27-12-19 - SR - Icon All - GTM-4 - SET-B - Question Paper and Solutions PDF

Sri Chaitanya IIT Acedamy 27-12-19_Sr.
Icon All_GTM-4_SET-B_Question Paper

MATHEMATICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases
2 2
1. AB is a chord of the circle x  y  25 . The tangents to the circle at A and B intersect
at C . If  2,3 is the midpoint of AB , then the area of quadrilateral OACB (Where O is
origin) is
50 3 50
1) 2) 50 3) 50 3 4)
3 13 13
2. If the points A  2  x,2,2  , B  2,2  y,2  , C  2,2,2  z  and D 1,1,1 are coplanar, then
locus of P  x, y, z  is
1 1 1
1)   1 2) x  y  z  1
x y z
1 1 1 1 1 1
3)   1 4)    2
1 x 1 y 1 z x y z
3. If a1 , a2 , a3 ,.........., a20 are A.M's between 13 and 67, then the value of
a1  a2  a3  .......  a20 is equal to
1) 600 2) 800 3)400 4)200
1
4. If a   28 3  3  b, then  a, b  is
 1 1   1 1   1 1 
1)  ,  2)  ,  3)  27, 28  4)  , 
 28 27   28 29   27 26 
Sec:Sr.Icon All Space For Rough Work 2

Sri Chaitanya IIT Acedamy 27-12-19_Sr.Icon All_GTM-4_SET-B_Question Paper
5. A coin whose faces are marked 3 and 5 is tossed 4 times. The probability that the sum of
the numbers thrown is greater than 15 is
11 5 5 1
1) 2) 3) 4)
16 16 8 16
23
6. Sum of the last 12 coefficients in the binomial expansion of 1 x  is
1) 222 2) 223 3) 223  23 C11 4) 2 23  211
tan x K  K tan x  1 
7. If  1  tan x  tan 2 x dx  x  tan 1    C , ( C is a constant of integration),
A  A 
then the ordered pair  K , A  is equal to
1)  2,3 2)  2,1 3)  2,1 4)  2,3

 z 3
8. If ' z ' lies on the circle z  3i  3 2, then the value of arg   is equal to
 z  3
   
1) 2) 3) 4)
3 4 6 2
9. ~ r   ~ p    ~ q  is equivalent to
1) p  q  r 2) r  p  q
3) p  q  r 4) r   p  q 
10. The mean and variance of ‘ n ’observations x1, x2 , x3 ,....., xn are 6 and 0, respectively. If
n
 xi2  900, then the value of n is equal to
i 1
1) 80 2) 25 3) 20 4) 16

1 1 1
0 1 2  2 2 2
 
11. If A  1 2 3 and A1   4 3 c  , then the values of a and c are respectively
 
3 a 1  5 3 1
 
2 2 2
equal to
1) 1,1 2) 1, 1 3) 1,2 4) 1,1
12. The distance of the point 1, 2,3 from the plane x  y  z  5  0, parallel to the line
x y z 1
  is
2 3 6
1) 1 2) 2 3) 3 4) 4
1
13. If a f  x   b f    x  1, x  0, a  b, then f  2  
 x
a  2b 2a  b a  2b 2a  b
1) 2) 3) 2 2 4)

2 a 2  b2  a 2  b2 a b

2 a 2  b2 
14. Let f  x satisfy all the conditions of Lagrange’s mean value theorem in  0,2 . If
1
f  0  0 and f ' x  for all x in  0,2 , then
2
1
1) f  x   2) f  x   1
2
3) f  x  2 x 4) f  x  3 for at least one x in  0,2

dy 1  y2
15. The solution of differential equation  determines family of circles with
dx y
1) variable radii and fixed centre at  0,1
2) variable radii and fixed centre at  0, 1
3) fixed radius 1 and variable centre along y  axis
4) fixed radius 1 and variable centre along x  axis
16. Two straight lines are perpendicular to each other. One of them touches the parabola
y 2  4a  x  a  and the other touches y 2  4b  x  b  .Their point of intersection lies on
the line
1) x  a  b  0 2) x  a  b  0
3) x  a  b  0 4) x  a  b  0
17. The sum of first two terms of Geometric Progression is 12 and the sum of third and
fourth terms is 48. If the terms of Geometric Progression are alternatively positive and
negative, then first term is
1) 4 2) 12 3) 12 4) 4
18. If f  x   ax  b, a  0 such that f :  1,1   0,2, then
cot cot 1 7  cot 1 8  cot 118  is equal to

 
1) f  1 2) f  0 3) f 1 4) f  2
19. The equation of the lines through the point  2,3 and making an intercept of length 2
units between the lines y  2 x  3 and y  2 x  5 is
1) y  3 2) x  3 3) x  2 4) y  2
20. If roots of x 2   a  3  x  a  0 are such that at least one of them is greater than 2, then
1) a  7,9 2) a  7,  3) a  9,  4) a  7,9

(NUMERICAL VALUE TYPE)
This section contains 5 questions. Each question is numerical value type. For each question, enter the correct
numerical value (in decimal notation, truncated/rounded-off to second decimal place.
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30).
Marking scheme: +4 for correct answer, 0 if not attempted and 0 in all other cases.
21. The area bounded by the curves y 2  4 x and x 2  4 y is k square units then,
k   5  ___ ; where [.] denotes the greatest integer function

22. The total number of ways in which three distinct numbers in Arithmetic Progression can
be selected from the set 1, 2,3,......., 24 is equal to
23. If PQ is a double ordinate of the hyperbola 16 x 2  25 y 2  400 be produced on both

sides to meet the asymptotes at R and S , then PR  PS 
 e px  log 1  4 x   q
e ,x  0

24. If the function g  x    x3 is continuous at x  0, then the

 r, x0
value of 6 pqr is
a b y cz
25. If x, y , z are different from zero and   a  x b c  z  0,
ax b y c
a b c
then the value of the expression   is
x y z

PHYSICS Max Marks: 100
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
26. A capacitor of capacity C1 is charged to the potential of V0 . On disconnecting from the
battery, it is connected with a capacitor of capacity C2 as shown in the adjoining figure.
The ratio of energies of system of capacitors before and after the connection of switch
‘ S ’ will be
S
C1V0 C2
1)  C1  C 2  C1 2) C1  C1  C 2  3) C1C2 4) C1 C2
27. In Young’s double slit experiment, the two slits act as coherent sources of equal
amplitude a and of wave length  . In other experiment with the same set up, the two
slits are sources of equal amplitude a and wavelength ‘  ’ but are incoherent. The ratio
of intensity of light at the midpoint of the screen in the first case to that in the second
case is
1) 2 :1 2) 1: 2 3) 3: 4 4) 4 : 3

28. Among the following identify the source which produces X -rays.
1) Vacuum tubes 2) Hot body
3) Hydrogen discharge tube 4) Coolidge tube
29. A gas mixture consists of 2 moles of oxygen and 4 moles of argon at temperature ‘ T ’.
Neglecting all vibrational mode, the total internal energy of the system is
1) 4RT 2) 15RT 3) 9RT 4) 11RT
30. A 0.1kg mass is suspended from a wire of negligible mass. The length of the wire is 1m
and its cross sectional area is 4.9  107 m2 . If the mass is pulled slightly in the vertically
downward direction and then released, it performs simple harmonic motion of angular
frequency 140 rad s . Then the Young’s modulus of material of the wire is(Assume that
the Hooke’s law is valid throughout the motion )
1) 4  109 N m2 2) 14  109 N m2
3) 4  108 N m 2 4) 5  108 N m 2
31. The following configuration of gate is equivalent to
OR
A
B G1 AND
NAND
G3
G2
1) NAND 2) XOR 3) OR 4) AND

32. 1 mole of a monoatomic gas at temperature T0 expand slowly according to the law P 2 is
proportional to T . Its final temperature is 2T0 , then heat supplied to the gas is
R 3
1) 2) RT0 3)RT0 4) 2RT0
T0 2 2
33. A rod PQ of mass ‘ m ’ and resistance ‘ r ’ is moving on two fixed, resistance less, smooth
conducting rails (closed on both sides by resistance R1 and R2 ). Then the current in the

rod at the instant when its velocity V is (A uniform magnetic field B exists in the region)
P
B r
R1  R2
l V
Q
BlV BlV BlV BlV  R1  R2 
1) i  2) i  3) i  4) i 
R1  R2 r  R1  R2 R1  R2 R1 R2  r  R1  R2 
34. The current in resistance R1 in the given circuit is
2V 3V 4V
R1  2  R2  2  R3  3
2V 3V 2V
1) 0A 2) 3A 3) 10A 4) 13A

35. From the figure, the potential difference between the points ' x ' and ' y ' is
24V 2
4 3µF
x 4µF
A B
4 y 6
1) 7 V 2) 5V 3) 20V 4) 10V
36. A cubical block of side 30cm is moving with velocity 2 m s on a smooth horizontal
surface. The surface has a bump at a point O as shown in figure. The angular velocity (in
rad sec ) of the block immediately after it hits the bump, is:
a30cm
O
1) 13.3 2) 5.0 3) 9.4 4) 6.7
37. A particle executes simple harmonic motion and is located at x  a, b and c at times
to ,3to and 5to respectively with respect to mean position . At t  0 , the particle is at the
mean position and moving toward positive x-axis. The frequency of the oscillation is
1 ab 1 ab
1) cos1   2) cos1  
2πto  2c  2πto  3c 
1 ac 1 ac
3) cos1   4) cos1  
4πto  2b  2πto  2b 

38. A point mass of 1kg collides elastically with a stationary point mass of 5kg . After their
collision, the 1kg mass reverses its direction and moves with a speed of 2 m s . Which of
the following statement(s) is (are) correct for the system of these two masses?
a) Total momentum of the system is 3kg m s
b) Momentum of 5kg mass after collision is 4 kg m s
1 2 
c) Kinetic energy of the centre of mass   totalmass  vcm  is 0.75J
2 
d) Total kinetic energy of the system is 4J
1) a & b correct 2) a & c correct
3) a & d correct 4) b & d correct
39. A carrier wave of peak voltage 12V is used to transmit a message signal. The modulation
index is 75%. The peak value of voltage of message signal is
1) 3V 2) 6V 3) 9V 4) 12V
40. A plate of thickness ' t ' made of a material of refractive index '  ' is placed in front of
one of the slits in a double slit experiment. What should be the minimum thickness ' t ',
which will make the intensity at the centre of the fringe pattern zero?
1)
   1  2)

3)

4)    1 
2    1 2    1
41. A tunnel is dug along the diameter of the earth (radius R and mass M ). There is a
particle of mass ' m ' at the centre of the tunnel. The minimum velocity given to the
particle so that it just reaches to the surface of the earth is
GM GM
1) 2)
R 2R
2GM GM
3) 4)
R 4R
42. A conducting sphere A of radius ' a ', with charge Q , is placed concentrically inside a
conducting shell B of radius ' b ' . The sphere B is earthed. ' C ' is the common center of
A and B . Study the following statements.
B
Q
A
C 
a
i. The potential at a distance r from C , where r  a is zero.

1 1 1
ii. The Potential difference between A and B is Q  
4π 0  a b 
1 1 1
iii. The potential at a distance r from C , where a  r  b is Q  
4π 0  r b 
Which of the above statements are correct?
1) Only (i) and (ii) 2) Only (ii) and (iii)
3) Only (i) and (iii) 4) All
43. A plane electromagnetic wave of frequency 25MHz travels in free space along the
x  direction . At a particular point in the space and time, if the intensity of electric field
 
E  6.3 ˆj V m , the magnetic induction B at this point is
1) 2.1  10 4 kˆ T 2) 2.1  10 6 kˆ T 3) 2.1  10 8 kˆ T 4) 2.1  10 3 kˆ T
44. A police van moving on a high way with a speed of 30km h fires a bullet at a thief’s car
speeding away in the same direction with a speed of 192 km h . If the speed of the bullet
with respect to police Van is 150 m s , with what relative speed does the bullet hit the
thief’s car?
1) 90 m s 2) 105m s 3) 110 m s 4) 120 m s

45. The image for the converging beam after refraction through the curved surface (in the
given figure) is formed at a distance ' x ' . Then the value of ' x ' is
[radius of refracting surface AB is 20cm , refractive index of the medium on left side of
3
the AB is n  and that on right side is n  1 ]
2
A
n1
n3 2
O P x
30cm
B
40 40 180
1) x  40cm 2) x  cm 3) x   cm 4) x  cm
3 3 7

(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30).
Marking scheme: +4 for correct answer, 0 if not attempted and 0 in all other cases.
46. A body of mass 0.5kg travels in a straight line with velocity v  5 x 3 2 . The work done by
the net force during the displacement from x  0 to x  2m is (in joule)
47. 
The rms value of alternating current i  2sin100πt  2cos 100πt  300 is 
(in ampere)

48. The electric field of plane electromagnetic wave of amplitude 2 V m varies with time,
propagating along z  axis . The average energy density of magnetic field in J m  is
3
equal to x  1012 J m3 . Then ' x ' value is equal to ( 0  8.854  1012 F m )
49. A boy riding on his bike is going towards east at a speed of 4 2 m s . At a certain point,
he produces a sound pulse of frequency 1650Hz that travels in air at a speed of 334 m s .
A second boy stands on the ground 450 south of east from him. The frequency of the
pulse as received by the second boy is (in Hz )
50. Sun radiates thermal radiation with maximum intensity at the wavelength   0.5µm
while its surface temperature is 6000K . If sun cools down to a temperature where it
emits only 81% of its present power, the maximum intensity will then be emitted at
wavelength  ' (in micro metre )is equal to  10  3.1622

 

CHEMISTRY Max Marks: 100
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases
51. The energy of second Bohr’s orbit of the hydrogen atom is 328 kJ/mol1 .Hence, the
energy of fourth Bohr’s orbit would be
1) 41kJ mol-1 2) 1312kJ mol-1 3) 164kJ mol-1 4) 82kJ mol-1
52. The correct order of second ionization enthalpy of carbon, nitrogen, oxygen and fluorine
is
1) C  N  O  F 2) O  N  F  C
3) O  F  N  C 4) F  O  N  C
53. The bond energies in NO,NO and NO  follow the order

1) NO  NO  NO 2) NO  NO  NO

3) NO  NO  NO  4) NO  NO   NO
54. Cu 3P  Cr2O72  H1  Cu 2 +H3PO4  Cr 3 the coefficient for Cu 3P in balanced

equation is
1) 2 2) 3 3) 6 4) 12
55. The number of P  P bonds and oxidation state of phosphorous in hypophosphoric acid
 H 4P2O6  respectivelyare
1) 0 and  3 . 2) 0 and  5 . 3) 1and  5 . 4) 1and  4 .

56. Which of the following reaction should show maximum reactivity for reaction below?
F
C
EtO- Na +
NO2
 
Et OH Et ONa +

Et OH
NO 2 NO 2
1) 2)
Br F
O2 N NO 2
EtONa + EtO- Na +
 

Et OH Et OH
3) NO 2
4) OMe
57. Find the incorrect expression among the following.

ΔGsystem
1)  -T
ΔS total
V
2) In isothermal process, Wreversible   nRT ln f
Vi
ΔH   TΔS 
3) ln K 
RT
o
4) K  e  ΔG / RT

58. What are the major products from the following reaction?
O  CH 2
HI

heat
?
I CH 2OH
1)
OH CH 2I
2)
OCH 2OH I
3)
OCH 2I OH
4)
59. Two buffer solutions A and B ,each made with acetic acid and sodium acetate differ in
their pH by one unit, A has salt : acid  x : y, B has salt : acid  y : x . If x  y , then the
value of x : y is
1) 10000 2) 3.17 3) 6.61 4) 2.10

60. Which one cannot be used to produce an aldehyde or ketone?
O
C 2 H
C 
Pd-BaSO4
1)
CO, HC

Anhyd AC 3 /CuC
2)
3) Hydration of 2  butynewith Hg 2  , H 2SO 4 and H 2O .
4) 2R  Mg  X  CdC  2 
61. 20g of a binary electrolyte (molecular weight = 100) are dissolved in 500 g of water. The
freezing point of the solution is 0.744 C; K f  1.86K molality 1 . The degree of

dissociation of electrolyte is
1) 50% 2) 75% 3) 100% 4) zero
62. Which of the following is incorrect?
Silent electric

1) 3O2  2O3; H  284.5kJ .

discharge
2) Ozone undergoes addition reaction with unsaturated hydrocarbons.

3) Sodiumthiosulphate reacts with I2 to form sodium tetrathionate and sodium iodide.
4) Ozone oxidizes lead sulphide to lead sulphate.

63. Which of the following compounds will form significant amount of meta product during
mono-nitration reaction?
OH OCOCH 3
1) 2)
NH 2 NHCOCH 3
3) 4)
64. Find the correct sequence of dipole moment from the following.
1) CH3F  CH 3C  CH 3Br  CH 3I 2) CH3I  CH3Br  CH 3C  CH 3F
3) CH3F  CH 3I  CH 3Br  CH 3C 4) CH3C   CH3F  CH 3Br  CH 3I
65. Calculate the concentration of cation vacancies of NaC is doped with 103 mole % of
SrC 2 .
1) 3  1020 mol1 2) 6  1018 mol1
3) 2  1022 mol1 4) 4  1021 mol1
66. ‘Dacron’ is a condensation polymer of
1) adipic acid and Hexamethylenediamine.
2) ethylene glycol and terephthalic acid.
3) ethylene glycol and phthalic acid.
4) phenol and formaldehyde.

67. The group reagent NH 4C and NH 4OH will not precipitate
1) A3+ 2) Fe3+ 3) Cr3+ 4) Ca 2+

3 2
68. The magnetic moment of  Mn  CN 6  is 2.8 BM and that of  MnBr4  is 5.9 BM.
Find the hybridization and geometries of these complex ions.
1) sp 3d 2 , octahedral and dsp 2 ,tetrahedral
2) d 2 sp 3 , octahedral and dsp 2 , square planar
3) d 2 sp 3 , octahedral and sp 3 , tetrahedral
4) sp 3d 2 , octahedral and sp 3 , square planar

69. Which process of purification is represented by the following equation?
250 C 1400 C
Ti  2I 2 
 TiI4  Ti  2I 2
 Impure  pure
1) Cupellation 2) Polling
3) Van Arkel process 4) Mond’s process
70. Bases common to RNA and DNA are
1) adenine, guanine and cytosine. 2) adenine, uracil and cytosine.
3) adenine, guanine and thymine. 4) guanine, uracil and thymine.

(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30).
Marking scheme: +4 for correct answer, 0 if not attempted and 0 in and 0 in all other cases.
71. In the electrolysis of aqueous NaC , what volume of C 2 g  (in lit) is produced in the
time that it takes to liberate 5.0 L of H2 g  ? Assume that both gases are measured at STP.
72. At what temperature (in Kelvin) will the molar kinetic energy of 0.3 mole of ‘He’ be the
same that of 0.4 mole of argon at 400 K ?
73. 75% of a first order reaction is completed in 32 minutes. 50% of the reaction would have
been completed in------- minutes.
X
74. The number of structural isomers of C 4 H10O is ' X ' and for C2 H 6O is 'Y '. Then the
Y
is
75. M  OH  x has KSP  4  1012 and solubility 104 M . Hence, x is


Sri Chaitanya IIT Academy 27-12-19_Sr.Icon All_GTM-4 SET-B_Key & Sol's
Sri Chaitanya IIT Academy., India.

AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON Central Office , Madhapur – Hyderabad
Sec: Sr.Icon All GTM-04 Date: 27-12-19
Time: 09.00 am to 12.00 SET-B Max.Marks:300
Key & Solutions
MATHEMATICS
1 2 2 1 3 2 4 1 5 1
6 1 7 1 8 2 9 1 10 2
11 2 12 1 13 4 14 2 15 4
16 3 17 2 18 4 19 3 20 3
21 0000.00 22 0132.00 23 0016.00 24 0256.00 25 0002.00
PHYSICS
26 1 27 1 28 4 29 4 30 1
31 2 32 4 33 4 34 1 35 1
36 2 37 3 38 2 39 3 40 3
41 1 42 2 43 3 44 2 45 1
46 0050.00 47 0001.41 48 0008.85 49 1670.00 50 0000.53
CHEMISTRY
51 4 52 3 53 1 54 3 55 4
56 3 57 3 58 2 59 2 60 4
61 4 62 1 63 3 64 4 65 2
66 2 67 4 68 3 69 3 70 1
71 0005.00 72 0400.00 73 0016.00 74 0003.50 75 0002.00
Sec:Sr.Icon All 1
SOLUTIONS
MATHEMATICS
1.
O
A  B
P
C
Here OB  OA  5 ( radius of circle)
2 2
OP  2  0  3  0  13
Let OBP  , then PCB  
OP
From OPB,cos  90    
OB
13

5
13
 sin  
5
2 3
 cot  
13
1
Area of quadrilateral OACB  2   OB  BC
2
BC BC
From OBC ,cot   
OB 5
 Area of quadrilateral OACB
 5  5cot 
2 3
 25 
13
3
 50 sq.units
13
Therefore,
 the
correct
 answer is (2).
2. Here AB  OB  OA xiˆ  yjˆ
Sec:Sr.Icon All 2
  
AC  OC ˆ ˆ
   OA
  xi  zk
AD  OD  OA   x  1 iˆ  ˆj  kˆ
x y 0
As these vectors are coplanar, x 0 z  0
x  1 1 1
 x   z   y   x  xz  z   0
 xy  yz  zx  xyz
1 1 1
   1
x y z
Therefore, the correct answer is (1).
3.  a1 , a2 , a3 ,.........., a20 are A.M's between 13 and 67, then
13, a1, a2 ,........, a20 ,67 are in A.P.
We know that if a1, a2 , a3 ,.........., an are A.M’s between a and b,
ab
a1  a2  a3  ...........  an  n   then
 2 
 13  67 
 a1  a2  a3  ...........  a20  20    800
 2 
1
4. Let f  x   x 3 , x   27,28
Differentiating with respect to x on both sides
1
 f ' x  
2
3x 3
f  b - f  a 
By Lagrange’s Mean value theorem:  f '  c  , where c   27,28 
b -a
1 1

 28 3   27  3  f ' c
28  27
2 1
  28  3  3 
2
3c 3
Now, 27  c  28
2 2
 9  c 3   28  3
Sec:Sr.Icon All 3
1 1 1
  
9 2 2
c 3 28 3
1

1

1

1

 28  3 1 
1
27 2 2 3 28 28
3.c 3 3 28 3
1 1 1
  
28 2 27
3 c  3
1 1 1
   28 3  3 
28 27
Therefore, the correct answer is(1).
5. let ' r ' denote the number of times 3 appears n  4, r  0,1,2,3,4
' P ' be the probability of a coin showing 3
1
 p  , p  q 1
2
1
q
2
Sum is greater than 15
 At least 2 coins show 5
 At most 2 coins show 3
P  0  X  r  2
 P  X  0   P  X  1  P  X  2  ( P  X  r   nC p r q n  r )
r
0 4 1 3 2 2
 4C .P .q  4C . p q  4C . p q
1
0 1 2
4
1
   1  4  6 
2
11

16
23
6. Sum of last 12 coefficients of 1 x  is
S  23C12  23C13  ......  23C23 ……(1)
Using n Cr n Cn  r
we get S  23C11  23C10  .....  23C0 ……(2)
Adding (1) and (2),
Sec:Sr.Icon All 4
we get 2 S  23C0  23C1  ..... 23C23  2 23

 S  222
23
 Sum of last 12 coefficients of 1 x  is 222
tan x
7. Let I   dx
2
1  tan x  tan x
I 
tan x  1  tan 2 x
dx  
1  tan 2 x  dx
tan x  1  tan 2 x 1  tan x  tan 2 x
sec 2 x
 I  x dx
1  tan x  tan 2 x
Put tan x  t
 sec2 x  dx  dt
dt
I  x  
t2  t 1
dt
I  x  
1 1
t2  t  1
4 4
dt
x
2 2
 1  3
t     
 2  2 
 1
 t 
2 2 C
I  x tan 1 
3  3 
 
 2 
2  2 tan x  1 
 I  x tan 1  C
3  3 
 A  3 and K  2
Sec:Sr.Icon All 5
8.
Im
C (3i)
O Re
B(-3) A(3)
Given ' z ' lies on the circle z  3i  3 2

CA  CB  3 2, OC  3
 OA  OB  3
 A  3  0i, B  3  0i
π
Clearly, BCA 
2
π
 BPA 
4
 z 3 π
 arg  
 z 3 4
9. Consider  ~ r  ~ p  ~ q 
  ~ r ~  p  q  
 pqr
10. Given mean x  6 and

n 2

 xi  x 
variance  2  i 1 0
n
2 2 2
  x1  6    x2  6   ......   xn  6   0
 x1  x2  .......  xn  6
(  Sum of perfect squares will be zero, when each of them is zero)
n
Given that  xi2  900
i 1
 n  62  900
 n  25
Sec:Sr.Icon All 6
1 1 1
2 
0 1 2  2 2
   1  
11. Given that A  1 2 3 and A  -4 3 c
 
3 a 1  5 3 1
  
2 2 2
we have I  AA1
0 1 2  1 1 1 
1
 1 2 3  8 6 2c 
2   
3 a 1   5 3 1 
 0  8  10 066 0  2c  2 
1
 1  16  15 1  12  9 1  4c  3 
2 
 3  8a  5 3  6a  3 3  2ac  1
 1 0 c 1 
 
 0 1 2  c  1
 4 1  a  3  a  1 2  ac 
1 0 0 
Comparing the elements of AA1 with those of I   0 1 0 ,
 
 0 0 1 
we have c  1  0 or c  1
a  1  0 or a  1
x y z 1
12. Equation of line through A 1, 2,3 and parallel to the line   is
2 3 6
x 1 y  2 z  3
   r ……….(1)
2 3 6
Any point P on this line is P  2r  1,3r  2, 6r  3  .
If P is the point of intersection of line (1) and plane x  y  z  5  0 , then
2r  1  3r  2  6r  3  5  0
1
r
7
 9 11 15 
P , , 
7 7 7 
2 2 2
 9  11   15 
Required distance  AP   1     2     3  
 7  7  7
Sec:Sr.Icon All 7
4 9 36
   1
49 49 49
1
13. Given that a f  x   b f    x  1
x
1
Replacing x by
x
1 1
b f  x  a f    1
x x
1
Eliminating f  
x
1 
 
we get a 2  b2 f  x   a  x  1  b   1
x 
b
 
 a 2  b2 f  2   a 
2
2a  b
 f  2 

2 a 2  b2 
f b   f  a 
14. By using Lagrange’s mean value theorem,  f ' x 
ba
f  2   f  0
  f ' x 
20
f 2  0
  f ' x 
2
df  x  f  2 
 
d 2
f  2
 f  x 
2
xc  f  0   0  c  0 
f  2
 f  x  x ……( 1 )
2
1
Also, f '  x  
2
f  2 1
 
2 2
From Eq. (1),
Sec:Sr.Icon All 8
f 2 f  2 1
f  x  x x x
2 2 2
In interval  0,2 , for maximum value of x take x  2
1
f  2   2
2
 f 2  1
dy 1  y2
15. We have, 
dx y
On integrating both sides ,
y
we get  dy   dx
2
1 y
1 2 y
  dy   dx
2 1 y 2
  1  y2  x  c
2
On squaring both sides, we get  x  c   y 2  1
Which is the equation of circle whose fixed radius is 1 and centre is variable on x  axis
16. Given parabola is y 2  4a  x  a 
a
Slope form of equation of tangent is y  m  x  a   …..(i)
m
1
Any tangent to y 2  4b  x  b  which is perpendicular to (i) is y    x  b   bm …(ii)
m
Subtracting (i) & (ii),
 1  1
we get  m   x   a  b   m    0
 m  m
 xab0
Which is a locus of their point of intersection.
17. Let a be the first term and r be the common ratio of Geometric Progression (G.P)
Since the sum of the first and second terms in G.P is 12
 a  ar  12
 a 1  r   12......(1)
Since the sum of the third and fourth terms in G.P. is 48
 ar 2  ar 3  48
Sec:Sr.Icon All 9
 ar 2 1  r   48......(2)
Solving (1) and (2), we get r  2
If r  2 ,then a  4
If r  2 and a  12
If r  2 , first two terms are 4,8.
If r  2 , first two terms are 12,24 .
First term, a  12 .
18. Given that f  x   ax  b

Differentiating with respect to x on both sides
 f ' x   a  0
 f  x  is an increasing function.
 f  1  0 and f 1  2
a  b  0 and a  b  2
 a  b 1
 f  x  x 1
Now, cot cot 1 7  cot 1 8  cot 118 
 
 1 1  1 
 cot  tan 1    tan 1    tan 1   
 7 8  18  
  1 1  
 1  7  8  1  1  
 cot  tan   tan  
1 1  18  
 1  
  7 8 
  15   1 
 cot tan 1    tan 1   
  55   18  
 3  1 
 cot  tan 1    tan 1   
  11   18  
  3 1 
 1  11  18  
 cot  tan 
3 1 
  1  . 
  11 18  
  65  
 cot  tan 1  
  195  
Sec:Sr.Icon All 10
  1 
 cot  tan 1   
  3 

 cot cot 1 3 
3
1 2
 f  2
53 2
19. As the lines are parallel, distance between them    BC
4 1 3
4 4
 AB  4  
5 5
 2 
 
 5 1
From ABC , tan   
 4  2
 
 5
A
 2,3 2

4
5 C
B
2
5
Slope of the given line is 2.

Let m1 be the slope of the required line
1 m1  2
Now tan   
2 1  2m1
m 2
 1 1
1  2m1 2
1 m 2
Consider  1
2 1  2m1
 1  2m1  2m1  4
 4 m1  3
3
 m1  
4
Sec:Sr.Icon All 11
1
Similarly by taking  , other value of m1 is undefined.
2
The equation of the line having slope m and Passing through the point  x , y  is
1 1
y  y1  m  x  x1 
3 1
 y  3    x  2 and y  3   x  2
4 0
Equations to the required lines are 3x  4 y  18  0 and x  2
20. Given equation is x 2   a  3  x  a  0
2
Now discriminant  D    a  3  4a  D= b2  4ac
 a 2  10a  9
  a  1 a  9 
Case I: Both the roots are greater than 2.
B
D  0, f  2   0,  2
2A
a 3
  a  1 a  9   0,4   a  3 2  a  0 and 2
2
 a   ,1  9,   , a  10 and a  7
 a  9,10  …….(1)
Case II: One root is greater than 2 and the other root is less than or equal
to 2. Hence, f  2   0,D  0
 4   a  3 2  a  0,  a  1 a  9   0
 a  10 and a   ,1   9,  
 a  10,   ........ 2 
From Eqs. (1) and (2),
a  9,10   10,  
 a  9,  
Sec:Sr.Icon All 12
21.
y
x2  4y
y2 4x
4 x
The two parabolas intersect at  0,0  and  4,4 

Given y 2  4 x
 y2 x ( Intersection point is above x  axis)
4
x2 
 Required area    2 x   dx
 4 
0 
4
 3 4
 x2  1  x3 
k  2    
 3  4  3 
0
 2  0
4 1 64
 8 
3 4 3
16
 sq. units.
3
 k  5.33 sq. units (approx)
 k  5  0
Therefore, the correct answer is 0
22. Let the numbers selected be x1, x2 , x3
We must have 2 x2  x1  x3
 x1  x3  even
Therefore both x1, x3 are odd (or) both are even.
If x1 and x3 both are even, we can select them in 12 C2 ways.
Similarly, if both x1 and x3 are odd,
we can again select them in 12 C2 ways.
Sec:Sr.Icon All 13
Thus, the total number of ways is 2  12C2  132

Therefore, the correct answer is 132.
23. Given hyperbola is 16 x 2  25 y 2  400
y
x
O
Q
x asecθ
x2 y 2
  1
25 16
Here a 2  25, b 2  16
Let P  a sec , b tan   be a point on hyperbola
 Q  a sec , b tan   (Image of P with respect to x-axis)
Equation of PQ is x  a sec
x2 y2
It intersects with asymptotes  0
a2 b2
 y  b sec
So, R  a sec , b sec  , S  a sec , b sec 

 PR  PS  b 2 sec 2   tan 2  
 b2
 16
Therefore, the correct answer is 16.00.
24. Since g  x  is continuous at x  0 then
e px  loge 1  4 x   q
lim r
x 0 x3
 p 2 x 2 p3 x 3   16 x 2 64 3  
 1   px     ......    4 x   x  ......   q 
 2! 3!   2 3  
 lim     
r
x 0  3
x 
 
 
Sec:Sr.Icon All 14
  p2   p 3 64  3 
 1  q    p  4  x    8  x2     x  ..... 
  2   6 3  
 lim    
r
x 0  x3 
 
 
p2 p3 64
1  q  0, p  4  0 and  8  0 and  r
2 6 3
32
 q  1, p  4, r 
3
 32 
 6 pqr  641   256
 3 
a b y cz
25. Given that   a  x b cz 0
ax b y c
Applying R2  R2  R1, R3  R3  R1, we get
a b y cz
  x y 0 0
x 0 z
Expanding along C3 , we get
x y a b y
c  z  z 0
x 0 x y
  c  z  xy   z  ay  bx  xy   0
 cxy  xyz  ayz  bxz  xyz  0
 ayz  bzx  cxy  2 xyz
a b c
   2
x y z
Sec:Sr.Icon All 15
PHYSICS
26.
S
C1V0 C2
Given Capacity of capacitor  C1 , C2

Potential V1  V0
C V  C2V2
We know Common potential V  1 1
C1  C2
CV  0 C1V0
Common potential, V   1 0  
 C1  C2  C1  C2
We know potential energy stored in capacitor,
1
U  CV 2
2
1
C1V02  C  C2 
Ui 2
Now   1 
U f 1 C  C V 2  C1 
 1 2
2
Therefore, the correct answer is (A)
27. Given
Amplitude  a
Wave length  
When sources are coherent, intensity at mid-point
2
I max   a1  a2 
2
 I max   a  a   4a 2
When sources are incoherent, no interference occurs.
Intensity at mid point,
I  I1  I 2  a 2  a 2  2a 2
I max 4a 2
  2  2 :1
I 2a
Therefore, the correct answer is (A).
28. X -rays are produced by Coolidge tube.
Therefore, the correct answer is (D)
29. Total Internal Energy of System = U oxygen  U argon
f1 f
 RT   2 2 RT
2 2
 f =degreeof fredom 
Sec:Sr.Icon All 16
5 3
 2 RT  4 RT
2 2
 5RT  6 RT
 11RT
As f1  5  for oxygen  and f 2  3  for Argon 
Therefore, the correct answer is (D).
k
30. We know that   ……….. (i)
m
FL  YA 
Here Y   F   l
Al  L 
Comparing the above equation with F  kl we get
 YA 
k    …….. (ii)
 L 
From equations (i) and (ii) we get
Y  4.9  107
140 
0.1  1
Y  4  109 N m 2
31.
OR
A
B G1 AND
NAND
G3
G2
Output of G1   A  B  ; Output of G2  A.B;

Output of G3   A  B . A.B , which gives XOR gate.
Output of XOR gate is A.B  A.B
Therefore, the correct answer is (B).
32. Given ,Number of moles=1 mole
Temperature  T0
From Question
P 2  T  P  c T , c is constant
dP 1 dT
  ....1
P 2 T
PV  RT .... 2 
 PdV  VdP  RdT
 PdV  RdT  VdP
Sec:Sr.Icon All 17
dP
 RdT  RT .
P
RT dT
 RdT 
2 T
 by using 1 
Rd T

2
2T0 2T0
RdT RT0
  PdV   
T0 T0
2 2
From first law of thermodynamics
3R RT
Q  U  W  nCV T   PdV  T0  0
2 2
 2RT0
33.
P
B r
R1  R2
l V
Q
Given mass= m
R1R2
Equivalent Resistance of R1 and R2 in parallel 
R1  R2
Velocity= V
e
We know current i 
r  Req
Also, e  BlV
Then ,
BlV
i
RR
r 1 2
R1  R2
Sec:Sr.Icon All 18
34.
2V
9V 7V 3V 4V 4V 0V
R1  2 R2  2 R3 3
9V 4V 2V
2V 7V 3V 2V
From Kirchhoff’s second law

77
 i1  0
2
35.
24V 2
4 3µF
x 4µF
A B
4 y 6
From diagram, in the branch AxB , the current will be 0 in the steady state. Hence the
current will flow only in the branch AyB .
The effective resistance experienced by the 24V battery can we calculated as shown
below
Effective resistance 2+4+6=12
By using ohm’s law we can get the current in the circuit, which is equal to 2A .
By using KVL, we can find the potential difference across BA , which is equal to 20V
 R1 
By using the formula V1   V ,
 R1  R2 
6
We get VB  V y  20   12V
10
 C1 
By using formula V1   V ,
 C1  C2 
We get VB  Vx  5V
From above equations Vx  V y  7 V
Sec:Sr.Icon All 19
36.
a30cm
1. O
Given Side of block a  30cm=0.3m
Velocity v  2 m s
a
Before hitting point O ,We know angular momentum L  mvr  mv
2
Also, after hitting point O, L  I 
a
2. Using conservation of angular momentum, mv  I
2
3. Moment of inertia (I) of cubical block about one edge is given by
 a2  a 2 
I  m  
 6  2  
 
a
m.2
  2
 a  a 2 
2
m    
 6  2  
12 3 10
     5rad sec
8a 2  0.3 2
37. Using y  Asin t

a  A sin t0
b  Asin 3t0
c  Asin 5t0
a  c   A sin t0  A sin 5t0 
 2 A sin 3t0 cos 2t0
 2b cos 2t0
ac
  2cos 2t0
b
ac
  cos 2t0
2b
1 ac
  cos1     2πf 
2t0  2b 
Sec:Sr.Icon All 20
1 ac
f   cos1  
4πt0  2b 
Therefore, the correct answer is (C).
38. Given point
Mass of m  1kg
Mass of stationary point m  5kg
Speed v  2 m s
By conservation of linear momentum
5kg
1kg

BeforeCollision
5kg
2m s
v
After Collision
u  5v  2... i 
v2  v1
2. As we know, the coefficient of restitution is given by e   1 for elastic
u1  u2
collision. Using this we get, u  v  2.... ii 
Using Equation (i) and (ii), we have v  1m s and u  3m s
1 2
Kinetic energy of the centre of mass  msystemvCM  0.75J
2
39. Given Peak Voltage V p  12V
The Modulation Index is 75%
Am 75 A
   m  0.75
Ac 100 Ac
 Am  0.75, Ac  0.75  12  9 V
40. Intensity at the centre of the pattern will be zero,

 
if path difference at the centre is   .
2
Now, the path difference introduced by glass plate of thickness ' t ' is    1 t
 
    1 t  or t  .
2 2    1
Sec:Sr.Icon All 21
41. Given Mass of Earth  M
Radius of Earth  R
Let the minimum speed imparted to the particle of mass m so that it just reaches surface
of earth is v .
Applying the principle of conservation of energy,
1 2  3 GM  GM
mv    m   m0
2  2 R  R
1 2 GM 3 GM
v  
2 R 2 R
GM GM
 , we get v  .
R R
42. Charge +Q will flow into earth.
 B will have Q
B
Q
A
C 
a
For a  r  b ,
kQ kQ
Vr  
r b
For r  a ,
kQ kQ
Vr  
a b
kQ kQ
2. VA  
a b
Potential at B is zero.
43. 1. Given
Wave Frequency  25MHz
Intensity of Electric Field E  6.3 ˆj V m
The magnitude of the magnetic field is given by
E 6.3
B  8
 2.1  108 T.
c 3  10  
2. The vector E  B should be along x  direction, and so
 
ˆj  Aˆ  iˆ, indicates that Â  kˆ .
Sec:Sr.Icon All 22

Thus, B  2.1  10 8 kˆ T.
44. 1. The speed of the bullet with respect to police
vBP  150 m s,
Speed of police van
vP  30 km h  8.3m s
 vBP  vB  vP
vB  vBP  vP  150m s  8.3m s   158.3m s .
5
vT  192km h  192  m s  53.3m s
18
 vBT  vB  vT  158.3  53.3 m s  105m s
45.
A
n 1
n3 2
O P x
30
B
    1
From diagram and using the formula 2  1  2
v u R
3
1 3 1
  2
V 2  30 20
1 1 1 
  
V 40 20 40
V  40cm.
46. 1. Given Mass of Body m  0.5kg

Velocity V  5 x 3 2
Work done=Change Kinetic Energy
Given Velocity
3/2
At x  0, vi  5  0   0
32
And x  2 m, v f  5  2   5 8 m s
By using work-energy theorem
Sec:Sr.Icon All 23
W  K
1
 m  v 2f  vi2 
2
1 2
  0.5  5 8  02 
 
2  
 50J
Therefore, the correct answer is 50.00
47. 
1. Given i  2sin100πt  2cos 100πt  300 

The equation can be written as i  2sin100πt  2sin 100πt  1200 
So phase difference   1200
( I m )res  A12  A22  2 A1 A2 cos 
A1  2; A2  2 .
I  1 2
I rms   4  4  2  2  2    ,
2  2 2
So effective value or rms value 2 2  2 A
48. 1. Given Electric Field E  2 V m
 0  8.854  1012 F m
Equating the average energy density of electric and magnetic field
u B  uE
1 1 2
  0 E02   8.854  10 12   2 
4 4
12
 8.85  10 J m 2
49. 1. Speed of boy v  4 2 m s
Frequency of sound pulse v0  1650 Hz
B1 or the first boy is the source of the sound and B2 is the listener. vs is the component of
the velocity of the source along the source – listener axis (SL axis). Here,
vs  4 2 cos 450  4 m s
Sec:Sr.Icon All 24
B1
S 4 2m s

45
B2
L
 ve
 v  vL 
Using Doppler’s effect formula v    v0
 v  vA 
Speed of sound in air
v  334 m s, vs  4 m s, vL  0
 334  334
v   1650Hz   1650Hz  1670Hz
 334  4  330
50. 1. When sun cools to the temperature T where it emits only 81% of its present radiating
power, then
 81  4
T 4     6000   E   T 
4
 100 
 T  0.9  6000 
 0.95  6000  5700K
2. By Wien’s displacement law, mT  constant
Hence if m is the required wavelength m  5700   0.5  6000
6000 10
m   0.5   0.53µm
5700 19
Sec:Sr.Icon All 25
CHEMISTRY
51. The energy of hydrogen atom is inversely proportional to square of principle quantum
number.
E2 n22 328 16
  
E4 n12 E4 4
 E4  82 kJ/mol
52. After the removal of an electron from C,N,O and F, their electronic configurations are:
   
C  1s 2 2 s 2 2 p1 , N  1s 2 2 s 2 2 p 2 ,
O  1s 2 2 s 2 2 p1x 2 p1y 2 p1z  and
F 1s 2 2 s 2 2 p x2 2 p1y 2 p1z  .
Since O + gives a stable electronic configuration with exactly half – filled 2 p  subshell,
therefore, IE 2 of O is higher than that of F. The IE 2 of C because of the larger size is
lower than that of N. Thus, the overall order is O  F  N  C
1
53. Bond Order in NO  10  5   2.5
2
1
Bond Order in NO+  10  4   3.0
2
1
Bond Order in NO-  10  6   2.0
2
Since, the bond energies are directly related to bond order, therefore, the correct order of
increasing bond energies is: NO+  NO  NO-
54. Step1:
Reduction half- cell reaction:
Cr2O7 2  Cr 3
Step2:
Balancing species undergoing
Cr2O72  2Cr 3
Step3:
Oxidation half- cell reaction:
P3-  PO3-
4
Adding reduction half-cell and Oxidation half-cell reactions:
Cr2O7 2-  P3-  2Cr 3  PO3-4
Step4:
Multiplying change in Oxidation half-cell number in reduction half-cell reaction to
Oxidation half reaction and vice versa
Sec:Sr.Icon All 26
Cr2O7 2-  3P3-  2Cr 3  3PO3-

4
Step5:
Balancing the Oxygen using H 2O and hydrogen using H ions
5Cr2O7 2   6Cu 3P+22H   10Cr 3  6PO3 4  18Cu 2   11H 2O
55. Structure of Hypophosphoricacid :
O O
HO  P  P  OH
OH OH
H  1,
P  x, O  2
H 2 P2O6  4  2 x 12  0
 2x  8  0
 2x  8
 xoxidation number   4
 P  P bonds = 1
56. Electron withdrawing group at Ortho and Para increases Aromatic substitution
Nucleophilic reaction.
57. Applying gibbs energy,
ΔG  ΔH  TΔS
Where, G is the change in gibbs energy
H is the change in enthalpy
S is the change in entropy
T is temperature
a) For a system, total entropy change  ΔS total
ΔH total  0
 ΔGsystem  TΔS total
ΔGsystem
  -T
ΔStotal
Thus (a) is correct
b) For isothermal reversible process, ΔE  0
By first law of thermodynamics, ΔE  q  W
Vf
 Wreversible  q    p dV
Vi
V
 Wreversible  nRT ln f
Vi
Thus, (b) is correct.
c) ΔG  ΔH   TΔS 
Sec:Sr.Icon All 27

Also, ΔG   RT ln K
ΔG 
 ln K 
RT
 ΔH   TΔS  
 ln K  from Equation 1 
RT
Thus (c) is incorrect.
d) The standard free energy ΔG  is released to equilibrium constant K as
 
ΔG    RT ln K
 ΔG 
ΔG
 ln K   K  e RT
RT
Thus, (d) is also correct.

58.
OH CH 2I
O  CH 2
HI

?
heat
Phenol Benzyl iodide
59. Buffer  A  :
x
pH1  pK a  log   ……….(i)
 y
Buffer  B  :
 y
pH 2  pK a  log   ………. (ii)
x
Since x  y
x y
 pH1  pH 2  1  log  log
y x
x
 1  2 log
y
x 1
log   0.5
y 2
x
 100.5  3.17
y
60. 1) Rosenmond’s reduction,
2) Gattermann-Koch reaction,
Sec:Sr.Icon All 28
4) 2RMgX  CdC 2  R 2Cd  2Mg  X  C
61. Applying Depression freezing point,
Tf  iK f  m
Where, Tf is the Depression freezing point
K f is
m is the molality the Cryoscopic constant
i is the Van’t Hoff factor
20 1000
 0.744  i  1.86  
100 500
5  0.744
i  1
1.80  2
1  i 11 0
α    0
n 1 2 1 1
62. The formation of ozone from oxygen is an endothermic reaction not exothermic reaction.
Electric
3O2 
 2O3 ; H  287 kJ
discharge
So, statement
Silent
 2O3;
3O2  H  284.5kJ is not correct statement.
discharge
63.
NH 2
Aniline in presence of nitrating mixture conc.HNO3  conc.H 2SO 4 

gives significance amount  47% of meta-product because in presence of H 2SO 2 its
protonation takes place and anilinium ion is formed.

NH 2 NH3 HSO4
H SO

2 4
Aniline Anilinium ion

Here, anilinium ion is strongly deactivating group and meta-directing in nature. So, it
gives meta-nitration product.
Sec:Sr.Icon All 29

NH 2 NH3 HSO4
Conc. H SO

2 4 
Conc. HNO3
NO 2
64. Dipole Moment
The Dipole Moment of methyl halides follows the order:
CH3C  CH3F  CH 3Br  CH 3I. Due to the very small size of F, fluorides have lower
dipole moments than chlorides.
65. For every 1 mole of SrC 2 dopping, one mole of cationic vacancies are formed
103 mole of SrC 2  6  1020 cationic valance
10 3 moles of SrC 2 is dopped in 100 moles of NaC
How many moles dopped in 1 mole of NaC
= 105 moles of SrC 2
66. (1) Nylon 66
(2) Dacron [Terylene]
(3) Glyptal
(4) Bakelite, Novolac
67. The group reagent NH 4C and NH 4OH will not precipitate. Due to
Ca 2+ is a 5th group cation.
68.  The oxidation state of Mn is 3 in this complex.
The outer electronic configuration of Mn  Ar 3d 4 4 s 4 p 
 When  CN 6 comes it needs 6 orbitals but the available orbitals are 5 only ( one S, 1
orbital of d as rest are filled with single electrons and 3 orbitals of
P) CN being strong ligand will make one electron of d orbital to pair with other d orbital
to pair with other d orbital hence vacating one more orbitals in d,s and p will be 6 which
will be taken by  CN 6
So hybridization is d 2 sp 3 and unpaired electrons is 2.
(  CN  is a strong ligand, electrons forced to pair against Hund’s rule )
2
 Mn  CN 6 3 d 2 sp 3 ,octahedral and  MnBr4  sp3 , tetrahedral
 
69. Van Arkel process:
Titanium metal is purified by this method. When the impure titanium metal is heated with
iodine at a temperature of 250 C, volatile titanium tetra-iodide is formed TiI4 . The
impurities are left behind, as they do not react with iodine.
Sec:Sr.Icon All 30
The titanium tetra-iodide vapour is passed over a hot tungsten filament at 1400 C. The
vapour is decomposed and pure titanium is deposited on the filament and is removed. The
iodide reused.
2500 C
Ti  2I 2 TiI 4
Ti tan ium
tetra iodide
14000 C
TiI 4 Ti  2I 2
Tungsten metal
filament
70. RNA also contains four different bases. Three of these are the same as in DNA.
adenine, guanine, and cytosine. RNAcontains uracil (U) instead of thymine.
71. Number of equivalent of H 2  Number of equivalent of C 2
5 1 VCl2
 2  2
22.4 22.4
 VC  g   5L
2
72. Given,
number of mole of He, n1  0.3mol
number of mole of Ar, n2  0.4 mol
Temperature, T2  400K
Temperature, T1  ?
3
KE  nRT
2
Where, R is the gas constant
K.E is the kinetic energy
n  1 , for molar kinetic energy
3  3 
   1 R  T     1  R  400 
2 Helium  2 Argon
T  400K
73. Applying 1st order kinetics,
2.303  a 
log10 
 a  x 
K=
t
2.303  100 
log10  ...........1
100  75 
K=
32
Sec:Sr.Icon All 31
2.303  100 
log10  ...........2
100  50 
K=
t
From the two equation 1 & 2
 t = 16 minutes
(or)
t75%  2t50%
74. 1) In C 4H10O, x  four Alcohols and three ethers
2) In C 2H 6O,  one ethanol and dimethyl ether
 X is 7 and Y is 2
75. Given,
KSP  4  1012 and solubility 104 M .
M  OH  x  M sx   xOH xs
 s  xs  x  KSP
 x x .s x 1  4  1012
x 1
 
 x x . 104  4  10 12
 x2
Sec:Sr.Icon All 32

27-12-19 - SR - Icon All - GTM-4 - SET-B - Question Paper and Solutions PDF

Încărcat de

Informații document

Titlu original

Drepturi de autor

Formate disponibile

Partajați acest document

Partajați sau inserați document

Opțiuni de partajare

Vi se pare util acest document?

Este necorespunzător acest conținut?

Drepturi de autor:

Formate disponibile

27-12-19 - SR - Icon All - GTM-4 - SET-B - Question Paper and Solutions PDF

Încărcat de

Drepturi de autor:

Formate disponibile

Sri Chaitanya IIT Acedamy 27-12-19_Sr.

Icon All_GTM-4_SET-B_Question Paper

Sec:Sr.Icon All Space For Rough Work 2

1) 222 2) 223 3) 223  23 C11 4) 2 23  211

1)  2,3 2)  2,1 3)  2,1 4)  2,3

Sec:Sr.Icon All Space For Rough Work 3

Sec:Sr.Icon All Space For Rough Work 4

cot cot 1 7  cot 1 8  cot 118  is equal to

Sec:Sr.Icon All Space For Rough Work 5

k   5  ___ ; where [.] denotes the greatest integer function

23. If PQ is a double ordinate of the hyperbola 16 x 2  25 y 2  400 be produced on both

Sec:Sr.Icon All Space For Rough Work 6

Sec:Sr.Icon All Space For Rough Work 7

Sec:Sr.Icon All Space For Rough Work 8

Sec:Sr.Icon All Space For Rough Work 9

Sec:Sr.Icon All Space For Rough Work 10

i. The potential at a distance r from C , where r  a is zero.

Sec:Sr.Icon All Space For Rough Work 12

(NUMERICAL VALUE TYPE)

Sec:Sr.Icon All Space For Rough Work 13

equal to x  1012 J m3 . Then ' x ' value is equal to ( 0  8.854  1012 F m )

wavelength  ' (in micro metre )is equal to  10  3.1622

Sec:Sr.Icon All Space For Rough Work 14

1) NO  NO  NO 2) NO  NO  NO

54. Cu 3P  Cr2O72  H1  Cu 2 +H3PO4  Cr 3 the coefficient for Cu 3P in balanced

Sec:Sr.Icon All Space For Rough Work 15

57. Find the incorrect expression among the following.

Sec:Sr.Icon All Space For Rough Work 16

Sec:Sr.Icon All Space For Rough Work 17

freezing point of the solution is 0.744 C; K f  1.86K molality 1 . The degree of

2) Ozone undergoes addition reaction with unsaturated hydrocarbons.

Sec:Sr.Icon All Space For Rough Work 18

Sec:Sr.Icon All Space For Rough Work 19

1) A3+ 2) Fe3+ 3) Cr3+ 4) Ca 2+

Find the hybridization and geometries of these complex ions.

1) sp 3d 2 , octahedral and dsp 2 ,tetrahedral

2) d 2 sp 3 , octahedral and dsp 2 , square planar

3) d 2 sp 3 , octahedral and sp 3 , tetrahedral

4) sp 3d 2 , octahedral and sp 3 , square planar

Sec:Sr.Icon All Space For Rough Work 20

75. M  OH  x has KSP  4  1012 and solubility 104 M . Hence, x is

Sec:Sr.Icon All Space For Rough Work 21

Sec:Sr.Icon All Space For Rough Work 22

Sri Chaitanya IIT Academy., India.

Time: 09.00 am to 12.00 SET-B Max.Marks:300

Key & Solutions

we get 2 S  23C0  23C1  ..... 23C23  2 23

Given ' z ' lies on the circle z  3i  3 2

10. Given mean x  6 and

18. Given that f  x   ax  b

Slope of the given line is 2.

The two parabolas intersect at  0,0  and  4,4 

Thus, the total number of ways is 2  12C2  132

Given Capacity of capacitor  C1 , C2

Output of G1   A  B  ; Output of G2  A.B;

From Kirchhoff’s second law

37. Using y  Asin t

40. Intensity at the centre of the pattern will be zero,

Therefore, the correct answer is (A).

46. 1. Given Mass of Body m  0.5kg

O  1s 2 2 s 2 2 p1x 2 p1y 2 p1z  and

F 1s 2 2 s 2 2 p x2 2 p1y 2 p1z  .

Cr2O7 2-  3P3-  2Cr 3  3PO3-