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Stereochemistry
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Example Tell whether the two structures in each pair represent enantiomers or two molecules
of the same compound in different orientations.
(R) and (S) Nomenclature of Chiral Carbon Atoms
Example Find R/S configuration of following compounds.
Racemic Mixture
We must always keep the Fischer projection formulas in the plane of the paper,
and we are not allowed to flip them over.
Biological Discrimination of Enantiomers
Enzymes in living systems are chiral, and they are capable of distinguishing
between enantiomers. Usually, only one enantiomer of a pair fits properly into the
chiral active site of an enzyme.
Biological Discrimination of Enantiomers
When a molecule has two chirality centres, and each can be R or S , four
stereoisomers are normally possible: RR , SS , RS , and SR .
Enantiomers and Diastereomers
Carbons C2 and C3 are the chirality centres and we can represent the four
stereoisomers, (2 R ,3 R ), (2 S ,3 S ), (2 R ,3 S ), and (2 S ,3 R ), by Fischer
projections.
Enantiomers and Diastereomers
Example Draw all possible stereoisomers for 2-bromo-4-chloropentane.
Example Find relationship between the given pairs.
Example Which Fischer projection represents the given wedge dash structure :
Example Which has D configuration.
Example Which is not the pair of enantiomers ?
Example How are compounds I and II related ?
Meso Compounds
is
A. –36º
B. 0º
C. +36º
D. unpredictable
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