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I. Constandache, R.R. Choudhury & I. Rhee. (2010) “Towards Molasses as Retarding Admixture
mobile phone localization without war-driving,” in IEEE for Concrete in Road Construction
INFOCOM, San Diego, CA, USA, March 2010. Leigh Dee S. Galvez, Joselle A. Gorro,
Honiedel V. Taotao and Jilljun D. Trinidad
Luyang Li; Yun-Hui Liu; Kai Wang. (2013). “An adaptive algorithm University of the Immaculate Conception, Davao City, Philippines
for localizing mobile robots using omnidirectional vision
system and odometry sensors,” Robotics and Biomimetics
(ROBIO), 2013 IEEE International Conference on, vol., no., ABSTRACT
pp.1131,1137, 12-14 Dec.
Industrial pollution continued to be a major factor causing the
Mizell, D. (2005). Using gravity to estimate accelerometer degradation of the environment around us. It affects the water we use,
orientation. Wearable Computers, 2003. Proceedings. Seventh the air we breathe and the soil we live on. Also, it is reported that Shree
IEEE International Symposium on, vol., no., pages 252, 253, Renuka Sugars LTD in India which is one of the largest sugar producers
18-21 in the world discharged fluids into the Belgaum fields. The farmers
claimed that it damaged their crops. They also claimed that the ground
Pierleoni, P., Belli, A., Palma, L., Pellegrini, M., Pernini, L. & water about two kilometers around the sugar factory had also been
Valenti, S. “A High Reliability Wearable Device for Elderly Fall contaminated. Molasses on the other hand is a viscous by-product of
Detection,” Sensors Journal, IEEE, vol. PP, no.99, pp.1,1 sugar industry, which used sugarcane in the production.

Yamaguchi, S., Tanaka, T. (2006). GPS Standard Positioning using The growing problem in pollution due to those waste prompted the
Kalman filter. SICE-ICASE, International Joint Conference. researchers to look for the possibility that the so called waste product
Volume number. pages 1351, 1354, 18-21 Oct. 2006 can be used as a retarding admixture for concrete. This study sought
to answer the following questions; what are the flexural strength of
concrete with molasses and stuccotard 80 on the fourteenth day and
thirty-fifth day? What are the initial and final setting time of the cement
paste with molasses and stuccotard 80?

The researchers investigated the usage molasses as a retarding


admixture for concrete by comparing it to the conventional retarder
specifically stuccotard 80. The same ratio of the retarders was used
which is 300ml of retarder is to 100kg of cement, concrete mixture used
in this study and both followed a ratio of 1:2:4 for cement, sand, and
gravel respectively. Five samples each were produced and were cured
for fourteen days and thirty-five days.

Based on the results of the study, it can be concluded molasses can be

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a retarding admixture; which could delay the initial and final setting mixture. Since it is costly and made of chemicals, the researchers would
time of concrete and at the same time it could increased the flexural find other product which can be possibly used as a retarder that is
strength of concrete. natural, cheap and widely available.

KEYWORDS: Molasses, retarding admixture, road construction One possible natural product is the molasses. Molasses is a by-
product of sugar industry, which uses sugarcane in the production. Like
lignosulphonate, which is a by-product of paper industry, molasses also
INTRODUCTION shows plasticizing properties in concrete. Due to the existence of sugar
in molasses, it exhibits retarding effect in fresh concrete (Yildirim &
Background of the Study Altun, 2012).

Concrete has been the most commonly used material for This study aimed to test the effect of molasses as retarding
construction particularly in making architectural structures, admixture in concrete as to be applied on road construction. The
foundations, dams, and road constructions. It has been used effect was tested and studied particularly in the concrete’s flexural
for over a century and has been an important part to the modern strength, initial, and final setting time. Flexural strength is defined
development. Decades after the concrete was invented, innovative as material’s ability to resist deformation under load. Initial Setting
studies in additive mixtures for the performance enhancement of Time is the time when the paste starts losing its plasticity. It can also
concrete began to advance for later usage, which are now called be defined as “time taken by paste to stiffen to such an extent that
admixtures. According to Juan Rodriguez from his article Seven Must- the Vicat’s needle is not permitted to move down through the paste
Use Concrete Admixtures (Additives), concrete quality, acceleration, through 25mm”. Final Setting Time can be defined as the time after
manageability and retardations of setting time are some properties which the paste becomes so hard that Vicat’s 5mm needle doesn’t sinks
that can be improved by adding admixtures. Admixtures are classified visibly and leave no impression. The success of this study provides
as air entrainments, plasticizers, corrosion, bonding agents, pumping, more economical retarding admixture for concrete.
and retarder.
The researchers believed that the positive result of this study would
Retarder, the second most commonly used admixture, delays be beneficial to the sugar industry and road construction industry. The
the setting rate of the concrete resulting in reduced moisture content positive result of this study would make the sugar producers realized
and reduced shrinkage possibility. The use of retarder is mostly the possibility of using the by-product of sugar as a retarder in concrete
advisable whenever the batching plant of concrete cement is far from mixture. With this they could optimize the use of their byproduct and
the construction site where it is needed. It reduces the effect of high they could introduce their byproduct in the markets which makes them
temperature that produces the faster initial setting time of concrete, increase their economy. In addition, the positive outcome of this study
which is very helpful in the condition of the concrete while placing it in would make the contractors realized that using molasses as a retarding
road construction (Khan and Ullah, 2004). admixture for concrete is possible. With this the road construction
industry would be able to help utilize the byproduct produced by the
Stuccotard80 is a concrete admixture product of Borcheme sugar industries thus helping the environment.
Industrial Sales and it is known to be used as a retarder for concrete

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Research Objectives molasses. The MBAs at 0.4% dosage reduced the water 5-7%. The same
retardation effect is expected from molasses due to its sucrose content.
The study intended to enrich and upgrade the retarding of concrete. Molasses-based admixtures are delaying final setting times up to 16:30h
Specifically, the study sought to answer the following queries: while control paste has only 5h (Yildirim & Altun, 2012).

1. What are the flexural strength of the concrete with molasses Girdhar 2005, an Associate Professor of K.S.R.M. College of
and the concrete with stuccotard80 on: Engineering, Kadapa, A.P, India made a research paper on Sugar and
1.1 the 14th day Jaggery as admixture. He concluded that sugar and jaggery having
1.2 the 35th day binding properties and used as plasticizer to reduce the water content
2. What is the initial and final setting time of the following: and increase the workability and compressive strength of the concrete.
2.1 Cement paste with molasses The result of workability and compressive strength are discussed in
2.2 Cement paste with stuccotard80 this review.
3. Is there a significant difference between the flexural strength
of the concrete with Stuccotard 80 and concrete with molasses, Workability of Concrete with Sugar and Jaggery Concrete has
cured for been prepared with addition of two different admixtures (Sugar and
3.1 Fourteen days Jaggery) with three different percentages as 0 %, 0.05% and 0.1%.
3.2 Thirty-five days All test results were compared with conventional concrete and results
4. Is there a significant difference between the cement paste with were tabulated in table 1. Based on the experimental results, as the
Stuccotard 80 and with molasses in their: percentage of admixtures increased, consequently both slump and
4.1 Initial Setting Time compaction factor also increased. Addition of Sugar and Jaggery to the
4.2 Final Setting Time concrete greatly influenced the setting property and clear collapse of
slump witnessed during the experimentation. Setting of cube specimens
after 24 hours was difficult. During the de moulding after 24 hours, cube
Review of Related Literature specimens were exhibited cracks. So, de moulding of specimens carried
out after 48 hours for 0.05% of admixture and 72 hours for 0.1%.The
Molasses has been used in many industries as raw material, like basic reason for extending the setting of time is adsorption of sugar and
animal food industry, in the production of alcohol, ferment and glycerin. jaggery acted as thin layer over the cement particles and it slows down
Molasses consist of 50% sucrose, 30% of other sugars (ash and nitrous the hydration process. Formation of calcium ions would increase the
materials) and 20% water approximately. About 4-8% of beet remains solubility and discouraging the formation of calcium hydroxide. By this
molasses after process. The composition of molasses differs depending reason setting property of concrete has been improved.
on the source it has been obtained, such as from reed or beet. Pigments
of molasses are surfactants and electronegative colloids that contain Khan and Ullah, 2002 made a research paper entitled Effect of
unsaturated groups, hydroxyl groups, and carboxyl groups. Pigments a Retarding Admixture on the Setting Time of Cement Pastes in Hot
of molasses contain 63.1-81.3% products of alkaline hydrolysis of Weather. “Retarding admixtures are mainly based on materials having
inverted sugar, 4.0-18.7% melanoidins, and 9.5-17.8% caramels. These lignosulfonic acids and their salts, hydroxy-carboxylic acids and their salts,
components have an important effect on the plasticizing property of sugar and their derivatives and inorganic salts such as borates, phosphates,

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zinc and lead salts. The basic reason for extending the setting of time is incorporated into cement paste forms some kind of complexes with
adsorption of molasses acted as thin layer over the cement particles and it calcium ions released by the cement grains during the first few minutes.
slows down the hydration process. Formation of calcium ions will increase Formation of the complexes increase the solubility of cement, i.e.,
the solubility and discouraging the formation of calcium hydroxide. By this increased concentration of Ca2+, OH, Si, Al and Fe in the aqueous
reason setting property of concrete has been improved. phase of the cement pastes will occur when hydrated in the presence
of the retarding admixture. Thus the calcium ions and hydroxyl ions
According to the first mechanism, a retarding admixture is will accumulate in solution and will be unable to precipitate to form
adsorbed on the surface of cement particles. This layer of retarding calcium hydroxide. For example, when ordinary Portland cement is
admixture around the cement particles acts as a diffusion barrier. Due hydrated in sucrose solution, lime is solubilised and a sucrose calcium
to this diffusion barrier, it becomes difficult for the water molecules complex (R - -O –Ca+ - -OH) is formed in which Ca+ - -OH group
to reach the surface of the unhydrated cement grains and hence the is attached to the five membered ring (R) of the sucrose molecule.
hydration slows down, and the dormant period (period of relatively Such sucrose–calcium complex will be able to become absorbed
inactivity) is lengthened. Due to the slow hydration, no considerable on the growing calcium hydroxide nucleus. The adsorption of the
amount of the hydration products giving rigidity to the cement paste complex on the calcium hydroxide nucleus will inhibit its growth as
will be formed and thus the paste remains plastic for a longer time. the calcium and hydroxyl ions will not be able to precipitate. In this
Later, when the admixture is removed from solution by reaction with way, hydration is retarded.
C3A from cement or by some other way it is removed and incorporated
into the hydrated material, further hydration is eliminated. The fourth mechanism is similar to the first but here some kind
of insoluble derivatives of retarder are formed by reaction with the
On first contact of water with cement grains (C3S and C2S) highly alkaline solution as pH of the solution rises to over 12 within
calcium ions and hydroxyl ions are rapidly released from the surface few minutes after first contact of water with cement. For example,
of the cement grains. When concentration of these ions reaches inorganic salt admixtures (borates, phosphates, zinc and lead salts etc.)
a critical value (at which the solution becomes saturated), the give insoluble hydroxides in alkaline solution. The cement hydration
hydration products calcium hydroxide and calcium silicate hydrate is suppressed through the precipitation of protective coatings of these
start to crystallize from the solution and then hydration proceeds insoluble derivatives around the cement grains.”
rapidly. According to the second mechanism, a retarding admixture
incorporated into cement paste is adsorbed on the calcium hydroxide According to ASTM Designation: C 191-04a, these test methods
nuclei and prevents its growth until some level of super saturation determine the time of setting of hydraulic cement by means of the
is reached during the induction period of hydration. Thus, retarder Vicat needle. Two test methods are given; Method A is the Reference
lengthens the induction period by causing an increase in the level of Test Method using the manually operated standard Vicat apparatus,
calcium hydroxide super saturation before crystallization begins. This while Method B permits the use of an automatic Vicat machine that
is analogous to the poisoning of crystal growth of calcium hydroxide has, in accordance with the qualification requirements of this method,
by the retarding admixture as both calcium and hydroxyl ions are demonstrated acceptable performance. Another ASTM Designation: C
present in the solution but unable to precipitate as a result of poisoning 78-02 covers the determination of the flexural strength of concrete by
of the calcium hydroxide nuclei. the use of a simple beam with third-point loading.
According to the third mechanism, a retarding admixture

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Conceptual Framework Research Locale

This study was conducted at the University of Immaculate


Independent Variable Dependent Variable Conception Bonifacio Campus where the Civil Engineering laboratory
is located. University of Immaculate Conception is a Roman Catholic
• Initial Setting Time University and has three campuses in Davao City: the main campus
• Concrete with • Final Setting Time located at Fr. Selga St., Bankerohan, and the annex campus located at
Stuccotard80 • Flexural Strength on Bonifacio St., and the Elementary and High School campus at Bajada,
• Concrete with the 14th and on the Davao City.
Molasses 35th day

Figure 1. Framework of the study Data Collection

The researchers asked permission from the Program Dean of the


Figure 1 shows the conceptual framework of the study, it illustrates Engineering and Architecture Program, the Directress of the laboratories,
the independent and dependent variable approach. The concrete and the CE laboratory in-charge to conduct the study and to allow
with conventional retarder and concrete with molasses served as the the researchers to use the equipment and apparatus inside the Civil
independent variables and the concrete’s setting time both initial and Engineering Laboratory. All the materials and equipment were prepared
final as well as flexural strength on the fourteen and thirty-fifth day as for the experiment such as Portland cement, molasses, conventional
the dependent variables. retarder, water, coarse aggregates, fine aggregates, shovels, Vicat
Apparatus, slump cone and six by six by twenty-four inches rectangular
molds. The molds were coated with oil for the concrete be easy to remove.
METHOD
The equipment and apparatus were cleaned as it should be to
Research Design avoid unnecessary substances in the mixture. The required amount of
cement, fine aggregates, and coarse aggregates were weighed and the
An experimental method was used for this study to determine the amount of molasses and conventional retarders were measured based
result of adding molasses on concrete mixture as retarding admixture. on the dosage of the conventional retarder, 300ml per 100kg of cement.
It is define as a systematic and scientific approach to research in which
the researcher manipulates one or more variables, and controls and There were two types of concrete mixture used in this study and
measures any change in other variables (Blakstad, 2008). In this both followed a ratio of 1:2:4 for cement, sand, and gravel respectively
study, Stuccotard80 is the control material while the molasses is which was Class A type mixture commonly used for road construction.
the experimental material and a comparison will be made if there is First, the concrete mixture with Stuccotard80 and the other one is with
significant difference between the concrete with Stuccotard 80 and the molasses. All the materials were prepared for mixing and were mixed
concrete with molasses as a retarder. manually. Afterwards a slump cone was prepared and filled with the
mixed concrete by three layers; each layer was rod with twenty-five

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strokes. The strokes were uniformly distributed over the cross-section the scale, or take an initial reading. Release the rod quickly by releasing
of each layer. After the top layer has been rod, the surface was stroke the set screw, E, and allow the needle to settle for 30 seconds; then take
by means of rolling motion of the tampering rod. the reading to determine the penetration. At the option of the tester, if
the paste is obviously quite soft on the early readings, retard the fall of
The mold was removed immediately and was inverted; a meter the rod to avoid bending the 1-mm needle, but when actual penetration
stick was placed that extends over the slumped concrete. The distance measurements to determine the time of setting are made, release the
was immediately measured from the bottom of the meter stick to the rod only by the set screw. Make each penetration test at least 5mm
center of the surface of the sample. away from any previous penetration and at least 10mm away from
the inner side of the mold. Record the results of all penetration tests
The concrete mixture was placed in a rectangular mould six by and, by interpolation, determine the time when a penetration of 25mm
six by twenty-four inches in dimension using a shovel. The mould was is obtained. The elapsed time between the initial contact of cement
filled in three equal layers and each layer was rod twenty-five times and water and the penetration of 25mm is the Vicat time of setting or
uniformly. After every layer has been rod, the top layer was smoothened Vicat initial time of setting. Determine the Vicat final time of setting
by a triangular pallet. The number of samples used in this study were end point to be the first penetration measure that does not mark the
five per independent variable to give reliable results. After twenty-four specimen surface with a complete circular impression. Verify final set
hours the moulds were removed and the concrete samples were cured by performing two additional penetration measurements on different
for fourteen and thirty-five days. areas of the specimen surface. Obtain verification measurements within
90’s of the first “final set” measurement. The elapsed time between the
On the fourteenth and thirty-fifth days the concrete samples initial contact of cement and water and the end point determination
were tested based on its flexural strength at Qualitest Solutions and above is the Vicat final time of setting.
Technologies Inc. (QSTI), at Diversion Road, Ma-a, Davao City.

In the course, to determine the setting time, cement paste mixture Data Analysis
that contains molasses and another samples of cement paste mixture
with Stuccotard 80 with the same dosage, 300ml per 100kg of cement The gathered data were interpreted by the following statistical
were mixed, placed, and smoothened in the mould of the Vicat method. First is Mean, this was used to find out the average flexural
apparatus using a triangular pallet. ASTM C191-04a standard was used strength and average setting time of the concrete samples with
in this experimentation. Stuccotard 80 and concrete samples with molasses as retarders.
Second, Paired T-test was suitable for this study because there were
Allow the time of setting specimen to remain in the moist cabinet only two variables that were compared and analyzed. It was used
for 30 minutes after molding without being disturbed. Determine the to measure if there was a significant difference that exists in the
penetration of the 1-mm needle at this time and every 15 minutes flexural strength of concrete samples and setting time of cement
thereafter (every 10 minutes for Type III cements) until a penetration of pastes between the conventional retarder and molasses, these were
25mm or less is obtained. Perform the penetration test by lowering the performed using statistical software called IBM SPSS Statistical Data
needle, D, of the rod B until it rests on the surface of the cement paste. Editor; the software analyzes the p-value for each comparison. All the
Tighten the set screw, E, and set the indicator, F, at the upper end of interpretations were based at ρ = 0.05 level of significance.

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Ethical Consideration Table 2. Results of the flexural strength of concrete samples with
stuccotard80 and with molasses after 35 days of curing
The study provided no sensitive ethical issues and the researchers
Flexural Strength (psi)
did strictly follow the guidelines to assume scientific soundness. The
researchers also did not use animals, biologics and human participants Stuccotard 80 Molasses

during the experimentation or in any part of the methodology. This Sample 1 254.78 357.82
study was submitted to the UIC Research Ethics Committee (UIC REC) Sample 2 222.94 284.76
for the review of the measures that the researchers should follow. Sample 3 215.44 314.73
Sample 4 337.21 340.96
Sample 5 254.78 325.97
RESULTS Mean 257.03 324.85

The results and interpretations of the gathered data from the


study are presented in this section. The items that were analyzed and Table 2 shows the results of the flexural strength test of the concrete
interpreted were supported with tables to describe the comparison of samples with Stuccotard80 and with Molasses after thirty-five days of
flexural strengths of concrete mixtures with different number of curing curing. The mean flexural strength of the concrete with Stuccotard80
days, and the initial and final setting time between cement paste with and with Molasses is 257.03 psi and 324.85psi, respectively.
Stuccotard 80 and molasses.

Table 1. Results of the flexural strength of concrete samples with Table 3. Results of the initial setting time of cement paste samples with
stuccotard80 and with molasses after 14 days of curing stuccotard80 and with molasses

Flexural Strength (psi) TIME (minutes)

Stuccotard 80 Molasses Stuccotard 80 Molasses

Sample 1 211.70 269.77 Sample 1 53.10 66.80


Sample 2 196.71 267.90 Sample 2 51.40 65.60
Sample 3 228.56 254.78 Sample 3 47.50 64.50
Sample 4 207.95 236.05 Sample 4 45.00 62.50
Sample 5 196.71 237.92 Sample 5 50.00 61.90
Mean 208.326 253.284 Mean 49.40 64.26

Table 1 shows the results of the flexural strength test of the concrete Table 3 shows the results of the initial setting time of the cement
samples with Stuccotard80 and with Molasses after fourteen days of paste with Stuccotard80 and with Molasses. The mean initial setting
curing. The mean flexural strength of the concrete with Stuccotard80 time of the cement paste with Stuccotard80 and with Molasses is
and with Molasses is 208.326psi and 253.284psi, respectively. 49.40mins and 64.26mins, respectively.

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Table 4. Results of the final setting time of cement paste samples with the two variables were incomparable and far different from each other.
stuccotard80 and with molasses This further means that the flexural strength of the concrete samples
with molasses is significantly higher that of the concrete samples with
TIME (minutes) Stuccotard80.
Stuccotard 80 Molasses

Sample 1 386 472


Sample 2 375 460
Table 6. Significant difference between the flexural strength of concrete
Sample 3 350 455 samples with stuccotard80 and concrete samples with molasses for 35
Sample 4 335 450 days of curing
Sample 5 370 440 ⨱
Mean 363.20 455.40 p-value Decision
Stuccotard 80 Molasses

257.03 324.85 0.02 Significant


Table 4 shows the results of the final setting time test of the
cement paste with Stuccotard80 and with Molasses. The mean final
setting time of the cement paste with Stuccotard80 and with Molasses Table 6 presents the results of the flexural strength test after thirty-
is 363.20mins and 455.40mins, respectively. five days curing of concrete samples with Stuccotard80 with the mean
value of 257.03 psi and concrete samples with molasses with the mean
value of 324.848psi.
Table 5. Significant difference between the flexural strength of concrete
samples with stuccotard80 and with molasses after 14 days of curing The table also shows the significant difference between the two
variables in terms of their flexural strength after thirty-five days of
⨱ curing, with the p-value of 0.02 which is less than 0.05. It implies that
p-value Decision the two variables were incomparable and far different from each other.
Stuccotard 80 Molasses
This further means that the flexural strength of the concrete samples
208.326 253.284 0.01 Significant with molasses is significantly higher that of the concrete samples with
Stuccotard80.

Table 5 presents the results of the flexural strength test after


fourteen days curing of concrete samples with Stuccotard80 with the Table 7. Significant difference between the initial setting time of
mean value of 208.326psi and concrete samples with molasses with the cement paste samples with stuccotard80 and cement paste samples
mean value of 253.284psi. with molasses

The table also shows the significant difference between the two p-value Decision
Stuccotard 80 Molasses
variables in terms of their flexural strength after fourteen days of
curing, with the p-value of 0.01 which is less than 0.05. It implies that 49.40 64.26 0.00 Significant

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Table 7 presents the results of the initial setting time test of cement DISCUSSION
paste samples with Stuccotard80 with the mean value of 49.40mins and
cement paste samples with molasses with the mean value of 64.26min. The analysis of the data that had been gathered from the results are
discussed in this section. Findings, conclusions, and recommendations
The table also shows the significant difference between the two are also included in this part for further understanding.
variables in terms of their initial setting time, with the p-value of 0.00
which is less than 0.05. Resulting to zero p-value is possible and it
indicates that the two variables were very incomparable. It was due to Findings
the big difference on their initial setting time. This means that the initial
setting time of the cement paste samples with molasses was significantly The study was conducted to determine whether molasses can be a
longer that of the cement paste samples with Stuccotard80. Molasses retarding admixture for concrete.
caused a great retarding effect on the cement paste.
There were five samples each for two different variables and for
two different number of curing days and were tested. In terms of the
Table 8. Significant difference between the final setting time of cement flexural strength, the concrete samples with molasses that are cured
paste samples with stuccotard80 and cement paste samples with for thirty-five days obtained the highest strength. Unfortunately, all
molasses results gathered were not able to reach the standard strength for

road construction which is 650 psi based on the third point loading
p-value Decision as specified in the ASTM C78. Manual mixing was different from
Stuccotard 80 Molasses thorough mixing using concrete mixer; it affected the quality of the
363.20 455.40 0.00 Significant concrete mixture.

The paired-sample t-test showed results of the significant difference


Table 8 presents the results of the final setting time test of cement of the flexural strengths of concrete samples after fourteen and thirty-
paste samples with Stuccotard80 with the mean value of 363.20min five days of curing. There is a significant difference between flexural
and cement paste samples with molasses with the mean value of strength of concrete samples with Stuccotard80 and with molasses
455.40min. cured for fourteen days and thirty-five days. The two variables were
incomparable in terms of their strength and it was in favor for molasses
The table also shows the significant difference between the two because it exceeded the strength of the Stuccotard 80. Based on the
variables in terms of their final setting time, with the p-value of 0.00 Indian Journal of Engineering & Materials Sciences, 2015 entitled Usage
which is less than 0.05. Resulting to zero p-value is possible and it of molasses in concrete as water reducing and retarding admixture;
indicates that the two variables were very incomparable. It is due to “The increase of the flexural strength of the concrete samples with
the big difference on their final setting time. This means that the final molasses is because of the decreasing of water-cement ratios of the
setting time of the cement paste samples with molasses was significantly concrete.”
longer that of the cement paste samples with Stuccotard 80. Molasses
caused a great retarding effect on the cement paste.

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There is a significant difference between initial and final setting Recommendation


time of the cement paste with stuccotard80 and molasses as retarding
admixture. The initial and final setting time of the cement pastes Based on the findings and conclusion of the study, the researchers
with molasses were greater than of the cement paste with Stuccotard recommend the following:
80. Based on the study of Khan and Ullah, 2002 entitled Effect of a
Retarding Admixture on the Setting Time of Cement Pastes in Hot The use of molasses as retarding admixture may be explored.
Weather; “The basic reason for extending the setting of time was
adsorption of molasses acted as thin layer over the cement particles The use of clean containers for the curing process to avoid any
and it slowed down the hydration process. Formation of calcium impurities to the samples may be implemented.
ions would increase the solubility and discouraging the formation of
calcium hydroxide. By this reason setting property of concrete has Instead of fine aggregates, crushed coarse aggregate is
been improved.” recommended to be used for a higher result in the flexural strength of
the concrete due to its physical and mechanical properties

Conclusions A similar study be conducted using different dosage of molasses to


determine if there is a great effect on the setting and flexural strength
Based on the findings of the study, it could be concluded that there of the concrete.
is a significant difference between the following:
For the batching plant companies, the use of molasses as retarding
Flexural strength of the concrete with Stuccotard 80 and concrete admixture wherein a mixer will be used for the thorough mixing of
with molasses cured for fourteen days. concrete and to determine its strength if there is a difference between
manual mixing and concrete mixer.
Flexural strength of the concrete with Stuccotard 80 and concrete
with molasses cured for thirty-five days. The flexural strength of concrete with molasses must be compared
to the standard strength for roads.
Initial setting time of the cement paste with Stuccotard 80 and  
cement paste with molasses.

Final setting time of the cement paste with Stuccotard 80 and


cement paste with molasses.

30•PULSAR UNIVERSITY OF THE IMMACULATE CONCEPTION PULSAR•31


THE OFFICIAL JOURNAL OF ENGINEERING RESEARCH THE OFFICIAL JOURNAL OF ENGINEERING RESEARCH

REFERENCES James O., Ndoke P.N. & Kolo S.S. (2007). Effect of Different Curing
Methods on the Compressive Strength of Concrete. Retrieved
AASHTO. (2006). Standard Method of Test for Time of Setting January 15, 2016 from http://www.engineeringcivil.com/
of Hydraulic Cement by Vicat Needle. Retrieved January 15, effect-of-different-curing-methods-on-the-compressive-
2016 from https://www.pdffiller.com/88594657--T-131- strength-of-concrete.html
06---Time-of-Setting-of-Hydraulic-Cement-by-Vicat-Needle-
AASHTO-Designation- Khan, B. & Ullah, M. (2004). Effect of a Retarding Admixture on
the Setting Time of Cement Pastes in Hot Weather. JKAU: Eng.
Abalaka, A.E. (2011). Effects of Sugar on Physical Properties of Sci., vol. 15 no. 1, pp. 63-79 (1425 A.H./ 2004 A.D.). http://
Ordinary Portland Cement Paste and Concrete. Retrieved March www.kau.edu.sa/Files/135/Researches/54945_25263.pdf
8, 2015 from http://www.journal.au.edu/au_techno/2011/
jan2011/journal143_article09.pdf Kumar, D. (2015). Sugarcane Molasses in Concrete as a Water
Reducing-Retarding Admixture: A Review. Retrieved January
Akinwumi, I.I., Gbadamosi, Z.O. (2014). Effects of Curing 15, 2016 from http://www.internationaljournalssrg.org/
Condition and Curing Period on the Compressive Strength IJCE/2015/Special-Issue/EFES/IJCE-EFES-P130.pdf
Development of Plain Concrete. Retrieved January 15, 2016
from http://www.academia.edu/7803480/Effects_of_ Lane, D.S. (1998). Evaluation of concrete characteristics for rigid
Curing_Condition_and_Curing_Period_on_the_Compressive_ pavements. Retrieved January 15, 2016 from http://www.
Strength_Development_of_Plain_Concrete virginiadot.org/vtrc/main/online_reports/pdf/98-r24.pdf

Blakstad, O. (2008). Experimental Research. Retrieved Nov Rodriguez, J. (2017). Seven Must-Use Concrete Admixtures
29, 2017 from Explorable.com: https://explorable.com/ (Additives). Retrieved August 3, 2017 from https://www.
experimental-research thebalance.com/common-used-concrete-admixtures-845036

Collepardi, M. (2007). Admixtures-enhancing concrete Yildirim, H. & Altun, B. (2012(. Usage of molasses in concrete as
performance. Retrieved March 9, 2015 from http://www. a water reducing and retarding admixture. IJEMS Vol.19(6).
encosrl.it/enco%20srl%20ITA/servizi/pdf/additivi/94.pdf http://hdl.handle.net/123456789/15817

Curtin, L. (1983). Molasses – General Consideration. Retrieved


March 8, 2015 from http://rcrec-ona.ifas.ufl.edu/pdf/
publications/molasses-general-considerations..pdf

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