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LANES WORK

1. Sample treatment stage

25 mL corn oil

Boil in 15, 30, 45, 60, and 100 minutes


Sample

Reaction :

R1-CH2-CH=CH-CH2-R2 energy

R1-CH*-CH=CH-CH2-R2 + H* (free radical)

Half oxidation : oxidized oil + KI → product + I2 + KI

Perfect oxidation : oxidized oil + KI → product + I2

KI (aq) + ROOH (aq) + H2O (l) → KOH (aq) + ROH (aq) + I2

CH3(CH2)HCOOH(aq) + KI(aq) + H2O(l) → CH3(CH2)HCOOH (aq) +I2 + 2KOH


(aq)

2. Determining of peroxide number stage

2 mL sample each time

Add 3,6 glacial acid


Add 2,4 mL chlorofom
Add 3 drops of KI saturated solution
Let it in 1 minutes
Add 6 mL aquadest while shaking
Add 2 drops of amylum 1%
Titrate with Na2S2O3 0,1 M
V Na2S2O3

NUMBER OF PEROXIDE

I2 + 2e → 2I-

2S2O32- → S4O62- + 2e -

I2 + 2S2O32- → 2I- + S4O62-

RANCIDITY OF OIL

R-CH=CH-R’ + O=O → O=CH-R’R-CH=O

COMPLEX IOD AND AMYLUM


3. Blanco titration

3,6 glacial acid

Add 2,4 mL chlorofom


Add 3 drops of KI saturated solution
Let it in 1 minutes
Add 6 mL aquadest while shaking
Add 2 drops of amylum 1%
Titrate with Na2S2O3 0,1 M
V Na2S2O3
CALCULATION

Known :
⍴ corn oil = ⍴ linoleat acid = 0,902 gram/mL
Mass of corn oil = Volume of corn oil x ⍴ corn oil
= 2 mL x 0,902 gram/mL
= 1,804 gram
Mr linoleat acid = 280,4472 gram/mol
Mol corn oil (a) = 6,432 mmol (a)
Volume of blanko = 0.3 mL
Volume of Na2S2O3 =
15 minutes : 0,8 mL
30 minutes : 1,3 mL
45 minutes : 1,6 mL
60 minutes : 2,3 mL
100 minutes : 2,8 mL
1. Peroxide Value
V Na 2 S 2 O3 x N Na 2 S 2O 3 x 1 0 00
Peroxide Value =
mass of corn oil
a. Titration 15 minutes
( 0,8−0,3 ) mL x 0,2 N x 10 00
Peroxide value =
1,804 gram
= 55,43 moleq/gram
b. Titration 30 minutes
( 1,3−0,3 ) mL x 0,2 N x 1 0 00
Peroxide value =
1,804 gram
= 110,86 moleq/gram
c. Titration 45 minutes
( 1,6−0,3 ) mL x 0,2 N x 10 00
Peroxide value =
1,804 gram
= 144,13 moleq/gram
d. Titration 60 minutes
( 2,3−0,3 ) mL x 0,2 N x 1 0 00
Peroxide value =
1,804 gram
= 221,73 moleq/gram
e. Titration 100 minutes
( 2,8−0,3 ) mL x 0,2 N x 1 0 00
Peroxide value =
1,804 gram
= 277,16 moleq/gram
Time (s) Peroxide Number (moleq O2/100g)
900 55,43
1800 110,86
2700 144,13
3600 221,73
6000 277,16

2. Determine of Orde Reaction


a. Determine x value

- 15 minutes

moleq corn oil = moleq Na2S2O3


= 0,2 N x 0,8 mL
= 0,16 mmol
- 30 minutes
moleq corn oil = moleq Na2S2O3
= 0,2 N x 1,3 mL
= 0,26 mmol

- 45 minutes
moleq corn oil = moleq Na2S2O3
= 0,2 N x 1,6 mL
= 0,32 mmol
- 60 minutes
moleq corn oil = moleq Na2S2O3
= 0,2 N x 2,3 mL
= 0,46 mmol
- 100 minutes
moleq corn oil = moleq Na2S2O3
= 0,2 N x 2,8 mL
= 0,56 mmol
b. Determine orde reaction
- Orde reaction 1
1 a
k= ln
t a−x
- Orde reaction 2
1 1 1
k= ( −
t ( a−x ) a )
- Orde reaction 3
1 1 1
k= t ( 2
− 2
2(a−x) 2 a )
Time (s) a x (a-x) ln (a-x) 1/(a-x) 1/2(a-x)2 k Orde 1 k Orde 2 k Orde 3
-5 -6
900 6,432 0,16 6,272 1,836 0,000159 0,01271 2,798 x 10 4,4 x 10 1,41 x 10-5
1800 6,432 0,26 6,172 1,820 0,000162 0,013126 2,29 x 10-5 3,63 x 10-6 7,29 x 10-6
2700 6,432 0,32 6,112 1,810 0,000164 0,013385 1,89 x 10-5 3,01 x 10-6 4,96 x 10-6
3600 6,432 0,46 5,972 1,787 0,000167 0,014019 2,06 x 10-5 3,32 x 10-6 3,89 x 10-6
6000 6,432 0,56 5,872 1,770 0,00017 0,014502 1,51 x 10-5 2,47 x 10-6 2,42 x 10-6
Orde 1
1,860
1,840
1,820 f(x) = − 0.01 x + 1843.89
1,800 R² = 0.95
ln(a-x)

1,780
1,760
1,740
1,720
0 1000 2000 3000 4000 5000 6000 7000
time (s)

Orde 2
0.18

0.17 f(x) = 0 x + 0.16


R² = 0.95
0.17
1/(a-x)

0.16

0.16

0.15
0 1000 2000 3000 4000 5000 6000 7000
times (s)

Orde 3
0.02
0.01 f(x) = 0 x + 0.01
0.01 R² = 0.96
1/2(a-x)2

0.01
0.01
0.01
0.01
0.01
0 1000 2000 3000 4000 5000 6000 7000
times (s)
Documentation

Lanes Work Picture Explanation


Preparation Tools and Materials

Sample Boil in 15, 30, 45, 60, and


Treatment Stage 100 minutes

Blanco Titration
3,6 glacial acid + 2,4 mL
chlorofom and let it in 1
minutes

Add 3 drops of KI saturated


solution

Add 6 mL aquadest while


shaking

Add 2 drops of amylum 1%


become yellowish

Titrate with Na2S2O3 0,1 M

The color changed into


colorless

Determining of - 2 mL sample 15 minutes


Peroxide boiled + 3,6 glacial acid
number stage + 2,4 mL chlorofom + 3
drops of KI saturated
solution + 6 mL aquadest
while shaking + 2 drops of
amylum 1%

- Titrated with Na2S2O3 0,1


M need 0,8 mL

- 2 mL sample 30 minutes
boiled + 3,6 glacial acid
+ 2,4 mL chlorofom + 3
drops of KI saturated
solution + 6 mL aquadest
while shaking + 2 drops of
amylum 1%

Titrated with Na2S2O3 0,1 M


need 1,3 mL

- 2 mL sample 45 minutes
boiled + 3,6 glacial acid
+ 2,4 mL chlorofom + 3
drops of KI saturated
solution + 6 mL aquadest
while shaking + 2 drops of
amylum 1%

Titrated with Na2S2O3 0,1 M


need 1,6 mL
- 2 mL sample 60 minutes
boiled + 3,6 glacial acid
+ 2,4 mL chlorofom + 3
drops of KI saturated
solution + 6 mL aquadest
while shaking + 2 drops of
amylum 1%

Titrated with Na2S2O3 0,1 M


need 2,3 mL

- 2 mL sample 100 minutes


boiled + 3,6 glacial acid
+ 2,4 mL chlorofom + 3
drops of KI saturated
solution + 6 mL aquadest
while shaking + 2 drops of
amylum 1%

Titrated with Na2S2O3 0,1 M


need 2,8 mL