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Printed in Great Britain. ( 1993 Pergamon Press Ltd
G. PALOSO, JR a n d B. MOHANTY
Division of Energy Technology, Asian Institute of Technology, G.P.O. Box 2754, Bangkok, Thailand
669
670 G. PALOS(), JR and B. MOHANTY
perature by the same degree of 20 C results in an even cooling water. The condensed refrigerant is then
higher ~/,.of 24.1% or an increase of 28.6% from the pressurized by a feed pump and enters the evaporator
base case. This is illustrated in Fig. 1. where it vaporizes at constant pressure. This vapour is
An actual cycle, however, is irreversible and does absorbed by the solution with high LiBr concentration
not follow the Carnot cycle process path. In the first coming from the generator producing heat which is
place, the heat transfers from the heat source and to transferred to the working fluid of the ORC. The
the heat sink do not occur isothermally, leading to resulting dilute solution is passed through a re-
temperature gradients in the vaporizer and the con- cuperator before its expansion and subsequent heat-
denser. Moreover, contrary to what occurs in a Car- ing in the generator. Vapour is separated from the
not cycle, there has to be a certain temperature differ- solution and directed to the condenser while the
ence between the two fluids in the exchangers in order residual strong solution heads back to the recuperator
to allow the heat to flow from a high temperature to and finally to the absorber. The organic fluid (R-113)
the lower one, In addition, the turbine and pump are of the ORC is vaporized at high temperature in the
also not ideal, i.e. the vapour expansion in the turbine integrated absorber/vaporizer. This vapour is passed
and the liquid compression in the pump arc not isen- through the turbine and produces the desired work.
tropic. Therefore, detailed analyses of the proposed The exhaust fluid from the turbine is condensed at
combined cycles are necessary to determine their tech- constant pressure and pumped back to the integrated
nical performances and economic viability. component.
2. T H E C O M B I N E D AHT-ORC 3. T H E C O M B I N E D ORC-VAC
The configuration of the proposed combined AHT- The basic components and the working fluids of the
ORC is shown schematically in Fig. 2. The system ORC VAC are similar to those of the AHT ORC.
basically consists of heat exchangers, pumps and the Here the ORC condenser is integrated with the VAC
work-producing device a turbine or a positive dis- ewiporator into a single component. A schematic
placement machine. A salient feature of the system is diagram of the combined cycle is shown in Fig. 3. in
the integration of the ORC vaporizer and the AHT the system, the geothermal brine passes through thc
absorber. The working fluid chosen for the AHT is a ORC vaporizer, evaporating the organic fluid, and
water and lithium bromide (H 20 LiBr) solution while then proceeds to the VAC generator, separating the
trichlorotrifluoroethane (R-113) is selected for the refrigerant from the solution, before being rejected to
ORC. the surrounding or reinjected back to the geothermal
The operation of the combined cycle commences well. The refrigerant vaporized from the heated solu-
with the extraction of heat from the geothermal brine tion in the VAC generator is delivered to the con-
in the generator and evaporator of the AHT. Refer- denser where it is condensed by rejecting its latent
ring to the state points in Fig. 2, the refrigerant (water) heat to the cooling water. It is then expanded before
vaporized from the generator is condensed by reject- it enters the integrated evaporator~ondenser where
ing its sensible (desuperhcat) and latent heat to the it provides a cooling effect. In this integrated com-
ponent, the VAC refrigerant vaporizes as it absorbs
the heat rejected by the ORC working fluid which in
Temperature ('C) consequence condenses and exits the component as
140 140
a saturated liquid. The condensed organic fluid is
r -~'~ee
=-I pumped to the vaporizer where it leaves as saturated
120 . . . . . . . . . . I I . . . . . . . . . 120
I I i vapour and proceeds to the turbine to do motive work.
10ft
!
4. MODELLING AND SIMULATION
80 ; " , ": 80
heo =, i hei
I
; I
evaporator
J vaporizer/ I
r3
t4 absorber
r2
i
t3
Absorption
Organic
Heat recuperator
Transformer ~Rankine
Cycle Cycle
2
rl
/ tI
condenser L J generator condenser
I I ;"
= 4.
I l
4, | | •
geothermal fluid
I I . . . . . . . . . . . . . . . ! I-- "1~
rgi l
T T
I rgo hci i hco
f : , t
f :
co.~;nser ci
"~e.orato;]
r3 r z c2
Vapour
Organic
recuperator
Absorption
'bin, Rankine
Cooling
Cycle
r4 r| c3 Cycle
cA
VAC-evapora~r J absorber
rm ~
J
I
I I
hai = • hao
Fig. 3. Schematic diagram of ORC VAC.
672 G. PALOSO, JR and B. MOHANTY
same time improve simulation accuracy. A uniform for a 1 kW turbine work output, 45.5 kW is supplied
heat exchanger temperature pinch, Tp, of 3 C is taken in the vaporizer, which means that only 2% of the
for all heat exchange components. Appropriate values heat available from the geothermal brine is converted
of the overall heat transfer coefficients, U, are con- to work. Moreover, a sizeable amount of energy is
sidered which take into account the various modes of also lost in the condenser. Such an energy analysis
heat transfer and the types of heat exchanges taking does not present a rational evaluation of the thermo-
place [8 10]. dynamic cycle performance. The exergy analysis of
the ORC (Fig. 5) shows that to produce I kW of
turbine work, the geothermal fluid that is required at
5. C O M P A R I S O N OF P E R F O R M A N C E FOR ORC,
the given temperature has a maximum power genera-
AHT-ORC AND ORC-VAC
tion potential of 3.26 kW, which suggests that the
With the use of the developed models, the per- cycle efficiency is 31%--a more realistic assessment
formances of the ORC, A H T - O R C and ORC VAC of the cycle performance. Aside from that, this method
are analysed and compared. A geothermal heat source stipulates where and how much the losses are and it
at 100C and cooling water at 3 0 C are initially con- takes into account not only the quantity of the energy
sidered for comparing the three cycles. For the A H T - flow but also its quality [14]. Similar comparisons on
ORC, the absorption heat pumping process upgrades the A H T - O R C and ORC-VAC performances can be
the Rankine heat source temperature by 20~C, while drawn from Figs 6-9.
for the ORC-VAC the absorption refrigeration pro- As mentioned earlier, the actual cycles differ from
cess lowers the Rankine cycle heat sink temperature the Carnot cycle since the latter does not consider the
by a similar degree of 20C. losses incurred in the operation of the actual system.
The performances of the three cycles, as detailed by The system losses which are caused by the heat trans-
the thermodynamic properties and mass flow rates of fers between the interacting media, machine ineffici-
the working fluids at various state points, are shown ences and heat rejections are shown in Figs 5, 7 and
in Tables 1-3. The enthalpy and entropy values are 9 for the three different cycles. In the absorption side
determined from equations available in the literature of the combined cycles, exergy losses caused by heat
[5, 11-13]. The exergy values are calculated from a transfers in the different components are lumped toge-
reference temperature of 3OC. All calculations arc ther in order to simplify the presentation (see Figs 7
made on the basis of a 1 kW turbine work output. and 9). These losses, however, are elaborated in Tables
To give a more vivid presentation of the per- 4--6. Referring to Tables 5 and 6, it is noticed that in
formance of the cycles, Sankey flow diagrams of the absorber of both the ORC-VAC and AHT ORC,
energy and exergy flows are illustrated in Figs ~ 9 . the exergy balance results in an exergy gain (indicated
The diagrams show the energy and exergy content of by the negative sign) rather than a loss. This is attri-
the fluids (in kW) at the different state points for a buted to the exothermic reaction in the absorption
given work output of I kW. The values are determined process. The mixing of H 2 0 vapour and the LiBr-rich
by multiplying the mass flow rate and the specific solution produces a large amount of chemical exergy
enthalpy or exergy of the working fluid at those state which offsets the exergy loss due to the heat transfer
points. The energy and exergy flow diagrams are between the reacting fluids. On the other hand, a large
shown here to stress the importance of the exergy amount of energy is required in the generator for the
method in analysing energy systems. For example, the separation of the same H 20 vapour from the solution.
ORC energy analysis shown in Fig. 4 indicates that This endothermic process consequently incurs a con-
Cycle T // s Ex m
point (C) (kJ/kg) (kJ/kg' C) (kJ/kg) (kg/s)
Cycle T h s Ex m
point CC) (kJ/kg) (kJ/kg. C) (kJ/kg) (kg/s)
siderable a m o u n t o f exergy loss in addition to the maximum a m o u n t o f energy from the geothermal heat
loss due to heat transfer. The large exergy loss in the source since the geothermal fluid leaves the system at
generator, as shown in Tables 5 and 6, is therefore a the lowest temperature.
s u m m a t i o n o f the exergy loss due to the separation For a wider range o f comparison, the geothermal
process and heat transfer. fluid temperature is varied from 80 to 130 C while
It is seen from the Sankey flow diagrams that the maintaining a 20 C increase in the heat source tem-
O R C V A C requires the least a m o u n t o f exergy from perature for the A H T - O R C and a similar 2 0 C
the heat source to produce 1 kW o f work output. decrease in the heat sink temperature for the O R C
Referring to Tables I-3, the O R C - V A C extracts the VAC. Figure 10 shows that the O R C - V A C produces
Cycle T h s Ex m
point (C) (kJ/kg) (kJ/kg" C) (kJ/kg) (kg/s)
29.073
45.506
vaporizer
~
6.520 22.952
turbine
feed pump All values in kW
0.012
I1~ 1.0
109.778
124.!
3.260 0.712
0.876
vaporizer
).016 1.688
All values in kW
0.004
~ii heat rejection
turbine
feed pump [] heat transfer loss/
machine inefficiency
0.012 I1~ 1.0
[] work output
condenser 0.323
0.008 0.365
" 0.260
Fig. 5. ORC exergy flow diagram.
Cascading vapour absorption cycle 675
66.151 49.614
absorption
heat
d
0.028 ,,m
All values in kW 1.0
2.774 9.871
condenser
36.676
43.773
the largest work output per kg of geothermal fluid at Another important aspect which deserves attention
temperatures > 9 0 C . It is also seen that the A H T is the mass flow rate of the Rankine fluid. This would
ORC has the least work output. This is mainly due to be a factor in determining the sizes of components.
the fitct thai the A H T - O R C can extract a limited Figure 13 shows the mass flow rates of the Rankine
amount of energy from the geothermal fluid because fluid per MW of work output. The figure indicates
of the temperature pinch constraints in the generator that the ORC VAC requires the least Rankine fluid
and absorber. Hence in the AHT-ORC, the geo- flow rate--around 40-70% less than that of the ORC.
thermal fluid is rejected at a relatively high tempera- Therefore, the power cycle components, notably the
ture. The overall geothermal utilization efficiency in pump and heat exchangers, of the ORC-VAC would
such a situation can be greatly improved if this rejected be smaller than those of the ORC and AHT ORC.
fluid can find some other thermal applications like However, this may not be true for the turbine. The
drying and water heating. size of turbine is determined not only by the mass flow
The ORC VAC also produces the largest work out- rate but also by the specific volume of the expanding
put per kg of Rankine fluid, closely followed by the fluid. Figure 14 presents a schematic illustration of
AHT ORC, but the ORC generates a considerably the possible sizes of turbines that would be necessary
smallcr work output (see Fig. 11). This is attributed for the three cycles. In the figure, the turbine's inlet
to the large difference between the inlet and outlet and outlet volumetric flow rates, which are calculated
temperatures in the turbine of the combined cycles as by multiplying the specific volume of the fluid by the
compared with that of the ORC. These temperature mass flow rate, are plotted against its corresponding
differences directly affect the enthalpy changes and specific volume. These values are computed for a geo-
consequently the work output. Figure 12 shows the thermal fluid temperature of 100 C. The absolute
variation of the vaporizing temperature, Tr3 , with the values of the volumetric flow rates are divided into
change in the geothermal fluid temperature. It is seen two, one of which is plotted in the negative Y-scale.
that the AHT~ORC has the highest Tr3, but since the This is done to demonstrate the increase in the fluid
ORC VAC has a lower condensing temperature, it volume as it traverses the turbine and expands. It is
compensates to produce greater work output. seen here that the turbine of the ORC-VAC would be
676 G. PALOSO, JR and B. MOHANTY
1.536
0.023
All v a l u e s in kW
0.150
0.010 ~g heat rejection
turbine
feed pump heat transfer loss/
machine inefficiency
0.028 10
[] work output
j _.... ~ 0.298
condenser
0.005 0.239
-- ¢ .......... ~. . . . . . . . . I ,-'-~:~. . . . . :---
t
0.142
0.092
Fig. 7. AHT ORC exergy flow diagram.
42.704
vaporizer
34.874
1.770 9.602
92.319
turbine
1.0
feed pump
8.602
0.012
absorption
All values in kW. chiller
1.758 107.706
26.331
3.061 0.356
1.758
vaporizer
0.023 0.970
0.294
0.726 0.348
Heat
transfer Machine Heat Total
loss inefficiency rejection loss
Component (kW) (kW) (kW) (kW)
Heat
transfer Machine Heat Total
loss inefficiency rejection loss
Component (kW) (kW) (kW) (kW)
Heat
transfer Machine Heat Total
loss inefficiency rejection loss
Component (kW) (kW) (kW) (kW)
25 160
/
140
~2o L~ 120
/ J
~100 / / o,~Cv ~ c ~ ~ ~ ~
~80 oRC
~=10 °v'c =~ 60
m,
40
20
0 0 ~ i I q q
80 9; 76o ,io 1~o 1;0 80 90 100 110 12(1 130
Geothermal Huid Temperature (*C) Geothermal Fluid Temperature(*C)
Fig, 10. Comparison of net work output per kg of geothermal Fig. 12. Variation of vaporizing temperature with the geo-
fluid. thermal fluid temperature.
35 160
140
~3o
o ~ - ~ ~--~120
25
20
'~100
,,e
8o
~oR e
/
ORC
"5 60
ORC~VAC
o i 4°
0
80 9'0 100 1'10 120 1;0 80 90 100 110 120 130
GeothermalFluid Temperature('C) Geothermal Fluid Temperature ('C)
Fig. 11. Work output per kg of Rankine fluid varying with Fig. 13. Mass flow rate of Rankine fluid per MW of power
geothermal fluid temperature. output.
Cascading vapour absorption cycle 679
5
OR__~_C
"~ 2- Illl
iiii
01 Illi
I i i i /
fill ~IIIIIlIHIIIIlllIl~IIIHllll~HIIll~HIIIll|H|IIII~IIl~IIIIIl~
80 90 100 110 I20 130 ~0 .... i i i ~ i
Geothermal Fluid Temperature ('C) 80 90 100 110 120 130
Geothermal Fluid Temperature ('C)
Fig. 15. Change in pressure ratio with the geothermal fluid
temperature. Fig. 17. Heat exchanger area of Rankine cycle components.
680 G. PALOSO, JR and B. MOHANTY
p o n e n t s (i.e. vaporizer a n d condenser) reveals that between the Asian Institute of Technology and the Electricity
those of the c o m b i n e d cycles are significantly smaller Generating Authority of Thailand.
than the O R C : 5 6 - 6 3 % smaller in the case of O R C
VAC, while in the case of the A H T - O R C it is smaller
NOMENCLATURE
in the order of 7 - 2 6 % (Fig. 17).
A = heat exchanger area, m 2
cl ...c8 = state points in the VAC (see Fig. 3)
E x = Exergy, kJ/kg
6. CONCLUSIONS h = specific enthalpy, kJ/kg
hat = VAC absorber inlet
F r o m the various c o m p a r a t i v e analyses presented,
hao = VAC absorber outlet
the a d v a n t a g e s of employing the c o m b i n e d cycles are hci = AHT and VAC condenser inlet
d e m o n s t r a t e d . Based on a t h e r m o d y n a m i c view point, hco = AHT and VAC condenser outlet
the O R C - V A C provides the best utilization efficiency. hei = AHT evaporator inlet
F r o m an available geothermal heat source, it can gen- heo = AHT evaporator outlet
hgi = AHT and VAC generator inlet
erate the m a x i m u m work output, thereby exploiting hgo = AHT and VAC generator outlet
the heat source to its full potential. Aside from that, n l = mass flow rate, kg/s
this cycle also requires the least mass flow rate of the Q = heat flow in a heat exchanger, kW
R a n k i n e fluid which results in smaller heat exchange r l . . . r4 = state points in the ORC (see Figs 2 and 3)
rci = ORC condenser inlet
c o m p o n e n t s . However, due to the addition o f more
r c o = ORC condenser outlet
heat exchangers in the a b s o r p t i o n cycle, it requires a rgi = ORC vaporizer inlet
slightly larger total heat exchanger area per unit of rgo = ORC vaporizer outlet
power output. Its low c o n d e n s i n g t e m p e r a t u r e would s = specific entropy, kJ/kg" C
also necessitate the use o f a relatively large turbine. tl ... t8 = state points in the AHT (see Fig. 2)
rp = pinch point temperature difference, C
These m a y result in a higher initial investment. Never- = ORC vaporizing temperature, 'C
theless, the economic incentive o f its greater power Tsink = heat sink temperature, 'C
o u t p u t may, in the long run, overcome the higher T,,,orce - heat source temperature, ;C
initial costs. These aspects merit a detailed e c o n o m i c U = overall heat transfer coefficient, kW. m -'/'C
x,,b~ = concentration of LiBr-H20 solution leaving
analysis which is b e y o n d the scope o f this work. the absorber
On the other h a n d , the A H T - O R C offers the Xg~n= concentration of LiB~H20 solution leaving
a d v a n t a g e of using a c o m p a c t a n d smaller turbine. the generator
However, its heat exchange area requirement is even AT = logarithmic mean temperature difference, C
q, - Carnot cycle efficiency.
larger t h a n t h a t for the O R C - V A C . Also, this option
would require more geothermal fluid to generate a
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