 75 0005.00
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Sri Chaitanya IIT Academy 26-12-19_Sr.Icon All_GTM-3 _Key & Sol's
SOLUTIONS
Mathematics
1. x2 2x a 2
x2 2 x a 2 0
D 0
4 4 a 2 0
1 a 2 0
3 a
x2 2 x a 2 0
4 4 a 2 0
1 a 2 0
a 1
2. Let A1H11 A2 H10 A3H9 A4 H8 A5 H 7 = 9
2
G2G10 G4G8 G6 9
5
Ak .G12 2 k H12 k
k 1
A1H11 A2 H10 A3 H 9 A4 H 8 A4 H 7 A5 H 7 G10G8G6G4G2
2
95 9 3
315
4 3 2
3. Let f x a x 2 b x 2 c x 2 d x 2 1
3 2
f' x 4a x 2 3b x 2 2c x 2 d
2
f '' x 12 a x 2 6b x 2 2c
f ''' x 24a x 2 6b
f '''' x 24a
Since f 2 1
And f ' 2 0
0 0 0 d 0
d 0
and f '' 2 0
0 0 2c 2
c 1
And f "' 2 2
0 6b 12
Sec: Sr.Icon All 2
b 2
And f "" 2 24
24a 24
a 1
2
f" x 12 1 x 1 6 2 x 2 21
2
12 x 1 12 x 2 2
2
Hence,f " 1 12 1 2 12 1 2 2
26
4. Volume of the right circular cylinder
2 h2 h2
V a2 a2 r2
4 4
h3
a 2h
4
Differentiate with respect to ' h '
dv 2 3h 2 2a
a h
dh 4 3
5. Similarly A2 and A3 and compare
6. Let P : I become a teacher
Q¨I will open a school
Negation of p q is ~ p q p ~q
I will became a teacher, then I will not open a school
7. r { a, b | a, b R and a b 3 is an irrational number }, then r is reflexive as,
aRa a a 3 which is an irrational number 3Rl
3 3 1 3 2 3 1 which
is an irrational number but lR 3 1 3 3 1 which is not irrational number
3Rl 2 3 1
r is not symmetric
Also r is not transitive
3Rl and lR2 3 but 3 R2 2
3 2 3 3 0
Hence, r is not an equivalence relation
8. Sum of the coefficient in the expansion
n
x 2y 3z is 1 2 3 n 2n Put x y z 1
i.e. 2 n 128 n 7
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7 7 7
therefore, greatest coefficient in the expansion of 1 x is C3 or C4
7
C3 7 C 4 35
9. Given that x12 300 and x1 60
2
n n
x12 x1
i 1 i 1
n n
2
300 60
n n
n 12
By options the possible value of n is 15
ln a ln b
10.
a b
dy 1 ln x
dx x2
a 2
b 4
ln 2 ln 4
As
2 4
a b 4 2 6
2 2 2
11. Given that I cos sin x dx , J sin cos x dx , k cos x dx
0 0 0
We know that cos sin x cos x sin cos x for x 0,

2
2 2 2
cos sin x dx cos x dx sin cos x dx I K J
0 0 0
1
12. lim cos x a3 sin b6 x x
x 0
1
3 6
lim cos x a sin b x 1 x
ex 0
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1 cos x a 3 sin b 6 x
lim
x 0 x x
e
x
2sin 2 a3 sin b6 x
2
lim
x 0 x x
e
3 6
e0 a b
e512 given
a3b6 512
2 3 3
ab 8
ab 2 8
13. x2 y2 2x 1
2 2
x 1 y2 2
p r
1 c
2
2
c 3; c 1
Reject c 3 and c 1
14. Ans: D
15. Ans: b
Sol:
y
x
0
f x x 2 2
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y
x
0
16. Given that x2 3 sin x 3

6
Given equation can be written as x3 3 3 sin x

6
Hence, x 2 3 3,0,3
x 0, x 3 is only solution
17. RMS AM
2 2 2
z 3 z z 3 z 3 z z 3
3 3
2
3 z 3
4
3
z 13 (equality does not exist)
Also z 3 z z 3 3 z
(Triangular inequality)
z 4
Hence, 13 z 4
number of integral value of z is1
1
2 2
18. Given that f x x x f t dt
0
1
2
f' x x x2 f2 t 2 x f t dt
0
1 1
2 2 1
x x t 0 f ' t dt 2 x f t dt
0 0
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1 1
f x f 2 t dt 2 x f t dt
0 0
1
f' x 2 f t dt ........( i)
0
= constant
f must be linear.
So, let f x ax b
1
a 2 at b dt
0
1
2
&b at b dt
0
a 3, b 3
f x 3 x 1
So, f 4 3 4 1 9
19.
A 0, 0
3x y 10 0
B
x 2y 5
Point C will be image of A in 3x – y –10 0

x 0 y 0 10
2
3 1 10
C x, y 6, 2
Image of A in x 2 y – 5 0 lie on BC
x 0 y 0 5 h x1 k y1 2 ax1 by1 c
2 Im age
1 2 5 a b a2 b2
x, y 2,4
6 3
Slope of BC , mBC
4 2
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3
cos3
4cos3
8cos3
20. 9 8cos40
sec 40 9 cos2 40 8cos3 40
sec 40 9cos2 40 2cos 120 6cos 40
1
9cos 2 40 1 6cos 40
cos 40
1 2
3cos 4 1
cos 40
1
3cos 4
cos40
3 sec40
a b sec 40 given
a 3, b 1
Hence a b 3 1 2
21. Let probability of head P
2
P1 1 P P 1 P 1 P 1 P P .....
5
2 4
1 P P 1 1 P 1 P .....
2 1 a
1 P P In G.Pseries, S
5 2 1 r
1 1 P
2 P P2
5 2P P2
5P 5P 2 4 P 2 P 2
1
P 0 or P
3
1
P 0.33
3
22. Possible positive value of A is multiple of 4 and its maximum value A is 4
There is only one positive value of A
i.e 4
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65
4
dx
23.
0 1 2cos x 1 2sin x
16
4 a xt t
dx
f x dx f x dx
cos x sin x
0 1 2 1 2 a 0
16
dx
0 1 2cos x 1 2sin x
82
dx
0 1 2cos x 1 2sin x
2 nT T
dx
8 ..... 1 f x dx n f x dx
cos x
0 1 2 1 2sin x a 0
2 a a
dx
8 ..... 2 f x dx f a x dx
cos x
0 1 2 1 2 sin x 0 0
(1) + (2)
2 1 2sin x
I 8 dx
cos x sin x
0 1 2 1 2
2 nT t
1
I 4 dx f x dx n f x dx
cos x
0 1 2 0 0
1
I 4 2 dx........ 3
cos x
0 1 2
1
I 8 dx........ 4
cos x
0 1 2
2I 8 1 dx........ 4
0
I 4
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24. x1 1
y1 8 2
z1 9 3
1 2 8 2 9 3 0
1 16 4 9 3 0
1
8 2
4
1 3
2 4
3 1
1
2 2
2
0
2
2
3 9 3
3
2 4 4
3
3
2
3
2
1 3
2
2 2
1 4 3
2
6
3
2
9
25. C4 39 C5 39 C6 9 C7
9
C 4 9 C5 2 9 C5 9 C6 9
C6 9 C7
10
C5 2 10 C6 10
C7
10
C5 10 C6 10 C6 10 C7
11
C6 11 C7
12
C7 x C y given
792
Maximum value of x y 792 791 1583
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PHYSICS
26.
Sol: Given
Coefficient of friction=
From diagram y 2 4 ax
Differentiating on both sides
dy
2y 4a
dx
dy 2a
dx y
dy
For bead to be stationary slope of tangent on the curve tan
dx
2a
y
27. Ans: 2
Sol: Given y1 x, t A sin kx t .... 1
y2 x , t A sin kx .... 2 t
3
From principle of superpostion
y y1 y2
y A sin kx t A sin kx t
3
C D C D
sin C sin D 2sin .cos
2 2
2 A sin kx cos t
6 6
Nodes are given by kx n
6
kx n k
6
2 x
n
6
x n
6 2
1
xn n
6 2
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28. Ans: 1
Sol: We know fundamental frequency
v
fo v 2lf o
2l
v v
Beat frequency f1 f 2
L L
2 L 2 L
2 2
4 L 8 fo L
2 fo L
2 2 L
L 4 L
29. Ans: 3
Sol: Given
Radius of hollow sphere R
Specific gravity=
Now mass of spherical shell
M1 Solid volume of the sphere density of material
M 1 4 R 2t
Where M1 =Mass of the hollow sphere
t Thickness of the hollow sphere
While the mass of water having same volume
M 2 Whole volume of the sphere density of the water
4 3
M2 R w
3
For the floatation of sphere M1 M 2
4 3
4 R 2t R w
3
R 3
t w 1g cm
3
R
Thickness t
3
30. Ans: 4
Sol: Given
Charge q 5µC
kq 2
We know coloumb force F ..... 1
r2
2
k 5 10 6 k 5 Q 5 Q
r 2 2.5 r2
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5 10 6
5 Q 5 Q 10 12
2.5
25 10 12
25 Q 2 10 12
2.5
Q 15 µC
31. Ans: 1
SOL-
T T T T0
T1 T0 1 0 T0 1
2 2
Also, m1c1 T1 T0 m2c2 T0 T2
T T T T
m1c1 1 0 m2c2 1 2
2 2
m1 c2
m2 c1
32. Ans: 3
Sol: Given
v t
k dv k k
Force F m vdv dt
v dt v m
u 0
m 2
v u 2 kt
2
33. Ans: 2
SOL- Given
Object distance u u u 50.1 0.5 cm
Image distance v v v 20.1 0.2 cm
From mirror formula
1 1 1 1 1 1 1
F v u F 50.1 20.1 0.0697
F 14.34cm
F v u
and
F2 v2 u2
2 2
F f
F u v
u v
2 2
14.3 14.3
0.5 0.2
50.1 20.1
0.04 0.10 0.14cm
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Hence, f 14.3 0.1 cm
34. Ans: A
Sol: Given
Constant speed v 1.5m s
dm
5 kg s
dt
dp
From Newton’s law F p mv
dt
dmv dm
F v.
dt dt
dm
F v 1.5 5 7.5 N
dt
Power P F v 7.5 1.5 11.25W
35. Ans: 1
A. A.B A B
A
Y A B . A B
AB AB
B
B. A.B A B
AB AB
A B AB
36. Ans: 2
Sol: Given
Peak voltage of carrier wave Ec 12V
Peak voltage of modulating signal Em ?
Modulation index M a 0.75
Em
We know modulation index M a
Ec
Em M a Em
Em 0.75 12
Em 9V
37. Ans: 2
Sol- Given
Frequency of electro magnetic wave= 25MHz 25 10 6 Hz
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Electric field E 6.3 ˆj V m
E E 6.3
c B 2.1 10 18 T
B C 3 10 8
Also velocity of EMW is along E B
38. Ans: 1
Sol: From mirror formula
1 1 1
F u v
1 1 1
v 6 cm
0.02 v 0.03
1 1 1
f ' 2.5cm
0.02 0.1 f '
1 1 1
v ' 15cm
2.5 v ' 3
Eye piece must be moved away from objective by 15 6 9cm
39. Ans: 1
Sol: Given
Temperature of inside T2 273K
Temperature of outside T1 303K
Q2 T2 273
k
W T1 T2 30
Heat delivered to surrounding
Q1 Q2 W k 1 W 9 1 J 10 J
40. Ans: 3
Sol: The relation between polarization angle and refractive index is given by
tan
41.
Sol: Given
Magnetic moment M 10 Am 2
Cross sectional Area A 2.5 10 4 m 2
M
Intensity of magnetization I V AL
V
M
I
AL
10
I
2.5 10 4 L
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10
L
2.5 10 4 10 6
L 4 10 2 m
Ans: 3
42. Ans: 4
Sol: According to Einstein’s photo electric effect equation
KE max h
k1 h 1 ; k2 h 2
k1 h1 1 h 1k h 2
h o
k2 h 2 k k 1
k 1 2
0
k 1
43. Ans: 1
2
sin
Sol: I Io where is path difference 0 ; for principal maxima
Hence intensity will remain same, increasing the slit width of the slit will make the
central peak more narrow.
44. Ans: 2
Sol: As LED is connected to a battery through a resistance in series
The current flowing, 10mA is the same
The voltage drop across LED= 2V
As the battery has voltage of 6V , the potential difference across R 4V
V iR
4V 4
R A
i 10 10 3
R 400
45. Ans: 4
1
Sol: Separation between the slit=
2
Distance between the slits and screen= 2x
D
Young’s Double slit experiment on interference of light has the formula X
d
Where X is the band width or fringe width, is the wave length of the monochromatic
light, D is the distance between the slits and screen, and d is the distance between the
slits.
D
Maxima n 1
d
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th
Yn Distance of n
n D
Maxima
d
Therefore, D2 2 D1
D2 d1
D1 d 2
2 2
4
Thus, if the distance between the slits is doubled, the fringe width is quadrupled.
46. Ans: 0005.00

2
x 5 z3
Sol: Given relation Q
y t
Q 2 x z y 1 t
3
Q 5 x z y 2 t
2 1
2.5 3 2 0.5 1
5 2
1 6 0.5 0.5
0008.00
47. Ans: 0120.00
Sol:
A B
10 km
Velocity toward east, V A 30iˆ m s
Velocity towards North VB 40 ˆj m s
Distance AB 10km
V BA 40 ˆj 30iˆ
2 2
VB 40 30 50 m s
4
tan V BA
3
AB cos
Required time
VBA
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3
104
3000 5
t 120s
50 25
48. Ans: 0064.00
SOL- We know
t
V Vo e , after 1 second
V1 100 e 80 100 e
4
e
5
After 2 seconds
2 2
4
V2 100 e 100
5
16
100 64
25
49. Ans: 00.00
Sol-Maximum power will be delivered when internal resistance of the battery is minimum.
50. Ans: 0002.05
Sol: 1msd 200 0.005 1 mm
Diameter 2r 4 1 25 0.005 5 0.005 4.1
radius r 2.05mm
CHEMISTRY
51.
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Above three combinations gives tertiary alcohols
52.
3 OH
6 5 4 2 1 OH
1,5-dimethyl hexanole Br Bromonium ion
O O Br
2 1 6 2 5
1
3 4 5
3 4
Major Br
Minor
The reaction is an example of electrophillic additon
53.
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O
OH Br
MgBr
Br2 +P Mg
Cyclohexyl magnesium
bromide
1-bromo cyclohexane HCHO
Cyclohexanone Cyclohexanole
OH
Cyclohexyl methanol
PCC
H
O
Cyclohaxane carbaldehyde
Ph-CH 2Mgx
OH
Ph
Secondary alcohol
A 2 O3
Ph
Alkene
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54.
O
HBr
HO
Br
Tetrahedro furon (THF) 4- Bromo,1-butanol
HBr
Br
Br
1,4 -dibromo butane
55.
OH
OH
X
OH
OH
56.
OH
Ph
OH
+ O
Ph
57. Applying Osmotic pressure
WB
V RT
MB
WB RT RT
C 100 1
V MB MB
While C conc. in g / cc , 4 x m 2
Combination equation 1 & 2
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RT
Slope 1000
MB
RT 0.0821 293 1000
MB 1000 5.17 10 6
Slope 3
4.65 10
58. + 3+
Na > A
59. Number equivalent of hypo = Number equivalent of CaOC 2
M1V1 M 2V2
0.05 2 100 0.1 V2 ( n f of CaOC 2 =2)
V2 1000mL
H
C O
C C C H
C O
60. C 3C-CHO Structure Hydrogen bond H

C 3C-CHO forms intramolecular H-Bond in dihydroxyl form .
61.
Element F C Br I
Electron gain 3.6 3.8 3.5 3.2

enthalpy(ev)
The Slight difference in electron affinity for chlorine is caused by two factor
1. Atomic size
2. The Shielding effect
62. In NO 2 , there is no lone pair, only bond pairs so the molecule is linear leading to a
bond angle of 180 .
In NO2 , the one lone electron exerts a less repulsion than a lone pair of electrons, so two
bonding oxygen atoms are able to spread out more leading to bond angle greater than
the ideal of 120 .
For NO2- the molecule is bent but we have 1 lone pair on nitrogen. Lone pair electron
repulsion is more than the bonding electrons so the bond angle will be less than 120
63. 75% ortho H2 +25% para H2
64. Para-Acetamidophenol (paracetamol) is used as an antipyretic as well as an analgesic.
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65. Smelting involves heating of oxide of the metal with carbon or coke at very high
temperature.
66. Dipole moment of MH3 decreases down the group as the electro negativity of the central
atom M decreases.
67. Molecular weight of H3PO4 98 In the reaction only one H atom is replaced.
Molecular weight 98
Equivalentweight = = =98.
Number of ionsof Hions replaced 1
68. Greater the pK a log K a value weaker the acid. Perchloric acid HC O4 is the
strongest acid
pK a 8 followed by nitric acid HNO3
69. Ptotal P AXA P B 1 XA
PT P B XA P B P A
254 XA119
P B 254 P B P A 119
254 119 PA
P A 135
60
70. Vc 75 cm3mol-1;
0.80
Vc
b 25 cm3mol-1 0.025L mol 1
3
8a
Tc
27 Rb
4 105 8 a
821 27 0.0821 0.025
a 3.375
71. Ecell 0.06 5 4 0.06V
Ecell E + E -
H |H 2 OH |Cd OH 2 |Cd
(or)
2
Cd 2+ OH -
E Cell 0.03log
2
Kw
Ecell 0
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- 2
Cd 2+ OH
Ecell 0.03log
K w2
Ksp 0.39
log 13
2 0.03
Kw
2
Ksp 1013 10 14 10 15
72. According to the Freundlich equation
x
KP1/n
m
x 1
or log log K log P
m n
x
Plot of log versus log P is linear with slope
m
1
Thus, tan n
n
Log K 0.3010 or K= antilog 0.3010 2
At
x 1
KP1/ n 2 0.5 1.0
m
CH3
|
C CH 2 C H CH 2 CH 3
73.
CH3
|
C CH CH CH 2 CH3
|
C (1)
CH2 Cl
|
C CH 2 C H CH 2 CH3 (1)
C (2)
CH 3
C 8 (2)
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CH 3
(1)
74. According to first – order reaction, d N 2O5 / dt k N 2O5 . The half life can be found
2.303 a
as t log
k a x
Where,
a 100 and
a x 100 99.6 0.4 .
In2 0.693
Then half-life period for first-order reaction is t 1 With temperature k
k k
2
increases (according to Arrhenius equation) and since t1/2 is directly proportional to k, so
if k increases then t1/ 2 also increases. If the reaction completes to 99.6% completion then,
2.303 100 2.303 0.693
t99.6 log 2.4 8 8t1/2
k 0.4 k k
75.
o Br OH o
CH3 C NH2 , C NH2 CH C
o , o ,
NH 2
,
O
NH
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26-12-19 - SR - Icon All - GTM-3 - Key & Sol's NOPASS

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Sri Chaitanya IIT Academy 26-12-19_Sr.

Icon All_GTM-3 _Key & Sol's

Sri Chaitanya IIT Academy., India.

Time: 09.00am to 12.00 Max.Marks:300

Key & Solutions

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We know that cos sin x cos x sin cos x for x 0,

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16. Given that x2 3 sin x 3

Given equation can be written as x3 3 3 sin x

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Point C will be image of A in 3x – y –10 0

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46. Ans: 0005.00

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Above three combinations gives tertiary alcohols

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Combination equation 1 & 2

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60. C 3C-CHO Structure Hydrogen bond H

Electron gain 3.6 3.8 3.5 3.2

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